CN102899102B - Methanol gasoline instantizer - Google Patents

Methanol gasoline instantizer Download PDF

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Publication number
CN102899102B
CN102899102B CN201210425851.1A CN201210425851A CN102899102B CN 102899102 B CN102899102 B CN 102899102B CN 201210425851 A CN201210425851 A CN 201210425851A CN 102899102 B CN102899102 B CN 102899102B
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trans
alicyclic ring
mixed ether
aromatic ketone
methanol gasoline
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CN201210425851.1A
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CN102899102A (en
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李奕男
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Century Guohong New Energy Technology (beijing) Co Ltd
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Century Guohong New Energy Technology (beijing) Co Ltd
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Abstract

The invention discloses a gasoline gasoline instantizer, which comprises aromatic ketone, alkylaryl mixed ether and alicyclic alcohol, wherein the weight ratio of aromatic ketone to alkylaryl mixed ether to alicyclic alcohol is 1: (0.1 to 0.7): (2 to 3.5). The miscibility of gasoline and methanol can be improved, so that the methanol and gasoline are evenly mixed without being layered.

Description

Methanol gasoline quick-dissolving agent
Technical field
The present invention relates to a kind of methanol gasoline additive, particularly a kind of methanol gasoline quick-dissolving agent.
Background technology
In the prior art, growing along with petroleum demand, oil extraction is also strengthening gradually, and petroleum resources are day by day exhausted; Countries in the world all can substitute or the fuel of part petroleum replacing completely in research and development.Wherein, in gasoline, adding the methanol gasoline that methyl alcohol makes has been applied on gasoline-fueled automobile.But, in gasoline, adding the ratio of methyl alcohol when higher, can not be applied on the engine of automobile in prior art, need to improve engine.When adding the ratio of methyl alcohol in gasoline when lower, do not need the engine of automobile in prior art to improve and can use; But if the methyl alcohol ratio of adding in gasoline is lower, the compatibility performance of gasoline and methyl alcohol is poor, the in the situation that of low temperature or long-term storage, easily there is layering, thereby affect the normal use of methanol gasoline; And, by gasoline and methanol mixed time, need abundant stirring for a long time just can make the two complete miscibility, use very inconvenient in reality.
Summary of the invention
For the deficiencies in the prior art, the object of the present invention is to provide a kind of intermiscibility that can improve gasoline and methyl alcohol, make methyl alcohol and gasoline mix and layering does not occur, and the methanol gasoline quick-dissolving agent that can make gasoline and methyl alcohol dissolve each other fast.
Technical scheme of the present invention is achieved in that methanol gasoline quick-dissolving agent, be made up of aromatic ketone, alkane virtue mixed ether and alicyclic ring alcohol, aromatic ketone, alkane virtue mixed ether and alicyclic ring alcohol three's weight proportion is: aromatic ketone: alkane virtue mixed ether: alicyclic ring alcohol=1:(0.1~0.7): (2~3.5).
Above-mentioned methanol gasoline quick-dissolving agent, aromatic ketone, alkane virtue mixed ether and alicyclic ring alcohol three's weight proportion is: aromatic ketone: alkane virtue mixed ether: alicyclic ring alcohol=1:0.5:2.6.
Above-mentioned methanol gasoline quick-dissolving agent, aromatic ketone is one or both in diphenylmethanone and phenylbenzene ethyl ketone.
Above-mentioned methanol gasoline quick-dissolving agent, aromatic ketone is made up of diphenylmethanone and phenylbenzene ethyl ketone, the weight proportion of diphenylmethanone and phenylbenzene ethyl ketone is: diphenylmethanone: phenylbenzene ethyl ketone=1:(1.2~1.8).
Above-mentioned methanol gasoline quick-dissolving agent, alkane virtue mixed ether is one or both in methyl-phenoxide and p-dimethyoxy benzene.
