CN102925676B - Novel energy-saving technology for producing pellets with fine-grained iron ore concentrates - Google Patents
Novel energy-saving technology for producing pellets with fine-grained iron ore concentrates Download PDFInfo
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- CN102925676B CN102925676B CN 201210461696 CN201210461696A CN102925676B CN 102925676 B CN102925676 B CN 102925676B CN 201210461696 CN201210461696 CN 201210461696 CN 201210461696 A CN201210461696 A CN 201210461696A CN 102925676 B CN102925676 B CN 102925676B
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 title claims abstract description 56
- 239000012141 concentrate Substances 0.000 title claims abstract description 35
- 239000008188 pellet Substances 0.000 title claims abstract description 29
- 229910052742 iron Inorganic materials 0.000 title claims abstract description 28
- 238000005516 engineering process Methods 0.000 title description 3
- 238000005453 pelletization Methods 0.000 claims abstract description 35
- 238000000034 method Methods 0.000 claims abstract description 26
- 239000000919 ceramic Substances 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 239000002562 thickening agent Substances 0.000 claims abstract description 5
- 238000001816 cooling Methods 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 30
- 239000002245 particle Substances 0.000 claims description 16
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 2
- 229940095674 pellet product Drugs 0.000 claims description 2
- 238000012545 processing Methods 0.000 claims description 2
- 238000005303 weighing Methods 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 2
- 238000007664 blowing Methods 0.000 claims 1
- 230000006835 compression Effects 0.000 claims 1
- 238000007906 compression Methods 0.000 claims 1
- 230000002950 deficient Effects 0.000 claims 1
- 238000007599 discharging Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 22
- 238000012216 screening Methods 0.000 abstract description 7
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 4
- 239000011707 mineral Substances 0.000 abstract description 4
- 239000002002 slurry Substances 0.000 abstract description 3
- 239000013590 bulk material Substances 0.000 description 8
- 229910000278 bentonite Inorganic materials 0.000 description 4
- 239000000440 bentonite Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000843 powder Substances 0.000 description 3
- 239000003245 coal Substances 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910000805 Pig iron Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
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Abstract
本发明一种细粒铁精矿生产球团矿节能工艺。其特征在于包括下列步骤:将铁精矿矿浆给入精矿浓密机进行浓缩→陶瓷过滤机→配料作业→强力混合机进行混合作业→圆盘造球机进行造球作业后,经过造球后的生球给入小辊筛进行筛分,经过小辊筛处理后粒度不合格的生球返回造球工序重新参与造球,粒度合格的生球给入大辊筛进行二次筛分,大辊筛筛下产品重新返回造球工序,大辊筛筛上产品给入链箅机,给入链箅机后的合格生球经过链箅机干燥、预热后给入回转窑进行焙烧、冷却后成为合格球团矿产品。其优点是:在保证球团矿产品质量的前提下,通过优化生产工艺,完善生产流程,实现了节能减排。
The invention discloses an energy-saving process for producing pellets from fine-grained iron concentrate. It is characterized in that it includes the following steps: feed the iron ore concentrate slurry into the concentrate thickener for concentration → ceramic filter → batching operation → strong mixer for mixing operation → disc pelletizing machine for pelletizing operation, after pelletizing The raw balls are sent to the small roller sieve for screening, after the treatment of the small roller sieve, the unqualified raw balls return to the pelletizing process to participate in the pelletizing process again, and the qualified raw balls are sent to the large roller sieve for secondary screening. The product under the roller screen returns to the pelletizing process, and the product on the large roller screen is fed into the chain grate machine. After being fed into the chain grate machine, the qualified green balls are dried and preheated by the chain grate machine, and then sent to the rotary kiln for roasting and cooling. Afterwards, it becomes a qualified pellet mineral product. Its advantages are: on the premise of ensuring the quality of pellet products, by optimizing the production process and improving the production process, energy saving and emission reduction are realized.
