CN102838161B - Tin disulfide intercalation compound and hydrothermal synthesis method thereof - Google Patents
Tin disulfide intercalation compound and hydrothermal synthesis method thereof Download PDFInfo
- Publication number
- CN102838161B CN102838161B CN201210359380.9A CN201210359380A CN102838161B CN 102838161 B CN102838161 B CN 102838161B CN 201210359380 A CN201210359380 A CN 201210359380A CN 102838161 B CN102838161 B CN 102838161B
- Authority
- CN
- China
- Prior art keywords
- intercalation compound
- tin disulfide
- tin
- intercalation
- synthesis method
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Catalysts (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
The invention relates to a tin disulfide intercalation compound and a hydrothermal synthesis method thereof. According to the intercalation compound, tin disulfide is taken as a main body; one or two of hexadecyl trimethyl ammonium bromide, sodium dodecyl benzene sulfonate, lauryl sodium sulfate and polyvinyl pyrrolidone is/are taken as an intercalation object(s), and the hexadecyl trimethyl ammonium bromide, the sodium dodecyl benzene sulfonate, the lauryl sodium sulfate or the polyvinyl pyrrolidone enter an interlayer of the tin disulfide, so that the intercalation compound can be obtained by using the hydrothermal synthesis method. Compared with the prior art, the hydrothermal synthesis method of the tin disulfide intercalation compound disclosed by the invention has the advantages of simple process, low production cost and the like.
Description
Technical field
The present invention relates to one and belong to inorganic materials preparing technical field, especially relate to a kind of tin disulfide intercalation compound and hydrothermal synthesis method thereof.
Background technology
The existing century-old history of discovery of intercalation compound.In 1841, C.Schafhautl immersed graphite in the mixed solution of sulfuric acid and nitric acid, found along almost reaching original twice perpendicular to the expansion of graphite in cleavage surface direction.At the beginning of 1930's, x-ray thing identification of phases technology is quite perfect, and the structure of the basic metal intercalation compound of graphite is determined by diffraction photo.Many mineral compound, as phosphoric acid salt, metal oxide, disulphide, layered silicate etc., also have typical laminate structure.The feature of these compounds be atom on laminate interact with strong covalent linkage and interlayer with power effect between Van der Waals force equimolecular.Due to Intermolecular Forces a little less than, under certain condition, between the mode saboteurs such as some polar molecules can be by adsorbing, insert, sandwich, suspension, pillared, embedding, power enters the interlayer of lamellar compound and does not destroy its laminate structure, this lamellar compound is called intercalation main body (Host), the polar molecule entering is called intercalation object (Guest), and product is called intercalated compound (Intercalation complex).Intercalation inorganic layered compounds is the important solid functional materials of a class, has wide application at numerous areas such as absorption, conduction, separation, environmental protection, biology, catalysis, thermoelectricity, transistor, Conversion of energy and storages.
Tin disulfide (SnS
2) also there is CdI
2the laminate structure of type, can be used as the host lattice of " intercalation ".From 1975, initial intercalation object was mainly the alkalimetal ion such as Li, Na, was mainly that research is by SnS
2as a kind of potential energy storage material, as anode material for lithium-ion batteries; Dicyclopentadienylcobalt intercalation compound receives long-term concern with its special magnetics, optics and electrology characteristic subsequently; Subsequently, the flexible high molecular material such as propylene carbonate, diamine and PVP, MEEP, POEGO, POMOE is also all used as SnS
2the intercalation object of intercalation compound.Recent study is found to insert SnS when MEH-PPV, PFO, F8, F8BT equiconjugate compound
2can form afterwards and there is unique optical property and the intercalation compound of photoelectric response characteristic.SnS
2the synthetic method of intercalation compound mainly contains by direct graft process, light assisted electrochemical synthesizes and LiSnS
2delamination composite algorithm, wherein LiSnS
2delamination composite algorithm is the main method of synthetic polymer intercalation sulfide.These are all first to form SnS
2material and then carry out intercalation, efficiency is lower; Generally need butyllithium etc. as intercalator simultaneously.Therefore the method that, develops the intercalation compound under new, mild conditions still awaits further exploitation.
