CN102863229A - Basic refractory attapulgite volcaniclastic-rock aggregate sand - Google Patents

Basic refractory attapulgite volcaniclastic-rock aggregate sand Download PDF

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CN102863229A
CN102863229A CN2012103731245A CN201210373124A CN102863229A CN 102863229 A CN102863229 A CN 102863229A CN 2012103731245 A CN2012103731245 A CN 2012103731245A CN 201210373124 A CN201210373124 A CN 201210373124A CN 102863229 A CN102863229 A CN 102863229A
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attapulgite
aggregate sand
volcanoclastic rock
fire resistant
silica fire
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CN2012103731245A
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CN102863229B (en
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许庆华
李学东
许盛英
袁长兵
蒋文兰
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Rugao Fan Chuan Trading Co Ltd
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许庆华
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Abstract

The invention discloses basic refractory attapulgite volcaniclastic-rock aggregate sand. The basic refractory attapulgite volcaniclastic-rock aggregate sand in the technical scheme is mainly characterized by comprising highly-viscous attapulgite clay powder, dolomite attapulgite clay tailings, volcaniclastic rock mixture, magnesite, serpentine, coal gangue and bentonite tailings. A finished product of the basic refractory attapulgite volcaniclastic-rock aggregate sand is obtained by uniformly stirring the ingredients, crushing, soaking, extruding, roasting, crushing, screening and packaging. The basic refractory attapulgite volcaniclastic-rock aggregate sand has the advantages of good particle strength, high refractoriness and high basic slag resistance. The basic refractory attapulgite volcaniclastic-rock aggregate sand is made of a great quantity of various wastes, so that resource utilization rate is increased beneficially, the wastes turn into wealth, land occupation can be reduced, environmental protection and purification are achieved, energy is saved, and production cost is lowered. Besides, the basic refractory attapulgite volcaniclastic-rock aggregate sand is applicable to engineering such as basic steel refining furnaces, non-ferrous metal smelting furnaces and cement kilns.

