CN102875029A - Composite rubber glassy alloy material and preparation method thereof - Google Patents
Composite rubber glassy alloy material and preparation method thereof Download PDFInfo
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- CN102875029A CN102875029A CN201210366296XA CN201210366296A CN102875029A CN 102875029 A CN102875029 A CN 102875029A CN 201210366296X A CN201210366296X A CN 201210366296XA CN 201210366296 A CN201210366296 A CN 201210366296A CN 102875029 A CN102875029 A CN 102875029A
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Abstract
The invention discloses composite rubber glassy alloy material. The composite rubber glassy alloy material comprises, by weight percent, 50%-60% of glass powder, 10-15% of rubber, 6%-10% of beryllium oxide, 0.2%-0.5% of coupling agent, 1%-2% of thallium, and the balance of zirconium. The composite rubber glassy alloy material is available in bulky composite alloy material, has rigidity and extensibility of glassy metals, is easier to process, and is more elastic than the existing glassy metals.
Description
Technical field
The present invention relates to alloy material, belong to polymeric material field.
Background technology
It is synthetic that alloy mostly is metallic substance, or be mixed with a small amount of non-metallic elements such as boron, but can not form transparent amorphous structure.Metallic glass claims again amorphous alloy, the advantage of its existing metal and glass, overcome again their disadvantages separately. such as Glass breadks easily, there is not ductility. the intensity of metallic glass but is higher than steel, hardness surpasses high hard tool steel, and have certain toughness and rigidity, so it is " king of glass " of " strike not broken, cannot not pound mashedly " that people praise metallic glass.
Most metal all can crystallization in when cooling, and their atomic arrangement is become well-regulated pattern, is called lattice (lattice).If but crystallization do not occur, just atom can random alignment (random arrangement), become metallic glass.
The atom of simple glass also is random alignment, but it is not metal.Metallic glass is also opaque, and it has unique machinery (mechanical) and magnetic (magnetic) speciality, is difficult for broken and not yielding (deform).It is the desirable material of making transformer, golf club and other products.
The metallic glass of producing at present is thinner and thinner, just can crystallization because very fast during metal cools, so need very fast freezing.The researcher He Naqiao (Todd Hufnagel) of U.S. Johns's Stephen Hopkins university (John Hopkins University) is just studying and how to produce superpowerful, elastic force and magnetic force speciality, but the metallic glass of bulk comparatively.This new metal can keep solid and not at high temperature crystallization, and this will be suitable for making engine parts and military weapon.
Existing metallic glass is mainly take zirconium as main, and cost is high, be difficult for forming bulk and processing difficulties.
Summary of the invention
The technical problem to be solved in the present invention is to overcome existing defective, and the compounded rubber glassy alloy that a kind of elasticity is strong, cost is low, be easy to process material is provided;
Another object of the present invention provides the preparation method of above-mentioned compounded rubber glassy alloy.
Purpose of the present invention is come specific implementation by the following technical programs:
A kind of compounded rubber glassy alloy material, each compositions in weight percentage of its raw material is: glass powder 50%-60%, rubber 10-15%, beryllium oxide 6%-10%, coupling agent 0.2%-0.5%, thallium 1%-2%, all the other are metal zirconium.
As preferred version, above-mentioned compounded rubber glassy alloy material, each compositions in weight percentage of its raw material is: glass powder 60%, rubber 15%, beryllium oxide 7%, coupling agent 0.3%, thallium 1.5%, all the other are metal zirconium.
Above-mentioned compounded rubber glassy alloy material preparation method comprises the steps:
Step 1, with the glass powder melting, add coupling agent, stir under the high temperature, add again rubber, stir;
Step 2, the melting in vacuum arc fumace of metal zirconium, thallium, beryllium oxide is even, removal of impurities;
Step 3, the liquid in the step 1 is added in the liquid in the step 2, after mixing, be cooled to rapidly below 60 ℃.
Further, the method that impurity-removing method adopts the lower yttrium of argon gas stream protection to adsorb in the described step 2.
Beneficial effect of the present invention:
Compounded rubber glassy alloy material provided by the present invention can form the composite alloy material of bulk, not only has rigidity and the ductility of glass metal, and is easier to processing, and the elasticity of the existing glass metal of elasticity is strong.
Embodiment
Below the preferred embodiments of the present invention are described, should be appreciated that preferred embodiment described herein only is used for description and interpretation the present invention, is not intended to limit the present invention.
Embodiment 1:
A kind of compounded rubber glassy alloy material, each compositions in weight percentage of its raw material is: glass powder 60%, rubber 15%, beryllium oxide 7%, coupling agent 0.3%, thallium 1.5%, all the other are metal zirconium.
