CN102912263B - A kind of fibre reinforced titanium alloy composite material and preparation method thereof - Google Patents

A kind of fibre reinforced titanium alloy composite material and preparation method thereof Download PDF

Info

Publication number
CN102912263B
CN102912263B CN201210382504.5A CN201210382504A CN102912263B CN 102912263 B CN102912263 B CN 102912263B CN 201210382504 A CN201210382504 A CN 201210382504A CN 102912263 B CN102912263 B CN 102912263B
Authority
CN
China
Prior art keywords
carbon fiber
titanium alloy
powder
copper
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201210382504.5A
Other languages
Chinese (zh)
Other versions
CN102912263A (en
Inventor
刘金旭
骆雨萌
李树奎
李沐
吴腾腾
杨秋榕
王迎春
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing Institute of Technology BIT
Original Assignee
Beijing Institute of Technology BIT
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beijing Institute of Technology BIT filed Critical Beijing Institute of Technology BIT
Priority to CN201210382504.5A priority Critical patent/CN102912263B/en
Publication of CN102912263A publication Critical patent/CN102912263A/en
Application granted granted Critical
Publication of CN102912263B publication Critical patent/CN102912263B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Manufacture Of Alloys Or Alloy Compounds (AREA)
  • Powder Metallurgy (AREA)

Abstract

The invention discloses a kind of fibre reinforced titanium alloy composite material and preparation method thereof.The concrete steps of the method are: step 1, pre-treatment of carbon fiber; Step 2, carbon fiber surface electroless copper: utilize chemical plating method that copper-clad is overlying on carbon fiber surface; Step 3, chemical vapour deposition pure tungsten: obtain tungsten settled layer by chemical Vapor deposition process at the carbon fiber surface of coated copper; Step 4, obtained the carbon fiber of appropriate length by the method for cutting by design requirements; Step 5, to mix by titanium alloy component requirements of design and together load hot-forming in pressing mold with carbon fiber after powder and sinter the fibre reinforced titanium alloy composite material finally obtaining needing shape.Fibre reinforced titanium alloy material compound prepared by the present invention is good, and titanium alloy component is adjustable, and the distribution of carbon fiber is controlled, and carbon fiber decarburization can not occur.This matrix material has high specific modulus, and have low density, high specific tenacity, impelling strength and good anti-Adiabatic Shear destructiveness, be a kind of high performance structural material simultaneously.