Above-mentioned methanol gasoline quick-dissolving agent, alkane virtue mixed ether is made up of methyl-phenoxide and p-dimethyoxy benzene, the weight proportion of methyl-phenoxide and p-dimethyoxy benzene is: methyl-phenoxide: p-dimethyoxy benzene=1:(0.3~1).
Above-mentioned methanol gasoline quick-dissolving agent, alicyclic ring alcohol is trans-2-methylcyclopentanol and trans-1, one or both in 2-cyclohexanediol.
Above-mentioned methanol gasoline quick-dissolving agent, alicyclic ring alcohol is by trans-2-methylcyclopentanol and trans-1,2-cyclohexanediol composition, trans-2-methylcyclopentanol and trans-1, the weight proportion of 2-cyclohexanediol is: trans-2-methylcyclopentanol: trans-1,2-cyclohexanediol=1:(1~1.5).
Above-mentioned methanol gasoline quick-dissolving agent, be made up of aromatic ketone, alkane virtue mixed ether, alicyclic ring alcohol and monocarboxylic acid, the weight proportion of aromatic ketone, alkane virtue mixed ether, alicyclic ring alcohol and monocarboxylic acid is: aromatic ketone: alkane virtue mixed ether: alicyclic ring alcohol: monocarboxylic acid=1:(0.1~0.7): (2~3.5): (0.2~0.6).
Above-mentioned methanol gasoline quick-dissolving agent, be made up of aromatic ketone, alkane virtue mixed ether, alicyclic ring alcohol and monocarboxylic acid, the weight proportion of aromatic ketone, alkane virtue mixed ether, alicyclic ring alcohol and monocarboxylic acid is: aromatic ketone: alkane virtue mixed ether: alicyclic ring alcohol: monocarboxylic acid=1:0.4:2.8:0.5.
The invention has the beneficial effects as follows: methanol gasoline quick-dissolving agent of the present invention can improve gasoline and methyl alcohol intermiscibility, methyl alcohol and gasoline are mixed and layering do not occur; And can make gasoline and methyl alcohol dissolve each other fast, not need to stir and can make gasoline and methyl alcohol dissolve each other completely in 10 minutes.
Embodiment
Following examples methanol gasoline used is the mixture of methyl alcohol and GB 90# gasoline, get respectively methyl alcohol volume fraction and be 5%, 15% and 25% methanol gasoline (representing with M5, M15 and M25 respectively), and carry out characteristic of solubilizing test in temperature for-25 DEG C ,-15 DEG C, 0 DEG C, 15 DEG C and 25 DEG C respectively.
Embodiment 1
Methanol gasoline quick-dissolving agent, is made up of aromatic ketone, alkane virtue mixed ether and alicyclic ring alcohol, and aromatic ketone, alkane virtue mixed ether and alicyclic ring alcohol three's weight proportion is: aromatic ketone: alkane virtue mixed ether: alicyclic ring alcohol=1:0.1:2.Aromatic ketone is diphenylmethanone, and alkane virtue mixed ether is methyl-phenoxide, and alicyclic ring alcohol is trans-2-methylcyclopentanol.
In upper table, the addition of methanol gasoline quick-dissolving agent is the addition in 100mL methanol gasoline.
Embodiment 2
Methanol gasoline quick-dissolving agent, is made up of aromatic ketone, alkane virtue mixed ether and alicyclic ring alcohol, and aromatic ketone, alkane virtue mixed ether and alicyclic ring alcohol three's weight proportion is: aromatic ketone: alkane virtue mixed ether: alicyclic ring alcohol=1:0.7:3.5.Aromatic ketone is diphenylmethanone, and alkane virtue mixed ether is p-dimethyoxy benzene, and alicyclic ring alcohol is trans-2-methylcyclopentanol.
In upper table, the addition of methanol gasoline quick-dissolving agent is the addition in 100mL methanol gasoline.