Above-mentioned compounded rubber glassy alloy material preparation method comprises the steps:
Step 1, with the glass powder melting, add coupling agent, stir under the high temperature, add again rubber, stir;
Step 2, the melting in vacuum arc fumace of metal zirconium, thallium, beryllium oxide is even, the method for yttrium absorption is carried out the removal of impurities processing under the argon gas stream protection;
Step 3, the liquid in the step 1 is added in the liquid in the step 2, after mixing, be cooled to rapidly below 60 ℃.
Embodiment 2:
A kind of compounded rubber glassy alloy material, according to the manufacture method of embodiment 1, each compositions in weight percentage of its raw material is: glass powder 50%%, rubber 10%, beryllium oxide 6%, coupling agent 0.2%, thallium 2%, all the other are metal zirconium.
Embodiment 3:
A kind of compounded rubber glassy alloy material, according to the manufacture method of embodiment 1, each compositions in weight percentage of its raw material is: glass powder 60%, rubber 15%, beryllium oxide 10%, coupling agent 0.5%, thallium 1%, all the other are metal zirconium.
The above only is the preferred embodiments of the present invention, be not limited to the present invention, although with reference to previous embodiment the present invention is had been described in detail, for a person skilled in the art, it still can be made amendment to the technical scheme that aforementioned each embodiment puts down in writing, and perhaps part technical characterictic wherein is equal to replacement.Within the spirit and principles in the present invention all, any modification of doing, be equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (4)
1. compounded rubber glassy alloy material, it is characterized in that: each compositions in weight percentage of its raw material is: glass powder 50%-60%, rubber 10-15%, beryllium oxide 6%-10%, coupling agent 0.2%-0.5%, thallium 1%-2%, all the other are metal zirconium.
2. compounded rubber glassy alloy material according to claim 1, it is characterized in that: each compositions in weight percentage of its raw material is: glass powder 60%, rubber 15%, beryllium oxide 7%, coupling agent 0.3%, thallium 1.5%, all the other are metal zirconium.
3. compounded rubber glassy alloy material preparation method according to claim 1 and 2 is characterized in that: comprise the steps:
Step 1, with the glass powder melting, add coupling agent, stir under the high temperature, add again rubber, stir;
Step 2, the melting in vacuum arc fumace of metal zirconium, thallium, beryllium oxide is even, removal of impurities;
Step 3, the liquid in the step 1 is added in the liquid in the step 2, after mixing, be cooled to rapidly below 60 ℃.
4. compounded rubber glassy alloy material preparation method according to claim 3 is characterized in that: the method for the lower yttrium absorption of impurity-removing method employing argon gas stream protection in the described step 2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201210366296XA CN102875029A (en) | 2012-09-27 | 2012-09-27 | Composite rubber glassy alloy material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210366296XA CN102875029A (en) | 2012-09-27 | 2012-09-27 | Composite rubber glassy alloy material and preparation method thereof |
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| CN102875029A true CN102875029A (en) | 2013-01-16 |
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| CN201210366296XA Pending CN102875029A (en) | 2012-09-27 | 2012-09-27 | Composite rubber glassy alloy material and preparation method thereof |
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Citations (6)
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|---|---|---|---|---|
| CN1422741A (en) * | 2001-11-08 | 2003-06-11 | 希普利公司 | Method for forming resin composite material |
| WO2005000928A1 (en) * | 2003-06-27 | 2005-01-06 | Kaneka Corporation | Curing composition having mold releasability |
| CN101193835A (en) * | 2005-05-31 | 2008-06-04 | 先进玻璃陶瓷公司 | Heat insulating composite and methods of manufacturing thereof |
| CN101451003A (en) * | 2007-11-28 | 2009-06-10 | 王广武 | High molecule glass alloy |
| CN101502987A (en) * | 2008-02-04 | 2009-08-12 | 王广武 | Method and device for preparing polymer glassy alloy |
| CN102504358A (en) * | 2011-11-22 | 2012-06-20 | 广东石油化工学院 | High-heat-conductivity rubber composite material and preparation method thereof |
-
2012
- 2012-09-27 CN CN201210366296XA patent/CN102875029A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1422741A (en) * | 2001-11-08 | 2003-06-11 | 希普利公司 | Method for forming resin composite material |
| WO2005000928A1 (en) * | 2003-06-27 | 2005-01-06 | Kaneka Corporation | Curing composition having mold releasability |
| CN101193835A (en) * | 2005-05-31 | 2008-06-04 | 先进玻璃陶瓷公司 | Heat insulating composite and methods of manufacturing thereof |
| CN101451003A (en) * | 2007-11-28 | 2009-06-10 | 王广武 | High molecule glass alloy |
| CN101502987A (en) * | 2008-02-04 | 2009-08-12 | 王广武 | Method and device for preparing polymer glassy alloy |
| CN102504358A (en) * | 2011-11-22 | 2012-06-20 | 广东石油化工学院 | High-heat-conductivity rubber composite material and preparation method thereof |
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