Description
技术领域 technical field
本发明属于选矿技术领域,特别涉及一种细粒铁精矿生产球团矿节能工艺。 The invention belongs to the technical field of mineral processing, and in particular relates to an energy-saving process for producing pellets from fine-grained iron concentrates.
背景技术 Background technique
随着我国钢铁工业宏观调控和结果优化的有效进行,球团厂的建设速度十分迅猛,目前百万吨以上规模球团生产线已经达到50条以上,球团矿的使用为高炉实行精料和改善炉料结构,达到增铁节焦、降低生铁生产成本,提供最基本的条件和最有效的技术措施。球团矿的生产一般有三种工艺,即竖炉、带式机和链箅机-回转窑,目前大、中型企业球团矿生产工艺基本以带式机和链箅机-回转窑为主,由于链箅机-回转窑具有可用煤粉做基本燃料、对原料变化的适应性比带式机强、高温材质要求低和生产成本低等明显优势,新建的大、中型球团厂大都采用这种工艺。但链箅机-回转窑生产工艺过程并非尽善尽美,如生产球团矿所需铁精矿均需要通过干燥窑干燥将水分降低到9%以下才能满足下一步混合及造球工序的要求,折算成每吨球团矿大约需要消耗1公斤左右燃煤,还有造球过程产生的湿返料和链箅机箅板筛下的碎球和粉末即干燥散料均需设专门的破碎设备(一般用柱磨机)来处理,但是,由于湿返料破碎设备本身设计的必要性就不高,干返料设备的破碎效果又一直不理想,因此白白浪费大量备件、电能和人工维护费用。 With the effective implementation of the macro-control and result optimization of my country's iron and steel industry, the construction speed of the pellet plant is very rapid. At present, there are more than 50 pellet production lines with a scale of more than one million tons. Furnace charge structure, to increase iron and save coke, reduce pig iron production cost, provide the most basic conditions and the most effective technical measures. There are generally three processes for the production of pellets, namely shaft furnace, belt machine and chain grate machine-rotary kiln. At present, the pellet production process of large and medium-sized enterprises is mainly based on belt machine and chain grate machine-rotary kiln. Because the chain grate machine-rotary kiln has obvious advantages such as coal powder can be used as the basic fuel, the adaptability to raw material changes is stronger than that of the belt machine, the requirement for high-temperature materials is low, and the production cost is low, most of the newly built large and medium-sized pelletizing plants adopt this method. kind of craft. However, the chain grate machine-rotary kiln production process is not perfect. For example, the iron concentrate required for the production of pellets needs to be dried in a drying kiln to reduce the moisture content to below 9% to meet the requirements of the next mixing and pelletizing process. Converted into Each ton of pellets needs to consume about 1 kg of coal, and the wet return material produced during the pelletizing process and the broken balls and powder under the chain grate plate sieve, that is, dry bulk materials, require special crushing equipment (generally However, since the design of the wet return crushing equipment itself is not necessary, and the crushing effect of the dry return equipment has not been ideal, a lot of spare parts, electric energy and labor maintenance costs are wasted in vain.
发明内容 Contents of the invention
本发明的目的是针对现有技术的不足,提供一种在保证球团矿产品质量的前提下,通过优化生产工艺,完善生产流程,实现节能减排的细粒铁精矿生产球团矿节能工艺。 The purpose of the present invention is to address the deficiencies of the prior art, to provide a fine-grained iron concentrate production pellet energy saving by optimizing the production process, improving the production process, and realizing energy saving and emission reduction under the premise of ensuring the quality of the pellet product. craft.
