CN102867606A - Weak-magnetism alloy material - Google Patents

Weak-magnetism alloy material Download PDF

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Publication number
CN102867606A
CN102867606A CN2012103343860A CN201210334386A CN102867606A CN 102867606 A CN102867606 A CN 102867606A CN 2012103343860 A CN2012103343860 A CN 2012103343860A CN 201210334386 A CN201210334386 A CN 201210334386A CN 102867606 A CN102867606 A CN 102867606A
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Prior art keywords
alloy material
weak
vanadium
copper
combination
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CN2012103343860A
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虞雪君
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Abstract

The invention relates to a weak-magnetism alloy material. The weak-magnetism alloy material is of a FeCOMSiBTi base material, and comprises the following compositions in atomic percentage (at%): 20-25% of cobalt, 3-5% of M, 8-12% of silicon, 10-15% of boron, 1.5-2.5% of titanium and the rest of ferrum and a small amount of inevitable impurities, wherein M is one or combination of copper, niobium, molybdenum, vanadium and zirconium.

Description

A kind of weak magnetic alloy material
Technical field
The invention belongs to field of functional materials, refer to especially a kind of weak magnetic alloy material.
Background technology
In the prior art, magnetic material particularly magnetic material is used as producing the product that high frequency transformer, magnetic head etc. need to utilize magnetic material properties.Magnetic material refers to compare the magnetic material with demagnetization performance with permanent magnetic material.The now production of main magnetic material prepares with Ferrite Material substantially, and the key property of this class Ferrite Material is the advantages such as resistivity is high, and the high-frequency vortex loss is little.But the saturation induction density of the magnetic product of this material preparation is on the low side, temperature characterisitic is poor, only can be used in the scope that temperature is lower than 100 ℃, when temperature surpasses this scope, its performance sharply descends even magnetic disappears, so this class material is not suitable for the application under the hot conditions.
China's patent 20041002990 provides a kind of FeCOMSiB of employing alloy material and has improved the consumption of Co element.Although this technical scheme can have higher temperature characterisitic, contain Co high magnetic alloy storage magnetic property and demagnetization speed not high, CO belongs to narrow resources with respect to China simultaneously, and the import dependency degree surpasses more than 90%, therefore is necessary prior art is improved.
Summary of the invention
The objective of the invention is by improvements over the prior art, also can improve the demagnetization performance of this class magnetic material at the temperature characterisitic that guarantees magnetic material and storage magnetic property.
The present invention is achieved by the following technical solutions:
A kind of weak magnetic alloy material, described magnetic alloy material is the FeCOMSiBTi base material, each composition forms and comprising by atomic percentage conc (at%): the cobalt of 20-25, the M of 3-5, the silicon of 8-12, the boron of 10-15,1.5-2.5 titanium, all the other are iron and a small amount of inevitably impurity; Described M is one or more combination in copper and niobium, molybdenum, vanadium, the zirconium.
The atomic percentage conc of described copper (at%) is 0.8-1.2; The atomic percentage conc of one or more combination (at%) is 3.5-4.5 in described niobium, molybdenum, vanadium, the zirconium.
Further improve, described M is the combination of copper and vanadium.
The invention has the beneficial effects as follows:
Compare with prior art, this magnetic material alloy has preferably hot properties and storage magnetic property, is for the preferred magnetic material of making magnetic head.
Embodiment
So that the present invention is described in detail, select in this application the performance of organizing embodiment more and drawing each component by the detection to each embodiment below in conjunction with specific embodiment.6 groups of embodiment have been selected altogether in this application.
A kind of weak magnetic alloy material, described magnetic alloy material is the FeCOMSiBTi base material, each composition forms and comprising by atomic percentage conc (at%): the cobalt of 20-25, the M of 3-5, the silicon of 8-12, the boron of 10-15,1.5-2.5 titanium, all the other are iron and a small amount of inevitably impurity; One or more combination in described M copper and niobium, molybdenum, vanadium, the zirconium.
The atomic percentage conc of described copper (at%) is 0.8-1.2; The atomic percentage conc of one or more combination (at%) is 3.5-4.5 in described niobium, molybdenum, vanadium, the zirconium.
Described M is the combination of copper and vanadium.
The preparation of embodiment is to carry out melting in vaccum sensitive stove, at first will be evacuated to 10 in the stove -3More than the Pa; then be filled with 1 atmospheric argon gas, melting is to adopt argon shield and through being cast into the alloy base substrate after the electromagnetic agitation fully, again base substrate is being processed into semi-finished product according to need; again through 500-520 ℃ and 30 minutes annealing of insulation, then to product test.
The testing experiment of product
The measurement of magnetic permeability is to be 10 in vacuum degree -3Carry out in the Pa vacuum furnace, metering system employing heating rate is that 3.5 ℃/minute linear temperature increase is measured.Through measuring, the technical program has good temperature characterisitic.
The concrete composition of embodiment 1-6 sees Table 1
The atomic percent at% of composition (table 1) unit of various embodiments of the present invention
Figure BSA00000776359000041
Can show by above measurement result, technical scheme of the present invention is similar with the performance of the magnetic material that rolls up cobalt content in the prior art, but cost reduces in a large number.

