Summary of the invention
Based on the defect of prior art, the object of the invention is to propose one and wear-resistant paint is subdivided into according to function: precoated layer, protective layer and upper layer three layers, and the Scour-resistant anticorrosive paint be combined.Find that this coating effectively can avoid coating shedding after tested, in slurry, solids is drawn, is hit, and effectively reduces the resistance in slurry transportation, improves conveying efficiency.Its principle be by improve coating tap density with strengthens resistance to abrasion and improve bonding force, enhancing tear strength.Adopt the scientific matching of differing materials, the coating of difference in functionality combines the treatment effect of solidification its performance rear far above existing single abrasion resistant anticorrosive paint.
A kind of Scour-resistant anticorrosive paint, is characterized in that this Scour-resistant anticorrosive paint comprises:
Brushing substrate surface is for strengthening the precoated layer of substrate surface and protective layer bonding force;
Be aggregated on precoated layer for resistance to wearing, corroding and resistant to elevated temperatures protective layer;
Be painted on protective layer for improving the extexine of protective layer surface flatness;
Described precoated layer is mixed by A, B two groups according to 10:1 mass ratio, stirs evenly and make; Wherein
A group: epoxy resin 300 ~ 345 parts, titanium dioxide 90 ~ 120 parts, talcum powder 80 ~ 115 parts, aluminium sesquioxide 210 ~ 260 parts, dimethylbenzene 15 ~ 45 parts;
B group: TriMethylolPropane(TMP) 10 ~ 15 parts, tolylene diisocyanate 30 ~ 45 parts.
Described protective layer is mixed by C, D two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
C group: epoxy resin 80 ~ 100 parts, aluminium sesquioxide 550 ~ 660 parts, 50 parts, silicon carbide, wolfram varbide 100 ~ 150 parts, dimethylbenzene 8 ~ 10 parts, titanium dioxide 20 parts;
D group: TriMethylolPropane(TMP) 10 ~ 15 parts, tolylene diisocyanate 30 ~ 45 parts, reactive thinner 1 ~ 2 part, wolfram varbide 50 parts, aluminium sesquioxide 70 ~ 90 parts.
Described extexine is mixed by E, F two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
E group: epoxy resin 300 ~ 345 parts, titanium dioxide 90 ~ 120 parts, talcum powder 80 ~ 115 parts, aluminium sesquioxide 210 ~ 260 parts, dimethylbenzene 15 ~ 45 parts;
F group: TriMethylolPropane(TMP) 10 ~ 15 parts, tolylene diisocyanate 30 ~ 45 parts.
Precoated layer for main component, coordinates epoxy resin with titanium dioxide, talcum powder.Epoxy resin can with polytype solidifying agent generation crosslinking reaction and formed and insoluble, molten not there is the cancellated superpolymer of three-dimensional.Titanium dioxide, talcum powder, the Wuli-Shili-Renli system approach that such that precoated layer has reinforcement, fusing point is high, opacifying power good, soft, adsorptive power is strong etc. excellent.This characteristic can guarantee the bonding force of precoated layer and substrate surface.
Protective layer is main component with aluminium sesquioxide, has the characteristics such as high temperature resistant, resistance to grinding, silicon carbide, such that coatings chemistry performance is more stable, thermal expansivity reduces, wear resisting property improves.Protective layer as the main stor(e)y of Scour-resistant anticorrosive paint, thickness general control at 3 ~ 8cm, with aluminium sesquioxide, silicon carbide, wolfram varbide for aggregate is equipped with epoxy resin can this thickness of heap smoothly, and very firm.
Extexine and precoated layer similar, but special emphasis various frictional force in minimizing slurry transportation.
In described A group, aluminium sesquioxide particle diameter is 1 ~ 5um;
In described C group, aluminium sesquioxide is 8 ~ 24 orders, and silicon carbide is 80 ~ 120 orders, and wolfram varbide is 200 ~ 240 orders;
In described D group, wolfram varbide is 200 ~ 240 orders, and aluminium sesquioxide is 80 ~ 130 orders;
In described E group, aluminium sesquioxide particle diameter is 1um.