Summary of the invention
Object of the present invention is exactly the defect existing in order to overcome above-mentioned prior art, especially present stage lacks the preparation method's of economic, effective tin disulfide intercalation compound present situation, provide a kind of in forming tin disulfide thing phase, under the effect of the intercalation objects such as cetyl trimethylammonium bromide, dodecyl sulfonated acid sodium, sodium lauryl sulphate and Polyvinylpyrolidone (PVP), original position forms the hydrothermal synthesis method of tin disulfide intercalation compound.The method technique is simple, and production cost is low, and the tin disulfide intercalation compound of gained can further meet industrial requirement.
Object of the present invention can be achieved through the following technical solutions:
A kind of tin disulfide intercalation compound, this intercalation compound is taking tin disulfide as main body, taking one or both in cetyl trimethylammonium bromide, Sodium dodecylbenzene sulfonate, sodium lauryl sulphate or Polyvinylpyrolidone (PVP) as intercalation object, cetyl trimethylammonium bromide, Sodium dodecylbenzene sulfonate, sodium lauryl sulphate or Polyvinylpyrolidone (PVP) enter into tin disulfide interlayer, expand tin disulfide interlamellar spacing.
A hydrothermal synthesis method for tin disulfide intercalation compound, comprises the following steps:
(1) be 1: 2～20: 4～32 to be mixed to join in reactor in molar ratio by pink salt, sulphur source and intercalation object, then add solvent, be made into the solution that pink salt concentration is 0.005-0.1mol/L, stir or ultrasonic dissolution;
(2) by reactor sealing, control temperature 140-220 DEG C, reaction times 1-72h, after reaction finishes, reactor is naturally cooled to room temperature, product is filtered or centrifugation, with absolute ethanol washing several, vacuum is drained, and obtains tin disulfide intercalation compound.
Described pink salt is selected from one or more in stannous oxalate, stannous sulfate, tin protochloride, tin chloride, tin acetate or stannous acetate.
Described sulphur source is compound or the simple substance that can discharge sulfonium ion.
Described sulphur source is thiocarbamide, dithiocarbonic anhydride or thioacetamide.
Described solvent is the hydrochloric acid soln of 0～2mol/L.Described intercalation object is one or both in cetyl trimethylammonium bromide, Sodium dodecylbenzene sulfonate, sodium lauryl sulphate and Polyvinylpyrolidone (PVP).
Compared with prior art, the present invention is generating tin disulfide nucleus, when producing tin disulfide single sheet, the intercalation objects such as cetyl trimethylammonium bromide, dodecyl sulfonated acid sodium, sodium lauryl sulphate and Polyvinylpyrolidone (PVP) produce to interact with tin disulfide single sheet and form composite single layer, along with further stacking, growth formation tin disulfide intercalation compound of composite single layer under the carrying out of reaction, the method technique is simple, production cost is low, and the tin disulfide intercalation compound of gained can further meet industrial requirement.
Brief description of the drawings
Fig. 1 is the XRD spectra of embodiment 1 gained cetyl trimethylammonium bromide/tin disulfide intercalation compound.
Fig. 2 is FESEM (a-b) and TEM (c-e) photo of embodiment 1 gained cetyl trimethylammonium bromide/tin disulfide intercalation compound.
Fig. 3 is embodiment 1 gained cetyl trimethylammonium bromide/tin disulfide intercalation compound (CTAB-SnS
2) and tin disulfide (SnS
2) ultraviolet-visible absorption spectroscopy.
Fig. 4 is the XRD spectra of embodiment 2 gained cetyl trimethylammonium bromide/tin disulfide intercalation compounds.
Fig. 5 is the XRD spectra of embodiment 3 gained cetyl trimethylammonium bromide/tin disulfide intercalation compounds.
Fig. 6 be embodiment 4 gained cetyl trimethylammonium bromide/tin disulfide intercalation compounds XRD spectra (a) and FESEM photo (b-c).
