CN102876003A - Polyphenyl ether composite material and preparation method of polyphenyl ether composite material - Google Patents
Polyphenyl ether composite material and preparation method of polyphenyl ether composite material Download PDFInfo
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- CN102876003A CN102876003A CN2012103952407A CN201210395240A CN102876003A CN 102876003 A CN102876003 A CN 102876003A CN 2012103952407 A CN2012103952407 A CN 2012103952407A CN 201210395240 A CN201210395240 A CN 201210395240A CN 102876003 A CN102876003 A CN 102876003A
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Abstract
The invention discloses a polyphenyl ether composite material, which is prepared from the following ingredients in parts by weight according to the following mixture ratios: 45 to 60 parts of polyphenyl ether, 38 to 40 parts of polyphenylene sulfide, 5 to 10 parts of sodium stearate, 25 to 30 parts of glass fibers, 1 to 2 parts of compatilizers, 1 to 2 parts of lubricating agents, 1.5 to 2 parts of antioxidants, 2 to 4 parts of silicon dioxide, 1 to 2 parts of zinc oxide and 1 to 2 parts of aluminum oxide. The polyphenyl ether composite material prepared according to a method provided by the invention has the advantages that good high-temperature resistance performance and good mechanical performance are realized, the dimension is stable, the deformation cannot easily occur, and in addition, the water boiling resistance performance of the composite material is excellent.
Description
Technical field
The present invention relates to technical field of polymer materials, be specifically related to a kind of polyphenylene oxide composite material and preparation method thereof.
Background technology
Polyphenylene oxide (PPO) is a kind of engineering plastics of excellent combination property.High temperature resistant, corrosion-resistant, radiation-resistant physical and mechanical properties that PPO has and fabulous dimensional stability and the good characteristics such as electrical property are widely used as structural macromolecular material, by filling, being widely used as special engineering plastics after the modification.
Along with the development of technology, present polyphenylene oxide (PPO) material almost is applied to every field, but its durability is not well solved.Special standby is when polyphenyl ether material being applied to the equipment such as electric kettle, electric coffee maker, higher to its water boiling resistance, can not ftracture in the life-time service process to guarantee it.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of polyphenylene oxide composite material, and this matrix material not only has good resistance to elevated temperatures and good mechanical property, and dimensional stabilizing is not yielding; And the water boiling resistance excellent performance of this matrix material.
The present invention solves the problems of the technologies described above the technical scheme that adopts: a kind of polyphenylene oxide composite material, and it is formulated by the raw materials by weight portion of following proportioning:
A kind of polyphenylene oxide composite material is characterized in that, it is formulated by the raw materials by weight portion of following proportioning:
45 ~ 60 parts of polyphenylene oxide,
38 ~ 40 parts of polyphenylene sulfides,
5 ~ 10 parts of sodium stearate,
25 ~ 30 parts in glass fibre,
1 ~ 2 part of compatilizer,
1 ~ 2 part of lubricant,
1.5 ~ 2 parts in oxidation inhibitor,
2 ~ 4 parts of silicon-dioxide,
1 ~ 2 part in zinc oxide,
1 ~ 2 part in aluminum oxide.
Described compatilizer is ethylene-methyl acrylate copolymer.
Described lubricant is silicone lubricant.
Described oxidation inhibitor is hydroxy phenyl acrylate or hydroxybenzene methacrylic ester.
Described silicon-dioxide is nano silicon, and particle diameter is 100 ~ 200 nanometers.
Technical problem to be solved by this invention is to provide the preparation method of above-mentioned polyphenylene oxide composite material.
The present invention solves the problems of the technologies described above the technical scheme that adopts: the preparation method of above-mentioned polyphenylene oxide composite material comprises the steps:
Step 1, take by weighing respectively raw material by the parts by weight of claim 1;
Step 2, polyphenylene oxide, polyphenylene sulfide and sodium stearate mixed in homogenizer after, and then add glass fibre, compatilizer, lubricant, oxidation inhibitor, silicon-dioxide, zinc oxide and aluminum oxide, make compound;
Step 3, described compound is placed twin screw extruder, through melt extruding, granulation, described screw rod is respectively distinguished temperature setting and is set to: 250 ~ 260 ℃ of twin screw one district's temperature, 270 ~ 280 ℃ of two district's temperature, 285 ~ 290 ℃ of three district's temperature, 300 ~ 310 ℃ of four district's temperature, 3 minutes residence time in barrel, melt pressure is 25Mpa
The present invention compared with prior art has following beneficial effect: the polyphenylene oxide composite material that the present invention prepares not only has good resistance to elevated temperatures and good mechanical property, and dimensional stabilizing is not yielding; And the water boiling resistance excellent performance of this matrix material.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, but embodiments of the present invention are not limited to this.
