CN102849959B - Production method and device for fly ash superfine fiber - Google Patents

Production method and device for fly ash superfine fiber Download PDF

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Publication number
CN102849959B
CN102849959B CN201210234864.0A CN201210234864A CN102849959B CN 102849959 B CN102849959 B CN 102849959B CN 201210234864 A CN201210234864 A CN 201210234864A CN 102849959 B CN102849959 B CN 102849959B
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China
Prior art keywords
cotton
fiber
raw material
flyash
fly ash
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CN201210234864.0A
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CN102849959A (en
Inventor
陈福金
黄妙源
陈敬榕
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Zhangjiagang Jin Fengzhen asset management company
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JIANGSU FUYANG NEW MATERIAL TECHNOLOGY Co Ltd
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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C13/00Fibre or filament compositions
    • C03C13/06Mineral fibres, e.g. slag wool, mineral wool, rock wool
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/002Use of waste materials, e.g. slags
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/076Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/083Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
    • C03C3/085Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
    • C03C3/087Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass

Abstract

The invention discloses a production method and a device for fly ash superfine fibers, and the method comprises the following steps: melting raw materials composed of a main raw material of fly ash and auxiliary materials of dolomite and slag, introducing the raw materials into a centrifuge for drawing to form fibers, simultaneously spraying a binder and dustproof oil on the fiber surfaces, blowing the fibers into a cotton-collecting machine to form a primary cotton layer, and then feeding the primary cotton layer into a granulating machine to form a uniform fiber cotton mass; the device comprises a melting system, a fiber-forming system, a cotton-collecting system and a granulating system. The invention effectively solves the problem of waste resource reutilization, and also solves the problem of environmental pollution caused by fly ash.