In precoated layer A group, aluminium sesquioxide particle diameter is that the particle diameter of 1 ~ 5um, 1 ~ 5um is very little, effectively can improve the tap density of precoated layer, strengthens the bonding force on precoated layer and base material top layer.
Employing particle diameter in protective layer C group, D group is comparatively large, but different aluminium sesquioxide, silicon carbide, wolfram varbide are aggregate, guarantees there are enough denseness on the one hand, be convenient to generate thicker protective layer, simultaneously by the combination between different-grain diameter, reduce space, strengthen bonding force.High temperature resistant, the resistance to abrasive characteristic of effective raising protective layer.
In extexine E group, aluminium sesquioxide particle diameter is 1um, adopt the aggregate of aluminium sesquioxide as upper layer of minimum grain size, what can make extexine reaches minimal level in conjunction with gap, brushing is on protective layer, effectively can must fill up space that protective layer particle diameter causes more greatly, depression, form the most smooth surface.
8 ~ 24 order aluminium sesquioxides in described C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 33:2 mass ratio with the zirconium oxide bead of particle diameter 6mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
80 ~ 120 order silicon carbide in described C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:4 mass ratio with the zirconium oxide bead of particle diameter 4mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
200 ~ 240 order wolfram varbides in described C, D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:6 mass ratio with the zirconium oxide bead of particle diameter 0.2mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
80 ~ 130 order aluminium sesquioxides in described D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:2 mass ratio with the zirconium oxide bead of particle diameter 1mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out.
Because aluminium sesquioxide, silicon carbide, wolfram varbide belong to together, quality is hard, the solid particulate of stable performance, although particle diameter is less, out-of-shape, in order to its corner angle of polishing, realizes better bonding properties, therefore carry out pre-treatment in the manner described above.Our experiments show that, pretreated aluminium sesquioxide, silicon carbide, tungsten carbide particle, more close to spherical, are conducive to proportioning and the combination of coating.
Described epoxy resin is epoxy resin E-44 or E-51 or E-54 type.
The invention has the beneficial effects as follows:
Common abrasion resistant anticorrosive paint does not establish precoated layer and extexine, directly by piling on substrate surface, be similar to and directly the protective layer in the present invention be stacked into substrate surface.Owing to needing to guarantee that coating needs certain denseness, hardness; to generate thicker protective layer; so just bring Railway Project: first; if internal particle thing particle diameter is too small; then mixture is similar to liquid; cannot pile up the protective layer to have wear-and corrosion-resistant effect, and the general thickness of slurry transportation equipment protective layer must at more than 3cm at all.Second, internal particle thing is comparatively large, then occur with base material top layer in conjunction with hypodynamic problem, because coating and base material top layer do not belong to allied substances, bonding force one is directly subordinate to an industry difficult problem, when internal particle thing just appears in the problem that in use procedure, big area comes off comparatively greatly.3rd, individual layer cannot solve substrate surface and the excessive problem of slurry contact partial frictional power.The partial frictional power of substrate surface and slurry contact is excessive, and transmission efficiency can be caused low, and machine utilization is large, and easily because aforesaid frictional force and machine utilization problem cause sag of protecting coating further, this point, slurry transport pipeline shows particularly evident.
The present invention, by by traditional abrasion resistant anticorrosive paint, according to the specific requirement in real production work, is broken down into three layers: precoated layer, protective layer, extexine.Wherein precoated layer main purpose is the bonding force strengthening coating and substrate surface, by increasing the composition of epoxy resin, reduces wherein non-solubility solid, and the particle diameter of the aluminium sesquioxide in concrete finger A group reaches the object strengthening bonding force.The combination of the known material of the same type of industry in conjunction with much easier than foreign peoples material, will exceed far away directly on base material top layer, apply protective layer so increase protective layer bonding properties of the same type on precoated layer.Protective layer as main layer of the present invention, its thickness more than precoated layer and extexine thick, effectively realize resistance to erosion rot-resistant object.On protective layer, brushing one deck has very thin, but extremely hard smooth extexine again, and main purpose reduces various frictional force in slurry transportation.
Embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is elaborated.
