CN102887526B - Aluminosilicate mesoporous material and synthesis method thereof - Google Patents
Aluminosilicate mesoporous material and synthesis method thereof Download PDFInfo
- Publication number
- CN102887526B CN102887526B CN201110204917.XA CN201110204917A CN102887526B CN 102887526 B CN102887526 B CN 102887526B CN 201110204917 A CN201110204917 A CN 201110204917A CN 102887526 B CN102887526 B CN 102887526B
- Authority
- CN
- China
- Prior art keywords
- mesoporous material
- aluminate
- silico
- preparation
- silicon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000013335 mesoporous material Substances 0.000 title claims abstract description 38
- 229910000323 aluminium silicate Inorganic materials 0.000 title abstract 8
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 title abstract 8
- 238000001308 synthesis method Methods 0.000 title abstract 2
- 239000011148 porous material Substances 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 15
- 239000010703 silicon Substances 0.000 claims description 15
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 13
- 241000282326 Felis catus Species 0.000 claims description 11
- 238000002360 preparation method Methods 0.000 claims description 11
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 239000004411 aluminium Substances 0.000 claims description 7
- 239000003513 alkali Substances 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 6
- 239000011707 mineral Substances 0.000 claims description 6
- 238000003786 synthesis reaction Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 238000002425 crystallisation Methods 0.000 claims description 4
- 230000008025 crystallization Effects 0.000 claims description 4
- 150000002500 ions Chemical class 0.000 claims description 4
- -1 silicon ester Chemical class 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 150000004645 aluminates Chemical class 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 159000000013 aluminium salts Chemical class 0.000 claims description 2
- 229910000329 aluminium sulfate Inorganic materials 0.000 claims description 2
- 235000019353 potassium silicate Nutrition 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 6
- 238000010521 absorption reaction Methods 0.000 abstract description 3
- 238000006555 catalytic reaction Methods 0.000 abstract description 3
- 239000003814 drug Substances 0.000 abstract description 3
- 238000001027 hydrothermal synthesis Methods 0.000 abstract description 2
- 239000003093 cationic surfactant Substances 0.000 abstract 1
- 238000013270 controlled release Methods 0.000 abstract 1
- 150000007529 inorganic bases Chemical class 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 230000002194 synthesizing effect Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 230000005540 biological transmission Effects 0.000 description 5
- 229910004298 SiO 2 Inorganic materials 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 238000010189 synthetic method Methods 0.000 description 4
- 238000004375 physisorption Methods 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000004438 BET method Methods 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000009415 formwork Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 238000001988 small-angle X-ray diffraction Methods 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
Landscapes
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
The invention relates to a disk type aluminosilicate mesoporous material with an annular pore structure and a synthesis method of the disk type aluminosilicate mesoporous material. The disk type aluminosilicate mesoporous material has an annular pore structure, wherein the disk diameter of the disk type aluminosilicate mesoporous material is about 60-80nm, the diameter of an annular pore is about 3-5nm, the pore wall thickness is 4-6nm, and the disk type aluminosilicate mesoporous material has a specific surface area being about 500-1200m<2>.g<-1> and a pore volume being 0.70-1.30cm<3>.g<-1>. A dimeric cationic surfactant is used as a structure directing agent, under the condition of the existence of inorganic base, the disk type aluminosilicate mesoporous material with the annular pore structure is obtained through a hydro-thermal synthesis method. The disk type aluminosilicate mesoporous material with the annular pore structure has a wide application prospect in fields such as catalysis, absorption and separation, medicine controlled release, and electronic sensing and can be used as templates for synthesizing other materials.
Description
Technical field
The present invention relates to a kind of inorganic porous material and synthetic method thereof, particularly a kind of silico-aluminate mesoporous material and synthetic method thereof.
Background technology
Mesoporous material is owing to having the features such as larger specific surface area and pore volume, adjustable aperture and pore structure, controllable pattern and modifiable surface properties, thus in catalysis, absorption and separate, medicament slow release, electronic sensor and have potential application prospect as every field such as the templates of synthetic other materials.