按照本发明的细粒铁精矿生产球团矿节能工艺,其特征在于:包括下列步骤: According to the fine-grained iron concentrate production pellet energy-saving technology of the present invention, it is characterized in that: comprise the following steps:
(1)将浓度25-35%、粒度-200目含量90-95%、品位67-67.5%的铁精矿矿浆给入精矿浓密机进行浓缩,浓缩后的浓度55%-65%的矿浆给入陶瓷过滤机进行过滤,过滤后的精矿水分控制在9%以下; (1) Feed the iron concentrate slurry with a concentration of 25-35%, a particle size of -200 mesh, a content of 90-95%, and a grade of 67-67.5% into the concentrate thickener for concentration, and the concentration of the concentrated slurry is 55%-65% Feed into a ceramic filter for filtration, and the moisture content of the filtered concentrate is controlled below 9%;
(2)将过滤后的铁精矿给入配料作业,其配料按重量比是按:铁精矿∶膨润土∶除尘灰为1∶0.011-0.016∶0.012-0.02给入强力混合机进行混合作业,混合后物料的铁品位为66-66.5%,水分为9.1%以下; (2) Feed the filtered iron concentrate into the batching operation, and the batching is according to the weight ratio: iron concentrate: bentonite: dedusting ash is 1: 0.011-0.016: 0.012-0.02 and fed into the intensive mixer for mixing operation, The iron grade of the mixed material is 66-66.5%, and the water content is below 9.1%;
(3)将混合后的物料给入圆盘造球机进行造球作业,造球后的生球水分为9.3%±0.2%、落下高度500mm,落下强度为4次以上,抗压强度为11N/球以上,平均粒度为10-13mm; (3) Feed the mixed material into the disc pelletizer for pelletizing operation. After pelletizing, the moisture content of the raw pellets is 9.3%±0.2%, the drop height is 500mm, the drop strength is more than 4 times, and the compressive strength is 11N More than / ball, the average particle size is 10-13mm;
(4)经过造球后的生球给入小辊筛进行筛分,将小辊筛上部筛辊间隙控制在6-9mm,小辊筛下部筛辊间隙控制在12-16mm,筛分出粒度9-16mm合格生球,粒度<9mm和粒度>16mm为不合格生球; (4) After pelletizing, the raw balls are sent to a small roller screen for screening, and the upper roller gap of the small roller screen is controlled at 6-9mm, and the lower roller gap of the small roller screen is controlled at 12-16mm, and the particle size is obtained by screening. 9-16mm qualified green balls, particle size < 9mm and particle size > 16mm are unqualified green balls;
(5)经过小辊筛处理后粒度不合格的生球返回造球工序重新参与造球,粒度合格的生球给入大辊筛,其大辊筛间隙控制在5-7mm进行二次筛分,大辊筛筛下产品重新返回造球工序,大辊筛筛上产品给入链箅机,其箅板缝隙控制在5-7mm; (5) After being processed by the small roller sieve, the unqualified raw pellets return to the pelletizing process to participate in pelletizing again, and the qualified raw pellets are sent to the large roller sieve, and the gap between the large roller sieves is controlled at 5-7mm for secondary screening , the product under the large roller sieve returns to the pelletizing process, and the product on the large roller sieve is fed into the chain grate machine, and the gap between the grate plates is controlled at 5-7mm;
(6)给入链箅机后的合格生球经过链箅机干燥、预热后给入回转窑进行焙烧,焙烧后经过环冷机冷却后成为最终品位65-65.2%、FeO含量小于1%的合格球团矿产品。 (6) The qualified raw balls fed into the chain grate machine are dried and preheated by the chain grate machine, and then sent to the rotary kiln for roasting. After roasting, they are cooled by the ring cooler and become the final grade of 65-65.2% and the FeO content is less than 1%. Qualified pelletized mineral products.
