CN102848678B - A fiber composite material and its manufacturing method - Google Patents

A fiber composite material and its manufacturing method Download PDF

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Publication number
CN102848678B
CN102848678B CN201110176174.XA CN201110176174A CN102848678B CN 102848678 B CN102848678 B CN 102848678B CN 201110176174 A CN201110176174 A CN 201110176174A CN 102848678 B CN102848678 B CN 102848678B
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fibrous composite
manufacture method
release liners
fiber prepreg
layer
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CN102848678A (en
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田雅楠
张晓东
张建强
杨锦添
李江辉
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BYD Co Ltd
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BYD Co Ltd
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Abstract

A fiber composite material comprises a fiber layer with concave-convex patterns on the surface thereof; and a resin layer uniformly coated on at least one surface of the fiber layer, wherein the surface of the resin layer is provided with concave-convex patterns corresponding to the fiber layer. A method for manufacturing the fiber composite material is also provided. A fiber prepreg comprises a fiber layer with concave-convex patterns on the surface thereof, an isolation layer and a soft layer are coated to the surface of the fiber prepreg with the resin layer, and hot pressing is performed through a hot pressing mold, to display the concave-convex patterns of the fiber prepreg through the resin layer after the hot pressing. The manufactured fiber composite material has patterns corresponding to the concave-convex patterns of the fiber layer on the surface thereof, to provide comfortable hand feeling and antiskid property.

