CN102878821A - Smoke purifying and waste heat recycling device for low-grade composition brass smelting and control method of smoke purifying and waste heat recycling device - Google Patents

Smoke purifying and waste heat recycling device for low-grade composition brass smelting and control method of smoke purifying and waste heat recycling device Download PDF

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Publication number
CN102878821A
CN102878821A CN2012104092959A CN201210409295A CN102878821A CN 102878821 A CN102878821 A CN 102878821A CN 2012104092959 A CN2012104092959 A CN 2012104092959A CN 201210409295 A CN201210409295 A CN 201210409295A CN 102878821 A CN102878821 A CN 102878821A
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flue
smoke
waste heat
flue gas
boiler
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CN2012104092959A
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黄斌
陈波
周瑞生
涂建华
王伟
肖会勇
付晓光
孙宝华
周荣欢
杨平
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GUANGXI NONFERROUS RECYCLE METALS CO Ltd
China Nerin Engineering Co Ltd
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GUANGXI NONFERROUS RECYCLE METALS CO Ltd
China Nerin Engineering Co Ltd
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Priority to CN2012104092959A priority Critical patent/CN102878821A/en
Publication of CN102878821A publication Critical patent/CN102878821A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

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  • Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)

Abstract

Disclosed is a smoke purifying and waste heat recycling device for low-grade composition brass smelting. A top-blown converter of the smoke purifying and waste heat recycling device is in a shape with bigger middle part and smaller round ends, a flue-type waste heat boiler is arranged at a smoke outlet at the top end of the top-blown converter, a water cooled furnace wall of the waste heat boiler is provided with an oxygen enrichment nozzle and a vibrating spring, an oxygen online detector is arranged at an outlet of the waste heat boiler, the flue-type waste heat boiler is connected with a spray cooling tower which is a connected with a plate-type cooler via a smoke pipe, the plate-type cooler is connected with a bag collector via an outlet smoke pipe, the smoke pipe between the plate-type cooler and the bag collector is provided with an activated carbon jet device and a shock cooling air suction valve, an outlet of the bag collector is connected with a smoke exhaust fan, and an outlet of the smoke exhaust fan is connected with the lower end of a chimney. By the aid of the smoke purifying and waste heat recycling device, temperature of the smoke can be lowered to below 170 DEG C, waste heat in the smoke can be recycled, halogen in the smoke can be prevented from corroding inner walls of the boiler, running life of the boiler can be prolonged, valuable metal in the smoke can be recycled, and contained dust in exhausted smoke is enabled to be lower than 25mg/Nm<3>.