Description

A kind of production method of flyash ultra-fine fibre and device
Technical field
The present invention relates to a kind of production technique of ultra-fine fibre, relate in particular to a kind of production method and device of flyash ultra-fine fibre.
Background technology
In recent years, developing rapidly of China's power industry, has brought the sharply increase of flyash quantity discharged, and annual the discharged flyash total amount of Hazards in Power Plant increases year by year, and flyash discharges to the development of the national economy of China and ecotope and exerts heavy pressures on; On the other hand, China is again a country that per capita resource reserve is limited, and the comprehensive utilization of flyash has become an important techno-economic policy in China's economic construction, to solve China's electrical production environmental pollution, the important means of contradiction between resource shortage.
And in flyash, contain SiO 2, Al 2o 3, CaO, MgO, Fe 2o 3, the Multiple components such as FeO, therefore can use coal ash fiber to manufacture ultra-fine fibre for the alternative natural phant of preparation of raw material ultra-fine fibre, not only economical and practical, and be conducive to environmental protection.
Summary of the invention
The object of the present invention is to provide a kind of production method and device that saves flyash ultra-fine fibre, the method can utilize rejected fly ash resource to prepare ultra-fine fibre, the problem that efficiently solves waste resource recycling has solved the problem of environmental pollution that flyash causes simultaneously.
For achieving the above object, the present invention has adopted following technical scheme:
A kind of production method of flyash ultra-fine fibre; the method is: will take flyash as main raw material; after rhombspar, slag are the raw material fusing of auxiliary material composition; import drawing-off in whizzer and form fiber; at fiber surface, spray into surface adhesion agent and dust laying oil simultaneously; and fiber is blowed to cotton collecting machine and forms just cotton felt, subsequently first cotton felt is sent into tablets press and cut into uniform fiber cotton-wool, just can make target product.
Preferably, comprise the slag of the flyash of 50-80wt%, the rhombspar of 10-30wt% and 10-20wt% in described raw material, described slag preferably adopts iron smelting slag.
Particularly preferred, the acidity quotient of described raw material is at 2.0-3.
Preferably, described fiber cotton-wool diameter is 4-6cm.
A production equipment for flyash ultra-fine fibre, it comprises:
Be used for the system of founding of the raw materials melt mainly being formed by flyash;
For the melt-flow drawing-off by founding system output being become the fiberizing system of fiber, described fiberizing system comprise whizzer, the vane coordinating with whizzer and for spray the spraying mechanism of binding agent at fiber surface;
For collecting the fiber of being exported by fiberizing system, and be processed to form the just cotton system of collection of cotton felt, the cotton system of described collection is mainly comprised of triangle guipure cotton collecting machine;
For the first cotton felt of the cotton system output of collection being cut into the granulating system of fiber cotton-wool.
Preferably, described in, the system of founding comprises electric furnace.
Preferably, described fiberizing system comprises four roller whizzers, around the vane of the Centrifugal rolling setting in whizzer and for spray the spraying mechanism of binding agent and dust laying oil at fiber surface, and described vane is communicated with high pressure positive blower.
Preferably, described cotton collecting machine comprises cotton collecting chamber, the triangulation network, wind chamber, quill shaft, chain drive system, the cotton device of liter, sealed roller, slag ball tripping device and collection web plate purging system, and described slag ball tripping device comprises that front curtain, slag ball roller, slag ball stopper plate and slag ball pivot cutter, described collection web plate purging system comprise plural groups brush roll, water blast gun, high pressure air rifle, chute and blowing dryer.
Preferably, described granulating system comprises tablets press.
Compared with prior art, this real beneficial effect of the invention is: utilize rejected fly ash to make ultra-fine fibre, realized waste resource and again utilized, efficiently solve the routed weary and environmental issue of resource.
Accompanying drawing explanation
Fig. 1 is the schema of flyash ultra-fine fibre production method in a preferred embodiment of the present invention;
Fig. 2 is the structural representation of flyash ultra-fine fibre production equipment in Fig. 1 embodiment.
Embodiment
Below in conjunction with accompanying drawing and a preferred embodiment, technical scheme of the present invention is further described.
Consult Fig. 1-2, this coal ash ultra-fine fibre production equipment comprises electric furnace 1, whizzer 2, cotton collecting machine 3 and tablets press 4.
The production equipment that the present embodiment adopts comprises following integral part:
Found system: the system of founding adopts clean energy, that is, electric energy carries out inside heating to flyash at electric furnace 1, and it is introduced electric current in flyash solution by electrode, solution by electrode produces joule heating under the effect of alternating-current, thereby reaches the object of fusing and temperature adjustment.Electric furnace 1 power transmission is three electrode pair electric furnace 1 three phase supplies (power supply parameter is low voltage, large electric current) by being inserted above by electric furnace 1.Electrode is contained on electrode holde, adjusts the upper-lower position of electrode, to guarantee the temperature of melt with electrode holde.The interior melt of electric furnace 1 is flowed out by the electric furnace 1 special head piece in side.The iron restoring in melting process is emitted by putting iron machine in electric furnace 1 bottom side.
Fiberizing system: melt-flow falls into the whizzer 2 of being furnished with vane through movable chute, draftedly under the action of high-speed airflow providing with vane in high speed centrifugation power become fiber, also can spray into binding agent and dust laying oil by sprinkling system simultaneously, fiber is blown in cotton collecting machine 3, the separated pit that falls into of slag ball, is regularly transported by load wagon cleaning.
Collect cotton system: by the cotton mode of triangle guipure collection fiber that fiberizing system is sent into, that sprayed binding agent, collect.The fiber that contains binding agent, under the blowing of whizzer 2 and vane and the acting in conjunction of cotton collecting machine 3 suction wind, forms just cotton felt on the collection web plate surface of high-speed cruising.The square meter that collects the first cotton felt of speed adjustment of cotton drum by change weighs to reach the requirement of product, and meanwhile, the slag ball of generation passes through slag ball roller by effectively separated.
Granulating system: the first cotton felt that triangle guipure is collected is through tablets press 4, and cutting into diameter is the fiber cotton-wool of 4.5-5.5cm, and further that slag ball is separated with fiber cotton balls by roller screen.
Wherein, whizzer 2 adopts four roller whizzers, and it is around around the vane being communicated with high-pressure blowing-in equipment is set; Whizzer 2 can be designed to dolly form, and can walk in orbit, each roller of whizzer is fixed on tubular shaft, the latter is supported by the bearing of mist lubrication, each is by a motor-driven, each running roller is with chilled water unit, and high-temperature fusant, under the effect of four roller centrifugal force, is got rid of and makes fiber.Cotton collecting machine 3 adopts the cotton mode of triangle guipure collection, and it is mainly comprised of cotton collecting chamber, the triangulation network, wind chamber, quill shaft, chain drive system, the cotton device of liter, sealed roller, slag ball tripping device (comprising front curtain, slag ball roller, slag ball stopper plate, slag ball pivot cutter), collection web plate purging system (comprising three groups of brush rolls, water blast gun, high pressure air rifle, chute, blowing dryer), platform etc.
The production method that the present embodiment adopts is as follows: adopt and take flyash as main raw material, rhombspar, slag are the raw material that auxiliary material forms, and adopts electric furnace 1 fusing.Acceptable material, by after proportioning automatic weighing, is dropped in electric furnace 1 and is carried out electrically heated by conveyor, melt raw material, and electric furnace 1 Nei Wenduda is more than 1800 ℃, and melt is flowed out by electric furnace 1 stream material mouthful, through movable chute, is imported into whizzer 2 fibroblasts.Whizzer 2 forms by the Centrifugal rolling running up with around the vane outside Centrifugal rolling.The high-temperature fusant drawing-off under the centrifugal force of Centrifugal rolling and the compound action of the high velocity air being sprayed by vane that flows into whizzer 2 becomes fiber, and fiber is blowed to cotton collecting machine 3, in fiberizing process, the velocity contrast that utilizes itself and slag ball is separated the slag ball of fibroblast not effectively, very convenient, meanwhile, adopt air atomizing and multi-point injection mode, binding agent is applied to fiber surface equably.
Fiber is evenly adsorbed to the collection cotton of high-speed cruising and is with under the negative pressure wind suction function of cotton collecting machine 3, forms very thin first cotton felt, and first cotton felt is sent into tablets press 4.Tablets press 4 cuts into first cotton felt the fiber cotton-wool of diameter 4.5-5.5cm, and fiber cotton-wool rotates by roller screen, further that slag ball is separated with fiber cotton-wool.Remove the fiber cotton-wool of slag and just can pack warehouse-in.
Wherein, raw material packet is containing the slag of the flyash of 60wt%, the rhombspar of 20wt% and 20wt%, and its composition is roughly as follows: SiO 243.94wt%, Al 2o 312.58wt%, CaO 12.3wt%, MgO 9.64wt%, Fe 2o 3+ FeO 5.29wt%, Na 2o 2.70wt%, and its acidity quotient is about 2.0 left and right.
Below be only concrete exemplary applications of the present invention, protection scope of the present invention is not constituted any limitation.All employing equivalents or equivalence are replaced and the technical scheme of formation, within all dropping on rights protection scope of the present invention.