Description

A kind of fibrous composite and manufacture method thereof
Technical field
The present invention relates to fibrous composite field, be specifically related to a kind of fibrous composite and manufacture method thereof.
Background technology
Along with the development of electronics and information industry, hand-hold communication appliance such as the product such as mobile phone, panel computer obtains tremendous expansion, and market competition is day by day fierce.The outward appearance of the differentiation of product and feel can improve the competitiveness of product.The decorative pattern or the pattern that realize 3D on the surface of product not only can provide comfortable feel, increase aesthetics, can also strengthen the antiskid of product, scratch resistance.
Adopt forming plastic pieces to go out surperficial 3D decorative pattern comparatively simple and easy, only need to process corresponding decorative pattern in a mold, but due to plastic parts poor-performing, be difficult to meet the demands in shaping electronic product such as performance during panel computer.If employing metal material, one is to increase product weight, and two are feel and bad.Fibre reinforced materials obtains with the feature that the light intensity of its quality is high and applies more and more widely.Meanwhile, due to the property of fibre reinforced materials, cloth can be woven into as fiber, not only can be used as structural material, also can be used as incrustation.
The mainly fibre knitting cloth that current fibre reinforcing material uses as incrustation, the molding mode of forming method mainly hot pressing.Fibre knitting cloth surface after hot-forming is generally high light or matte effect.Because fibre knitting cloth itself has the surface effect of convex-concave, common forming method shaping complete after, fiber cover by matrix resin parcel, because resin is transparent, fiber is the equal of that " suspension " is within matrix resin, visual effect is 3D, but haptic effect remains plane, as shown in Figure 1, for the structural representation of existing fibrous composite, in figure, matrix resin 11 wraps up fibrous composite 10, the irregular 3D pattern of this fibrous composite surface tool, but matrix resin 11 surface is the structure of plane, and haptic effect is planar structure.
Summary of the invention
The present invention solves the problem that existing middle matrix resin surface is planar structure, thus provides fibrous composite and manufacture method thereof that a kind of matrix resin surface of wrapping up fibrous composite is concavo-convex 3D structure plan.
For solving the problems of the technologies described above, the invention provides following technical scheme:
A kind of fibrous composite, comprising: fibrage, its surface has relief pattern; Fibrolaminar at least one side is evenly coated with resin bed, and described resin layer surface is provided with the relief pattern corresponding with above-mentioned fibrage.
Present invention also offers a kind of manufacture method of fibrous composite, comprise the following steps: step one: provide Fiber prepreg, described Fiber prepreg comprises the fibrage that surface has relief pattern, and described fibrolaminar at least one side is soaked with resin bed; Step 2: have above resin bed in Fiber prepreg and be covered with one deck separation layer; Step 3: be covered with a soft layer on described separation layer; Step 4: hot pressing is carried out to the Fiber prepreg after above-mentioned steps process; Step 5: remove soft layer and separation layer.
Compared with prior art, the present invention has following beneficial effect: a kind of fibrous composite provided by the invention and manufacture method thereof, Fiber prepreg comprises the fibrage that surface has relief pattern, after Fiber prepreg has and is covered with separation layer and soft layer above resin bed, hot pressing is carried out by hot-die, the relief pattern lines of Fiber prepreg can be made to be displayed by resin bed after hot-pressing, the fibrous composite surface manufactured has the pattern corresponding with fibrage relief pattern, thus provides comfortable feel and non-skid property.
Accompanying drawing explanation
Fig. 1 is the structural representation of existing fibrous composite.
Fig. 2 is the flow chart of embodiment of the present invention fibrous composite manufacture method.
Fig. 3 is the schematic diagram of step 2 in Fig. 2 flow chart.
Fig. 4 is the schematic diagram of step 3 in Fig. 2 flow chart.
Fig. 5 is the schematic diagram not carrying out hot pressing in Fig. 2 flow chart step four.
Fig. 6 is the schematic diagram after carrying out hot pressing in Fig. 2 flow chart step four.
Fig. 7 removes the structural representation after soft layer and separation layer after being Fig. 2 flow chart step four.
Detailed description of the invention
In order to make technical problem solved by the invention, technical scheme and beneficial effect clearly understand, below in conjunction with drawings and Examples, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
A kind of fibrous composite, with reference to shown in Fig. 7, comprising: fibrage 20, its surface has relief pattern; At least one side of fibrage 20 is evenly coated with resin bed 21, and described resin bed 21 surface is provided with the relief pattern corresponding with above-mentioned fibrage 20; Thus this fibrous composite surface has the pattern corresponding with fibrolaminar relief pattern.The present embodiment have employed and is evenly coated with resin bed 21 on the two sides of fibrage 20, and this resin bed 21 is for having the novolac epoxy resin of heat resistance.
Present invention also offers a kind of manufacture method of fibrous composite, with reference to shown in Fig. 2, the flow chart of embodiment of the present invention fibrous composite manufacture method, comprise the following steps: step one: Fiber prepreg is provided, described Fiber prepreg comprises the fibrage that surface has relief pattern, and described fibrolaminar at least one side is soaked with resin bed; Step 2: have above resin bed in Fiber prepreg and be covered with one deck separation layer; Step 3: be covered with a soft layer on described separation layer; Step 4: lead to and hot pressing is carried out to the Fiber prepreg after above-mentioned steps process; Step 5: remove soft layer and separation layer.Fiber prepreg comprises the fibrage that surface has relief pattern, after Fiber prepreg has and is covered with separation layer and soft layer above resin bed, hot pressing is carried out by hot-die, the relief pattern lines of Fiber prepreg can be made to be displayed by resin bed after hot-pressing, the fibrous composite surface manufactured has the pattern corresponding with fibrage relief pattern, thus provides comfortable feel and non-skid property.
All there is resin bed for fibrolaminar two sides below, the detailed step of fibrous composite manufacture method of the present invention be described in detail in detail:
Step one: provide Fiber prepreg, described Fiber prepreg comprises the fibrage 20 that surface has relief pattern, and described fibrolaminar at least one side is soaked with resin bed 21, and this resin bed 21 is for having the novolac epoxy resin of heat resistance.
Step 2: have above resin bed in Fiber prepreg and be covered with one deck separation layer 22; As shown in Figure 3, the epoxy resin layer of the present embodiment on two sides is covered with separation layer 22 on the surface; Separation layer 22 in the present embodiment is release liners, release liners can select PE(polyethylene, polyethylene) release liners, PET(polyethylene terephthalate, PETG) release liners, OPP(O-phenylphenol, o-phenyl phenol) one in release liners or compound release liners, because release liners just plays the effect of isolation, so its thickness gets over Bao Yuehao, existing release liners general thickness is 0.03 ~ 0.05mm, and the release liners in this thickness range can meet the demands.The area of release liners is greater than the area of Fiber prepreg, because when hot pressing, have resin and flow out, this part resin flowed out, if in release liners, is just unlikely to flow on mould.Because the content of resin in Fiber prepreg is different, the area larger than the area of Fiber prepreg 30% ~ 50% of release liners.
Step 3: be covered with a soft layer 23 on described separation layer, as shown in Figure 4; This soft layer 23 can select flexible film material, and should meet following two conditions: 1, soft, can not be broken or crack after can making bending; 2, easily sprawl, easily pave when making shaping on release liners surface.Soft layer material can be formed at the identical shape in Fiber prepreg surface with the part of Fiber prepreg surface contact when being heated, because this portion of material needs to utilize its morphotropism, so thickness can not be too thin, General Requirements is not less than 0.05mm; Simultaneously can not be too thick, if thickness is too large, the heat conduction of mould can be made to be affected, and General Requirements is not higher than 0.1mm.Certainly, if in practical condition, the lines of Fiber prepreg is very wide, can choose thicker flexible film material.The material of soft layer is thermoplastic or thermosets; Thermoplastic can select TPU (Thermoplastic polyurethanes, TPUE rubber), and this material can deliquescing under certain temperature, and can remain unchanged at normal temperatures.Thermosets can select PU(ploy urethane, polyurethane) flexible film material is used for the decorative pattern of shaping fiber prepreg cloth, so its size should be in the same size with Fiber prepreg, when placing, its position also should match with prepreg cloth position.
Because the matrix material of Fiber prepreg is generally epoxy resin, and the cementability of epoxy resin is extremely strong, because release liners is not bonding with other material, if there is no release liners, directly overlay on Fiber prepreg by flexible film material, after shaping, both will be bonded together and cause being difficult to peel off.
Step 4: hot pressing is carried out to the above-mentioned material being covered with soft layer by hot-die; Release liners and flexible film material cover good after just can put into mould 24 hot pressing, as shown in Figure 5, be the schematic diagram not carrying out hot pressing in step 4, when non-plus-pressure and temperature, release liners and flexible film material indeformable; After plus-pressure and temperature, release liners and flexible film material can be out of shape, and as shown in Figure 6, are the schematic diagrames after carrying out hot pressing in step 4.Under suitable temperature and pressure, the resin solidification in Fiber prepreg forms the shape of surface relief.Hot pressing temperature generally selects 110 ~ 160 DEG C, the pressure of hot pressing generally select 5 ~ 30 kgfs/centimetre 2; Due to the distortion of flexible film material require, so the deformation temperature of flexible film material also should at 110 ~ 160 DEG C, and flexible film material thermal degradation temperature should higher than this scope.
Step 5: removal soft layer and separation layer as shown in Figure 7, remove the structural representation after soft layer and separation layer after being step 4; After hot pressing, goods are taken out in die sinking, and flexible film material now and release liners are bonded at product surface and take out with product, and product surface does not now have irregular 3D pattern effect.The concavo-convex 3D pattern effect of product surface must be obtained after needing flexible film material and release liners to remove.The method not only can shaping two-sided 3D effect, and the above embodiments are two-sided 3D pattern effect; Also the 3D lines of one side be can form, namely release liners and flexible film material added in one side; Its step is two-sided identical with aforementioned, repeats no more herein.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.