Description

The purification of low-grade composition brass flue gas during smelting, waste-heat recovery device and control method thereof
One, technical field
The present invention relates to the flue gas purifying equipment technical field, particularly a kind of low-grade composition brass flue gas during smelting purification, exhaust heat recovering method and device.
Two, background technology
Along with to the lasting exploitation of copper ore resource so that copper mine faces exhausted edge, report by the mineral products general view that U.S. mineral office delivered in 1993, the reserves of World Nonferrous Metals are by expense, the spendable time limit of copper only is 45 years, especially in the country of copper resource shortage, more need to strengthen the recycling dynamics of useless composition brass.At present, low-grade composition brass is recycled the blast furnaces that adopt more, and reverberatory furnace technology, technology level are low, and metal recovery rate is low, unstable product quality, and particularly environmental issue is serious.Smelt useless composition brass equipment top-blown converter, can adapt to various complicated raw materials, the rate of recovery is high, can produce as required blister copper or copper alloy, flue-gas temperature is up to 1100 ℃ during work, waste heat has very high recovery value, but useless composition brass source is numerous and diverse, often contain organic matter in the raw material, top-blown converter produces a large amount of high-temperature dust-containing flue gas in the process of operation, contain a small amount of Cl in the flue gas, the halogens such as Br, halogen easily corrodes boiler inner wall under HTHP, and in the raw materials temperature-rise period, the partial organic substances incomplete combustion generates intermediate product and enters flue gas, in the process of low temperature reduction, these organic intermediate products stop enough times at 250 ℃~600 ℃ to flue gas, also can produce dioxin by high temperature simultaneously, environmental pollution is very big, also there is not at present the flue gas waste heat recovery technology and equipment under the above-mentioned specified conditions, both at home and abroad constantly exploration of the same trade, research, test, but effect is always not ideal.
Three, summary of the invention
The object of the present invention is to provide a kind of low-grade composition brass flue gas during smelting purification, waste heat recovery system device, this device can drop to below 170 ℃ from 1100 ℃ smelting low-grade useless composition brass flue-gas temperature, a large amount of waste heat in the recovered flue gas, produce saturated vapor required for the electrolysis production heating, reach energy-conservation purpose; Stop the flue gas halogen to the corrosion of boiler inner wall, prolong waste heat boiler service life; The generation of dioxin gas in the containment flue gas, the valuable metal in the recovered flue gas makes the discharged gas fume dust-laden less than 25mg/Nm 3
The present invention is achieved through the following technical solutions above-mentioned purpose: a kind of low-grade composition brass flue gas during smelting purifies, waste-heat recovery device, comprise top-blown converter, flue type waste heat boiler, rich-oxygen nozzle, the rapping spring, the oxygen on-line detector, spray cooling tower, panel cooler, the active carbon injection apparatus, the quench air inlet valve, bagroom, smoke exhaust fan and chimney, described top-blown converter is two broad in the middle roundlet shape, flue type waste heat boiler is placed in top-blown converter top smoke outlet, the waste heat boiler water-cooling wall is equipped with rich-oxygen nozzle and rapping spring, the oxygen on-line detector is equipped with in the exit, flue type waste heat boiler links to each other with spray cooling tower, spray cooling tower links to each other with panel cooler by smoke pipe, panel cooler is connected with bagroom by the outlet smoke pipe, flue is provided with active carbon injection apparatus and quench air inlet valve in the middle of panel cooler and the bagroom, the bagroom outlet is connected with smoke exhaust fan, and the smoke exhaust fan outlet is connected into the chimney lower end.
Described flue type waste heat boiler divides rise and fall two-period form flue, and the flue entrance section adopts straight-through uptake flue formula structure, and the flue inwall is equipped with fin panel casing; The exhaust-heat boiler inlet inner wall overlaying has high-temp corrosion-resisting alloy.
Described top-blown converter outlet is connected with the import of flue type waste heat boiler to be adopted with the gland sealed flexible connection mode, and heat boiler outlet and rear portion flue directly weld.
The boiler-steam dome operating pressure of described waste heat boiler is 1.25Mpa, and stove water saturation temperature is 194 ℃.Stove water saturation temperature is higher than the dew-point temperature of sulfureous in flue gas acid, HCl steam, avoids the steam dewfall of sulfuric acid and HCl on the boiler heat exchange face.
