CN102901738A - Identification method for self-explosion of toughened glass - Google Patents
Identification method for self-explosion of toughened glass Download PDFInfo
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- CN102901738A CN102901738A CN2012104606064A CN201210460606A CN102901738A CN 102901738 A CN102901738 A CN 102901738A CN 2012104606064 A CN2012104606064 A CN 2012104606064A CN 201210460606 A CN201210460606 A CN 201210460606A CN 102901738 A CN102901738 A CN 102901738A
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- explosion
- self
- toughened glass
- tempered glass
- glass
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- 239000005341 toughened glass Substances 0.000 title claims abstract description 62
- 238000004880 explosion Methods 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims abstract description 27
- 238000004458 analytical method Methods 0.000 claims abstract description 8
- 230000003287 optical effect Effects 0.000 claims abstract description 7
- 239000004575 stone Substances 0.000 claims abstract description 6
- 239000002245 particle Substances 0.000 claims abstract description 4
- 238000005336 cracking Methods 0.000 claims description 5
- 208000037656 Respiratory Sounds Diseases 0.000 claims description 3
- 238000007689 inspection Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 230000002159 abnormal effect Effects 0.000 abstract 1
- 230000003116 impacting effect Effects 0.000 abstract 1
- 230000009885 systemic effect Effects 0.000 abstract 1
- 239000011521 glass Substances 0.000 description 10
- 239000012634 fragment Substances 0.000 description 4
- WWNBZGLDODTKEM-UHFFFAOYSA-N sulfanylidenenickel Chemical group [Ni]=S WWNBZGLDODTKEM-UHFFFAOYSA-N 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KRQUFUKTQHISJB-YYADALCUSA-N 2-[(E)-N-[2-(4-chlorophenoxy)propoxy]-C-propylcarbonimidoyl]-3-hydroxy-5-(thian-3-yl)cyclohex-2-en-1-one Chemical compound CCC\C(=N/OCC(C)OC1=CC=C(Cl)C=C1)C1=C(O)CC(CC1=O)C1CCCSC1 KRQUFUKTQHISJB-YYADALCUSA-N 0.000 description 1
- 206010025421 Macule Diseases 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- 239000005347 annealed glass Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000009172 bursting Effects 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 238000005816 glass manufacturing process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000005336 safety glass Substances 0.000 description 1
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Abstract
The invention provides an identification method for self-explosion of toughened glass. The identification method comprises steps of: A, inspecting original appearance of a site subjected to explosion of the toughened glass, and determining the position of a gap of the toughened glass in explosion and the direction in which the gap is generated; B, observing the appearance of the crack of the toughened glass in aspects of the shape and dimension; C, optically observing the gap through an optical microscope, and searching whether abnormal objects are contained in the gap; and D, determining stone elements by a X-ray characteristic particle energy spectrometer under a scanning electron microscope after the observing and analysis in steps A, B and C are finished, no characteristic that the explosion is caused by outside force impacting is founded, and self-explosion stone is found; and if the stone in a self-explosion point contains elements S and Ni, determining that the toughened glass is subjected to self-explosion. The identification method is clear and simple in steps, and can effectively determine the self-explosion of the toughened glass, so that a systemic, scientific and unified method is provided for analyzing and determining the self-explosion of the toughened glass.
Description
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Technical field
The present invention relates to the material analysis field, particularly relate to a kind of analysis of causes field of tempered glass explosion.
Background technology
Tempered glass is annealed glass to be processed into require size shape,, carry out again the specific glass that obtains after quenching is processed, thereby make the surface of glass form powerful compressive stress to the temperature near softening point through high-temperature heating, the powerful tension stress of inner formation, physical strength is multiplied.Fragment is radial diffusion behind the toughened glass crushing, without sharp corners, does not hurt sb.'s feelings, and belongs to safety glass.
Along with the development of society, glass is used more and more extensive in people's routine work and life, and for the security and the intensity that improve glass, tempered glass generally is used in the goods such as vehicle glass, building curtain wall.But because glass itself is a kind of hard brittle material, in fracture process, almost without any plastic deformation, destroy sudden and catastrophic often.
