CN102951933A - Production method of granulated calcium ammonium nitrate - Google Patents
Production method of granulated calcium ammonium nitrate Download PDFInfo
- Publication number
- CN102951933A CN102951933A CN2011102385433A CN201110238543A CN102951933A CN 102951933 A CN102951933 A CN 102951933A CN 2011102385433 A CN2011102385433 A CN 2011102385433A CN 201110238543 A CN201110238543 A CN 201110238543A CN 102951933 A CN102951933 A CN 102951933A
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- China
- Prior art keywords
- ammonium nitrate
- granulation
- production method
- calcium ammonium
- calcium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- NGLMYMJASOJOJY-UHFFFAOYSA-O azanium;calcium;nitrate Chemical compound [NH4+].[Ca].[O-][N+]([O-])=O NGLMYMJASOJOJY-UHFFFAOYSA-O 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 21
- 238000005469 granulation Methods 0.000 claims abstract description 22
- 230000003179 granulation Effects 0.000 claims abstract description 22
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000001914 filtration Methods 0.000 claims abstract description 14
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 10
- 239000007788 liquid Substances 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 9
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000006386 neutralization reaction Methods 0.000 claims abstract description 6
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 5
- 229910017604 nitric acid Inorganic materials 0.000 claims abstract description 5
- 238000004806 packaging method and process Methods 0.000 claims abstract description 5
- 229910002651 NO3 Inorganic materials 0.000 claims description 6
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 5
- 239000011575 calcium Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 2
- 238000000465 moulding Methods 0.000 claims description 2
- 239000007921 spray Substances 0.000 claims description 2
- 229910001220 stainless steel Inorganic materials 0.000 claims description 2
- 239000010935 stainless steel Substances 0.000 claims description 2
- 238000002347 injection Methods 0.000 claims 2
- 239000007924 injection Substances 0.000 claims 2
- 239000006200 vaporizer Substances 0.000 claims 1
- 239000003337 fertilizer Substances 0.000 abstract description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
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- Fertilizers (AREA)
Abstract
The invention belongs to the field of fertilizer industry, and relates to a production method of granulated calcium ammonium nitrate. The method comprises the steps that: dilute nitric acid and calcium carbonate are subjected to a neutralization reaction; a calcium nitrate solution is subjected to pres-filtration; the calcium nitrate liquid is mixed with an ammonium nitrate liquid; press-filtration, concentration, granulation, packaging, and inspecting are carried out; and the obtained granulated calcium ammonium nitrate is stored. The method provided by the invention has the advantages of novel design, unique method, low production cost, easy operation, and high practicality. The method can be popularized.
Description
Technical field
What the present invention relates to is a kind of production method of granulation calcium ammonium nitrate, belongs to fertilizer industry.
Background technology
At present, the drawback that has ammonium nitrate and calcium indissoluble in the fertilizer industry production.There is the large problem high with input of consumption and use simultaneously two kinds of fertilizer.
Summary of the invention
The invention provides a kind of production method of granulation calcium ammonium nitrate, can overcome above-mentioned drawback.
The present invention realizes by the following technical solutions; A kind of production method of granulation calcium ammonium nitrate, it comprises rare nitric acid, calcium carbonate neutralization reaction, the ca nitrate soln press filtration, nitrocalcite liquid, ammonium nitrate solution mix, and press filtration is concentrated, granulation, packing, check warehouse-in is characterized in that: the production method of granulation calcium ammonium nitrate is the rare nitric acid of 30-60% and 92% calcium carbonate to be packed into neutralization reaction generates ca nitrate soln in the stainless steel reactor; Ca nitrate soln is injected plate-and-frame filter press to carry out press filtration and generates 80% nitrocalcite liquid; 80% nitrocalcite liquid and 20-30% ammonium nitrate solution are injected agitator to be mixed; With nitrocalcite and the press filtration of ammonium nitrate mixed solution process plate-and-frame filter press; Liquid after the press filtration adds 130 ℃ after injecting vaporizer--and 150 ℃ of steam always 〉=15% are condensed into N, the calcium ammonium nitrate of Ca 〉=18%; Calcium ammonium nitrate after steam is concentrated injects granulation in the spray granulating machine; Product behind the granulating and forming flows into the packaging machine weight packaging; After moulding product passed through experience in batches, the salable product warehouse-in.