In synthesize meso-porous material, under general condition, all to use organic formwork agent as structure directing agent.The structure directing agent that people often adopt mainly comprises cats product, anion surfactant and nonionogenic tenside.Document Nature 359,710-712 (1992) has reported that use cats product has synthesized the irregular SiO 2 mesoporous materials of pattern.Document Science 273,768-771 (1996) has reported that guiding has synthesized the SiO 2 mesoporous materials of hollow sphere by controlling oil-water interface.Document Science 282,1302-1305 (1998) has reported that having used neutral double type synthesis of surfactant has a SiO 2 mesoporous materials of imitated vesicle structure.Recently, document Adv.Funct.Mater., 14,507-512 (2004) has reported that having used asymmetric double subtype synthesis of surfactant has a stratiform SiO 2 mesoporous materials of striped pore passage structure.In addition, document J.Am.Chem.Soc., 132,15144-15147 (2010) has reported that use segmented copolymer and cats product are as double template, has synthesized the spherical material of silicon-dioxide with two mesopore orbits, nucleocapsid structure.But up to now, the synthetic method with the disc-shaped silico-aluminate mesoporous material of annulus structure there is no report in document and patent at home and abroad.
Summary of the invention
The object of the invention is to propose a kind of method of the synthetic disc-shaped silico-aluminate mesoporous material with annulus structure.
The feature of silico-aluminate mesoporous material of the present invention is as follows:
Its chemical constitution is: Si
xalO
ywherein, X=1-500; Y=2X+1.5;
It is to have annulus structure, is the silico-aluminate mesoporous material that disc-shaped or disc-shaped are assembled.Wherein, the diameter of the annulus of this material is about 3-5nm, and pore wall thickness is 4-6nm, and the diameter of disk is 60-80nm, and specific surface area is 500-1300m
2g
-1, pore volume is 0.70-1.30cm
3g
-1.
The disc-shaped silico-aluminate mesoporous material with annulus structure of the present invention adopts double type cats product as structure directing agent, under the existence condition of mineral alkali, obtains by the method for Hydrothermal Synthesis.
Specifically comprise following process and step:
1) preparation of initial gel:
He Lv source, silicon source is joined in a certain amount of water according to a certain percentage, after stirring, under 20～60 DEG C of continuous stirring conditions, add mineral alkali regulation system pH value to alkalescence, add again afterwards double type cats product, continue to stir 1～8h, obtain initial gel; The silicon of reaction colloidal sol: aluminium: water: the molar ratio of double type positively charged ion template is 1: 0.002-1: 20-10000: 0.025-0.20.
2) hydrothermal crystallizing:
The reaction colloidal sol that step 1 is made is transferred in Autoclaves for synthesis, in 90～130 DEG C, and hydrothermal crystallizing 1～6 day under autogenous pressure.
3) dry and roasting:
By product good step 2 hydrothermal crystallizing through washing and filtering, and at 100～120 DEG C dry 12～48h, finally in retort furnace, at 500～650 DEG C, calcine 4～12h, remove double type cats product, must there is the disc-shaped silico-aluminate mesoporous material of annulus structure.
The pH value of reacting colloidal sol in step 1 of the present invention is 8-13.
In step 1 of the present invention, react the silicon of colloidal sol: aluminium: water: the preferred molar ratio example of double type positively charged ion template is 1: 0.01-0.1: 100-1000: 0.05-0.10.
Mineral alkali used in the present invention is sodium hydroxide and/or potassium hydroxide.
Silicon used in the present invention source is one or more the mixture in silicon sol, silicon gel, water glass, active silica or positive silicon ester; Aluminium source is one or more the mixture in aluminium salt, aluminate, activated alumina or aluminum alkoxide.
Double type cats product used herein is [C
mh
2m+1n (CH
3)
2-(CH
2)
s-N (CH
3)
2c
mh
2m+1] X
2, be abbreviated as [Cm-s-m] X
2, wherein m=12,14,16,18, s=2,3,4,5, X is Cl
-, Br
-or OH
-.
The disc-shaped silico-aluminate mesoporous material with annulus structure of the present invention can be applicable to catalysis, absorption and separate, medicament slow release, electronic sensor and as fields such as the templates of synthetic other materials.
Brief description of the drawings
Fig. 1 is the typical transmission electron microscope picture that the sample 8 that obtains in 1 in embodiment has the silico-aluminate mesoporous material of annulus structure.
Fig. 2 is the typical scan Electronic Speculum figure that the sample 11 that obtains in 1 in embodiment has the silico-aluminate mesoporous material of annulus structure.
Fig. 3 is the Small angle XRD diffracting spectrum that the sample 1-12 that obtains in 1 in embodiment has the silico-aluminate mesoporous material of annulus structure.