Embodiment 1
A kind of Scour-resistant anticorrosive paint, comprising:
Brushing substrate surface is for strengthening the precoated layer of substrate surface and protective layer bonding force;
Be aggregated on precoated layer for resistance to wearing, corroding and resistant to elevated temperatures protective layer;
Be painted on protective layer for improving the extexine of the slickness on protective layer surface;
Precoated layer is mixed by A, B two groups according to 10:1 mass ratio, stirs evenly and make; Wherein
A group: epoxy resin 300 parts, titanium dioxide 90 parts, talcum powder 80 parts, aluminium sesquioxide 210 parts, dimethylbenzene 15 parts;
B group: TriMethylolPropane(TMP) 10 parts, tolylene diisocyanate 30 parts;
Protective layer is mixed by C, D two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
C group: epoxy resin 80 parts, aluminium sesquioxide 550 parts, 50 parts, silicon carbide, wolfram varbide 100 parts, dimethylbenzene 8 parts, titanium dioxide 20 parts;
D group: TriMethylolPropane(TMP) 10 parts, tolylene diisocyanate 30 parts, reactive thinner 1 part, wolfram varbide 50 parts, aluminium sesquioxide 70 parts;
Described extexine is mixed by E, F two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
E group: epoxy resin 300 parts, titanium dioxide 90 parts, talcum powder 80 parts, aluminium sesquioxide 210 parts, dimethylbenzene 15 parts;
F group: TriMethylolPropane(TMP) 10 parts, tolylene diisocyanate 30 parts.
Wherein in A group, aluminium sesquioxide particle diameter is 1um; In C group, aluminium sesquioxide is 8 orders, and silicon carbide is 80 orders, and wolfram varbide is 20 orders; In D group, wolfram varbide is 200 orders, and aluminium sesquioxide is 80 orders; In E group, aluminium sesquioxide particle diameter is 1um.
8 order aluminium sesquioxides wherein in C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 33:2 mass ratio with the zirconium oxide bead of particle diameter 6mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
80 order silicon carbide in C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:4 mass ratio with the zirconium oxide bead of particle diameter 4mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
200 order wolfram varbides in C, D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:6 mass ratio with the zirconium oxide bead of particle diameter 0.2mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
80 order aluminium sesquioxides in D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:2 mass ratio with the zirconium oxide bead of particle diameter 1mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out.
Its epoxy resin is epoxy resin is E-44 type.
Embodiment 2
A kind of Scour-resistant anticorrosive paint, comprising:
Brushing substrate surface is for strengthening the precoated layer of substrate surface and protective layer bonding force;
Be aggregated on precoated layer for resistance to wearing, corroding and resistant to elevated temperatures protective layer;
Be painted on protective layer for improving the extexine of the slickness on protective layer surface;
Described precoated layer is mixed by A, B two groups according to 10:1 mass ratio, stirs evenly and make; Wherein
A group: epoxy resin 345 parts, titanium dioxide 120 parts, talcum powder 115 parts, aluminium sesquioxide 260 parts, dimethylbenzene 45 parts;
B group: TriMethylolPropane(TMP) 15 parts, tolylene diisocyanate 45 parts;
Described protective layer is mixed by C, D two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
C group: epoxy resin 100 parts, aluminium sesquioxide 660 parts, 50 parts, silicon carbide, wolfram varbide 150 parts, dimethylbenzene 10 parts, titanium dioxide 20 parts;
D group: TriMethylolPropane(TMP) 15 parts, tolylene diisocyanate 45 parts, reactive thinner 2 parts, wolfram varbide 50 parts, aluminium sesquioxide 90 parts;
Described extexine is mixed by E, F two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
E group: epoxy resin 345 parts, titanium dioxide 120 parts, talcum powder 115 parts, aluminium sesquioxide 260 parts, dimethylbenzene 45 parts;
F group: TriMethylolPropane(TMP) 15 parts, tolylene diisocyanate 45 parts.
Wherein in A group, aluminium sesquioxide particle diameter is 5um;
In C group, aluminium sesquioxide is 24 orders, and silicon carbide is 120 orders, and wolfram varbide is 240 orders;
In D group, wolfram varbide is 240 orders, and aluminium sesquioxide is 130 orders;
In E group, aluminium sesquioxide particle diameter is 1um.