Description

Attapulgite volcanoclastic rock alkalescence refractory aggregate sand
Technical field
The present invention relates to refractory materials, be specifically related to a kind of Attapulgite volcanoclastic rock alkalescence refractory aggregate sand.
Background technology
Basic refractory mainly refers to take the refractory materials that magnesium oxide, calcium oxide is main component, and basic refractory has stronger corrosion resistance to basic slag.
Mineral Resources in China 80% is intergrowth mineral, and a large amount of valuable resources retain among mine tailing, and tailings impoundment need to take a large amount of soils.A lot of Tailings Dams exceed the time limit or excess load is used, and even violation operation, make Tailings Dam have great potential safety hazard, and people's property and the life security of surrounding area caused to serious threat.
Attapulgite clay, except containing attapulgite, often contains the mineral such as wilkinite, kaolinite, hydromica, sepiolite, quartz, opal and carbonate.
With the volcanoclastic rock that also has of attapulgite clay ore deposit symbiosis, volcanoclastic rock is mostly on the upper strata in attapulgite clay ore deposit, the volcanoclastic rock ore bed on upper strata, some attapulgite clays mining area 'sthickness is up to tens of rice, at attapulgite clay in recovery process, the volcanoclastic rock on upper strata, attapulgite clay mining area is abandoned as waste, investigates factually, 1 ton of attapulgite clay of every exploitation, the volcanoclastic rock produced has more than 30 tons, by the output of producing 150000 tons per year, calculate, the volcanoclastic rock of generation, up to 4,500,000 tons, all can be utilized for many years, whole mining area is the volcanoclastic rock mixture of again piling up everywhere, causes the serious wasting of resources and financial loss.
Coal gangue is thrown aside, takies tract, and sulfide in coal gangue is overflowed or leached can atmosphere pollution, farmland and water body, and waste dump also can the spontaneous combustion presence of fire, or, in the avalanche in rainy season, silts river up and cause disaster.
Summary of the invention
The objective of the invention is to overcome weak point in prior art, a kind of Attapulgite volcanoclastic rock alkalescence refractory aggregate sand is provided.
The batching of Attapulgite volcanoclastic rock alkalescence refractory aggregate sand is comprised of the sticky attapulgite clay powder of height, rhombspar attapulgite clay mine tailing, volcanoclastic rock mixture, magnesite, serpentine, coal gangue and wilkinite mine tailing.
The production method of Attapulgite volcanoclastic rock alkalescence refractory aggregate sand: the finished product that the batching of Attapulgite volcanoclastic rock alkalescence refractory aggregate sand is stirred and pulverized, soak, be packaged as Attapulgite volcanoclastic rock alkalescence refractory aggregate sand after extruding, roasting, pulverizing and screening.
Attapulgite clay be a kind of layer of chain-like structure containing Shuifu County's zeopan clay mineral, attapulgite clay soil property exquisiteness, water-absorbent is strong, tool viscosity and plasticity-when wet, be conducive to the bonding between raw material, can improve the granule strength of Attapulgite volcanoclastic rock alkalescence refractory aggregate sand.
High sticky attapulgite clay powder refers to gets 28.0g attapulgite clay powder sample, add in the suspension cup of homogenizer, add again 372g water, the suspension cup is placed on homogenizer, under the rotating speed of 11000 rev/mins, stir 20 minutes, to pour in the beaker of 250ml through the high-speed stirring sample suspension again the viscosity of using NDJ-1 type rotational viscosimeter to be tested its suspension, tested viscosity value>=2200 into mPasthe attapulgite clay powder be high sticky attapulgite clay powder, the height that the present invention selects glues attapulgite clay powder particles fineness≤0.074 millimeter.
Attapulgite clay can mix in recovery process a certain amount of rubble and earth, as a kind of attapulgite clay mine tailing, abandon, cause a large amount of wastings of resources, more containing magnesian amount in the rhombspar attapulgite clay, and quality is harder, the rhombspar attapulgite clay mine tailing particle fineness that the present invention selects≤1.0 millimeters.
Volcanoclastic rock is the rock of the transitional type between magma lava and sedimentogeneous rock, wherein the composition more than 50% is comprised of the material of pyroclastic flow ejection, and these tephras are mainly the lava of premature coagulation on volcano, the rock formation that passage is burst on every side when volcanic eruption.The volcanoclastic rock mixture comprises landwaste, brilliant bits, glassiness bits, slurry bits, volcanic block (diameter is greater than 100 millimeters), volcanic gravel (diameter is greater than 2 millimeters) and volcanic ash (diameter is less than 2 millimeters), the volcanoclastic rock main chemical compositions is silicon-dioxide and aluminum oxide, there is fire performance and the intensity that increases Attapulgite volcanoclastic rock alkalescence refractory aggregate sand, the volcanoclastic rock particle fineness that the present invention selects≤5.0 millimeters preferably.
Magnesite is a kind of magnesiumcarbonate mineral, and it is the main source of magnesium, the using magnesite granule fineness that the present invention selects≤2.0 millimeters.
Serpentine is high magnesium mineral, has heat-resisting, anticorrosive, wear-resisting, heat insulation, sound insulation, operational characteristic preferably, the serpentine particles fineness that the present invention selects≤2.0 millimeters.