Claims (3)

1. magnetic alloy material a little less than a kind, it is characterized in that: described magnetic alloy material is the FeCOMSiBTi base material, each composition forms and comprising by atomic percentage conc (at%): the cobalt of 20-25, the M of 3-5, the silicon of 8-12, the boron of 10-15, the titanium of 1.5-2.5, all the other are iron and a small amount of inevitably impurity; One or more combination in described M copper and niobium, molybdenum, vanadium, the zirconium.
2. weak magnetic alloy material according to claim 1, it is characterized in that: the atomic percentage conc of described copper (a t%) is 0.8-1.2; The atomic percentage conc of one or more combination in described niobium, molybdenum, vanadium, the zirconium (a t%) is 3.5-4.5.
3. weak magnetic alloy material according to claim 1, it is characterized in that: described M is the combination of copper and vanadium.
CN2012103343860A 2012-09-10 2012-09-10 Weak-magnetism alloy material Pending CN102867606A (en)

Priority Applications (1)

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CN102867606A true CN102867606A (en) 2013-01-09

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106601412A (en) * 2016-11-23 2017-04-26 俞虹 Weak magnetic alloy material

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040051614A1 (en) * 2001-11-22 2004-03-18 Hirokazu Kanekiyo Nanocomposite magnet
CN1564271A (en) * 2004-04-01 2005-01-12 安泰科技股份有限公司 High temp non-crystal, microcrystal soft-magnet alloy
CN1781624A (en) * 1999-04-15 2006-06-07 日立金属株式会社 Soft magnetic alloy thin band, magnetic part made therefrom and its making method
CN101320617A (en) * 2007-06-08 2008-12-10 财团法人工业技术研究院 Soft magnetic film inductor and magnetic multi-component alloy thin film
CN101353775A (en) * 2008-09-17 2009-01-28 安泰科技股份有限公司 Nanocrystalline alloy coating and preparation thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1781624A (en) * 1999-04-15 2006-06-07 日立金属株式会社 Soft magnetic alloy thin band, magnetic part made therefrom and its making method
US20040051614A1 (en) * 2001-11-22 2004-03-18 Hirokazu Kanekiyo Nanocomposite magnet
CN1564271A (en) * 2004-04-01 2005-01-12 安泰科技股份有限公司 High temp non-crystal, microcrystal soft-magnet alloy
CN101320617A (en) * 2007-06-08 2008-12-10 财团法人工业技术研究院 Soft magnetic film inductor and magnetic multi-component alloy thin film
CN101353775A (en) * 2008-09-17 2009-01-28 安泰科技股份有限公司 Nanocrystalline alloy coating and preparation thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106601412A (en) * 2016-11-23 2017-04-26 俞虹 Weak magnetic alloy material

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Application publication date: 20130109