Embodiment 3
Methanol gasoline quick-dissolving agent, aromatic ketone, alkane virtue mixed ether and alicyclic ring alcohol three's weight proportion is: aromatic ketone: alkane virtue mixed ether: alicyclic ring alcohol=1:0.5:2.6.Aromatic ketone is phenylbenzene ethyl ketone, and alkane virtue mixed ether is methyl-phenoxide, and alicyclic ring alcohol is trans-1,2-cyclohexanediol.
In upper table, the addition of methanol gasoline quick-dissolving agent is the addition in 100mL methanol gasoline.
Embodiment 4
The difference of the present embodiment methanol gasoline quick-dissolving agent and embodiment 1 is: aromatic ketone is made up of diphenylmethanone and phenylbenzene ethyl ketone, and the weight proportion of diphenylmethanone and phenylbenzene ethyl ketone is: diphenylmethanone: phenylbenzene ethyl ketone=1:1.2.Alkane virtue mixed ether is made up of methyl-phenoxide and p-dimethyoxy benzene, and the weight proportion of methyl-phenoxide and p-dimethyoxy benzene is: methyl-phenoxide: p-dimethyoxy benzene=1:0.3.Alicyclic ring alcohol is by trans-2-methylcyclopentanol and trans-1,2-cyclohexanediol composition, and trans-2-methylcyclopentanol and trans-1, the weight proportion of 2-cyclohexanediol is: trans-2-methylcyclopentanol: trans-1,2-cyclohexanediol=1:1.
In upper table, the addition of methanol gasoline quick-dissolving agent is the addition in 100mL methanol gasoline.
Embodiment 5
The difference of the present embodiment methanol gasoline quick-dissolving agent and embodiment 2 is: aromatic ketone is made up of diphenylmethanone and phenylbenzene ethyl ketone, and the weight proportion of diphenylmethanone and phenylbenzene ethyl ketone is: diphenylmethanone: phenylbenzene ethyl ketone=1:1.8.Alkane virtue mixed ether is made up of methyl-phenoxide and p-dimethyoxy benzene, and the weight proportion of methyl-phenoxide and p-dimethyoxy benzene is: methyl-phenoxide: p-dimethyoxy benzene=1:1.Alicyclic ring alcohol is by trans-2-methylcyclopentanol and trans-1,2-cyclohexanediol composition, and trans-2-methylcyclopentanol and trans-1, the weight proportion of 2-cyclohexanediol is: trans-2-methylcyclopentanol: trans-1,2-cyclohexanediol=1:1.5.
In upper table, the addition of methanol gasoline quick-dissolving agent is the addition in 100mL methanol gasoline.
Embodiment 6
The difference of the present embodiment methanol gasoline quick-dissolving agent and embodiment 3 is: aromatic ketone is made up of diphenylmethanone and phenylbenzene ethyl ketone, and the weight proportion of diphenylmethanone and phenylbenzene ethyl ketone is: diphenylmethanone: phenylbenzene ethyl ketone=1:1.5.Alkane virtue mixed ether is made up of methyl-phenoxide and p-dimethyoxy benzene, and the weight proportion of methyl-phenoxide and p-dimethyoxy benzene is: methyl-phenoxide: p-dimethyoxy benzene=1:0.7.Alicyclic ring alcohol is by trans-2-methylcyclopentanol and trans-1,2-cyclohexanediol composition, and trans-2-methylcyclopentanol and trans-1, the weight proportion of 2-cyclohexanediol is: trans-2-methylcyclopentanol: trans-1,2-cyclohexanediol=1:1.2.
In upper table, the addition of methanol gasoline quick-dissolving agent is the addition in 100mL methanol gasoline.
Embodiment 7
Methanol gasoline quick-dissolving agent, be made up of aromatic ketone, alkane virtue mixed ether, alicyclic ring alcohol and monocarboxylic acid, the weight proportion of aromatic ketone, alkane virtue mixed ether, alicyclic ring alcohol and monocarboxylic acid is: aromatic ketone: alkane virtue mixed ether: alicyclic ring alcohol: formic acid=1:0.1:2:0.2.