Fig. 7 be gained cetyl trimethylammonium bromide/tin disulfide intercalation compound XRD spectra (a, embodiment 5; B, embodiment 6; C, embodiment 7; D, embodiment 8).
Fig. 8 be gained cetyl trimethylammonium bromide/tin disulfide intercalation compound FESEM spectrogram (a, embodiment 5; B, embodiment 6; C, embodiment 7; D, embodiment 8).
Fig. 9 is the XRD spectra of embodiment 18 gained sodium lauryl sulphate/tin disulfide intercalation compounds.
Figure 10 is the XRD spectra of embodiment 19 gained sodium laurylsulfonate/tin disulfide intercalation compounds.
Figure 11 is the XRD spectra of embodiment 21 gained Polyvinylpyrolidone (PVP)/tin disulfide intercalation compounds.
Embodiment
Below in conjunction with the drawings and specific embodiments, the present invention is described in detail.
The structural characterization that the present invention adopts and the method for performance test:
X-ray diffraction (XRD): structure characterization methods be to adopt X ray-6000 (Shimadzu) type x-ray diffractometer (Cu targets, the filtering of nickel filter plate, λ=0.15406nm, tube voltage 40kV, tube current 30mA, 15 °～65 ° of sweep limits) method.
Scanning electron microscope (FESEM): be dispersed in water or ethanol ultrasonic obtained nanoparticle, drop on aluminium foil, after at room temperature naturally drying, paste and in sample table, be placed in the lower observation of FESEM (JEOL JSM-7401F) with conductive resin, the picture of acquisition is scanning electron microscope (SEM) image.
Transmission electron microscope (TEM): obtained nanoparticle is dispersed in water or ethanol, drop on the copper mesh that is sprayed with carbon film, at room temperature naturally dry, put into JEM-2010 type transmission electron microscope and observe the shape characteristic and the self-assembled structures thereof that under differential responses condition, obtain product, the picture of acquisition is transmission electron microscope (TEM) image.
Ultraviolet-visible light (UV-Vis) spectrum: sample preparation is become to certain concentration, taking water as reference liquid, use spectrograph (Uv 2450, Shimadzu UV-Vis) in quartz container, the photoabsorption situation of the compound of test gained.
Embodiment 1
1. first take cetyl trimethylammonium bromide (CTAB), the 0.8mmolSnCl of 6.4mmol
45H
2the thioacetamide of O, 3.2mmol and 80mL dilute hydrochloric acid (1mol/L) are to 250mL beaker, and at room temperature magnetic agitation is dissolved 30min, and obtaining concentration is 0.01M SnCl
4, 0.04M thioacetamide (x=4) and 0.16M CTAB solution (y=8).Gained solution is transferred in 100mL reactor, reacted after 48 hours at 180 DEG C
2. after reaction finishes, reactor naturally cools to room temperature, and product is filtered, and with absolute ethanol washing several, vacuum is drained, and obtains cetyl trimethylammonium bromide/tin disulfide intercalation compound.
Fig. 1 is CTAB-SnS
2the XRD spectra of intercalation compound and SnS
2the standard spectrogram (JCPDS No.83-1705) of berndtite, two all show the feature basis of hexagonal system.According to Bragg equation, the XRD spectra of product is carried out indexing and can be obtained diffraction angle and the spacing of each characteristic diffraction peak.In hexagonal system, spacing and lattice parameter meet following relational expression:
Bragg equation is:
2d
hklsinθ
n＝nλ(n＝0，1，2，3......)