24 order aluminium sesquioxides wherein in C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 33:2 mass ratio with the zirconium oxide bead of particle diameter 6mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
120 order silicon carbide in C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:4 mass ratio with the zirconium oxide bead of particle diameter 4mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
240 order wolfram varbides in C, D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:6 mass ratio with the zirconium oxide bead of particle diameter 0.2mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
130 order aluminium sesquioxides in D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:2 mass ratio with the zirconium oxide bead of particle diameter 1mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out.
Its epoxy resin is epoxy resin E-51 type.
Embodiment 3
A kind of Scour-resistant anticorrosive paint, comprising:
Brushing substrate surface is for strengthening the precoated layer of substrate surface and protective layer bonding force;
Be aggregated on precoated layer for resistance to wearing, corroding and resistant to elevated temperatures protective layer;
Be painted on protective layer for improving the extexine of the slickness on protective layer surface;
Described precoated layer is mixed by A, B two groups according to 10:1 mass ratio, stirs evenly and make; Wherein
A group: epoxy resin 322 parts, titanium dioxide 105 parts, talcum powder 97 parts, aluminium sesquioxide 235 parts, dimethylbenzene 30 parts;
B group: TriMethylolPropane(TMP) 12 parts, tolylene diisocyanate 37 parts;
Described protective layer is mixed by C, D two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
C group: epoxy resin 90 parts, aluminium sesquioxide 605 parts, 50 parts, silicon carbide, wolfram varbide 125 parts, dimethylbenzene 9 parts, titanium dioxide 20 parts;
D group: TriMethylolPropane(TMP) 12 parts, tolylene diisocyanate 37 parts, reactive thinner 1 part, wolfram varbide 50 parts, aluminium sesquioxide 80 parts;
Described extexine is mixed by E, F two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
E group: epoxy resin 322 parts, titanium dioxide 105 parts, talcum powder 97 parts, aluminium sesquioxide 235 parts, dimethylbenzene 30 parts;
F group: TriMethylolPropane(TMP) 12 parts, tolylene diisocyanate 37 parts.
Wherein in A group, aluminium sesquioxide particle diameter is 3um;
In C group, aluminium sesquioxide is 16 orders, and silicon carbide is 100 orders, and wolfram varbide is 220 orders;
In D group, wolfram varbide is 220 orders, and aluminium sesquioxide is 105 orders;
In E group, aluminium sesquioxide particle diameter is 1um.
16 order aluminium sesquioxides wherein in C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 33:2 mass ratio with the zirconium oxide bead of particle diameter 6mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
100 order silicon carbide in C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:4 mass ratio with the zirconium oxide bead of particle diameter 4mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
220 order wolfram varbides in C, D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:6 mass ratio with the zirconium oxide bead of particle diameter 0.2mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
105 order aluminium sesquioxides in D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:2 mass ratio with the zirconium oxide bead of particle diameter 1mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out.
Its epoxy resin is epoxy resin E-54 type.
The loss of this formula is minimum, and ball mill, in the process to aggregate shaping, can produce waste material, and general loss is about 10% ~ 15%.Adopt this formula, loss value is minimum, is 8%.
Embodiment 4
A kind of Scour-resistant anticorrosive paint, comprising:
Brushing substrate surface is for strengthening the precoated layer of substrate surface and protective layer bonding force;
Be aggregated on precoated layer for resistance to wearing, corroding and resistant to elevated temperatures protective layer;
Be painted on protective layer for improving the extexine of the slickness on protective layer surface;
Described precoated layer is mixed by A, B two groups according to 10:1 mass ratio, stirs evenly and make; Wherein
A group: epoxy resin 303 parts, titanium dioxide 92 parts, talcum powder 82 parts, aluminium sesquioxide 213 parts, dimethylbenzene 16 parts;
B group: TriMethylolPropane(TMP) 11 parts, tolylene diisocyanate 32 parts;
Described protective layer is mixed by C, D two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
C group: epoxy resin 82 parts, aluminium sesquioxide 560 parts, 50 parts, silicon carbide, wolfram varbide 110 parts, dimethylbenzene 8 parts, titanium dioxide 20 parts;
D group: TriMethylolPropane(TMP) 11 parts, tolylene diisocyanate 32 parts, reactive thinner 1 part, wolfram varbide 50 parts, aluminium sesquioxide 73 parts;
Described extexine is mixed by E, F two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
E group: epoxy resin 303 parts, titanium dioxide 92 parts, talcum powder 82 parts, aluminium sesquioxide 213 parts, dimethylbenzene 16 parts;
F group: TriMethylolPropane(TMP) 11 parts, tolylene diisocyanate 32 parts.