Described low-grade composition brass flue gas during smelting purification, the gas cleaning of waste-heat recovery device, exhaust heat recovering method, comprise the steps: that the high-temperature flue gas of top-blown converter output enters the uptake flue of waste heat boiler, when high-temperature flue gas is flowed through the inboard fin panel casing of boiler flue, heat passes to water-cooling wall from flue gas, the cold water heat absorption evaporation in the water screen tube.The cigarette ash that is adsorbed on water-cooling wall is by the rapping spring action blow converter that returns back to top that drops, oxygen content in the oxygen on-line detector on-line monitoring flue gas of boiler export flue, in case abnormal combustion is arranged, the rich-oxygen nozzle that starts on the water-cooling wall blasts oxygenized air combustion supporting, flue gas enters spray cooling tower by the boiler downward-flow flue, spray cooler is injected at a high speed water smoke is down in 250 ℃ flue-gas temperature, the panel cooler of flowing through subsequently, further with below the cigarette temperature drop to 170 ℃, the dust that flue gas is separated out after cooling drops down onto below ash bag, and remaining dust contained flue gas still reaches 50mg/Nm 3Active carbon injection apparatus before the bagroom on the pipeline sprays into active carbon on time, according to quantity, dioxin particle in the absorption flue gas, the quench air inlet valve of bagroom entrance is looked inlet flue gas temperature and is automatically opened in the too high situation of flue-gas temperature, suck cold air, reduce flue-gas temperature, bagroom tail gas dust-laden<25mg/Nm out 3, drain into the 60m chimney stack through smoke exhaust fan and enter atmosphere.
Described low-grade composition brass flue gas during smelting purifies, the operation principle of waste-heat recovery device and process: the high-temperature flue gas that top-blown converter produces, be inhaled into waste heat boiler two-period form flue, the circulating water reclamation of boiler film-type water-cooling inwall a large amount of waste heat in the flue gas, producing steam electrolysis production heating uses, and flue-gas temperature in this process from about 1100 ℃ 600 ℃ of dropping to outlet temperature of exhaust-heat boiler inlet temperature, for preventing the wall bubble that forms in the lower boiler tube of the high-temperature flue gas baking floating of growing up, dry combustion method appears in the accompanying tube wall of steam bubble, adopts circulating pump to force cooling.The exhaust-heat boiler inlet section adopts straight-through uptake flue formula structure, high-melting-point substances is separated out and is attached on the water-cooling wall in the flue gas, the rapping spring that is arranged on the water-cooling wall outside forms regular resonance to water-cooling wall, make and separate out cigarette ash and fall back to top-blown converter, reduce the dust content of rear portion flue gas, improve the copper amount of producing.Because the halogen that organic burning can produce in the useless composition brass of flue gas can be combined to high temperature corrosion gas attack inboard wall of furnace body, the exhaust-heat boiler inlet inner wall overlaying has the corrosion-and high-temp-resistant alloy.Oxygen content is to judge the complete effect of burning in the oxygen on-line detector on-line monitoring flue gas of boiler export flue, in case abnormal combustion is arranged, the rich-oxygen nozzle that starts on the water-cooling wall blasts oxygenized air combustion supporting.Enter spray cooler through the spray of water smoke from waste heat boiler flue gas out, make flue gas 250 ℃~600 ℃ interval quenchings, contained that organic intermediate products forms dioxin.Flue-gas temperature even guarantee flue gas flow or temperature fluctuation, always keep dry in the tower, along with heat is evaporated taking away of moisture, can make flue gas be cooled to preference temperature by computer system control.The spray of flue gas process spray cooler enters plate type flue gas cooler and further enters bagroom after the cooling, panel cooler is to take away the cooling device of high-temperature flue gas tube wall heat in the mode of forced convertion, indirectly cooling, by axial flow fan for cooling, with entrance flue gas temperature from approximately 350 ℃ be down to the outlet below 170 ℃.The speed of axial flow fan for cooling can manual adjustments be controlled, temperature according to the control of bagroom entrance is different, its speed of service is also different, when the bagroom inlet temperature raises continuously, and the also corresponding raising of the speed of axial flow fan for cooling and the cooling effectiveness of cooler.In addition, in order to adsorb the dioxin that may form in the flue gas, the active carbon spraying system is set before bagroom, in flue gas, sprays activated carbon powder, so that the dioxin in the absorption flue gas.After cooled dusty gas entered dust-precipitator from air inlet, air-flow just diverted flow entered ash bucket, and air velocity is slack-off simultaneously, because effect of inertia makes the crude particle dust in the gas directly fall into ash bucket, played the effect of gathering dust in advance.Tiny dust is trapped in the outer surface of filter bag, and purified gas enters the clean room on top, filter bag chamber, is pooled to