Description

A kind of fibre reinforced titanium alloy composite material and preparation method thereof
Technical field
The present invention relates to the preparation technology of Copper Plating of Carbon Fiber, copper coating surface vapor deposition pure tungsten and metal composite, belong to metallurgical technology field, particularly relate to a kind of preparation method of fibre reinforced titanium alloy composite material.
Background technology
Fibre reinforced titanium alloy composite material by there is the titanium alloy of high specific strength and there is high ratio modulus, the carbon fiber of stretch-proof is composited, and has that density is low, specific tenacity is high, stretch-proof and a specific modulus advantages of higher.Its mechanical property carries out the adjustment in certain limit by the control of the distribution of adjustment carbon fiber in titanium alloy and titanium alloy component, be a kind of high performance lightweight structural material.
Carbon fiber and metallic substance compound tense is used to take simple mechanical complex method more or directly the metallurgical mode of carbon fiber are compound in metal blocks in the material of construction of present stage.Its shortcoming is that the matrix material bonding force obtained like this is very low, in use de-taking out easily occurs, is difficult to give play to carbon fiber stretch-proof and shear-stable advantage.
The specific tenacity of titanium alloy Yin Qigao is usually used in shock resistance field.Present stage can prepare short carbon fiber reinforced titanium alloy composite material, but staple fibre to its anti-shear ability effect of raising significantly and the arrangement of carbon fiber be difficult to control.
Can there is weightlessness being heated to more than 450 DEG C in carbon fiber, and this temperature cannot reach the powder metallurgy temperature of titanium alloy, and have hydrophobicity and surface inertness because of it, cannot directly by powder metallurgic method and titanium alloy compound; Because pure tungsten to react generation wolfram varbide with carbon fiber, directly utilize vapour deposition carbon fiber can be caused at high temperature weightless in the method for carbon fiber surface deposition pure tungsten.
After the present invention utilizes pre-treatment of carbon fiber, electroless copper plating method is first by its surface metalation; the method of vapour deposition is utilized to deposit one deck pure tungsten on its surface again; and then in the powder metallurgy process of titanium alloy compound with it; solve the problem that carbon fiber cannot bear high temperature when powder metallurgy prepares titanium alloy, also solve directly utilize tungsten as during protective layer and carbon fiber react when high temperature and form the problem of wolfram varbide.The material made has high specific tenacity and specific modulus, and the composition of the shape of finished product and the distribution of internal carbon fibers thereof, titanium alloy is all controlled.
Summary of the invention
The object of the invention is to overcome carbon fiber be difficult to compound and enter in titanium alloy and to combine difference and surface deposition tungsten in case can the shortcomings such as wolfram varbide be formed when blocking fiber high temperature is weightless, provide a kind of and there is high specific tenacity, specific modulus and fibre reinforced titanium alloy composite material that carbon fiber distribution is controlled, titanium alloy component is controlled and preparation method thereof.
The present invention solves the problems of the technologies described above taked technical scheme: make it metallize to prevent it from reacting with tungsten under the high temperature conditions at carbon fiber surface by copper facing and generate wolfram varbide; The resistant to elevated temperatures characteristic of recycling tungsten adopts powder metallurgic method and titanium alloy compound, improves the bonding strength with titanium alloy; For the Spreading requirements of carbon fiber in titanium alloy, adopt mechanical bonding it to be arranged in advance in pressing mold, then carry out warm-pressing formation and make it to form precast billet by Spreading requirements and Titanium Powder and finally carry out sintering and obtain finished product.
The above-mentioned preparation method with the fibre reinforced titanium alloy of high specific strength and specific modulus is as follows:
Step 1, pre-treatment of carbon fiber;
Step 2, carbon fiber surface electroless copper: utilize chemical plating method that copper-clad is overlying on carbon fiber surface;
Step 3, chemical vapour deposition pure tungsten: obtain tungsten settled layer by chemical Vapor deposition process at the carbon fiber surface of coated copper;
Step 4, obtained the carbon fiber of appropriate length by the method for cutting by design requirements;
Step 5, to mix by titanium alloy component requirements of design and together load hot-forming in pressing mold with carbon fiber after powder and sinter the fibre reinforced titanium alloy composite material finally obtaining needing shape.
The present invention, relative to the existing fibre reinforced titanium alloy composite material obtained by simple and mechanical complex method, be it is advantageous that:
(1) make it metallize at carbon fiber surface by copper facing, prevent from again while improve itself and pure tungsten bonding force reacting with tungsten under the high temperature conditions generating wolfram varbide; The resistant to elevated temperatures characteristic of recycling tungsten adopts powder metallurgic method and titanium alloy compound, improves the bonding strength with titanium alloy; For the Spreading requirements of carbon fiber in titanium alloy, mechanical means is adopted it to be arranged in advance in pressing mold, carry out warm-pressing formation again to make it to form precast billet by Spreading requirements and Titanium Powder and finally carry out sintering and obtain finished product, finally make to obtain fibre reinforced titanium alloy composite material by powder metallurgic method and become possibility.
(2) the fibre reinforced titanium alloy composite material interface cohesion obtained by powder metallurgic method is good, de-taking out not easily occurs, ensure that the high ratio modulus of material.
(3) long carbon fiber titanium alloy composite material can be obtained, and the distribution of carbon fiber in titanium alloy and titanium alloy component all can control.
Embodiment
Below in conjunction with four specific embodiments, exemplary illustration and help understand the present invention further.But embodiment detail is only in order to the present invention is described, do not represent the present invention conceive under whole technical schemes, therefore can not be interpreted as the restriction to technical solution of the present invention.Some unsubstantialities not departing from the present invention's design are changed, such as, simply change with the technical characteristic with same or similar technique effect or replace, all belonging to rights protection scope of the present invention.
Embodiment 1
1, first adopt the air calcination method of 300 DEG C except glue to carbon fiber, use thereafter that composition is nitric acid, the coarsening solution alligatoring of potassium bichromate, hydrogen peroxide and ammonium persulphate, then apply 10%NaOH solution and it is neutralized and uses SnCl 2carry out sensitization as sensitizing solution, adopt composition to be PdCl afterwards 2activate with the activation solution of AgCl, the inferior sodium phosphate solution soaking carbon fiber 1 ~ 3min of final utilization 20g/L is to complete reduction process;
2, the method for electroless copper is adopted to process carbon fiber.Solution composition comprises CuSO 4, HCHO, NaKC 4h 4o 6.Plating solution pH value is 12.7, plating temperature 60 DEG C, plating time 20min.For keeping the independent and uniform distribution state in carbon fiber plating process, ultra-sonic oscillation method is adopted to carry out dispersed to chemical bronze plating liquid.Wash 15min with deionized water after taking-up, then in the hot blast of 70 ~ 80 DEG C dry 20min;
3, chemical vapor depsotition equipment is utilized to carry out the vapour deposition of pure tungsten to copper-plated carbon fiber.The raw material adopted during deposition pure tungsten is WF 6and H 2, be warming up to 450 DEG C after emptying air, continue in temperature-rise period to pass into hydrogen, the time is about 1h, regulates hydrogen flowing quantity to 2L/min, and pass into WF after temperature-stable 6gas, flow is 0.8L/min; Stop after 1h passing into WF 6, stopped reaction during slow cooling to 100 DEG C;
4, carbon fiber is cut into the length of 5mm;
5, powdered alloy is prepared according to TC10 titanium alloy component (aluminium: 6%, vanadium: 6%, tin: 2%, titanium residue); Thereon with the spacing of the 1cm carbon fiber cut arranged in parallel after the powdered alloy that even laid 2cm is thick in mould, repave the powdered alloy putting 2cm, after repetition said process to mould fills up, mould and powder are heated, temperature is 120 ~ 180 DEG C simultaneously, pressing pressure is 500MPa, pressurize 30s, then sinter in vacuum oven, sintering temperature is 1250 DEG C, insulation 3h, air cooling obtains finished product.
Embodiment 2
1, first adopt the air calcination method of 300 DEG C except glue to carbon fiber, use thereafter that composition is nitric acid, the coarsening solution alligatoring of potassium bichromate, hydrogen peroxide and ammonium persulphate, then apply 10%NaOH solution and it is neutralized and uses SnCl 2carry out sensitization as sensitizing solution, adopt composition to be PdCl afterwards 2activate with the activation solution of AgCl, the inferior sodium phosphate solution soaking carbon fiber 1 ~ 3min of final utilization 20g/L is to complete reduction process;
2, the method for electroless copper is adopted to process carbon fiber.Solution composition comprises CuSO 4, HCHO, NaKC 4h 4o 6.Plating solution pH value is 12.7, plating temperature 60 DEG C, plating time 20min.For keeping the independent and uniform distribution state in carbon fiber plating process, ultra-sonic oscillation method is adopted to carry out dispersed to chemical bronze plating liquid.Wash 15min with deionized water after taking-up, then in the hot blast of 70 ~ 80 DEG C dry 20min; 3, chemical vapor depsotition equipment is utilized to carry out the vapour deposition of pure tungsten to copper-plated carbon fiber.The raw material adopted during deposition pure tungsten is WF 6and H 2, be warming up to 550 DEG C after emptying air, continue in temperature-rise period to pass into hydrogen, the time is about 1h, regulates hydrogen flowing quantity to 2L/min, and pass into WF after temperature-stable 6gas, flow is 1.2L/min; Stop after 1.5h passing into WF 6, stopped reaction during slow cooling to 100 DEG C;