Wherein in A group, aluminium sesquioxide particle diameter is 2um;
In C group, aluminium sesquioxide is 10 orders, and silicon carbide is 85 orders, and wolfram varbide is 210 orders;
In D group, wolfram varbide is 210 orders, and aluminium sesquioxide is 85 orders;
In E group, aluminium sesquioxide particle diameter is 1um.
10 order aluminium sesquioxides wherein in C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 33:2 mass ratio with the zirconium oxide bead of particle diameter 6mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
85 order silicon carbide in C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:4 mass ratio with the zirconium oxide bead of particle diameter 4mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
210 order wolfram varbides in C, D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:6 mass ratio with the zirconium oxide bead of particle diameter 0.2mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
85 order aluminium sesquioxides in D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:2 mass ratio with the zirconium oxide bead of particle diameter 1mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out.
Its epoxy resin is epoxy resin E-44 type.
Embodiment 5
A kind of Scour-resistant anticorrosive paint, comprising:
Brushing substrate surface is for strengthening the precoated layer of substrate surface and protective layer bonding force;
Be aggregated on precoated layer for resistance to wearing, corroding and resistant to elevated temperatures protective layer;
Be painted on protective layer for improving the extexine of the slickness on protective layer surface;
Described precoated layer is mixed by A, B two groups according to 10:1 mass ratio, stirs evenly and make; Wherein
A group: epoxy resin 307 parts, titanium dioxide 95 parts, talcum powder 85 parts, aluminium sesquioxide 218 parts, dimethylbenzene 19 parts;
B group: TriMethylolPropane(TMP) 13 parts, tolylene diisocyanate 35 parts;
Described protective layer is mixed by C, D two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
C group: epoxy resin 85 parts, aluminium sesquioxide 570 parts, 50 parts, silicon carbide, wolfram varbide 120 parts, dimethylbenzene 9 parts, titanium dioxide 20 parts;
D group: TriMethylolPropane(TMP) 12 parts, tolylene diisocyanate 35 parts, reactive thinner 1 part, wolfram varbide 50 parts, aluminium sesquioxide 75 parts;
Described extexine is mixed by E, F two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
E group: epoxy resin 310 parts, titanium dioxide 95 parts, talcum powder 98 parts, aluminium sesquioxide 220 parts, dimethylbenzene 20 parts;
F group: TriMethylolPropane(TMP) 13 parts, tolylene diisocyanate 35 parts.
Wherein in A group, aluminium sesquioxide particle diameter is 2um;
In C group, aluminium sesquioxide is 12 orders, and silicon carbide is 90 orders, and wolfram varbide is 215 orders;
In D group, wolfram varbide is 215 orders, and aluminium sesquioxide is 90 orders;
In E group, aluminium sesquioxide particle diameter is 1um.
12 order aluminium sesquioxides wherein in C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 33:2 mass ratio with the zirconium oxide bead of particle diameter 6mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
90 order silicon carbide in C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:4 mass ratio with the zirconium oxide bead of particle diameter 4mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
215 order wolfram varbides in C, D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:6 mass ratio with the zirconium oxide bead of particle diameter 0.2mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
90 order aluminium sesquioxides in D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:2 mass ratio with the zirconium oxide bead of particle diameter 1mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out.
Its epoxy resin is epoxy resin E-51 type.