The explosion of tempered glass except artificial active is knocked in a lot of situations all is because the tempered glass explosion that the self-destruction of tempered glass causes.Toughened glass self-explosion is without the Fragmentation Phenomena that occurs under the applied external force, glass fragment centered by the self-destruction starting point to around be radial diffusion, can have two larger fragments and present " butterfly macules " feature revealing the starting point place.Self-destruction can not be avoided fully for tempered glass, also is absence of aura, and the probability of its generation is usually 3 ‰.
The time of toughened glass self-explosion does not have determinacy, may be fresh baked, the 1-2 that also may dispatch from the factory just reveals, or even the rear 4-5 that dispatches from the factory just reveals.In recent years, because the generally application, the particularly surge of the use amount on vehicle glass and glass curtain wall of tempered glass, under 3 ‰ self-destruction rate background, the bursting accident frequent occurrence of tempered glass.So judge, lose the aspects such as setting loss the party responsible, the demand that society identifies for the rupture reasons of tempered glass also constantly increases.
In general the reason that causes toughened glass crushing of may disequilibrating has external cause and internal cause.External cause comprises undue load, collision, unsuitable gap and the infringement of limit section etc.; Internal cause comprises: 1. tempered glass limit section manufacturing deficiency, wedge angle, punching quit a post and thus leave it vacant equal stress concentrated area stress are excessive, 2. the tempered glass internal stress is excessive, 3. there is nickel sulphide inclusions in tempered glass inside, internal cause is 1. 2. owing to technology controlling and process reason in the tempered glass process causes, and the internal cause 3. factor of nickel sulfide is to produce in former sheet glass manufacturing process.
3. find after deliberation, after having got rid of external cause, in the immanent cause of tempered glass explosion, be that tempered glass inside exists the situation of nickel sulphide inclusions the most general with internal cause especially.This kind situation tempered glass " cancer " that in the industry cycle is otherwise known as.
At present domestic reason for the tempered glass explosion identifies that authentication method or the standard of corresponding system science are not identified, so whether the explosion of how to confirm tempered glass is revealed and become this field problem demanding prompt solution.
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Summary of the invention
There is no the method for corresponding system science in the prior art or whether reason that standard is carried out the tempered glass explosion is the problem that self-destruction is determined for solving, the invention provides following technical scheme:
A kind of authentication method of toughened glass self-explosion is characterized in that: the method may further comprise the steps:
A, the original appearance inspection is carried out at tempered glass explosion scene, confirmed the position of tempered glass explosion breach, the direction of breach cracking;
B, the crackle size of the crack shape of tempered glass is carried out appearance observe;
C, under optical microscope, the cracking breach is carried out optical observation, seek the breach place and whether have anomalies;
Behind D, process steps A, B, the C observation analysis, do not find that external force collision causes the feature of explosion, and find to exist the self-destruction calculus, under scanning electron microscope, carrying out the stone composition element by X ray characteristic particle energy spectrometer confirms, if self-destruction point calculus contains S element and Ni element, can confirm the former of tempered glass explosion because self-destruction.
As a preferred embodiment of the present invention, among the described step B, if find the pattern of the figure of eight or butterfly's wing shape, then this is characterized as the feature of toughened glass self-explosion.
As another kind of preferred version of the present invention, among the described step B, if find that the texture that breaks of tempered glass is even, then this is characterized as the feature of toughened glass self-explosion.
The present invention has the following advantages: whether the inventive method is that the evaluation of revealing was divided into for two steps on the whole for the tempered glass explosion, the first step determines that the reason of explosion is external cause or internal cause, second step, determine to carry out analysis of causes checking after the internal cause, the inventive method step is clear, simple, can effectively determine the self-destruction of tempered glass, for the self-destruction Analysis deterrmination of tempered glass provides system, science, unified method.
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Description of drawings
Fig. 1 the inventive method is carried out the energy spectrogram of X ray characteristic ion energy spectrometer.