Embodiment
Below by embodiment, the present invention is further elaborated, but the present invention is not limited to these embodiment.
Embodiment 1
According to a certain percentage aluminium source, silicon source are joined in deionized water, under stirring, make it even, add afterwards a certain amount of mineral alkali, regulate the pH value of reaction colloidal sol to pH=8～13, add again afterwards a certain amount of double type cats product, continue to stir 1～8h, obtain initial gel.By make mix after reaction colloidal sol move in stainless steel Autoclaves for synthesis and seal, in 90～130 DEG C, hydrothermal crystallizing 1～6 day under autogenous pressure.By solid product centrifugation good hydrothermal crystallizing, extremely neutral with deionized water wash, air drying 12～48h at 100～120 DEG C, and in finally calcining 4～12h at 500～650 DEG C in retort furnace, remove double type cats product, obtain having the disc-shaped silico-aluminate mesoporous material of annulus structure.The corresponding relation of pH value after proportioning raw materials in sample number into spectrum and initial gel, the sodium hydroxide that is used for adjusting initial pH of latex gel value and/or potassium hydroxide, adjustment, crystallization temperature, crystallization time is as shown in table 1.
Table 1: the corresponding relation of sample number into spectrum and preparation condition
Embodiment 2
Sample prepared in embodiment 1 is carried out to transmission electron microscope sign.Institute's employing instrument is JEOLJEM-2000EX transmission electron microscope, and instrument operating voltage is 120kV.Transmission electron microscope picture shows, all samples all has annulus structure, and the diameter of annulus is 3-5nm, and pore wall thickness is 4-6nm, and the diameter of disk is 60-80nm.Typical case annular pore passage structure transmission electron microscope picture taking sample 8 as representative, as shown in Figure 1.
Embodiment 3
Sample prepared in embodiment 1 is carried out to scanning electron microscope sign.Institute's employing instrument is FEIQuanta 200F scanning electron microscope, and acceleration voltage is 200V-30kV.Scanning Electron Microscope photos reveal, all samples pattern is all the gathering of disc-shaped or disc-shaped.Typical scanning electron microscope (SEM) photograph taking sample 11 as representative, as shown in Figure 2.
Embodiment 4
Sample 1-12 prepared in embodiment 1 is carried out to little angle XRD to be characterized.Institute's employing instrument is Philips X ' Pert PROX type X-ray diffractometer, and instrument operating voltage is 40kv, and working current is 40mA.The little angle XRD result obtaining as shown in Figure 3.Sample 1-12 in 2 θ=2 ° and 4 ° located all to occur intensity diffraction peak not etc., can be attributed to the diffraction peak of annular mesopore orbit; Wherein first diffraction peak of sample 11 appears at the position of 2 θ=2.5, and peak type is wider, the relative irregularity of meso-hole structure of interpret sample 11; Sample 12, in the diffraction peak of 2 θ=1, can be attributed to the layered mesoporous structure that disc-shaped sample stacking forms.
Embodiment 5
Sample 1-12 prepared in embodiment 1 is carried out to nitrogen physisorption to be characterized.Institute's employing instrument is Micromeritics Tristar3000 type nitrogen physisorption instrument.Before carrying out nitrogen physisorption sign, the sample 1-12 obtaining need to carry out pre-treatment.Pretreatment condition is as follows: at normal temperatures sieve sample is vacuumized; When reaching after vacuum condition, process 1h at 130 DEG C; Process 2h at 350 DEG C afterwards.Specific surface is tried to achieve by BET method, and pore volume is calculated by the adsorptive capacity of 0.99 correspondence of relative pressure in nitrogen adsorption isotherm.Specific surface area and the pore volume of the sample obtaining are as shown in table 2.From table 2, data can be found out, this mesoporous material has larger specific surface area and pore volume, can be used as adsorption separating agent and support of the catalyst.