Embodiment 1
A kind of polyphenylene oxide composite material takes by weighing following raw materials according by ratio of weight and the number of copies: 48 parts of polyphenylene oxide, 38 parts of polyphenylene sulfides, 5 parts of sodium stearate, 26 parts in glass fibre, 1 part of ethylene-methyl acrylate copolymer, 1 part of silicone lubricant, 1.6 parts of hydroxy phenyl acrylate, 1 part of silicon-dioxide (100nm), 1 part in zinc oxide, 1 part in aluminum oxide.
Embodiment 2
A kind of polyphenylene oxide composite material takes by weighing following raw materials according by ratio of weight and the number of copies: 50 parts of polyphenylene oxide, 39 parts of polyphenylene sulfides, 8 parts of sodium stearate, 28 parts in glass fibre, 1.5 parts of ethylene-methyl acrylate copolymers, 1.5 parts of silicone lubricants, 1.8 parts of hydroxy phenyl acrylate, 4 parts of silicon-dioxide (150nm), 1.8 parts in zinc oxide, 1.8 parts in aluminum oxide.
Embodiment 3
A kind of polyphenylene oxide composite material takes by weighing following raw materials according by ratio of weight and the number of copies: 60 parts of polyphenylene oxide, 40 parts of polyphenylene sulfides, 10 parts of sodium stearate, 30 parts in glass fibre, 2 parts of ethylene-methyl acrylate copolymers, 2 parts of silicone lubricants, 2 parts of hydroxybenzene methacrylic esters, 2 parts of silicon-dioxide (200nm), 2 parts in zinc oxide, 2 parts in aluminum oxide.
The preparation method of embodiment 4 polyphenylene oxide composite materials
The raw material that takes by weighing among the embodiment 1-3 is prepared as follows:
1, polyphenylene oxide, polyphenylene sulfide and the sodium stearate that takes by weighing mixed in homogenizer after, and then add glass fibre, compatilizer, lubricant, oxidation inhibitor and filler, make compound;
2, above-mentioned resulting compound is placed twin screw extruder, through melt extruding, granulation, described screw rod is respectively distinguished temperature setting and is set to: 250 ~ 260 ℃ of twin screw one district's temperature, 270 ~ 280 ℃ of two district's temperature, 285 ~ 290 ℃ of three district's temperature, 300 ~ 310 ℃ of four district's temperature, 3 minutes residence time in barrel, melt pressure is 25Mpa, can obtain polyphenylene oxide composite material of the present invention.
Embodiment 5 performance evaluations
The particle that obtains behind the above-mentioned extruding pelletization is injection molded into exemplar behind 125 ℃ of lower dry 2h, the injection mold temperature is controlled at about 130 ℃.
1, test by following standard, the result is as shown in table 1: this matrix material not only has good resistance to elevated temperatures and good mechanical property, and dimensional stabilizing is not yielding.
Table 1
2, test by the following method the water boiling resistance performance
The method of water boiling resistance performance test: the matrix material of embodiment 1-3 preparation was carried out respectively 100 ℃, poach 12 days, materialsed every 3 days, measure notched Izod impact strength, tensile strength, the extension at break intensity of material particle.
As mentioned above, just can realize well the present invention.
Claims (6)
1. a polyphenylene oxide composite material is characterized in that, it is formulated by the raw materials by weight portion of following proportioning:
45 ~ 60 parts of polyphenylene oxide,
38 ~ 40 parts of polyphenylene sulfides,
5 ~ 10 parts of sodium stearate,
25 ~ 30 parts in glass fibre,
1 ~ 2 part of compatilizer,
1 ~ 2 part of lubricant,
1.5 ~ 2 parts in oxidation inhibitor,
2 ~ 4 parts of silicon-dioxide,
1 ~ 2 part in zinc oxide,
1 ~ 2 part in aluminum oxide.
2. polyphenylene oxide composite material according to claim 1 is characterized in that, described compatilizer is ethylene-methyl acrylate copolymer.
3. polyphenylene oxide composite material according to claim 1 is characterized in that, described lubricant is silicone lubricant.
4. polyphenylene oxide composite material according to claim 1 is characterized in that, described oxidation inhibitor is hydroxy phenyl acrylate or hydroxybenzene methacrylic ester.
5. polyphenylene oxide composite material according to claim 1 is characterized in that, described silicon-dioxide is nano silicon.