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Embodiment
The below elaborates this process implementing example, thereby so that advantages and features of the invention can be easier to be it will be appreciated by those skilled in the art that protection scope of the present invention is made more explicit defining.
A kind of authentication method of toughened glass self-explosion is characterized in that: the method may further comprise the steps:
A, the original appearance inspection is carried out at tempered glass explosion scene, found that the direction of breaking of tempered glass is from inside to outside, the crack is the protrusion type, presents the crack, outside large, the del that internal fissure is little;
B, the crackle size of the crack shape of tempered glass is carried out appearance observe, the texture that breaks of this tempered glass is two fragments of the figure of eight or similar butterfly's wing shape, this grain distribution that breaks is even, and consistent with the texture that radially distributes centered by the self-destruction point;
C, under optical microscope the cracking breach is carried out optical observation, the glass texture of this tempered glass is even, meets the self-destruction texture, seeks the breach place and whether has anomalies, finds impurity;
Behind D, process steps A, B, the C observation analysis, do not find that external force collision causes the feature of explosion, and find to exist the self-destruction calculus, under scanning electron microscope, carrying out the stone composition element by X ray characteristic particle energy spectrometer confirms, obtaining as shown in Figure 1 can spectrogram, and a self-destruction point calculus contains S element and Ni element, can confirm the former of tempered glass explosion because reveal by above supposition.
The above; it only is one of the specific embodiment of the present invention; but protection scope of the present invention is not limited to this; any those of ordinary skill in the art are in the disclosed technical scope of the present invention; variation or the replacement that can expect without creative work all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.
Claims (3)
1. the authentication method of a toughened glass self-explosion, it is characterized in that: the method may further comprise the steps:
A, the original appearance inspection is carried out at tempered glass explosion scene, confirmed the position of tempered glass explosion breach, the direction of breach cracking;
B, the crackle size of the crack shape of tempered glass is carried out appearance observe;
C, under optical microscope, tempered glass cracking breach is carried out optical observation, seek the breach place and whether have anomalies;
Behind D, process steps A, B, the C observation analysis, do not find that external force collision causes the feature of explosion, and find to exist the self-destruction calculus, under scanning electron microscope, carrying out the stone composition element by X ray characteristic particle energy spectrometer confirms, if self-destruction point calculus contains S element and Ni element, can confirm the former of tempered glass explosion because self-destruction.
2. the authentication method of a kind of toughened glass self-explosion according to claim 1 is characterized in that: among the described step B, if find the pattern of the figure of eight or butterfly's wing shape, then this is characterized as the feature of toughened glass self-explosion.
3. the authentication method of a kind of toughened glass self-explosion according to claim 1 is characterized in that: among the described step B, if find that the texture that breaks of tempered glass is even, then this is characterized as the feature of toughened glass self-explosion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012104606064A CN102901738A (en) | 2012-11-15 | 2012-11-15 | Identification method for self-explosion of toughened glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012104606064A CN102901738A (en) | 2012-11-15 | 2012-11-15 | Identification method for self-explosion of toughened glass |
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| Publication Number | Publication Date |
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| CN102901738A true CN102901738A (en) | 2013-01-30 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012104606064A Pending CN102901738A (en) | 2012-11-15 | 2012-11-15 | Identification method for self-explosion of toughened glass |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6348444A (en) * | 1986-08-19 | 1988-03-01 | Narumi China Corp | Method and device for automatic inspection of surface of glass substrate |
| JP3053449B2 (en) * | 1991-03-28 | 2000-06-19 | 株式会社ニデック | Surface inspection equipment |
-
2012
- 2012-11-15 CN CN2012104606064A patent/CN102901738A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6348444A (en) * | 1986-08-19 | 1988-03-01 | Narumi China Corp | Method and device for automatic inspection of surface of glass substrate |
| JP3053449B2 (en) * | 1991-03-28 | 2000-06-19 | 株式会社ニデック | Surface inspection equipment |
Non-Patent Citations (1)
| Title |
|---|
| 杨建军等: "钢化玻璃自爆原因分析、诊断及解决方案", 《中国建材报》 * |
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Application publication date: 20130130 |