Claims (1)

1. the production method of a flyash ultra-fine fibre, it is characterized in that, the method is: will take flyash as main raw material, after rhombspar, ironmaking slag are the raw material fusing of auxiliary material composition, import drawing-off in whizzer and form fiber, at fiber surface, spray into binding agent and dust laying oil, and fiber is blowed to cotton collecting machine and forms just cotton felt simultaneously, subsequently first cotton felt is sent into tablets press and cut into the uniform fiber cotton-wool that diameter is 4-6cm, just can make target product;
Wherein, described raw material packet is containing the ironmaking slag of the flyash of 60wt%, the rhombspar of 20wt% and 20wt%, and described raw material is composed as follows: SiO 243.94wt%, Al 2o 312.58wt%, CaO12.3wt%, MgO9.64wt%, Fe 2o 3+ FeO5.29wt%, Na 2o2.70wt%; Meanwhile, the acidity quotient of described raw material is 2.0.
CN201210234864.0A 2012-07-09 2012-07-09 Production method and device for fly ash superfine fiber Active CN102849959B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108017272A (en) * 2017-12-16 2018-05-11 江苏巨盈节能环保科技有限公司 A kind of device of electric smelter production ultra-fine inorganic fibre
CN108264238A (en) * 2018-01-12 2018-07-10 杭州朗特建材有限公司 The process units and its production method of a kind of special fibre
CN112608021A (en) * 2020-11-28 2021-04-06 古县新源盛能源材料有限公司 Efficient production process and production equipment for special cellucotton