4, carbon fiber is cut into the length of 10mm;
5, powdered alloy is prepared according to TC10 titanium alloy component (aluminium: 6%, vanadium: 6%, tin: 2%, titanium residue); Put in the mode of meshy arrangement the carbon fiber cut thereon after the powdered alloy that even laid 1cm is thick in mould, between the parallel carbon fiber of two nearest neighbour, spacing is 1cm, then the powdered alloy of laid 1cm thereon, repeats after said process to mould fills up, mould and powder are heated simultaneously, temperature is 120 ~ 180 DEG C, and pressing pressure is 500MPa, pressurize 30s, sinter in vacuum oven again, sintering temperature is 1250 DEG C, and insulation 3h, air cooling obtains finished product.
Embodiment 3
1, first adopt the air calcination method of 300 DEG C except glue to carbon fiber, use thereafter that composition is nitric acid, the coarsening solution alligatoring of potassium bichromate, hydrogen peroxide and ammonium persulphate, then apply 10%NaOH solution and it is neutralized and uses SnCl 2carry out sensitization as sensitizing solution, adopt composition to be PdCl afterwards 2activate with the activation solution of AgCl, the inferior sodium phosphate solution soaking carbon fiber 1 ~ 3min of final utilization 20g/L is to complete reduction process;
2, the method for electroless copper is adopted to process carbon fiber.Solution composition comprises CuSO 4, HCHO, NaKC 4h 4o 6.Plating solution pH value is 12.7, plating temperature 60 DEG C, plating time 20min.For keeping the independent and uniform distribution state in carbon fiber plating process, ultra-sonic oscillation method is adopted to carry out dispersed to chemical bronze plating liquid.Wash 15min with deionized water after taking-up, then in the hot blast of 70 ~ 80 DEG C dry 20min;
3, chemical vapor depsotition equipment is utilized to carry out the vapour deposition of pure tungsten to copper-plated carbon fiber.The raw material adopted during deposition pure tungsten is WF 6and H 2, be warming up to 450 DEG C after emptying air, continue in temperature-rise period to pass into hydrogen, the time is about 1h, regulates hydrogen flowing quantity to 2L/min, and pass into WF after temperature-stable 6gas, flow is 0.8L/min; Stop after 1h passing into WF 6, stopped reaction during slow cooling to 100 DEG C;
4, carbon fiber is cut into the length of 5mm;
5, powdered alloy is prepared according to Ti153 titanium alloy component (vanadium: 15%, aluminium: 3%, chromium: 3%, tin: 3%, titanium residue); Put in the mode of meshy arrangement the carbon fiber cut thereon after the powdered alloy that even laid 1cm is thick in mould, between the parallel carbon fiber of two nearest neighbour, spacing is 1cm, then the powdered alloy of laid 1cm thereon, repeats after said process to mould fills up, mould and powder are heated simultaneously, temperature is 120 ~ 180 DEG C, and pressing pressure is 500MPa, pressurize 30s, sinter in vacuum oven again, sintering temperature is 1250 DEG C, and insulation 3h, air cooling obtains finished product.
Embodiment 4
1, first adopt the air calcination method of 300 DEG C except glue to carbon fiber, use thereafter that composition is nitric acid, the coarsening solution alligatoring of potassium bichromate, hydrogen peroxide and ammonium persulphate, then apply 10%NaOH solution and it is neutralized and uses SnCl 2carry out sensitization as sensitizing solution, adopt composition to be PdCl afterwards 2activate with the activation solution of AgCl, the inferior sodium phosphate solution soaking carbon fiber 1 ~ 3min of final utilization 20g/L is to complete reduction process;
2, the method for electroless copper is adopted to process carbon fiber.Solution composition comprises CuSO 4, HCHO, NaKC 4h 4o 6.Plating solution pH value is 12.7, plating temperature 60 DEG C, plating time 20min.For keeping the independent and uniform distribution state in carbon fiber plating process, ultra-sonic oscillation method is adopted to carry out dispersed to chemical bronze plating liquid.Wash 15min with deionized water after taking-up, then in the hot blast of 70 ~ 80 DEG C dry 20min;
3, chemical vapor depsotition equipment is utilized to carry out the vapour deposition of pure tungsten to copper-plated carbon fiber.The raw material adopted during deposition pure tungsten is WF 6and H 2, be warming up to 550 DEG C after emptying air, continue in temperature-rise period to pass into hydrogen, the time is about 1h, regulates hydrogen flowing quantity to 2L/min, and pass into WF after temperature-stable 6gas, flow is 1.2L/min; Stop after 1.5h passing into WF 6, stopped reaction during slow cooling to 100 DEG C;
4, carbon fiber is cut into the length of 10mm;
5, powdered alloy is prepared according to Ti153 titanium alloy component (vanadium: 15%, aluminium: 3%, chromium: 3%, tin: 3%, titanium residue); Thereon with the spacing of the 1cm carbon fiber cut arranged in parallel after the powdered alloy that even laid 2cm is thick in mould, repave the powdered alloy putting 2cm, after repetition said process to mould fills up, mould and powder are heated, temperature is 120 ~ 180 DEG C simultaneously, pressing pressure is 500MPa, pressurize 30s, then sinter in vacuum oven, sintering temperature is 1250 DEG C, insulation 3h, air cooling obtains finished product.