所述的链箅机干燥过程中通过箅板缝隙或缝隙排出的散碎干球称为干燥散料,干燥散料通过链箅机带有振打装置的灰腿排出,干燥散料的排出时间要与造球工序混合料上料时间同步,同时干燥散料或要通过皮带给入一个稳料控制装置,严格控制输出矿量后重新返回造球工序,单位时间的干燥散料的放料量和输送量要求小于单位时间混合料量的4%。 During the drying process of the chain grate machine, the broken dry balls discharged through the gaps or gaps of the grate plate are called dry bulk materials. The dry bulk materials are discharged through the ash legs of the chain grate machine with a vibration device. The discharge time of the dry bulk materials is It should be synchronized with the feeding time of the mixed material in the pelletizing process, and the bulk material should be dried at the same time or a material stabilization control device should be fed through the belt to strictly control the amount of output minerals and then return to the pelletizing process. The amount of dry bulk material per unit time should be discharged. And the delivery volume is required to be less than 4% of the mixed material volume per unit time. the
所述的稳料控制装置由矿仓,与此矿仓连接的给料机和设置在给料机上的计量称所组成。 The material stabilizing control device is composed of a mine bin, a feeder connected to the mine bin and a weighing scale arranged on the feeder.
与现有技术相比,本发明的优点是: Compared with prior art, the advantage of the present invention is:
本发明针对链箅机-回转窑球团生产工艺过程的生产实际,通过优化生产工艺,用陶瓷过滤机降低精矿水分,取消了原有的精矿干燥作业,节约大量动力消耗;同时针对生产过程生球破碎和干返料破碎环节效率低、能耗高的实际情况,通过优化辊筛设备参数和合理稳定控制干返料量,取消了原有的生球破碎和干返料破碎生产环节,使生产过程得到进一步优化。本发明的实施,使球团生产工艺效率得到充分提高,各项技术指标稳定,节能减排效果显著。 The present invention aims at the actual production process of the chain grate machine-rotary kiln pellet production process, by optimizing the production process, using a ceramic filter to reduce the moisture content of the concentrate, canceling the original concentrate drying operation, and saving a lot of power consumption; Due to the actual situation of low efficiency and high energy consumption in the process of raw pellet crushing and dry return crushing, the original green pellet crushing and dry return crushing production links have been canceled by optimizing the parameters of the roller screen equipment and controlling the amount of dry return material reasonably and stably. , so that the production process can be further optimized. The implementation of the invention fully improves the pellet production process efficiency, stabilizes various technical indicators, and has remarkable energy-saving and emission-reducing effects.
附图说明 Description of drawings
图1为本发明的工艺流程图。 Fig. 1 is a process flow diagram of the present invention.
具体实施方式 Detailed ways
下面结合附图和实施例对本发明作进一步说明。 The present invention will be further described below in conjunction with drawings and embodiments.
如图1所示,本发明的细粒铁精矿生产球团矿节能工艺,其特征在于:包括下列步骤: As shown in Fig. 1, fine-grained iron concentrate of the present invention produces pellet ore energy-saving technology, it is characterized in that: comprise the following steps:
(1)将浓度30%、粒度-200目含量93%、品位67.3%的铁精矿矿浆给入精矿浓密机进行浓缩,将浓缩后的浓度60%的矿浆给入陶瓷过滤机进行过滤,过滤后的精矿水分为8.8%; (1) Feed the iron ore concentrate pulp with a concentration of 30%, a particle size of -200 mesh, a content of 93%, and a grade of 67.3% into the concentrate thickener for concentration, and feed the concentrated pulp with a concentration of 60% into a ceramic filter for filtration. The filtered ore concentrate moisture is 8.8%;
(2)过滤后的铁精矿通过配料作业,其配料按重量比是按:铁精矿∶膨润土∶除尘灰为1∶0.014∶0.015给入强力混合机进行混合作业,混合后物料的铁品位为66.4%,水分为8.9%以下; (2) The filtered iron concentrate goes through the batching operation, and the batching is based on the weight ratio: iron concentrate: bentonite: dedusting ash is 1: 0.014: 0.015 and is fed into the intensive mixer for mixing operation. The iron grade of the mixed material is is 66.4%, and the water content is below 8.9%;
(3)将混合后的物料给入圆盘造球机11进行造球作业,造球后的生球水分平均为9.3%,落下高度500mm,落下强度为平均4.5次,抗压强度平均为12N/球,平均粒度为12.5mm; (3) Feed the mixed material into the disc pelletizer 11 for pelletizing operation. After pelletizing, the average moisture content of the raw pellets is 9.3%, the drop height is 500mm, the average drop strength is 4.5 times, and the average compressive strength is 12N / ball, the average particle size is 12.5mm;
(4)经过造球后的生球给入小辊筛,其小辊筛为21根筛辊,上部1-9根筛辊间隙为7mm、9-10根筛辊间隙为12mm,下部10-21根筛辊间隙为15mm,进行筛分,筛分出粒度9-16mm合格生球,粒度<9mm和粒度>16mm为不合格生球, (4) After pelletizing, the raw balls are fed into the small roller screen. The small roller screen has 21 sieve rollers. The gap between the 1-9 sieve rollers in the upper part is 7mm, the gap between the 9-10 sieve rollers is 12mm, and the bottom 10- The 21 sieve rollers have a gap of 15mm, and sieve, and sieve out qualified green balls with a particle size of 9-16mm, and unqualified green balls with a particle size of <9mm and particle size>16mm.
