CN102898965A - High-temperature-resistant acrylic ester adhesive - Google Patents
High-temperature-resistant acrylic ester adhesive Download PDFInfo
- Publication number
- CN102898965A CN102898965A CN2012103602329A CN201210360232A CN102898965A CN 102898965 A CN102898965 A CN 102898965A CN 2012103602329 A CN2012103602329 A CN 2012103602329A CN 201210360232 A CN201210360232 A CN 201210360232A CN 102898965 A CN102898965 A CN 102898965A
- Authority
- CN
- China
- Prior art keywords
- parts
- temperature
- acrylic ester
- resistant acrylic
- adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention relates to a high-temperature-resistant acrylic ester adhesive which comprises the components in parts by weight: 100-120 parts of acrylic ester copolymer, 2-5 parts of toluene diisocyanate-trimethylolpropane adduct, 15-20 parts of polymerized rosin pentaerythritol ester, 50-70 parts of hydrogen peroxide, 0.02-0.05 part of azodiisobutyronitrile, 0.5-1 part of lauryl mercaptan, 10-20 parts of acetic acid vinyl ester and 0.2-1.0 part of emulsifying agent. The high-temperature-resistant acrylic ester adhesive can be used for bonding metal or silicate material. The high-temperature-resistant acrylic ester is also used for bonding steel at the temperature of 80 DEG C and has the adhesive strength of 6MPa. The adhesive strength of the high-temperature-resistant acrylic ester adhesive for cement reaches 10MPa.
Description
Technical field
The invention belongs to the sizing agent technical field, relate in particular to a kind of high-temperature resisting acrylate sizing agent.
Background technology
Existing high-temperature-resistant adhesive, it is a kind of high-temperature resistant nano compound binding agent that utilizes nano material to make through polycondensation, by the screening to composition proportion and preparation technology parameter, obtaining binding agent is that the pH value is neutral suspended dispersed system, not only cohesive force is strong and to the metallic matrix non-corrosiveness, and keep good adhesiveproperties and erosion resistance, long service life under the high temperature again.The high temperature resistant inorganic tackiness agent is easy to use; can be used for the directly bonding of high temperature material; coating can spray by direct high temperature matrix surface at 400-1000 ℃; in moisture evaporation; coating can stick to matrix surface moment; the high temperature resistant supercoat even compact that forms, thermal shock resistance is good, and protection effect is remarkable.But mostly above-mentioned tackiness agent is that inorganic materials makes, relatively poor to the bonding effect of specialty metal and silicate material.
Summary of the invention
The technical problem that solves:The invention provides a kind of high temperature resistant acrylate adhesive, this tackiness agent can be used for the bonding of metal or silicate material.
Technical scheme:High temperature resistant acrylate adhesive, comprise 100～120 parts of acrylate copolymers in mass parts, 2～5 parts of tolylene diisocyanate-trimethylolpropane adduct, 15～20 parts of polymerized rosin pentaerythritol esters, also contain 50～70 parts of hydrogen peroxide, 0.02～0.05 part of Diisopropyl azodicarboxylate, 0.5～1 part of lauryl mercaptan, 10～20 parts of vinyl-acetic esters, 0.2～1.0 part of emulsifying agent.
Preferred version 1: 60 parts of described hydrogen peroxide, 0.03 part of Diisopropyl azodicarboxylate, 0.8 part of lauryl mercaptan, 15 parts of vinyl-acetic esters, 0.5 part of emulsifying agent.
Preferred version 2: 110 parts of described acrylate copolymers, 3 parts of tolylene diisocyanate-trimethylolpropane adduct, 15 parts of polymerized rosin pentaerythritol esters, 60 parts of described hydrogen peroxide, 0.03 part of Diisopropyl azodicarboxylate, 0.8 part of lauryl mercaptan, 15 parts of vinyl-acetic esters, 0.5 part of emulsifying agent.
Beneficial effect:High temperature resistant acrylate adhesive provided by the invention can be used for the bonding of metal or silicate material.Can carry out bondingly under 80 ℃ to steel, and bond strength reaches 6MPa.Bond strength for cement can reach 10MPa.
Embodiment
Embodiment 1
High temperature resistant acrylate adhesive, comprise 100～120 parts of acrylate copolymers in mass parts, 2～5 parts of tolylene diisocyanate-trimethylolpropane adduct, 15～20 parts of polymerized rosin pentaerythritol esters, 60 parts of hydrogen peroxide, 0.03 part of Diisopropyl azodicarboxylate, 0.8 part of lauryl mercaptan, 15 parts of vinyl-acetic esters, 0.5 part of emulsifying agent.This high temperature resistant acrylate adhesive can be used for the bonding of metal or silicate material.Can carry out bondingly under 80 ℃ to steel, and bond strength reaches 6MPa.
Embodiment 2
High temperature resistant acrylate adhesive, comprise 110 parts of acrylate copolymers in mass parts, 3 parts of tolylene diisocyanate-trimethylolpropane adduct, 15 parts of polymerized rosin pentaerythritol esters, 60 parts of described hydrogen peroxide, 0.03 part of Diisopropyl azodicarboxylate, 0.8 part of lauryl mercaptan, 15 parts of vinyl-acetic esters, 0.5 part of emulsifying agent.This high temperature resistant acrylate adhesive can be used for the bonding of cement, and intensity can reach 10MPa.