6. the preparation method of polyphenylene oxide composite material claimed in claim 1 is characterized in that, comprises the steps:
Step 1, take by weighing respectively raw material by the parts by weight of claim 1;
Step 2, polyphenylene oxide, polyphenylene sulfide and sodium stearate mixed in homogenizer after, and then add glass fibre, compatilizer, lubricant, oxidation inhibitor, silicon-dioxide, zinc oxide and aluminum oxide, make compound;
Step 3, described compound is placed twin screw extruder, through melt extruding, granulation, described screw rod is respectively distinguished temperature setting and is set to: 250 ~ 260 ℃ of twin screw one district's temperature, 270 ~ 280 ℃ of two district's temperature, 285 ~ 290 ℃ of three district's temperature, 300 ~ 310 ℃ of four district's temperature, 3 minutes residence time in barrel, melt pressure is 25Mpa.
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| CN2012103952407A CN102876003A (en) | 2012-10-17 | 2012-10-17 | Polyphenyl ether composite material and preparation method of polyphenyl ether composite material |
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| CN2012103952407A CN102876003A (en) | 2012-10-17 | 2012-10-17 | Polyphenyl ether composite material and preparation method of polyphenyl ether composite material |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103450656A (en) * | 2013-08-07 | 2013-12-18 | 上海日之升新技术发展有限公司 | Continuous long aluminum fiber reinforced PPO composite and preparation method thereof |
| CN103937208A (en) * | 2014-04-18 | 2014-07-23 | 芜湖凯奥尔环保科技有限公司 | Nanometer silicon dioxide modified polyphenyl ether material for automotive plastic parts |
| CN103937245A (en) * | 2014-04-18 | 2014-07-23 | 芜湖凯奥尔环保科技有限公司 | Moisture-proof ABS (Acrylonitrile Butadiene Styrene)-modified polyphenyl ether material for automobile plastic parts |
| CN106977921A (en) * | 2017-04-07 | 2017-07-25 | 深圳市华盈新材料有限公司 | Nanometer injection PPS composites and its preparation technology |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01213361A (en) * | 1988-02-23 | 1989-08-28 | Asahi Chem Ind Co Ltd | Thermoplastic resin composition |
| JP3151639B2 (en) * | 1992-10-08 | 2001-04-03 | アイシン精機株式会社 | Resin composition for automotive water pump related parts and automotive water pump related parts comprising the same |
| CN101768359A (en) * | 2008-12-31 | 2010-07-07 | 深圳市科聚新材料有限公司 | Fiberglass enhanced polyphenyl thioether/polyphenylether composite material and preparation method thereof |
| CN102643528A (en) * | 2012-05-08 | 2012-08-22 | 浙江三威防静电装备有限公司 | High-temperature anti-static polyphenyl ether composite engineering material and preparing method thereof |
-
2012
- 2012-10-17 CN CN2012103952407A patent/CN102876003A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01213361A (en) * | 1988-02-23 | 1989-08-28 | Asahi Chem Ind Co Ltd | Thermoplastic resin composition |
| JP3151639B2 (en) * | 1992-10-08 | 2001-04-03 | アイシン精機株式会社 | Resin composition for automotive water pump related parts and automotive water pump related parts comprising the same |
| CN101768359A (en) * | 2008-12-31 | 2010-07-07 | 深圳市科聚新材料有限公司 | Fiberglass enhanced polyphenyl thioether/polyphenylether composite material and preparation method thereof |
| CN102643528A (en) * | 2012-05-08 | 2012-08-22 | 浙江三威防静电装备有限公司 | High-temperature anti-static polyphenyl ether composite engineering material and preparing method thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103450656A (en) * | 2013-08-07 | 2013-12-18 | 上海日之升新技术发展有限公司 | Continuous long aluminum fiber reinforced PPO composite and preparation method thereof |
| CN103450656B (en) * | 2013-08-07 | 2016-04-06 | 上海日之升新技术发展有限公司 | Continuous long aluminum fiber strengthens PPO mixture and preparation method thereof |
| CN103937208A (en) * | 2014-04-18 | 2014-07-23 | 芜湖凯奥尔环保科技有限公司 | Nanometer silicon dioxide modified polyphenyl ether material for automotive plastic parts |
| CN103937245A (en) * | 2014-04-18 | 2014-07-23 | 芜湖凯奥尔环保科技有限公司 | Moisture-proof ABS (Acrylonitrile Butadiene Styrene)-modified polyphenyl ether material for automobile plastic parts |
| CN103937245B (en) * | 2014-04-18 | 2016-05-18 | 芜湖凯奥尔环保科技有限公司 | A kind of moistureproof ABS modified polyphenyl ether material for automotive plastic parts |
| CN106977921A (en) * | 2017-04-07 | 2017-07-25 | 深圳市华盈新材料有限公司 | Nanometer injection PPS composites and its preparation technology |
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Application publication date: 20130116 |