Claims (10)

1. a manufacture method for fibrous composite, is characterized in that, comprises the following steps:
Step one: Fiber prepreg is provided, described Fiber prepreg comprises the fibrage that surface has relief pattern, and described fibrolaminar at least one side is soaked with resin bed;
Step 2: have above resin bed in Fiber prepreg and be covered with one deck separation layer;
Step 3: be covered with a soft layer on described separation layer;
Step 4: hot pressing is carried out to the Fiber prepreg after above-mentioned steps process;
Step 5: remove soft layer and separation layer.
2. the manufacture method of fibrous composite according to claim 1, is characterized in that, described resin bed is novolac epoxy resin.
3. the manufacture method of fibrous composite according to claim 1, is characterized in that, described separation layer is release liners.
4. the manufacture method of fibrous composite according to claim 3, is characterized in that, described release liners is the one in PE release liners, PET release liners, OPP release liners or compound release liners.
5. the manufacture method of fibrous composite according to claim 3, is characterized in that, the thickness of described release liners is 0.03 ~ 0.05mm.
6. the manufacture method of fibrous composite according to claim 1, is characterized in that, the thickness of described soft layer is 0.05 ~ 0.1 mm.
7. the manufacture method of fibrous composite according to claim 1, is characterized in that, the material of described soft layer is thermoplastic or thermosets.
8. the manufacture method of fibrous composite according to claim 7, is characterized in that, described thermoplastic is TPUE rubber.
9. the manufacture method of fibrous composite according to claim 7, is characterized in that, described thermosets is polyurethane.
10. the manufacture method of fibrous composite according to claim 1, is characterized in that, described hot pressing temperature is 110 ~ 160 DEG C.
CN201110176174.XA 2011-06-28 2011-06-28 A fiber composite material and its manufacturing method Active CN102848678B (en)

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CN106285158A (en) * 2016-08-15 2017-01-04 云浮市欣粤电力器材有限公司 The production method of anti-skidding composite material electric pole
CN108582921A (en) * 2018-04-12 2018-09-28 江苏奥天利新材料有限公司 A kind of ultralow temperature penetration PVB intermediate coats

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW590888B (en) * 2002-10-24 2004-06-11 Tien Jiang Entpr Co Ltd Plastic composite material and method for producing product from composite material
CN101053988A (en) * 2006-04-13 2007-10-17 和成欣业股份有限公司 Panel forming method
CN101121310A (en) * 2006-08-10 2008-02-13 林雪霞 Method for manufacturing casing with textile fiber grain

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Publication number Priority date Publication date Assignee Title
JP2525120B2 (en) * 1993-08-19 1996-08-14 株式会社ワーロン Decorative synthetic resin plate

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW590888B (en) * 2002-10-24 2004-06-11 Tien Jiang Entpr Co Ltd Plastic composite material and method for producing product from composite material
CN101053988A (en) * 2006-04-13 2007-10-17 和成欣业股份有限公司 Panel forming method
CN101121310A (en) * 2006-08-10 2008-02-13 林雪霞 Method for manufacturing casing with textile fiber grain

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