Wherein, a, c, be the unit cell parameters of hexagonal system; H, k, l, for integer is called diffraction index; Dhkl is the spacing of intercalation compound (hkl) face; N (integer) is diffraction progression; θ n is diffraction angle; λ is incident X-rays wavelength
The unit cell parameters that can calculate intercalation compound according to above relational expression and XRD spectra is:
And the unit cell parameters of standard SnS2 berndtite (JCPDS No.83-1705) is:
Obviously, the intercalation of CTAB is difficult to change the Atomic Arrangement on a direction of principal axis, and its unit cell parameters does not change, and shows that S-Sn-S layer does not deform.What answer in contrast is can observe obvious expansion in c-axis direction, and this is the result of intercalation.In c-axis direction, interlamellar spacing has expanded
Can find out that from the FESEM photo (Fig. 2 a-b) of typical ct findings AB-SnS2 intercalation compound product is the flower-shaped multi-stage micro-nano structure of elliposoidal that is of a size of 2-3 μ m, this structure is to be assembled by finer and close smooth surface, nanometer sheet in irregular shape.(Fig. 2 c) has further proved that this structure is the three-dimensional multistage micro-nano structure being assembled by nanometer sheet to TEM photo.From Fig. 2 d can find these nanometer sheet by thinner (being less than 10nm), have that the nano flake of irregular profile is formed by stacking.(spacing that Fig. 2 e) is presented at the lattice fringe on two-dimensional directional is the TRTEM of tiling nano flake
this and the spacing of (100) face
basically identical; The lattice fringe that can find nano flake from figure also discontinuous simultaneously, illustrates that nano flake has a lot of amorphous domain or lattice distortion region, and this (100) face diffraction peak intensity is lower is consistent.
Intercalation compound strengthens to some extent at the luminous absorptance tin disulfide of visible region.
Embodiment 2
Step is with embodiment 1, and difference is that the sulphur source in embodiment 1 is become to thiocarbamide.Fig. 4 shows that product is intercalation compound.
Embodiment 3
Step is with embodiment 1, and difference is that the sulphur source in embodiment 1 is become to dithiocarbonic anhydride.Fig. 5 shows that product is intercalation compound.
Embodiment 4
Step is with embodiment 1, and difference is that the intercalation object concentration in embodiment 1 is become to 3.2mmol (y=4).Fig. 6 shows that product is intercalation compound.
Embodiment 5
Step is with embodiment 1, and difference is that the 80mL dilute hydrochloric acid (1mol/L) in embodiment 1 is changed into 80ml deionized water (0mol/L hydrochloric acid), and the reaction times is 1 hour.Fig. 7 .a shows that product is intercalation compound.Fig. 8 .a is the pattern of intercalation compound.
Embodiment 6
Step is with embodiment 5, and difference is to change the reaction times in embodiment 5 into 3 hours.Fig. 7 .b shows that product is intercalation compound.Fig. 8 .b is the pattern of intercalation compound.
Embodiment 7
Step is with embodiment 5, and difference is to change the reaction times in embodiment 5 into 12 hours.Fig. 7 c shows that product is intercalation compound.Fig. 8 c is the pattern of intercalation compound.
Embodiment 8
Step is with embodiment 5, and difference is to change the reaction times in embodiment 5 into 48 hours.Fig. 7 d shows that product is intercalation compound.Fig. 8 d is the pattern of intercalation compound.
Embodiment 9
Step is with embodiment 1, difference is to be 0.005mol/L by pink salt concentration in embodiment 1, the concentration of cetyl trimethylammonium bromide becomes 12.8mmol (y=32), and the consumption in sulphur source is changed into 8rnmol (x=20), and dilute hydrochloric acid concentration is 2mol/L.Product is intercalation compound.
Embodiment 10
Step is with embodiment 1, and difference is to be 0.1mol/L by pink salt concentration in embodiment 1.The concentration of cetyl trimethylammonium bromide becomes 32mmol (y=4), and the consumption in sulphur source is changed into 16mmol (x=2), and dilute hydrochloric acid concentration is 2mol/L.Product is intercalation compound.
Embodiment 11
Step is with embodiment 1, and difference is that temperature of reaction is 220 DEG C.Product is intercalation compound.
Embodiment 12
Step is with embodiment 1, and difference is that temperature of reaction is 140 DEG C, and the reaction times is 72 hours.Product is intercalation compound.
Embodiment 13
Step is with embodiment 1, and difference is that pink salt is stannous oxalate.Product is intercalation compound.
Embodiment 14
Step is with embodiment 1, and difference is that pink salt is stannous sulfate.Product is intercalation compound.
Embodiment 15
Step is with embodiment 1, and difference is that pink salt is tin protochloride.Product is intercalation compound.