Aromatic ketone is made up of diphenylmethanone and phenylbenzene ethyl ketone, and the weight proportion of diphenylmethanone and phenylbenzene ethyl ketone is: diphenylmethanone: phenylbenzene ethyl ketone=1:1.2.Alkane virtue mixed ether is made up of methyl-phenoxide and p-dimethyoxy benzene, and the weight proportion of methyl-phenoxide and p-dimethyoxy benzene is: methyl-phenoxide: p-dimethyoxy benzene=1:0.3.Alicyclic ring alcohol is by trans-2-methylcyclopentanol and trans-1,2-cyclohexanediol composition, and trans-2-methylcyclopentanol and trans-1, the weight proportion of 2-cyclohexanediol is: trans-2-methylcyclopentanol: trans-1,2-cyclohexanediol=1:1.
In upper table, the addition of methanol gasoline quick-dissolving agent is the addition in 100mL methanol gasoline.
Embodiment 8
Methanol gasoline quick-dissolving agent, be made up of aromatic ketone, alkane virtue mixed ether, alicyclic ring alcohol and monocarboxylic acid, the weight proportion of aromatic ketone, alkane virtue mixed ether, alicyclic ring alcohol and monocarboxylic acid is: aromatic ketone: alkane virtue mixed ether: alicyclic ring alcohol: acetic acid=1:0.7:3.5:0.6.
Aromatic ketone is made up of diphenylmethanone and phenylbenzene ethyl ketone, and the weight proportion of diphenylmethanone and phenylbenzene ethyl ketone is: diphenylmethanone: phenylbenzene ethyl ketone=1:1.8.Alkane virtue mixed ether is made up of methyl-phenoxide and p-dimethyoxy benzene, and the weight proportion of methyl-phenoxide and p-dimethyoxy benzene is: methyl-phenoxide: p-dimethyoxy benzene=1:1.Alicyclic ring alcohol is by trans-2-methylcyclopentanol and trans-1,2-cyclohexanediol composition, and trans-2-methylcyclopentanol and trans-1, the weight proportion of 2-cyclohexanediol is: trans-2-methylcyclopentanol: trans-1,2-cyclohexanediol=1:1.5.
In upper table, the addition of methanol gasoline quick-dissolving agent is the addition in 100mL methanol gasoline.
Embodiment 9
Methanol gasoline quick-dissolving agent, be made up of aromatic ketone, alkane virtue mixed ether, alicyclic ring alcohol and monocarboxylic acid, the weight proportion of aromatic ketone, alkane virtue mixed ether, alicyclic ring alcohol and monocarboxylic acid is: aromatic ketone: alkane virtue mixed ether: alicyclic ring alcohol: formic acid=1:0.4:2.8:0.5.
Aromatic ketone is made up of diphenylmethanone and phenylbenzene ethyl ketone, and the weight proportion of diphenylmethanone and phenylbenzene ethyl ketone is: diphenylmethanone: phenylbenzene ethyl ketone=1:1.5.Alkane virtue mixed ether is made up of methyl-phenoxide and p-dimethyoxy benzene, and the weight proportion of methyl-phenoxide and p-dimethyoxy benzene is: methyl-phenoxide: p-dimethyoxy benzene=1:0.7.Alicyclic ring alcohol is by trans-2-methylcyclopentanol and trans-1,2-cyclohexanediol composition, and trans-2-methylcyclopentanol and trans-1, the weight proportion of 2-cyclohexanediol is: trans-2-methylcyclopentanol: trans-1,2-cyclohexanediol=1:1.2.
In upper table, the addition of methanol gasoline quick-dissolving agent is the addition in 100mL methanol gasoline.
Above-described embodiment is only for the invention example is clearly described, and the not restriction to the invention embodiment.For those of ordinary skill in the field, can also make other changes in different forms on the basis of the above description.Here without also giving exhaustive to all embodiments.And the apparent variation of being amplified out thus or variation are still among the protection domain in the invention claim.