Advantage of the present invention and positively effect:
Modern design, method is unique, and production cost is low, and easy to operate.Has practicality, generalization.
Description of drawings
Legend is the process flow sheet of the production method of granulation calcium ammonium nitrate of the present invention
Embodiment
Provide specific embodiment by legend.What legend provided is the process flow sheet of the production method of granulation calcium ammonium nitrate, and it comprises neutralization reaction 1, and press filtration 2 mixes 3, and press filtration 4 concentrates 5, granulation 6, packing 7, check warehouse-in 8.
Claims (8)
1. the production method of a granulation calcium ammonium nitrate, it comprises rare nitric acid, calcium carbonate neutralization reaction, the ca nitrate soln press filtration, nitrocalcite liquid, ammonium nitrate solution mix, and press filtration is concentrated, granulation, packing, check warehouse-in is characterized in that: the production method of granulation calcium ammonium nitrate is the rare nitric acid of 30-60% and 92% calcium carbonate to be packed into neutralization reaction generates ca nitrate soln in the stainless steel reactor.
2. the production method of granulation calcium ammonium nitrate according to claim 1 is characterized in that: ca nitrate soln is injected plate-and-frame filter press carry out press filtration and generate 80% nitrocalcite liquid.
3. the production method of granulation calcium ammonium nitrate according to claim 1 is characterized in that: 80% nitrocalcite liquid and 20%-30% ammonium nitrate solution are injected agitator mix.
4. the production method of granulation calcium ammonium nitrate according to claim 1 is characterized in that: with nitrocalcite and the press filtration of ammonium nitrate mixed solution process plate-and-frame filter press.
5. the production method of granulation calcium ammonium nitrate according to claim 1 is characterized in that: add 130 ℃ of-150 ℃ of steam behind the liquid injection vaporizer after the press filtration and always 〉=15% be condensed into N, the calcium ammonium nitrate of Ca 〉=18%.
6. the production method of granulation calcium ammonium nitrate according to claim 1 is characterized in that: granulation in the calcium ammonium nitrate injection spray granulating machine after steam is concentrated.
7. the production method of granulation calcium ammonium nitrate according to claim 1 is characterized in that: the product inflow packaging machine weight packaging behind the granulating and forming.
8. the production method of granulation calcium ammonium nitrate according to claim 1 is characterized in that: with moulding product in batches through after the check, the salable product warehouse-in.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102385433A CN102951933A (en) | 2011-08-19 | 2011-08-19 | Production method of granulated calcium ammonium nitrate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102385433A CN102951933A (en) | 2011-08-19 | 2011-08-19 | Production method of granulated calcium ammonium nitrate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102951933A true CN102951933A (en) | 2013-03-06 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011102385433A Pending CN102951933A (en) | 2011-08-19 | 2011-08-19 | Production method of granulated calcium ammonium nitrate |
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| Country | Link |
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| CN (1) | CN102951933A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103936466A (en) * | 2014-04-29 | 2014-07-23 | 天脊煤化工集团股份有限公司 | Method and device for producing calcium ammonium nitrate |
| CN104086235A (en) * | 2014-07-22 | 2014-10-08 | 路永宽 | Method for producing full-water-soluble magnesium ammonium nitrate by using steel belt granulator |
| CN104725098A (en) * | 2015-03-20 | 2015-06-24 | 路永宽 | Method for producing all-water-soluble calcium ammonium magnesium nitrate by steel strip granulation |