Embodiment 16
Step is with embodiment 1, and difference is that pink salt is tin acetate.Product is intercalation compound.
Embodiment 17
Step is with embodiment 1, and difference is that pink salt is stannous acetate.Product is intercalation compound.
Embodiment 18
Step is with embodiment 1, and difference is that intercalation object is sodium lauryl sulphate.Fig. 9 shows that product is sodium lauryl sulphate/tin disulfide intercalation compound.
Embodiment 19
Step is with embodiment 1, and difference is that intercalation object is sodium laurylsulfonate.Figure 10 shows that product is sodium laurylsulfonate/tin disulfide intercalation compound.
Embodiment 20
Step is with embodiment 1, and difference is that intercalation object is the mixture (each 3.2mmol) of sodium laurylsulfonate and sodium lauryl sulphate.Product is intercalation compound.
Embodiment 21
Step is with embodiment 1, and difference is that intercalation object is 2g Polyvinylpyrolidone (PVP) ((C6H9NO) n, amount of substance is calculated as 18mmol, y=22.5 by repeating unit).Figure 11 shows that product is the poor Polyvinylpyrolidone (PVP)/tin disulfide intercalation compound of crystallinity.
Embodiment 22
A kind of tin disulfide intercalation compound, this intercalation compound is taking tin disulfide as main body, and taking cetyl trimethylammonium bromide as intercalation object, cetyl trimethylammonium bromide enters into tin disulfide interlayer, expands tin disulfide interlamellar spacing.The hydrothermal synthesis method of tin disulfide intercalation compound, comprises the following steps:
(1) by pink salt, sulphur source and intercalation object 1: 2: 4 in molar ratio for being mixed to join in reactor, then add deionized water as solvent, be made into the solution that pink salt concentration is 0.005mol/L, stirring and dissolving, wherein, the pink salt using is stannous oxalate, and sulphur source is thiocarbamide, and intercalation object is cetyl trimethylammonium bromide;
(2) by reactor sealing, control 140 DEG C of temperature, reaction times 72h, naturally cools to room temperature by reactor after reaction finishes, and product is filtered or centrifugation, and with absolute ethanol washing several, vacuum is drained, and obtains tin disulfide intercalation compound.
Embodiment 23
A kind of tin disulfide intercalation compound, this intercalation compound is taking tin disulfide as main body, taking Sodium dodecylbenzene sulfonate and sodium lauryl sulphate as intercalation object, Sodium dodecylbenzene sulfonate and sodium lauryl sulphate enter into tin disulfide interlayer, expand tin disulfide interlamellar spacing.The hydrothermal synthesis method of tin disulfide intercalation compound, comprises the following steps:
(1) by pink salt, sulphur source and intercalation object 1: 20: 32 in molar ratio for being mixed to join in reactor, then add solvent, be made into the solution that pink salt concentration is 0.1mol/L, ultrasonic dissolution, wherein, the pink salt using is tin protochloride and tin chloride, and sulphur source is thioacetamide, and intercalation object is Sodium dodecylbenzene sulfonate and sodium lauryl sulphate;
(2) by reactor sealing, control 220 DEG C of temperature, reaction times 1h, naturally cools to room temperature by reactor after reaction finishes, and product is filtered or centrifugation, and with absolute ethanol washing several, vacuum is drained, and obtains tin disulfide intercalation compound.
Claims (5)
1. a hydrothermal synthesis method for tin disulfide intercalation compound, is characterized in that, the method comprises the following steps:
(1) pink salt, sulphur source and intercalation object are mixed to join in reactor for 1:2～20:4～32 in molar ratio, then add solvent, be made into the solution that pink salt concentration is 0.005-0.1mol/L, stir or ultrasonic dissolution;
(2) by reactor sealing, control temperature 140-220 DEG C, reaction times 1-72h, naturally cools to room temperature by reactor after reaction finishes, and product is filtered or centrifugation, and with absolute ethanol washing several, vacuum is drained, and obtains tin disulfide intercalation compound;
Described intercalation object is one or both in cetyl trimethylammonium bromide, Sodium dodecylbenzene sulfonate, sodium lauryl sulphate and Polyvinylpyrolidone (PVP).