Embodiment 6
A kind of Scour-resistant anticorrosive paint, comprising:
Brushing substrate surface is for strengthening the precoated layer of substrate surface and protective layer bonding force;
Be aggregated on precoated layer for resistance to wearing, corroding and resistant to elevated temperatures protective layer;
Be painted on protective layer for improving the extexine of the slickness on protective layer surface;
Described precoated layer is mixed by A, B two groups according to 10:1 mass ratio, stirs evenly and make; Wherein
A group: epoxy resin 312 parts, titanium dioxide 98 parts, talcum powder 87 parts, aluminium sesquioxide 220 parts, dimethylbenzene 22 parts;
B group: TriMethylolPropane(TMP) 13 parts, tolylene diisocyanate 38 parts;
Described protective layer is mixed by C, D two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
C group: epoxy resin 88 parts, aluminium sesquioxide 585 parts, 50 parts, silicon carbide, wolfram varbide 125 parts, dimethylbenzene 9 parts, titanium dioxide 20 parts;
D group: TriMethylolPropane(TMP) 13 parts, tolylene diisocyanate 38 parts, reactive thinner 1 part, wolfram varbide 50 parts, aluminium sesquioxide 78 parts;
Described extexine is mixed by E, F two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
E group: epoxy resin 310 parts, titanium dioxide 98 parts, talcum powder 88 parts, aluminium sesquioxide 225 parts, dimethylbenzene 21 parts;
F group: TriMethylolPropane(TMP) 12 parts, tolylene diisocyanate 40 parts;
Wherein in A group, aluminium sesquioxide particle diameter is 3um;
In C group, aluminium sesquioxide is 14 orders, and silicon carbide is 95 orders, and wolfram varbide is 220 orders;
In D group, wolfram varbide is 220 orders, and aluminium sesquioxide is 95 orders;
In E group, aluminium sesquioxide particle diameter is 1um.
14 order aluminium sesquioxides wherein in C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 33:2 mass ratio with the zirconium oxide bead of particle diameter 6mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
95 order silicon carbide in C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:4 mass ratio with the zirconium oxide bead of particle diameter 4mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
220 order wolfram varbides in C, D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:6 mass ratio with the zirconium oxide bead of particle diameter 0.2mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
95 order aluminium sesquioxides in D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:2 mass ratio with the zirconium oxide bead of particle diameter 1mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out.
Its epoxy resin is epoxy resin E-54 type.
Embodiment 7
A kind of Scour-resistant anticorrosive paint, comprising:
Brushing substrate surface is for strengthening the precoated layer of substrate surface and protective layer bonding force;
Be aggregated on precoated layer for resistance to wearing, corroding and resistant to elevated temperatures protective layer;
Be painted on protective layer for improving the extexine of the slickness on protective layer surface;
Described precoated layer is mixed by A, B two groups according to 10:1 mass ratio, stirs evenly and make; Wherein
A group: epoxy resin 318 parts, titanium dioxide 102 parts, talcum powder 93 parts, aluminium sesquioxide 230 parts, dimethylbenzene 25 parts;
B group: TriMethylolPropane(TMP) 13 parts, tolylene diisocyanate 40 parts;
Described protective layer is mixed by C, D two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
C group: epoxy resin 95 parts, aluminium sesquioxide 600 parts, 50 parts, silicon carbide, wolfram varbide 135 parts, dimethylbenzene 9 parts, titanium dioxide 20 parts;
D group: TriMethylolPropane(TMP) 13 parts, tolylene diisocyanate 38 parts, reactive thinner 2 parts, wolfram varbide 50 parts, aluminium sesquioxide 80 parts;
Described extexine is mixed by E, F two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
E group: epoxy resin 320 parts, titanium dioxide 105 parts, talcum powder 92 parts, aluminium sesquioxide 235 parts, dimethylbenzene 25 parts;
F group: TriMethylolPropane(TMP) 13 parts, tolylene diisocyanate 40 parts;
Wherein in A group, aluminium sesquioxide particle diameter is 3um;
In C group, aluminium sesquioxide is 16 orders, and silicon carbide is 105 orders, and wolfram varbide is 235 orders;
In D group, wolfram varbide is 235 orders, and aluminium sesquioxide is 100 orders;
In E group, aluminium sesquioxide particle diameter is 1um.