| CN104744100A (en) * | 2015-03-20 | 2015-07-01 | 路永宽 | Method for full water-soluble calcium and magnesium ammonium nitrate by disc granulation |
| CN107266243A (en) * | 2017-06-19 | 2017-10-20 | 交城县田丰肥业有限公司 | A kind of preparation method of the silicon-calcium-magnesium fertilizer containing nitrate nitrogen |
| CN107365173A (en) * | 2017-08-16 | 2017-11-21 | 成都市心化工有限责任公司 | A kind of calcium ammonium nitrate fertilizer and its preparation method and application |
| CN107473776A (en) * | 2017-08-28 | 2017-12-15 | 成都云图控股股份有限公司 | A kind of method for eliminating iron ion and being influenceed on calcium ammonium nitrate product colour |
| CN108689748A (en) * | 2018-05-30 | 2018-10-23 | 贵州盈丰农业发展有限公司 | A kind of preparation method of high concentration nitro Water soluble fertilizer |
| RU2836971C1 (en) * | 2024-08-20 | 2025-03-24 | Акционерное общество "ЕВРАЗ Нижнетагильский металлургический комбинат" (АО "ЕВРАЗ НТМК") | Method for chemical processing of blast-furnace slag |
Citations (3)
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| CN1587210A (en) * | 2004-09-08 | 2005-03-02 | 云南解化集团有限公司 | Combined ammonium-calcium nitrate fertilizer with reduced explosive property and impring fertilizer effect and its producing process |
| WO2007084873A2 (en) * | 2006-01-13 | 2007-07-26 | Honeywell International Inc. | Stabilized compositions comprising ammonium nitrate |
| CN101348401A (en) * | 2008-09-03 | 2009-01-21 | 山西省交城红星化工有限公司 | Preparation of calcium ammonium nitrate coated fertilizer |
-
2011
- 2011-08-19 CN CN2011102385433A patent/CN102951933A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1587210A (en) * | 2004-09-08 | 2005-03-02 | 云南解化集团有限公司 | Combined ammonium-calcium nitrate fertilizer with reduced explosive property and impring fertilizer effect and its producing process |
| WO2007084873A2 (en) * | 2006-01-13 | 2007-07-26 | Honeywell International Inc. | Stabilized compositions comprising ammonium nitrate |
| CN101348401A (en) * | 2008-09-03 | 2009-01-21 | 山西省交城红星化工有限公司 | Preparation of calcium ammonium nitrate coated fertilizer |
Non-Patent Citations (1)
| Title |
|---|
| 唐文骞 等: "硝酸铵钙的生产技术", 《化肥工业》 * |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103936466A (en) * | 2014-04-29 | 2014-07-23 | 天脊煤化工集团股份有限公司 | Method and device for producing calcium ammonium nitrate |
| CN104086235A (en) * | 2014-07-22 | 2014-10-08 | 路永宽 | Method for producing full-water-soluble magnesium ammonium nitrate by using steel belt granulator |
| CN104086235B (en) * | 2014-07-22 | 2016-02-24 | 路永宽 | A kind of method utilizing steel band tablets press to produce full water-soluble ammonium nitrate magnesium |
| CN104725098A (en) * | 2015-03-20 | 2015-06-24 | 路永宽 | Method for producing all-water-soluble calcium ammonium magnesium nitrate by steel strip granulation |
| CN104744100A (en) * | 2015-03-20 | 2015-07-01 | 路永宽 | Method for full water-soluble calcium and magnesium ammonium nitrate by disc granulation |
| CN104744100B (en) * | 2015-03-20 | 2017-08-11 | 路永宽 | The method that disc granulation produces full water-soluble ammonium nitrate calcium and magnesium |
| CN107266243A (en) * | 2017-06-19 | 2017-10-20 | 交城县田丰肥业有限公司 | A kind of preparation method of the silicon-calcium-magnesium fertilizer containing nitrate nitrogen |
| CN107365173A (en) * | 2017-08-16 | 2017-11-21 | 成都市心化工有限责任公司 | A kind of calcium ammonium nitrate fertilizer and its preparation method and application |
| CN107473776A (en) * | 2017-08-28 | 2017-12-15 | 成都云图控股股份有限公司 | A kind of method for eliminating iron ion and being influenceed on calcium ammonium nitrate product colour |
| CN108689748A (en) * | 2018-05-30 | 2018-10-23 | 贵州盈丰农业发展有限公司 | A kind of preparation method of high concentration nitro Water soluble fertilizer |
| RU2836971C1 (en) * | 2024-08-20 | 2025-03-24 | Акционерное общество "ЕВРАЗ Нижнетагильский металлургический комбинат" (АО "ЕВРАЗ НТМК") | Method for chemical processing of blast-furnace slag |
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Application publication date: 20130306 |