(5)经过小辊筛处理后粒度不合格的粒度<9mm和粒度>16mm生球返回圆盘造球机重新参与造球,粒度合格的生球给入大辊筛,其大辊筛为27根辊,筛辊间隙均为5.5mm,进行二次筛分,筛分出筛上和筛下两种产品,经过大辊筛筛分后的筛下产品与小辊筛筛分出的不合格生球一起返回圆盘造球机进行重新造球, (5) After being processed by the small roller sieve, the unqualified particle size < 9mm and the particle size > 16mm raw pellets are returned to the disc pelletizer to participate in pelletizing again, and the qualified raw pellets are fed into the large roller sieve, and the large roller sieve is 27 The root roller and the gap between the sieve rollers are both 5.5mm. Secondary sieving is carried out to screen out two kinds of products on the sieve and under the sieve. The raw balls return to the disc pelletizer together for re-balling,
(6)大辊筛筛上产品给入链箅机后完成干燥和预热作业,并产生预热球和干燥散料两种产品,其箅板缝隙为5.5mm,干燥散料给入稳料控制装置后,经过输出量控制后输出干燥散料,干燥散料与经大辊筛筛分后的筛下产品和经小辊筛筛出的不合格生球一起返回圆盘造球机进行重新造球,预热球经过回转窑进行焙烧后给入环冷机,经冷却后成为最终品位65.1%、FeO含量0.8%的合格球团矿产品。 (6) After the products on the large roller screen are fed into the chain grate machine, the drying and preheating operations are completed, and two products of preheating balls and dry bulk materials are produced. The gap between the grate plates is 5.5mm, and the dry bulk materials are fed into the stable material After the control device, the dry bulk material is output after the output is controlled, and the dry bulk material is returned to the disc pelletizer together with the under-screened product sieved by the large roller sieve and the unqualified green balls sieved by the small roller sieve. For pelletizing, the preheated balls are roasted in a rotary kiln and then fed into a ring cooler. After cooling, they become qualified pellets with a final grade of 65.1% and a FeO content of 0.8%.
年产200万吨球团矿生产线平均日产按照6100吨计算,作业率90.5%,铁精矿消耗为980kg/t、膨润土的消耗为14kg/t、除尘灰的消耗为15kg/t,则混合料的量为6160吨/日。干燥散料的日产量以200吨/日计、设定铁精矿通过配料作业的精矿配料量为500t/h、膨润土的配比为1.4%、除尘灰的配比为1.5%,以此计算出混合料的量为514.5t/h,配料和混合系统需要运转12小时,确定干燥散料的放料次数为12次/天,2小时一次,则小时放料量为16.7吨,占混合料的比例为3.24%。 The average daily output of the pellet production line with an annual output of 2 million tons is calculated based on 6100 tons, the operating rate is 90.5%, the consumption of iron concentrate is 980kg/t, the consumption of bentonite is 14kg/t, and the consumption of dust removal ash is 15kg/t. The amount is 6160 tons / day. The daily output of dry bulk material is calculated as 200 tons per day, the batching amount of iron ore concentrate is set to 500t/h, the ratio of bentonite is 1.4%, and the ratio of dust removal ash is 1.5%. The amount of mixed material is calculated to be 514.5t/h, and the batching and mixing system needs to be operated for 12 hours. It is determined that the number of discharges of dry bulk materials is 12 times/day, once every 2 hours, and the hourly discharge amount is 16.7 tons, accounting for 16.7 tons of mixed materials. The proportion of material is 3.24%.