16 order aluminium sesquioxides wherein in C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 33:2 mass ratio with the zirconium oxide bead of particle diameter 6mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
105 order silicon carbide in C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:4 mass ratio with the zirconium oxide bead of particle diameter 4mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
235 order wolfram varbides in C, D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:6 mass ratio with the zirconium oxide bead of particle diameter 0.2mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
100 order aluminium sesquioxides in D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:2 mass ratio with the zirconium oxide bead of particle diameter 1mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out.
Its epoxy resin is epoxy resin E-54 type.
Embodiment 8
A kind of Scour-resistant anticorrosive paint, comprising:
Brushing substrate surface is for strengthening the precoated layer of substrate surface and protective layer bonding force;
Be aggregated on precoated layer for resistance to wearing, corroding and resistant to elevated temperatures protective layer;
Be painted on protective layer for improving the extexine of the slickness on protective layer surface;
Described precoated layer is mixed by A, B two groups according to 10:1 mass ratio, stirs evenly and make; Wherein
A group: epoxy resin 320 parts, titanium dioxide 105 parts, talcum powder 100 parts, aluminium sesquioxide 240 parts, dimethylbenzene 35 parts;
B group: TriMethylolPropane(TMP) 14 parts, tolylene diisocyanate 40 parts;
Described protective layer is mixed by C, D two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
C group: epoxy resin 95 parts, aluminium sesquioxide 620 parts, 50 parts, silicon carbide, wolfram varbide 140 parts, dimethylbenzene 9 parts, titanium dioxide 20 parts;
D group: TriMethylolPropane(TMP) 14 parts, tolylene diisocyanate 40 parts, reactive thinner 2 parts, wolfram varbide 50 parts, aluminium sesquioxide 83 parts;
Described extexine is mixed by E, F two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
E group: epoxy resin 320 parts, titanium dioxide 105 parts, talcum powder 105 parts, aluminium sesquioxide 245 parts, dimethylbenzene 30 parts;
F group: TriMethylolPropane(TMP) 14 parts, tolylene diisocyanate 40 parts;
Wherein in A group, aluminium sesquioxide particle diameter is 4um;
In C group, aluminium sesquioxide is 18 orders, and silicon carbide is 115 orders, and wolfram varbide is 235 orders;
In D group, wolfram varbide is 235 orders, and aluminium sesquioxide is 110 orders;
In E group, aluminium sesquioxide particle diameter is 1um.
18 order aluminium sesquioxides wherein in C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 33:2 mass ratio with the zirconium oxide bead of particle diameter 6mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
115 order silicon carbide in C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:4 mass ratio with the zirconium oxide bead of particle diameter 4mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
235 order wolfram varbides in C, D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:6 mass ratio with the zirconium oxide bead of particle diameter 0.2mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
110 order aluminium sesquioxides in D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:2 mass ratio with the zirconium oxide bead of particle diameter 1mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out.
Its epoxy resin is epoxy resin E-44 type.
Embodiment 9
A kind of Scour-resistant anticorrosive paint, comprising:
Brushing substrate surface is for strengthening the precoated layer of substrate surface and protective layer bonding force;
Be aggregated on precoated layer for resistance to wearing, corroding and resistant to elevated temperatures protective layer;
Be painted on protective layer for improving the extexine of the slickness on protective layer surface;
Described precoated layer is mixed by A, B two groups according to 10:1 mass ratio, stirs evenly and make; Wherein
A group: epoxy resin 330 parts, titanium dioxide 105 parts, talcum powder 103 parts, aluminium sesquioxide 250 parts, dimethylbenzene 45 parts;
B group: TriMethylolPropane(TMP) 15 parts, tolylene diisocyanate 45 parts;
Described protective layer is mixed by C, D two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
C group: epoxy resin 100 parts, aluminium sesquioxide 630 parts, 50 parts, silicon carbide, wolfram varbide 140 parts, dimethylbenzene 10 parts, titanium dioxide 20 parts;
D group: TriMethylolPropane(TMP) 15 parts, tolylene diisocyanate 45 parts, reactive thinner 2 parts, wolfram varbide 50 parts, aluminium sesquioxide 85 parts;
Described extexine is mixed by E, F two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
E group: epoxy resin 340 parts, titanium dioxide 120 parts, talcum powder 110 parts, aluminium sesquioxide 255 parts, dimethylbenzene 40 parts;
F group: TriMethylolPropane(TMP) 15 parts, tolylene diisocyanate 45 parts;
Wherein in A group, aluminium sesquioxide particle diameter is 5um;
In C group, aluminium sesquioxide is 22 orders, and silicon carbide is 120 orders, and wolfram varbide is 235 orders;
In D group, wolfram varbide is 235 orders, and aluminium sesquioxide is 125 orders;
In E group, aluminium sesquioxide particle diameter is 1um.