Claims (6)

1. a fibre reinforced titanium alloy composite material, it is characterized in that: carbon fiber is parallel or meshy arrangement is distributed in titanium alloy block, titanium alloy component is adjustable, carbon fiber distribution is controlled, and this matrix material is by adopting chemical Vapor deposition process to utilize WF on its surface again after carbon fiber surface electroless plating a layer thickness is the copper of 2 ~ 5 μm 6and H 2reactive deposition a layer thickness is the pure tungsten of 2 ~ 5 μm, finally utilizes powder metallurgic method the carbon fiber after process and the method for titanium alloy compound to be obtained.
2. material as claimed in claim 1, is characterized in that: the composition of titanium alloy allows to adjust as required.
3. material as claimed in claim 1, is characterized in that: distributing position, angle and the quantity of carbon fiber in the titanium alloy block that powder metallurgy is formed allows to adjust in the pressing mold used by powder metallurgy.
4. material as claimed in claim 1, is characterized in that: carbon fiber surface has thickness to be the copper plate of 2 ~ 5 μm, and layers of copper surface deposition has one deck to have thickness to be the pure tungsten of 2 ~ 5 μm;
Described material is prepared by following process: (1) carbon fiber will carry out 300 DEG C of air calcinations before use and remove photoresist, nitric acid, potassium bichromate, hydrogen peroxide and ammonium persulfate solution alligatoring, and 10%NaOH solution neutralizes, SnCl 2solution sensitization, PdCl 2with inferior sodium phosphate solution soaking 1 ~ 3min reduction pretreatment of the activation of AgCl solution, 20g/L;
(2) adopt pH value be the method for chemical plating fluid copper facing 20min at 60 DEG C of 12.7 in carbon fiber surface plating, after taking-up with deionized water washing and in the hot blast of 70 ~ 80 DEG C dry 20min;
(3) chemical Vapor deposition process is adopted, the pure tungsten that carbon fibres deposit one deck after copper facing 2 ~ 5 μm is thick;
(4) by the dimensional requirement of design, cutting is carried out to carbon fiber;
(5) carry out mixed powder by the requirement of titanium alloy component of design, powder and carbon fiber are placed in pressing mold by design requirements and carry out warm-pressing formation, finally sinter.
5. the preparation method of a kind of fibre reinforced titanium alloy composite material as claimed in claim 1, is characterized in that:
(1) carbon fiber will carry out 300 DEG C of air calcinations before use and removes photoresist, nitric acid, potassium bichromate, hydrogen peroxide and ammonium persulfate solution alligatoring, and 10%NaOH solution neutralizes, SnCl 2solution sensitization, PdCl 2with inferior sodium phosphate solution soaking 1 ~ 3min reduction pretreatment of the activation of AgCl solution, 20g/L;
(2) adopt pH value be the method for chemical plating fluid copper facing 20min at 60 DEG C of 12.7 in carbon fiber surface plating, after taking-up with deionized water washing and in the hot blast of 70 ~ 80 DEG C dry 20min;
(3) chemical Vapor deposition process is adopted, the pure tungsten that carbon fibres deposit one deck after copper facing 2 ~ 5 μm is thick;
(4) by the dimensional requirement of design, cutting is carried out to carbon fiber;
(5) carry out mixed powder by the requirement of titanium alloy component of design, powder and carbon fiber are placed in pressing mold by design requirements and carry out warm-pressing formation, finally sinter.
6. preparation method as claimed in claim 5, is characterized in that:
(1), when carrying out electroless copper to carbon fiber, employing solution composition is CuSO 4, HCHO, NaKC 4h 4o 6; Or use composition to be CuSO 45H 2o, EDTA, KNaC 4h 4o 64H 2o, NaOH, HCHO, 2,2 ' 2 dipyridyls, K 4fe (CN) 63H 2the pH value that O is made into is the plating solution plating of 12.7;
(2), when the copper-plated carbon fiber of effects on surface carries out vapour deposition pure tungsten, the raw material of employing is WF 6and H 2, react front-seat net air; Continue in temperature-rise period to pass into hydrogen, the time is 1h, after substrate temperature reaches 450 DEG C and maintenance is stable, regulates hydrogen flowing quantity, passes into WF 6gas; Stop after 1h passing into WF 6, stop during slow cooling to 100 DEG C passing into H 2, pass into N 2until cooling terminates;
(3) what the copper carbon fiber of effects on surface deposition pure tungsten carried out adopting with the compound tense of titanium alloy is powder metallurgic method, the last interpolation internal lubricant of Titanium Powder that powder obtains predetermined component is mixed by the component requirements of titanium alloy, powder and carbon fiber are placed in pressing mold by the Spreading requirements designed, mould and powder are heated simultaneously and pressurize and carries out warm compaction molding, then sinter in vacuum oven.
CN201210382504.5A 2012-10-11 2012-10-11 A kind of fibre reinforced titanium alloy composite material and preparation method thereof Expired - Fee Related CN102912263B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201210382504.5A CN102912263B (en) 2012-10-11 2012-10-11 A kind of fibre reinforced titanium alloy composite material and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201210382504.5A CN102912263B (en) 2012-10-11 2012-10-11 A kind of fibre reinforced titanium alloy composite material and preparation method thereof