Claims (3)
1. high temperature resistant acrylate adhesive, comprise 100～120 parts of acrylate copolymers in mass parts, 2～5 parts of tolylene diisocyanate-trimethylolpropane adduct, 15～20 parts of polymerized rosin pentaerythritol esters, it is characterized in that also containing 50～70 parts of hydrogen peroxide, 0.02～0.05 part of Diisopropyl azodicarboxylate, 0.5～1 part of lauryl mercaptan, 10～20 parts of vinyl-acetic esters, 0.2～1.0 part of emulsifying agent.
2. high temperature resistant acrylate adhesive according to claim 1 is characterized in that 60 parts of described hydrogen peroxide, 0.03 part of Diisopropyl azodicarboxylate, 0.8 part of lauryl mercaptan, 15 parts of vinyl-acetic esters, 0.5 part of emulsifying agent.
3. high temperature resistant acrylate adhesive according to claim 2 is characterized in that 110 parts of described acrylate copolymers, 3 parts of tolylene diisocyanate-trimethylolpropane adduct, 15 parts of polymerized rosin pentaerythritol esters.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103602329A CN102898965A (en) | 2012-09-25 | 2012-09-25 | High-temperature-resistant acrylic ester adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103602329A CN102898965A (en) | 2012-09-25 | 2012-09-25 | High-temperature-resistant acrylic ester adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102898965A true CN102898965A (en) | 2013-01-30 |
Family
ID=47571462
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012103602329A Pending CN102898965A (en) | 2012-09-25 | 2012-09-25 | High-temperature-resistant acrylic ester adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102898965A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103911856A (en) * | 2013-12-28 | 2014-07-09 | 苏州华策纺织科技有限公司 | Wool-like fancy suiting softener |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6964999B1 (en) * | 1998-02-27 | 2005-11-15 | Kaneka Corporation | Polymer and curable composition |
| CN1701106A (en) * | 2003-03-20 | 2005-11-23 | Lg化学株式会社 | Pressure sensitive adhesive composition for electro-magnetic shielding film and electro-magnetic shielding filter using the same |
-
2012
- 2012-09-25 CN CN2012103602329A patent/CN102898965A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6964999B1 (en) * | 1998-02-27 | 2005-11-15 | Kaneka Corporation | Polymer and curable composition |
| CN1701106A (en) * | 2003-03-20 | 2005-11-23 | Lg化学株式会社 | Pressure sensitive adhesive composition for electro-magnetic shielding film and electro-magnetic shielding filter using the same |
Non-Patent Citations (2)
| Title |
|---|
| 宋小平等: "《胶黏剂实用配方与生产工艺》", 31 May 2010, 中国纺织出版社 * |
| 李子东等: "《胶黏剂助剂》", 28 February 2005, 化学工艺出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103911856A (en) * | 2013-12-28 | 2014-07-09 | 苏州华策纺织科技有限公司 | Wool-like fancy suiting softener |
| CN103911856B (en) * | 2013-12-28 | 2016-09-07 | 苏州华策纺织科技有限公司 | Long fancy suiting softening agent in one |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| MY153907A (en) | Fusion bonded epoxy coating compositions that include magnesium oxide | |
| CN106752964B (en) | A kind of graphene abrasion resistant fire blocking anti-corrosive powder paint and preparation method thereof | |
| CN103058607B (en) | Binder for installation of thermal insulation decorative plate | |
| CN104559365A (en) | Building corrosion preventing composite coating | |
| CN105802421A (en) | Damping fireproof coating and preparing method thereof | |
| CN102898965A (en) | High-temperature-resistant acrylic ester adhesive | |
| CN103059653A (en) | JS waterproof coating | |
| CN105084922A (en) | Thermal radiation coating for kiln | |
| CN105385387A (en) | Hot-melt adhesive | |
| CN106811149B (en) | A kind of sprayable hot melt adhesive and preparation method thereof | |
| CN104861867B (en) | The preparation method of a kind of novel acid-proof abrasion-resistant coating and using method | |
| CN105131850B (en) | A kind of self-adhering environmental protection damping slab rubber and preparation method thereof | |
| CN110183585A (en) | A kind of preparation method and bi-component neoprene of the modified neoprene can be improved metal cohesive force | |
| CN102898978A (en) | Strong glue for pasting plastic | |
| CN109385216A (en) | A kind of interior plate fire prevention gap-filling glue | |
| CN105621973A (en) | High-performance wall insulation material | |
| CN104388019A (en) | Hot melt adhesive | |
| CN106277948A (en) | High temperature abrasion material | |
| JPS59156967A (en) | Sio2-cao-li2o low expansion flame spray material | |
| CN108587379A (en) | A kind of easily peelable enhanced coating and preparation method thereof | |
| CN104449479A (en) | High-temperature fireproof glue | |
| CN102993888A (en) | Heat-insulation waterproof paint for buildings | |
| CN111032596B (en) | Spray coating material for hot repair | |
| CA2437617A1 (en) | Process for joining solid-state compositions | |
| CN103374315A (en) | Reinforced latex |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20130130 |