本发明是用精矿浓密机和陶瓷过滤机替代了原有的转筒干燥机的功能,取消了用于小辊筛筛分出的不合格的-9mm生球、+16mm生球和大辊筛筛出的不合格筛下产品的原有破碎设备,并通过严格控制干燥散料的量,解决了原有破碎设备存在的缺陷,进而取消了用于干燥散料的原有破碎设备。 The present invention replaces the function of the original rotary drum dryer with the concentrate thickener and ceramic filter, and cancels the unqualified -9mm green balls, +16mm green balls and large rollers used for screening out by the small roller sieve. The original crushing equipment for unqualified under-screen products screened out, and by strictly controlling the amount of dry bulk materials, the defects of the original crushing equipment were solved, and the original crushing equipment for drying bulk materials was cancelled.
本发明优化了整个生产工艺流程,生产操作、技术方法比以前有了更合理的变化。 The present invention optimizes the entire production process, and the production operations and technical methods have more reasonable changes than before.
(1)采用陶瓷过滤机后精矿水分可以达到8.8%以下,而且精矿水分可以通过调整过滤机的给矿量、给矿浓度和清洗制度等来控制,运行成本远低于其它方法和工艺。 (1) After using the ceramic filter, the moisture content of the concentrate can reach below 8.8%, and the moisture content of the concentrate can be controlled by adjusting the ore feeding amount, feeding concentration and cleaning system of the filter, and the operating cost is much lower than other methods and processes .
(2)造球后续筛分作业产生的湿返料,经过多次皮带(带有一定落差)倒运后湿球基本已经变为粉状,对后续造球没有影响。 (2) The wet return material produced by the subsequent screening operation of pelletizing has basically turned into powder after repeated belt transportation (with a certain drop), which has no effect on subsequent pelletizing.
(3)通过严格控制大小辊筛间隙和链箅机箅板缝隙,特别是通过严格控制干燥散料返回造球工序的量、运转时间,使干燥散料占混合料的比例控制在4%以下,进而取消了干燥散料破碎设备,使干燥散料中对造球工序影响较大的+0.076mm~-8mm粒级含量可以比采用原破碎设备时降低20%左右,而-0.076mm粒级和+8mm粒级对造球工序没有影响,因此,改进后不但降低了工序成本,还提高了工序质量。 (3) By strictly controlling the gap between the large and small roller screens and the gap between the grate plates of the chain grate machine, especially by strictly controlling the amount and running time of the dry bulk material returning to the pelletizing process, the proportion of dry bulk material in the mixture is controlled below 4%. , and then canceled the dry bulk crushing equipment, so that the +0.076mm~-8mm particle size content in the dry bulk material that has a greater impact on the pelletizing process can be reduced by about 20% compared with the original crushing equipment, while the -0.076mm particle size And +8mm particle size has no effect on the pelletizing process, so the improvement not only reduces the cost of the process, but also improves the quality of the process.
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Address after: 114001 Anshan District, Liaoning, No. 219 Road, No. 39, Tiedong Patentee after: Anshan Iron and Steel Group Mining Co., Ltd. Address before: 114001 Anshan District, Liaoning, No. 219 Road, No. 39, Tiedong Patentee before: Angang Group Mine Company |