2. according to the hydrothermal synthesis method of tin disulfide intercalation compound as claimed in claim 1, it is characterized in that, described pink salt is selected from one or more in stannous oxalate, stannous sulfate, tin protochloride, tin chloride, tin acetate or stannous acetate.
3. according to the hydrothermal synthesis method of tin disulfide intercalation compound as claimed in claim 1, it is characterized in that, described sulphur source is compound or the simple substance that can discharge sulfonium ion.
4. according to the hydrothermal synthesis method of the tin disulfide intercalation compound as described in claim 1 or 3, it is characterized in that, described sulphur source is thiocarbamide, dithiocarbonic anhydride or thioacetamide.
5. according to the hydrothermal synthesis method of tin disulfide intercalation compound as claimed in claim 1, it is characterized in that the hydrochloric acid soln that described solvent is 0～2mol/L.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210359380.9A CN102838161B (en) | 2012-09-24 | 2012-09-24 | Tin disulfide intercalation compound and hydrothermal synthesis method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210359380.9A CN102838161B (en) | 2012-09-24 | 2012-09-24 | Tin disulfide intercalation compound and hydrothermal synthesis method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102838161A CN102838161A (en) | 2012-12-26 |
| CN102838161B true CN102838161B (en) | 2014-12-10 |
Family
ID=47365929
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210359380.9A Expired - Fee Related CN102838161B (en) | 2012-09-24 | 2012-09-24 | Tin disulfide intercalation compound and hydrothermal synthesis method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102838161B (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103373742B (en) * | 2013-07-05 | 2015-10-14 | 上海交通大学 | Hydrothermal Synthesis SnS 2the method of nano material |
| CN106587138A (en) * | 2015-10-19 | 2017-04-26 | 淮阴工学院 | Method for preparing morphology controllable tin sulfide nano material |
| CN106611837A (en) * | 2015-10-27 | 2017-05-03 | 上海交通大学 | Cobalt-intercalated molybdenum sulfide secondary battery material and preparation method and application thereof |
| CN107032345B (en) * | 2017-05-12 | 2019-05-24 | 湖南大学 | A kind of preparation method of compound between graphite layers |
| CN108249476B (en) * | 2018-01-17 | 2019-10-11 | 济南大学 | A kind of synthetic method and products obtained therefrom of SnS2/Mn3O4 three-dimensional multistage structure |
| CN111268720B (en) * | 2020-01-13 | 2022-07-01 | 信阳师范学院 | Preparation method of large interlayer spacing tin disulfide nanoflower sodium ion battery negative electrode material |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101950804A (en) * | 2010-07-14 | 2011-01-19 | 北京理工大学 | Method for preparing spherical SnS2 anode material of lithium ion battery |
| CN102101696A (en) * | 2010-12-02 | 2011-06-22 | 华东师范大学 | Preparation method of ethanediamine intercalation tin sulfide compound |
| CN102502791A (en) * | 2011-11-23 | 2012-06-20 | 陕西科技大学 | Method for preparing flower-cluster-shaped tin sulfide (SnS) nanometer particles by microwave hydrothermal method |
-
2012
- 2012-09-24 CN CN201210359380.9A patent/CN102838161B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101950804A (en) * | 2010-07-14 | 2011-01-19 | 北京理工大学 | Method for preparing spherical SnS2 anode material of lithium ion battery |
| CN102101696A (en) * | 2010-12-02 | 2011-06-22 | 华东师范大学 | Preparation method of ethanediamine intercalation tin sulfide compound |
| CN102502791A (en) * | 2011-11-23 | 2012-06-20 | 陕西科技大学 | Method for preparing flower-cluster-shaped tin sulfide (SnS) nanometer particles by microwave hydrothermal method |
Non-Patent Citations (4)
| Title |
|---|
| CTAB辅助微波水热合成花簇状SnS微球;张培培等;《无机化学学报》;20120229;第28卷(第2期);291-296 * |