Coal gangue is the solid waste discharged in coal mining process and coal washing process, there is lower heating value, carbon containing 20~30%, the present invention uses coal gangue can save part coal, increase the content of aluminum oxide, improve the intensity of Attapulgite volcanoclastic rock alkalescence refractory aggregate sand, the coal gangue particle fineness that the present invention selects≤3.0 millimeters.
The rock that wilkinite mainly is comprised of wilkinite, it is the important raw mineral materials of field of metallurgy, the wilkinite mine tailing that the present invention selects is distributed in the lower floor in attapulgite clay ore deposit mostly, be difficult to carry out independent exploitation, but the content of aluminum oxide >=16% in the wilkinite mine tailing, and there is plasticity-and agglutinating value(of coal), the coal gangue particle fineness that the present invention selects≤1.0 millimeters.
The present invention is achieved by following technical proposals:
1, the batching of Attapulgite volcanoclastic rock alkalescence refractory aggregate sand is comprised of following component by weight percentage: high sticky attapulgite clay powder 2~15%, rhombspar attapulgite clay mine tailing 5~25%, volcanoclastic rock mixture 15~35%, magnesite 5~35%, serpentine 5~25%, coal gangue 2~15% and wilkinite mine tailing 2~15%;
The production method of described Attapulgite volcanoclastic rock alkalescence refractory aggregate sand: (1) the batching of Attapulgite volcanoclastic rock silica fire resistant aggregate sand is added in the two shaft pugmill mixer moved and stirs, stirring, to pulverize in rear input pulverizer be the mixture of Attapulgite volcanoclastic rock silica fire resistant aggregate sand, the particle fineness of Attapulgite volcanoclastic rock silica fire resistant aggregate sand mixture≤0.5 millimeter; (2) will in Attapulgite volcanoclastic rock silica fire resistant aggregate sand mixture input fermentation vat, soak, soak time is controlled at 24~72 hours; (3) in the Attapulgite volcanoclastic rock silica fire resistant aggregate sand mixture input pair roller extrusion machine after soaking, extruding is flap, the thickness of flap≤3.0 millimeter; (4) by Attapulgite volcanoclastic rock silica fire resistant aggregate sand flap input rotary type roasting roasting in kilns, maturing temperature is controlled at 650~950 ℃; (5) cooled Attapulgite volcanoclastic rock silica fire resistant aggregate sand flap is pulverized and screening, the Attapulgite volcanoclastic rock silica fire resistant aggregate sand particle fineness after screening≤1.0 millimeters, be packaged as the finished product of Attapulgite volcanoclastic rock silica fire resistant aggregate sand;
Described batching when soaking in Attapulgite volcanoclastic rock silica fire resistant aggregate sand mixture input fermentation vat, be comprised of following component: Attapulgite volcanoclastic rock silica fire resistant aggregate sand mixture 55~80% and water 20~45% by weight percentage.
Attapulgite volcanoclastic rock alkalescence refractory aggregate sand has that granule strength is good, refractoriness is high, the strong characteristics of ability of opposing basic slag.
The various wastes of a large amount of employing in the batching of Attapulgite volcanoclastic rock alkalescence refractory aggregate sand, not only be conducive to improve resource utilization, turns waste into wealth, and can also reduce land occupation, and protection and environment purification, save the energy, reduces production costs, and increases economic efficiency.
Attapulgite volcanoclastic rock alkalescence refractory aggregate sand is applicable to the engineerings such as alkaline steel melting furnace, non-ferrous metal smelting furnace and cement kiln.
Embodiment
Below in conjunction with embodiment, the invention will be further described:
1, the batching of Attapulgite volcanoclastic rock alkalescence refractory aggregate sand is comprised of following component by weight percentage: high sticky attapulgite clay powder 10%, rhombspar attapulgite clay mine tailing 12%, volcanoclastic rock mixture 28%, magnesite 26%, serpentine 14%, coal gangue 6% and wilkinite mine tailing 4%;
The production method of described Attapulgite volcanoclastic rock alkalescence refractory aggregate sand: (1) the batching of Attapulgite volcanoclastic rock silica fire resistant aggregate sand is added in the two shaft pugmill mixer moved and stirs, stirring, to pulverize in rear input pulverizer be the mixture of Attapulgite volcanoclastic rock silica fire resistant aggregate sand, the particle fineness of Attapulgite volcanoclastic rock silica fire resistant aggregate sand mixture≤0.5 millimeter; (2) will in Attapulgite volcanoclastic rock silica fire resistant aggregate sand mixture input fermentation vat, soak, soak time is controlled at 48 hours; (3) in the Attapulgite volcanoclastic rock silica fire resistant aggregate sand mixture input pair roller extrusion machine after soaking, extruding is flap, the thickness of flap≤3.0 millimeter; (4) by Attapulgite volcanoclastic rock silica fire resistant aggregate sand flap input rotary type roasting roasting in kilns, maturing temperature is controlled at 800~900 ℃; (5) cooled Attapulgite volcanoclastic rock silica fire resistant aggregate sand flap is pulverized and screening, the Attapulgite volcanoclastic rock silica fire resistant aggregate sand particle fineness after screening≤1.0 millimeters, be packaged as the finished product of Attapulgite volcanoclastic rock silica fire resistant aggregate sand;
Described batching when soaking in Attapulgite volcanoclastic rock silica fire resistant aggregate sand mixture input fermentation vat, be comprised of following component: Attapulgite volcanoclastic rock silica fire resistant aggregate sand mixture 72% and water 28% by weight percentage.