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EP1061053A1 (en) * 1999-01-04 2000-12-20 Nitto Boseki Co., Ltd. Rock wool using as raw material granulated municipal waste incineration ash and production method thereof
CN1314319A (en) * 2000-03-16 2001-09-26 赵善茂 Method for directly converting liquid exhaust boiler slag into asbestos
CN102173588A (en) * 2011-03-10 2011-09-07 内蒙古科技大学 Slag glass ceramic pipe and preparation method thereof
CN102531375A (en) * 2012-01-06 2012-07-04 山西国际电力科技有限公司 Method for preparing inorganic refractory fiber product from thermal-state pulverized fuel ash or slag
CN202766415U (en) * 2012-07-09 2013-03-06 江苏富祥新材料科技有限公司 Device for manufacturing superfine fibers from coal ash

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EP1061053A1 (en) * 1999-01-04 2000-12-20 Nitto Boseki Co., Ltd. Rock wool using as raw material granulated municipal waste incineration ash and production method thereof
CN1314319A (en) * 2000-03-16 2001-09-26 赵善茂 Method for directly converting liquid exhaust boiler slag into asbestos
CN102173588A (en) * 2011-03-10 2011-09-07 内蒙古科技大学 Slag glass ceramic pipe and preparation method thereof
CN102531375A (en) * 2012-01-06 2012-07-04 山西国际电力科技有限公司 Method for preparing inorganic refractory fiber product from thermal-state pulverized fuel ash or slag
CN202766415U (en) * 2012-07-09 2013-03-06 江苏富祥新材料科技有限公司 Device for manufacturing superfine fibers from coal ash

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Owner name: JIANGSU RICH AUSPICIOUS NEW MATERIAL TECHNOLOGY CO

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Address after: 215600 Fengzhen Zhangjiagang Yangtze River International Metallurgical Industry Zone, Jiangsu, China

Applicant after: Jiangsu Fuyang New Material Technology Co., Ltd.

Address before: Guangming Village Jin Fengzhen Zhangjiagang 215600 Jiangsu Province Yangtze River International Metallurgical Industrial Park

Applicant before: Jiangsu Fuxing New Material Technology Co.,Ltd.

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C53 Correction of patent for invention or patent application
CB03 Change of inventor or designer information

Inventor after: Chen Fujin

Inventor after: Huang Miaoyuan

Inventor after: Chen Jingrong

Inventor before: Chen Fujin

Inventor before: Huang Miaoyuan

Inventor before: Chen Jingrong

Inventor before: Yu Shuai

COR Change of bibliographic data

Free format text: CORRECT: INVENTOR; FROM: CHEN FUJIN HUANG MIAOYUAN CHEN JINGRONG YU SHUAI TO: CHEN FUJIN HUANG MIAOYUAN CHEN JINGRONG

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Denomination of invention: Production method and device for fly ash superfine fiber

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Address after: 215600 Jiangsu Yangtze River International Metallurgical Industrial Park, Jinfeng Town, Zhangjiagang City, Suzhou City, Jiangsu Province

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Address before: 215600 Yangtze River International Metallurgical Industrial Park, Jinfeng Town, Zhangjiagang City, Jiangsu Province (Yuqiao Village)

Patentee before: Jiangsu Fuyang New Material Technology Co., Ltd.

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