Table 2: the specific surface area of gained sample and pore volume
| Sample number into spectrum | Specific surface area (m 2/g) | Pore volume (cm 3/g) |
| 1 | 576 | 0.73 |
| 2 | 724 | 0.83 |
| 3 | 900 | 1.10 |
| 4 | 1236 | 1.25 |
| 5 | 637 | 0.78 |
| 6 | 786 | 0.86 |
| 7 | 857 | 0.92 |
| 8 | 952 | 1.02 |
| 9 | 1.36 | 1.10 |
| 10 | 1064 | 1.17 |
| 11 | 1158 | 1.23 |
| 12 | 1276 | 1.28 |
Claims (8)
1. a preparation method for silico-aluminate mesoporous material, is characterized in that, described silico-aluminate mesoporous material has annular mesopore orbit structure, and pattern is the gathering of disc-shaped or disc-shaped, and its chemical constitution is:
Si
xalO
ywherein, X=1-1000; Y=2X+1.5,
The synthesis step of described silico-aluminate mesoporous material is as follows:
(1) preparation of initial gel: He Lv source, silicon source is added in a certain amount of water according to a certain percentage, after stirring, under 20～60 DEG C of continuous stirring conditions, add mineral alkali regulation system pH value to alkalescence, add again afterwards double type cats product, continue to stir 1～8h, obtain initial gel, silicon in described initial gel: aluminium: water: the molar ratio of double type positively charged ion template is 1:0.002-1:20-10000:0.025-0.2;
(2) hydrothermal crystallizing: the initial gel that step (1) is made is transferred in Autoclaves for synthesis, under 90～130 DEG C of autogenous pressures, hydrothermal crystallizing 1～6 day, obtains crystallization product;
(3) dry and roasting: by the crystallization product obtaining in step (2) through washing, filter, at 100～120 DEG C after dry 12～48h, roasting 4～12h at 500～650 DEG C, obtains described mesoporous aluminoshilicate material,
Wherein said double type cats product molecular formula is:
[C
mH
2m+1N(CH
3)
2-(CH
2)
S-N(CH
3)
2C
mH
2m+1]·X
2，
Wherein, m=12,14,16,18; S=2,3,4,5; X is Cl
-, Br
-or OH
-.
2. the preparation method of silico-aluminate mesoporous material according to claim 1, is characterized in that, the diameter of described annular mesopore orbit is 3～5nm, and pore wall thickness is 4-6nm.
3. the preparation method of silico-aluminate mesoporous material according to claim 1, is characterized in that, described disk diameter is 60-80nm.
4. the preparation method of silico-aluminate mesoporous material according to claim 1, is characterized in that, specific surface area is 500-1300m
2g
-1, pore volume is 0.70-1.30cm
3g
-1.
5. the preparation method of silico-aluminate mesoporous material according to claim 1, is characterized in that, described mineral alkali is sodium hydroxide and/or potassium hydroxide.
6. the preparation method of silico-aluminate mesoporous material according to claim 1, is characterized in that, described silicon source is one or more the mixture in silicon sol, silicon gel, water glass, white carbon black, active silica or positive silicon ester; Described aluminium source is one or more the mixture in aluminium salt, aluminate, aluminum oxyhydroxide, activated alumina or aluminum alkoxide.
7. the preparation method of silico-aluminate mesoporous material according to claim 1, is characterized in that, the pH value of described initial gel is 8-13.
8. the preparation method of silico-aluminate mesoporous material according to claim 1, is characterized in that, silicon in described initial gel: aluminium: water: the molar ratio of double type positively charged ion template is 1:0.01-0.1:100-1000:0.05-0.10.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110204917.XA CN102887526B (en) | 2011-07-20 | 2011-07-20 | Aluminosilicate mesoporous material and synthesis method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110204917.XA CN102887526B (en) | 2011-07-20 | 2011-07-20 | Aluminosilicate mesoporous material and synthesis method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102887526A CN102887526A (en) | 2013-01-23 |
| CN102887526B true CN102887526B (en) | 2014-10-08 |
Family
ID=47531233
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110204917.XA Expired - Fee Related CN102887526B (en) | 2011-07-20 | 2011-07-20 | Aluminosilicate mesoporous material and synthesis method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102887526B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105694846B (en) * | 2016-03-28 | 2019-07-05 | 华中科技大学 | A kind of hydridization supermolecule room temperature phosphorimetry material and preparation method thereof |