22 order aluminium sesquioxides wherein in C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 33:2 mass ratio with the zirconium oxide bead of particle diameter 6mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
120 order silicon carbide in C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:4 mass ratio with the zirconium oxide bead of particle diameter 4mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
235 order wolfram varbides in C, D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:6 mass ratio with the zirconium oxide bead of particle diameter 0.2mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
125 order aluminium sesquioxides in D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:2 mass ratio with the zirconium oxide bead of particle diameter 1mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out.
Its epoxy resin is epoxy resin E-54 type.
Embodiment 10
A kind of Scour-resistant anticorrosive paint, comprising:
Brushing substrate surface is for strengthening the precoated layer of substrate surface and protective layer bonding force;
Be aggregated on precoated layer for resistance to wearing, corroding and resistant to elevated temperatures protective layer;
Be painted on protective layer for improving the extexine of the slickness on protective layer surface;
Described precoated layer is mixed by A, B two groups according to 10:1 mass ratio, stirs evenly and make; Wherein
A group: epoxy resin 345 parts, titanium dioxide 120 parts, talcum powder 115 parts, aluminium sesquioxide 260 parts, dimethylbenzene 45 parts;
B group: TriMethylolPropane(TMP) 15 parts, tolylene diisocyanate 45 parts;
Described protective layer is mixed by C, D two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
C group: epoxy resin 90 parts, aluminium sesquioxide 600 parts, 50 parts, silicon carbide, wolfram varbide 130 parts, dimethylbenzene 9 parts, titanium dioxide 20 parts;
D group: TriMethylolPropane(TMP) 13 parts, tolylene diisocyanate 40 parts, reactive thinner 2 parts, wolfram varbide 50 parts, aluminium sesquioxide 80 parts;
Described extexine is mixed by E, F two groups according to 4:1 mass ratio, stirs evenly and make; Wherein
E group: epoxy resin 300 parts, titanium dioxide 90 parts, talcum powder 80 parts, aluminium sesquioxide 210 parts, dimethylbenzene 15 parts;
F group: TriMethylolPropane(TMP) 10 parts, tolylene diisocyanate 30 parts;
Wherein in A group, aluminium sesquioxide particle diameter is 5um;
In C group, aluminium sesquioxide is 20 orders, and silicon carbide is 100 orders, and wolfram varbide is 200 orders;
In D group, wolfram varbide is 200 orders, and aluminium sesquioxide is 80 orders;
In E group, aluminium sesquioxide particle diameter is 1um.
20 order aluminium sesquioxides wherein in C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 33:2 mass ratio with the zirconium oxide bead of particle diameter 6mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
100 order silicon carbide in C group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:4 mass ratio with the zirconium oxide bead of particle diameter 4mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
200 order wolfram varbides in C, D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:6 mass ratio with the zirconium oxide bead of particle diameter 0.2mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out;
80 order aluminium sesquioxides in D group, through pre-treatment, put into ball mill shaping 1 ~ 2 hour after it being mixed with 1:2 mass ratio with the zirconium oxide bead of particle diameter 1mm, and shaping uses 10% chlorohydric acid pickling, organics removal and impurity after taking out.
Its epoxy resin is epoxy resin E-54 type.
Below the preferred embodiment of invention is illustrated, but the present invention is not limited to described embodiment, those of ordinary skill in the art also can make all equivalent modification or replacement under the prerequisite without prejudice to the invention spirit, and these equivalent modification or replacement are all included in the application's claim limited range.