Claims (1)

1. Attapulgite volcanoclastic rock alkalescence refractory aggregate sand, it is characterized in that, the batching of Attapulgite volcanoclastic rock alkalescence refractory aggregate sand is comprised of following component by weight percentage: high sticky attapulgite clay powder 2~15%, rhombspar attapulgite clay mine tailing 5~25%, volcanoclastic rock mixture 15~35%, magnesite 5~35%, serpentine 5~25%, coal gangue 2~15% and wilkinite mine tailing 2~15%;
The production method of described Attapulgite volcanoclastic rock alkalescence refractory aggregate sand: (1) the batching of Attapulgite volcanoclastic rock silica fire resistant aggregate sand is added in the two shaft pugmill mixer moved and stirs, stirring, to pulverize in rear input pulverizer be the mixture of Attapulgite volcanoclastic rock silica fire resistant aggregate sand, the particle fineness of Attapulgite volcanoclastic rock silica fire resistant aggregate sand mixture≤0.5 millimeter; (2) will in Attapulgite volcanoclastic rock silica fire resistant aggregate sand mixture input fermentation vat, soak, soak time is controlled at 24~72 hours; (3) in the Attapulgite volcanoclastic rock silica fire resistant aggregate sand mixture input pair roller extrusion machine after soaking, extruding is flap, the thickness of flap≤3.0 millimeter; (4) by Attapulgite volcanoclastic rock silica fire resistant aggregate sand flap input rotary type roasting roasting in kilns, maturing temperature is controlled at 650~950 ℃; (5) cooled Attapulgite volcanoclastic rock silica fire resistant aggregate sand flap is pulverized and screening, the Attapulgite volcanoclastic rock silica fire resistant aggregate sand particle fineness after screening≤1.0 millimeters, be packaged as the finished product of Attapulgite volcanoclastic rock silica fire resistant aggregate sand;
Described batching when soaking in Attapulgite volcanoclastic rock silica fire resistant aggregate sand mixture input fermentation vat, be comprised of following component: Attapulgite volcanoclastic rock silica fire resistant aggregate sand mixture 55~80% and water 20~45% by weight percentage;
The sticky attapulgite clay powder of described height refers to gets 28.0g attapulgite clay powder sample, add in the suspension cup of homogenizer, add again 372g water, the suspension cup is placed on homogenizer, under the rotating speed of 11000 rev/mins, stir 20 minutes, to pour in the beaker of 250ml through the high-speed stirring sample suspension again the viscosity of using NDJ-1 type rotational viscosimeter to be tested its suspension, tested viscosity value>=2200 into mPasthe attapulgite clay powder be high sticky attapulgite clay powder, the height that the present invention selects glues attapulgite clay powder particles fineness≤0.074 millimeter.
CN2012103731245A 2012-09-30 2012-09-30 Basic refractory attapulgite volcaniclastic-rock aggregate sand Expired - Fee Related CN102863229B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103265310A (en) * 2013-06-07 2013-08-28 许盛英 Medical stone flame retardant foaming agent
CN103265314A (en) * 2013-06-07 2013-08-28 许盛英 Serpentine flame retardant foaming agent
CN108755246A (en) * 2018-06-11 2018-11-06 淮阴工学院 The method that low-grade recessed soil prepares Retention Aid in Papermaking

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10231166A (en) * 1997-02-18 1998-09-02 Tokyo Yogyo Co Ltd Baked building material block utilizing waste
CN101348626A (en) * 2008-09-17 2009-01-21 中国建筑材料科学研究总院 Temperature adjustment coating and preparation thereof
CN102503323A (en) * 2011-11-10 2012-06-20 许庆华 Baking-free cylindrical attapulgite fire-retarding ceramsite
CN102503490A (en) * 2011-11-10 2012-06-20 许庆华 Baking-free gravel attapulgite fire-retarding ceramsite

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH10231166A (en) * 1997-02-18 1998-09-02 Tokyo Yogyo Co Ltd Baked building material block utilizing waste
CN101348626A (en) * 2008-09-17 2009-01-21 中国建筑材料科学研究总院 Temperature adjustment coating and preparation thereof
CN102503323A (en) * 2011-11-10 2012-06-20 许庆华 Baking-free cylindrical attapulgite fire-retarding ceramsite
CN102503490A (en) * 2011-11-10 2012-06-20 许庆华 Baking-free gravel attapulgite fire-retarding ceramsite

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103265310A (en) * 2013-06-07 2013-08-28 许盛英 Medical stone flame retardant foaming agent
CN103265314A (en) * 2013-06-07 2013-08-28 许盛英 Serpentine flame retardant foaming agent
CN108755246A (en) * 2018-06-11 2018-11-06 淮阴工学院 The method that low-grade recessed soil prepares Retention Aid in Papermaking
CN108755246B (en) * 2018-06-11 2020-09-25 淮阴工学院 Method for preparing papermaking retention aid from low-grade attapulgite

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