Publications (2)

Publication Number Publication Date
CN102912263A CN102912263A (en) 2013-02-06
CN102912263B true CN102912263B (en) 2015-09-02

Family

ID=47610836

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201210382504.5A Expired - Fee Related CN102912263B (en) 2012-10-11 2012-10-11 A kind of fibre reinforced titanium alloy composite material and preparation method thereof

Country Status (1)

Country Link
CN (1) CN102912263B (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103710648B (en) * 2014-01-16 2015-07-29 徐茂航 A kind of long carbon fiber strengthens titanium alloy composite material
CN106591744B (en) * 2015-10-15 2019-01-29 中国航空制造技术研究院 A kind of composite material die for preparation and preparation method
CN105296897A (en) * 2015-10-25 2016-02-03 无棣向上机械设计服务有限公司 Method for preparing carbon fiber enhanced titanium alloy composite material
CN105861962A (en) * 2016-04-20 2016-08-17 苏州蔻美新材料有限公司 Composite material for preparing dental crown forceps for teeth and preparation method of composite material
CN106334787B (en) * 2016-10-24 2018-06-29 三峡大学 A kind of gradient graphite/aluminium base surface layer self-lubricating composite and preparation method
CN106498456A (en) * 2016-11-21 2017-03-15 江苏梦得新材料科技有限公司 A kind of carbon fiber surface copper-plating technique
CN106756656A (en) * 2016-12-20 2017-05-31 南京九致信息科技有限公司 Nitinol fiberboard and preparation method thereof
CN109825814A (en) * 2019-04-10 2019-05-31 北京工业大学 A method of strong adhesive force tungsten layer is prepared in titanium alloy surface
CN111235497A (en) * 2019-05-09 2020-06-05 重庆文理学院 Preparation method of high-toughness metal composite material
CN110315083A (en) * 2019-07-25 2019-10-11 西北有色金属研究院 A method of quickly preparing fibre reinforced titanium alloy laminar composite
CN111811322A (en) * 2020-07-22 2020-10-23 赛福纳米科技(徐州)有限公司 Ceramic-titanium alloy-PE composite bulletproof deck and preparation method thereof
CN112281088B (en) * 2020-10-23 2021-07-06 西北工业大学 Preparation method of carbon fiber reinforced titanium alloy composite material
CN112553547B (en) * 2020-12-07 2022-01-18 深圳市天士力神通本草技术开发有限公司 Preparation method of high-thermal-conductivity metal-based carbon fiber heating body material
CN114438425B (en) * 2022-02-09 2022-07-19 重庆金开泰达新材料科技有限公司 Long carbon fiber reinforced titanium alloy composite material