| CN109665542B (en) * | 2017-10-17 | 2022-07-12 | 中国石油化工股份有限公司 | Layered molecular sieve and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101108736A (en) * | 2006-07-21 | 2008-01-23 | 中国石油天然气集团公司 | Method of manufacturing Y type molecular sieve having micropore and mesohole at the same time |
-
2011
- 2011-07-20 CN CN201110204917.XA patent/CN102887526B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101108736A (en) * | 2006-07-21 | 2008-01-23 | 中国石油天然气集团公司 | Method of manufacturing Y type molecular sieve having micropore and mesohole at the same time |
Non-Patent Citations (6)
| Title |
|---|
| Aluminum In corporation into MCM-48 toward the Creation of Bronsted Acidity;Olivier Collart et al.;《Journal of Physics chemistry B》;20040824;第108卷;第13905－13912页 * |
| Hydrothermally Stable Ordered Hexagonal Mesoporous Aluminosilicates Assembled from a Triblock Copolymer and Preformed Aluminosilicate Precursors in Strongly Acidic Media;Yu Han et al.;《Chemistry of Materials》;20020201;第14卷;第1144－1148页 * |
| Olivier Collart et al..Aluminum In corporation into MCM-48 toward the Creation of Bronsted Acidity.《Journal of Physics chemistry B》.2004,第108卷第13905－13912页. |
| Sean M.Solberg et al..synthesis and Reactivity of Al-MMM-2: A New Microporous/Mesoporous Catalyst for the Alkylation of Toluene.《Journal of Inorganic and Organometallic Polymers and Materials》.2007,第17卷(第2期), |
| synthesis and Reactivity of Al-MMM-2: A New Microporous/Mesoporous Catalyst for the Alkylation of Toluene;Sean M.Solberg et al.;《Journal of Inorganic and Organometallic Polymers and Materials》;20070630;第17卷(第2期);第469－475页 * |
| Yu Han et al..Hydrothermally Stable Ordered Hexagonal Mesoporous Aluminosilicates Assembled from a Triblock Copolymer and Preformed Aluminosilicate Precursors in Strongly Acidic Media.《Chemistry of Materials》.2002,第14卷 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102887526A (en) | 2013-01-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Kim et al. | Synthesis of highly ordered mesoporous silica materials using sodium silicate and amphiphilic block copolymers | |
| CN104340991A (en) | Method for preparing ZSM-5 zeolite molecular sieve, product and purpose thereof | |
| CN107285332B (en) | Synthesis method of ZSM-22 molecular sieve and ZSM-22 molecular sieve synthesized by same | |
| CN107285330B (en) | A kind of preparation method of NU-88 molecular sieve | |
| CN108502897B (en) | Photochemical green synthesis method of Zr-doped SBA-15 mesoporous molecular sieve material | |
| JP3274867B2 (en) | Method for preparing mesoporous crystalline material | |
| CN102887526B (en) | Aluminosilicate mesoporous material and synthesis method thereof | |
| WO2003037511A1 (en) | Method of preparing highly ordered mesoporous molecular sieves | |
| CN112978756A (en) | Flaky TS-1 molecular sieve, and preparation method and application thereof | |
| Bao et al. | Synthesis of hydrophobic alumina aerogel with surface modification from oil shale ash | |
| CN109867293B (en) | Synthesis method of morphology-adjustable NaP type molecular sieve | |
| CN107151022B (en) | Mesoporous P-IM-5 molecular sieve, and preparation method and application thereof | |
| CN102674384B (en) | Hydrotalcite like compound-kaolin composite material and preparation method thereof | |
| CN109694086B (en) | Preparation method of nano ZSM-5 zeolite molecular sieve aggregate | |
| Lyu et al. | Selective cyclohexane oxidation over vanadium incorporated silica pillared clay catalysts: The effect of VOx content and dispersion | |
| JP2010155759A (en) | Method for synthesizing mesoporous aluminosilicate | |
| JP5766067B2 (en) | Method for synthesizing alumina-containing mesoporous material and alumina-containing mesoporous material | |
| CN110357123A (en) | A kind of high crystalline multi-stage porous nano X-type molecular sieve and preparation method thereof | |
| CN101417810A (en) | Mesoporous material and preparation method thereof | |
| CN101264929B (en) | Method for synthesizing mesoporous nano material by adopting solid state reaction structure guiding technology | |
| CN105732693B (en) | A kind of bisamide bond distance carbochain organosilan quaternary ammonium compound and its preparation and application | |
| CN109019629A (en) | A kind of FER molecular sieve synthetic method that external surface area is controllable | |
| JP2024511701A (en) | Porous calcium silicate hydrate, its preparation method, adsorbent and its application | |
| CN113336240A (en) | Method for preparing single/double crystal ZSM-5 zeolite based on kaolin mineral regulation and control | |
| CN107297220A (en) | A kind of worm meso-porous Al2O3/ molecular sieves compound material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20141008 |