air outlet and discharges.The deashing of filter bag adopts compressed air, each filter bag is carried out automatic ash removing by the time interval that PLC is given.Compressed air is ejected by each eyelet of injection tube, and the dust that bonds on the filter bag is got off clearly, makes cloth bag keep ventilating smooth and easy, continuously operation, bagroom is a kind of efficient dust collection device, as long as filter bag is not damaged, its dust collection rate can be greater than 95%, and flue dust character is little on the dust-collecting efficiency impact.The cigarette ash that spray cooling tower, panel cooler, bagroom are collected is packed grey bag into, send corresponding PROCESS FOR TREATMENT, valuable metal is reclaimed to greatest extent, and the flue gas after bagroom is processed enters atmosphere through smoke exhaust fan, chimney, and final tail gas dust-laden is less than 25mg/Nm 3
The invention has the beneficial effects as follows:
1, reclaimed the waste heat of high-temperature flue gas in the reclaimed copper smelting equipment top-blown converter smelting process, this purification, recovery system technology are advanced, adaptability to raw material is strong, the rate of recovery is high, energy consumption is low.
2, adopt spray cooling tower and active carbon injection apparatus, contained the generation of dioxin gas in the flue gas.
3, utilize the clarifying smoke effect of spray cooling tower, panel cooler and bagroom, make the discharged gas fume dust-laden less than 25mg/Nm 3
4, adopt the boiler low pressure operation, and at the exhaust-heat boiler inlet section inner wall overlaying of corrosion-vulnerable high-temp corrosion-resisting alloy is arranged, stoped the corrosion of flue gas to the stove inwall, prolong waste heat boiler service life.
Four, description of drawings
Fig. 1 is that low-grade composition brass flue gas during smelting of the present invention purifies, the structural representation of waste-heat recovery device.
Be labeled as among the figure: top-blown converter 1, flue type waste heat boiler 2, rapping spring 3, oxygen on-line detector 4, be rich in nozzle 5, spray cooling tower 6, panel cooler 7, bagroom 8, active carbon injection apparatus 9, quench air inlet valve 10, smoke exhaust fan 11 and chimney 12.
Five, the specific embodiment
Below by drawings and Examples technical scheme of the present invention is described further.
Top-blown converter 1 is two broad in the middle roundlet shape, flue type waste heat boiler 2 is installed in top-blown converter 1 top smoke outlet, flue type waste heat boiler 2 water-cooling walls are equipped with rich-oxygen nozzle 5 and rapping spring 3, oxygen on-line detector 4 is equipped with in the exit, flue type waste heat boiler 2 links to each other with spray cooling tower 6, spray cooling tower 6 links to each other with panel cooler 7 by smoke pipe, panel cooler 7 is connected with bagroom 8 by the outlet smoke pipe, panel cooler 7 is provided with active carbon injection apparatus 9 and quench air inlet valve 10 with bagroom 8 middle flues, bagroom 8 outlets are connected with smoke exhaust fan 11, smoke exhaust fan 11 outlets connect chimney 12 lower ends, and tail gas enters atmosphere from chimney 12 tops.
The high-temperature flue gas of top-blown converter 1 output of this device enters flue type waste heat boiler 2, the high-temperature flue gas inboard fin panel casing of flue-pipe boiler of flowing through, heat passes to water-cooling wall from flue gas, cold water heat absorption evaporation in the water screen tube, heat in the water is taken away the purpose that reaches flue gas cool-down, the cigarette ash that is adsorbed on water-cooling wall is acted on the blow converter that returns back to top that drops by rapping spring 3, oxygen content is to judge the complete effect of burning in the oxygen on-line detector 4 on-line monitoring flue gases of boiler export flue, in case abnormal combustion is arranged, the rich-oxygen nozzle 5 that starts on the water-cooling wall blasts oxygenized air combustion supporting.Flue gas enters spray cooling tower 6 by the boiler downward-flow flue, finish the process that heat exchange reaches rapid cooling in the water smoke injecting at a high speed, avoid dioxin and generate warm area (350 ℃~600 ℃), the panel cooler 7 of flowing through subsequently, further with below the cigarette temperature drop to 170 ℃, the dust that flue gas is separated out after cooling is the ash bag below Action of Gravity Field falls to, and remaining dust contained flue gas still reaches 50mg/Nm 3For further suppressing the formation of dioxin; the active carbon injection apparatus 9 that enters on bagroom 8 preceding pipelines can spray into active carbon on time, according to quantity; dioxin particle in the absorption flue gas; purifying smoke, the quench air inlet valve 10 of bagroom entrance is looked inlet flue gas temperature and is automatically opened, and sucks cold air; do not damaged bagroom tail gas dust-laden<25mg/Nm out by high temperature with the protecting cloth filter bag of bag dust collector 3, draining into 60m chimney stack 12 through smoke exhaust fan 11 and enter atmosphere, whole process is controlled the generation of harmful substance to greatest extent, and recovery rate of valuable metals is high.