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4853294A (en) * 1988-06-28 1989-08-01 United States Of America As Represented By The Secretary Of The Navy Carbon fiber reinforced metal matrix composites
CN101067192A (en) * 2007-04-10 2007-11-07 中北大学 Carbon fiber reinforced nickel-based composite material and producing method thereof
CN101279366A (en) * 2008-05-28 2008-10-08 天津大学 Method for producing diamond reinforced Cu-matrix compound material by surface metallization and chemical deposition

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06172033A (en) * 1992-12-11 1994-06-21 Nippon Cement Co Ltd Surface-coated carbon-fiber reinforced composite material and its production

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4853294A (en) * 1988-06-28 1989-08-01 United States Of America As Represented By The Secretary Of The Navy Carbon fiber reinforced metal matrix composites
CN101067192A (en) * 2007-04-10 2007-11-07 中北大学 Carbon fiber reinforced nickel-based composite material and producing method thereof
CN101279366A (en) * 2008-05-28 2008-10-08 天津大学 Method for producing diamond reinforced Cu-matrix compound material by surface metallization and chemical deposition

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
The design of an ephemeral interfacial zone for titanium matrix composites;C. Arvieua, et al.;《Composites Part A》;19981231;第29卷;第1193-1195、1199页 *
短碳纤维表面处理及粉末冶金法制备Cf/Al复合材料的研究;卢文成;《工程科技I辑》;20120415(第4期);第15-17页 *

Also Published As

Publication number Publication date
CN102912263A (en) 2013-02-06

Similar Documents

Publication Publication Date Title
CN102912263B (en) A kind of fibre reinforced titanium alloy composite material and preparation method thereof
CN103409732B (en) A kind of compounding method of diamond surface metallization
CN102936706B (en) A kind of Carbon fiber cloth-titanium alloy composite material and preparation method thereof
Fan et al. Preparation of nickel coating on ZTA particles by electroless plating
CN102295474B (en) Preparation method of SiC-TaC coating/matrix collaborative modified C/C composite material
CN111424270B (en) Method for laser cladding of copper-based diamond particle reinforced composite coating on surface of copper alloy
CN107353008B (en) Preparation method of layered metal-ceramic composite material part
CN103113123A (en) Preparation method of SiCf/SiC ceramic matrix composite turbine blades
CN102391015B (en) SiC ceramic surface treatment method and application thereof
CN102400001A (en) Method for preparing granule reinforced aluminum-based composite material of in-situ intermetallic compound
CN105568037B (en) A kind of chromium plating diamond particles disperse the preparation method of Cu-base composites
CN103469200B (en) A kind of method preparing nanocoating
CN102943225B (en) A kind of Carbon fiber cloth/aluminium alloy composite material and preparation method thereof
CN103302294B (en) A kind of powder metallurgic method prepares the method for nanometer Cu@SiC/Cu based composites
CN102071332A (en) Method for preparing diamond enhanced copper based composite with high volume fraction
Wang et al. Electroless copper plating of tungsten powders and preparation of WCu20 composites by microwave sintering
CN106756995B (en) A kind of method of the fibre reinforced metal-based composite coating of laser melting coating
CN107398544B (en) A kind of lost-foam casting method of three-dimensional network ceramics-iron base composite material
CN100491567C (en) Preparation method of WC-Cr3C2 ceramic coating ferrum radical surface composite material having mesh structure
CN104651658B (en) Preparation method of novel copper-based composite material having high thermal conductivity
CN109513905B (en) A kind of preparation method being surface-treated the iron-based composite wear-resistant part of ZTA particle enhanced steel
Fan et al. High thermal conductivity and mechanical properties of Si@ Graphite/Aluminum nitride/aluminum composites for high-efficiency thermal management
CN103302235B (en) A kind of method of cast(ing) surface reactive cladding alumina base coating
Anni et al. Thermoplastic coating on fiber reinforced polymer composites by cold spray additive manufacturing
CN101928909B (en) Method for preparing niobium titanium aluminum alloy coating by utilizing detonation spraying

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20150902

Termination date: 20161011

CF01 Termination of patent right due to non-payment of annual fee