| High stability and superior rate capability of three-dimensional hierarchical SnS2 microspheres as anode material in lithium ion batteries;Jiantao Zai et al.;《 Journal of Power Sources》;20101223;第196卷;3650-3654 * |
| Jiantao Zai et al..High stability and superior rate capability of three-dimensional hierarchical SnS2 microspheres as anode material in lithium ion batteries.《 Journal of Power Sources》.2010,第196卷3650-3654. * |
| 张培培等.CTAB辅助微波水热合成花簇状SnS微球.《无机化学学报》.2012,第28卷(第2期),291-296. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102838161A (en) | 2012-12-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Zhang et al. | Two‐dimensional transition metal carbides and nitrides (MXenes): synthesis, properties, and electrochemical energy storage applications | |
| Shinde et al. | Two-dimensional MXenes for electrochemical energy storage applications | |
| Jamil et al. | MXene based advanced materials for thermal energy storage: a recent review | |
| CN102838161B (en) | Tin disulfide intercalation compound and hydrothermal synthesis method thereof | |
| Qiu et al. | Current progress in black phosphorus materials and their applications in electrochemical energy storage | |
| Ye et al. | Serpent-cactus-like Co-doped Ni (OH) 2/Ni 3 S 2 hierarchical structure composed of ultrathin nanosheets for use in efficient asymmetric supercapacitors | |
| Ezeigwe et al. | One-step green synthesis of graphene/ZnO nanocomposites for electrochemical capacitors | |
| Xia et al. | Core-shell composite of hierarchical MoS2 nanosheets supported on graphitized hollow carbon microspheres for high performance lithium-ion batteries | |
| Jin et al. | Synthesis of unit-cell-thick α-Fe2O3 nanosheets and their transformation to γ-Fe2O3 nanosheets with enhanced LIB performances | |
| Yao et al. | Metal-organic framework derived flower-like FeS/C composite as an anode material in lithium-ion and sodium-ion batteries | |
| Li et al. | Research progress on transition metal sulfide-based materials as cathode materials for zinc-ion batteries | |
| Song et al. | Bottom-up approach design, band structure, and lithium storage properties of atomically thin γ-FeOOH nanosheets | |
| Jiang et al. | Facile synthesis and photocatalytic performance of self-assembly CuO microspheres | |
| Anandan et al. | Sonochemical synthesis and characterization of turbostratic MnNi (OH) 2 layered double hydroxide nanoparticles for supercapacitor applications | |
| Zhang et al. | Interface-induced enhanced electromagnetic wave absorption property of metal-organic frameworks wrapped by graphene sheets | |
| Fan et al. | 2D Fe2O3 nanosheets with bi-continuous pores inherited from Fe-MOF precursors: an advanced anode material for Li-ion half/full batteries | |
| Mao et al. | A new route for synthesizing VO2 (B) nanoribbons and 1D vanadium-based nanostructures | |
| Derkaoui et al. | Structural and optical properties of hydrothermally synthesized vanadium oxides nanobelts | |
| Ma et al. | Free-standing α-Co (OH) 2/graphene oxide thin films fabricated through delamination and reassembling of acetate anions intercalated α-Co (OH) 2 and graphene oxide in water | |
| Ma et al. | Ultra-large scale synthesis of Co–Ni layered double hydroxides monolayer nanosheets by a solvent-free bottom-up strategy | |
| CN102863955B (en) | Polyethylene glycol/stannic sulfide intercalation quantum dot and hydrothermal synthesis method | |
| Liu et al. | Liquid-phase exfoliation of NH4Co0. 4Ni0. 6PO4· H2O for energy storage device | |
| Lee et al. | Exfoliation of Dion-Jacobson layered perovskite into macromolecular nanoplatelet | |
| Hu et al. | Supercritical N, N-dimethylformamide exfoliation of the layered bulk titanate material into titania nanosheets | |
| Hu et al. | Low-temperature preparation of ultrathin nanoflakes assembled tremella-like NiO hierarchical nanostructures for high-performance lithium-ion batteries |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20141210 Termination date: 20170924 |