Claims (5)

1. low-grade composition brass flue gas during smelting purifies, waste-heat recovery device, comprise top-blown converter, flue type waste heat boiler, rich-oxygen nozzle, the rapping spring, the oxygen on-line detector, spray cooling tower, panel cooler, the active carbon injection apparatus, the quench air inlet valve, bagroom, smoke exhaust fan and chimney, it is characterized in that, described top-blown converter is two broad in the middle roundlet shape, flue type waste heat boiler is placed in top-blown converter top smoke outlet, the waste heat boiler water-cooling wall is equipped with rich-oxygen nozzle and rapping spring, the oxygen on-line detector is equipped with in the exit, flue type waste heat boiler links to each other with spray cooling tower, spray cooling tower links to each other with panel cooler by smoke pipe, panel cooler is connected with bagroom by the outlet smoke pipe, flue is provided with active carbon injection apparatus and quench air inlet valve in the middle of panel cooler and the bagroom, the bagroom outlet is connected with smoke exhaust fan, and the smoke exhaust fan outlet is connected into the chimney lower end.
Low-grade composition brass flue gas during smelting according to claim 1 purify, waste-heat recovery device, it is characterized in that, described flue type waste heat boiler divides rise and fall two-period form flue, and the flue entrance section adopts straight-through uptake flue formula structure, and the flue inwall is equipped with fin panel casing; The exhaust-heat boiler inlet inner wall overlaying has high-temp corrosion-resisting alloy.
Low-grade composition brass flue gas during smelting according to claim 1 purify, waste-heat recovery device, it is characterized in that, described top-blown converter outlet is connected with the import of flue type waste heat boiler to be adopted with the gland sealed flexible connection mode, and heat boiler outlet and rear portion flue directly weld.
4. low-grade composition brass flue gas during smelting purification according to claim 1, waste-heat recovery device is characterized in that, the boiler-steam dome operating pressure of described waste heat boiler is 1.25Mpa, and stove water saturation temperature is 194 ℃.
5. being applicable to the described low-grade composition brass flue gas during smelting of claim 1 purifies, the gas cleaning of waste-heat recovery device, exhaust heat recovering method, it is characterized in that, comprise the steps: that the high-temperature flue gas of top-blown converter output enters the uptake flue of waste heat boiler, when high-temperature flue gas is flowed through the inboard fin panel casing of boiler flue, heat passes to water-cooling wall from flue gas, cold water heat absorption evaporation in the water screen tube, the cigarette ash that is adsorbed on water-cooling wall is by the rapping spring action blow converter that returns back to top that drops, oxygen content in the oxygen on-line detector on-line monitoring flue gas of boiler export flue, in case abnormal combustion is arranged, the rich-oxygen nozzle that starts on the water-cooling wall blasts oxygenized air combustion supporting, flue gas enters spray cooling tower by the boiler downward-flow flue, spray cooler is injected at a high speed water smoke is down in 250 ℃ flue-gas temperature, the panel cooler of flowing through subsequently, further with below the cigarette temperature drop to 170 ℃, the dust that flue gas is separated out after cooling drops down onto below ash bag, and remaining dust contained flue gas still reaches 50mg/Nm 3Active carbon injection apparatus before the bagroom on the pipeline sprays into active carbon on time, according to quantity, dioxin particle in the absorption flue gas, the quench air inlet valve of bagroom entrance is looked inlet flue gas temperature and is automatically opened in the too high situation of flue-gas temperature, suck cold air, reduce flue-gas temperature, bagroom tail gas dust-laden<25mg/Nm out 3, drain into the 60m chimney stack through smoke exhaust fan and enter atmosphere.
CN2012104092959A 2012-10-24 2012-10-24 Smoke purifying and waste heat recycling device for low-grade composition brass smelting and control method of smoke purifying and waste heat recycling device Pending CN102878821A (en)