Claims (7)

1. methanol gasoline quick-dissolving agent, it is characterized in that, be made up of aromatic ketone, alkane virtue mixed ether and alicyclic ring alcohol, aromatic ketone, alkane virtue mixed ether and alicyclic ring alcohol three's weight proportion is: aromatic ketone: alkane virtue mixed ether: alicyclic ring alcohol=1:(0.1~0.7): (2~3.5); Described aromatic ketone is one or both in diphenylmethanone and phenylbenzene ethyl ketone; Described alkane virtue mixed ether is one or both in methyl-phenoxide and p-dimethyoxy benzene; Described alicyclic ring alcohol is trans-2-methylcyclopentanol and trans-1, one or both in 2-cyclohexanediol.
2. methanol gasoline quick-dissolving agent according to claim 1, is characterized in that, aromatic ketone, alkane virtue mixed ether and alicyclic ring alcohol three's weight proportion is: aromatic ketone: alkane virtue mixed ether: alicyclic ring alcohol=1:0.5:2.6.
3. methanol gasoline quick-dissolving agent according to claim 1, it is characterized in that, aromatic ketone is made up of diphenylmethanone and phenylbenzene ethyl ketone, and the weight proportion of diphenylmethanone and phenylbenzene ethyl ketone is: diphenylmethanone: phenylbenzene ethyl ketone=1:(1.2~1.8).
4. methanol gasoline quick-dissolving agent according to claim 1, is characterized in that, alkane virtue mixed ether is made up of methyl-phenoxide and p-dimethyoxy benzene, and the weight proportion of methyl-phenoxide and p-dimethyoxy benzene is: methyl-phenoxide: p-dimethyoxy benzene=1:(0.3~1).
5. methanol gasoline quick-dissolving agent according to claim 1, it is characterized in that, alicyclic ring alcohol is by trans-2-methylcyclopentanol and trans-1,2-cyclohexanediol composition, trans-2-methylcyclopentanol and trans-1, the weight proportion of 2-cyclohexanediol is: trans-2-methylcyclopentanol: trans-1, and 2-cyclohexanediol=1:(1~1.5).
6. methanol gasoline quick-dissolving agent, it is characterized in that, be made up of aromatic ketone, alkane virtue mixed ether, alicyclic ring alcohol and monocarboxylic acid, the weight proportion of aromatic ketone, alkane virtue mixed ether, alicyclic ring alcohol and monocarboxylic acid is: aromatic ketone: alkane virtue mixed ether: alicyclic ring alcohol: monocarboxylic acid=1:(0.1~0.7): (2~3.5): (0.2~0.6); Described aromatic ketone is one or both in diphenylmethanone and phenylbenzene ethyl ketone; Described alkane virtue mixed ether is one or both in methyl-phenoxide and p-dimethyoxy benzene; Described alicyclic ring alcohol is trans-2-methylcyclopentanol and trans-1, one or both in 2-cyclohexanediol; Described monocarboxylic acid is formic acid or acetic acid.
7. methanol gasoline quick-dissolving agent according to claim 6, it is characterized in that, be made up of aromatic ketone, alkane virtue mixed ether, alicyclic ring alcohol and monocarboxylic acid, the weight proportion of aromatic ketone, alkane virtue mixed ether, alicyclic ring alcohol and monocarboxylic acid is: aromatic ketone: alkane virtue mixed ether: alicyclic ring alcohol: monocarboxylic acid=1:0.4:2.8:0.5.
CN201210425851.1A 2012-10-30 2012-10-30 Methanol gasoline instantizer Expired - Fee Related CN102899102B (en)

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CN1800312A (en) * 2005-07-29 2006-07-12 陈斌 Cleaning alcohol ether gasoline
CN1884449A (en) * 2006-07-09 2006-12-27 顾杏泉 Clean and environment-friendly methanol gasoline
CN100580064C (en) * 2007-08-21 2010-01-13 上海龙津石油有限公司 Methanol gasoline for vehicle
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