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CN103471401A (en) * 2013-09-05 2013-12-25 山东金升有色集团有限公司 Unit of recovering flue gas waste heat and dust in reclaimed copper refining
CN103925806A (en) * 2014-04-01 2014-07-16 南昌江能热动工程技术有限责任公司 Multi-channel back type integrated alkali sulphide converter waste heat boiler device
CN104613783A (en) * 2015-01-23 2015-05-13 铜陵有色金属集团股份有限公司金冠铜业分公司 Flue gas treatment system for top-blowing furnace
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CN103160639A (en) * 2013-02-21 2013-06-19 江苏浦士达环保科技有限公司 Converter smoke waste heat utilizing system
CN103471401A (en) * 2013-09-05 2013-12-25 山东金升有色集团有限公司 Unit of recovering flue gas waste heat and dust in reclaimed copper refining
CN103471401B (en) * 2013-09-05 2016-03-30 东部铜业股份有限公司 The recycle device of waste heat and dust in reclaimed copper refining flue gas
CN103925806A (en) * 2014-04-01 2014-07-16 南昌江能热动工程技术有限责任公司 Multi-channel back type integrated alkali sulphide converter waste heat boiler device
CN103925806B (en) * 2014-04-01 2015-09-30 南昌江能热动工程技术有限责任公司 A kind of multichannel back of the body formula integration akali sulphide Converter Residual Heat Boiler device
CN104613783A (en) * 2015-01-23 2015-05-13 铜陵有色金属集团股份有限公司金冠铜业分公司 Flue gas treatment system for top-blowing furnace
CN104613783B (en) * 2015-01-23 2017-03-15 铜陵有色金属集团股份有限公司金冠铜业分公司 The smoke processing system of top blast stove
CN108534171A (en) * 2017-03-03 2018-09-14 中外炉工业株式会社 Heat storage clearing apparatus
CN107166970A (en) * 2017-05-23 2017-09-15 中冶东方工程技术有限公司 Recovery method and retracting device for high siliceous metal smelting mine heat furnace
CN107238298A (en) * 2017-07-24 2017-10-10 马鞍山钢铁股份有限公司 A kind of pelletizing production flue gas cool-down depositing dust and gather dust processing unit and its processing method
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CN111185297A (en) * 2020-02-12 2020-05-22 广东省资源综合利用研究所 Blast furnace low-grade copper slag enrichment method
CN111185297B (en) * 2020-02-12 2021-03-26 广东省科学院资源综合利用研究所 Blast furnace low-grade copper slag enrichment method
CN113731048A (en) * 2021-08-19 2021-12-03 中国恩菲工程技术有限公司 Arsenic collecting system and method for dioxin-containing smelting flue gas
CN113718114A (en) * 2021-08-20 2021-11-30 白银有色集团股份有限公司 Method for regulating flue gas temperature and hearth negative pressure in reduction stage of anode furnace
CN114199038A (en) * 2021-12-15 2022-03-18 科林环保技术有限责任公司 Electric furnace flue gas treatment system
CN118641330A (en) * 2024-08-14 2024-09-13 四川领先微晶玻璃有限公司 System for testing usability of glass ceramic pot
CN118641330B (en) * 2024-08-14 2024-10-25 四川领先微晶玻璃有限公司 System for testing usability of glass ceramic pot

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Free format text: CORRECT: INVENTOR; FROM: HUANG BIN CHEN BO ZHOU RUISHENG TU JIANHUA WANG WEI XIAO HUIYONG FU XIAOGUANG SUN BAOHUA ZHOU RONGHUAN YANG PING TO: CHEN BO HUANG BIN TU JIANHUA ZHOU RUISHENG XIAO HUIYONG WANG WEI SUN BAOHUA FU XIAOGUANG YANG PING ZHOU RONGHUAN

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Application publication date: 20130116