CN102827405A - Buffer block rubber composition for automobile - Google Patents
Buffer block rubber composition for automobile Download PDFInfo
- Publication number
- CN102827405A CN102827405A CN2012103475395A CN201210347539A CN102827405A CN 102827405 A CN102827405 A CN 102827405A CN 2012103475395 A CN2012103475395 A CN 2012103475395A CN 201210347539 A CN201210347539 A CN 201210347539A CN 102827405 A CN102827405 A CN 102827405A
- Authority
- CN
- China
- Prior art keywords
- buffer block
- parts
- weight part
- block rubber
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Images
Abstract
The invention discloses a buffer block rubber composition for an automobile, which is characterized by being prepared by raw materials in parts by weight: 60-70 parts of nature rubber, 30-40 parts of butadiene rubber, 1.5-2.5 parts of p-phenylenediamine anti-aging agent, 1.5-2.5 parts of dihydro-quinoline anti-aging agent, 2-4 parts of physical anti-aging agent, 3-5 parts of dispersion homogenizing agent, 30-50 parts of reinforcing agent, 3-5 parts of plasticizer, 10-20 parts of zinc methacrylate, 1.5-2.5 parts of vulcanizing agent, 5-8 parts of active agent, 1-3 parts of stearic acid and 1.6-2.0 parts of accelerant. According to the buffer block rubber composition, the hardness of rubber is improved, and the rubber content of the rubber is effectively increased, so that the buffer block rubber composition is more excellent in elasticity, is not easily deformed and is very small in deformation.
Description
Technical field
The present invention relates to a kind of automobile and use the buffer block thick rubber products, the rubber bumper that particularly a kind of light truck uses belongs to rubber item and chemical technology field.
Background technology
General automobile chassis buffer block material main composition is tree elastomer or its blended rubber; Natural gum has good elasticity and higher mechanical strength properties because of it, and is excellent from the reinforcement degree, cold-resistantly, anti-circumnutate, repeatedly deformation to give birth to heat few; Tension and characteristics such as wear-resisting are generally adopted.But, improve the whole damping effect of vehicle body and obviously improve because of the effect of chassis buffer block is that beating of vehicle bridge (axle) limited.Because buffer block is stressed bigger, frequent again buffering is squeezed.Shown in Fig. 1-2, be the structural representation of buffer block, described buffer block comprises the skeleton of bolt 3 compositions that pass back up pad 2, skeleton is provided with block rubber 1.Through sulfuration block rubber 1 and back up pad 2 are connected as one, through the bolt 3 that is welded on the back up pad 2 block rubber 1 is fixed on vehicle frame (vehicle body) or other position again, play the effect of restriction suspension range.Because buffer block is stressed bigger when spacing, particularly in the relatively poor environment operation down of road conditions, buffer block very likely is compressed serious or is the extreme higher position of jumping on the wheel.So this phenomenon will cause subframe to contact (being that iron bumps iron) with control arm, and noise increases, and damages vehicle frame even, if monolateral inefficacy will cause body roll, more seriously can cause vehicle body to run into wheel.
Because of gently card automobile chassis buffer block is stressed bigger; That the weather resistance fatigue experiment requires is very high (the height set deformation volume is not more than 10% after the vibration cycles 200000 times for ultimate load 28000N, frequency 1HZ); Under this reactive force, rigidity requirement is very high naturally could to satisfy its requirement.As everyone knows, want to increase substantially rigidity, must increase the hardness of rubber; Satisfy the rigidity requirement of this condition, ordinary rubber hardness will be promoted to about seventy or eighty degree, and has improved the hardness of rubber; Loading level increases; Gum content descends naturally, causes to cause rubber to lose advantages such as original snappiness and low compression set, thus the major cause that has also caused damping rubber block to lose efficacy.
Summary of the invention
Technical problem to be solved by this invention provides a kind of on-deformable high durometer rubber compsn that is used for gently blocking the automobile chassis buffer block.
In order to achieve the above object, technical scheme of the present invention provides a kind of on-deformable high durometer rubber compsn that is used for gently blocking the automobile chassis buffer block, it is characterized in that, is processed by following raw material in weight part:
Tree elastomer 60-70 weight part;
Cis-1,4-polybutadiene rubber 30-40 weight part;
P phenylenediamine type antioxidant 1.5-2.5 weight part;
Dihyaroquinoline class anti-aging agent 1.5-2.5 weight part;
Physical antioxidant 2-4 weight part;
Agent 3-5 weight part is uniformly dispersed;
Strengthening agent 30-50 weight part;
Softening agent 3-5 weight part;
Zinc methacrylate 10-20 weight part;
Vulcanizing agent 1.5-2.5 weight part;
Promoting agent 5-8 weight part;
Triple Pressed Stearic Acid 1-3 weight part;
Promotor 1.6-2.0 weight part.
Preferably, described tree elastomer is Vietnam SVR-3L.
Preferably, described cis-butadiene cement is the BR9000 of Shanghai Gaoqiao Chemical Manufacture.
Preferably, described p phenylenediamine type antioxidant is N-sec.-propyl-N '-diphenyl-para-phenylene diamine (antioxidant 4010NA).
Preferably, described dihyaroquinoline class anti-aging agent is 2,2,4-trimethylammonium-1,2-dichloride quinoline polymkeric substance (anti-aging agent RD).
Preferably, described physical antioxidant is a microcrystalline wax 1900.
Preferably, described softening agent is a NO.
Preferably, described strengthening agent is carbon black N-550.
Preferably, the described agent that is uniformly dispersed is WB212.
Preferably, described vulcanizing agent is a SULPHUR POWDER.
Preferably, described promoting agent zinc oxide.
Preferably, described promotor is dithiocarbamatetype accelerator.
Preferably, described dithiocarbamatetype accelerator is the mixture of zinc dibutyl dithiocarbamate (accelerant B Z) and N tert butyl benzothiazole 2 sulfenamide (accelerator NS).
The present invention has found that the effect that a kind of additive (zinc methacrylate) and other preferred compositions are produced is: can effectively in a kind of light card automobile chassis buffer block high durometer rubber compsn, give high firmness and high elastic coefficient; Reduce thick rubber products and under dynamic fatigue, give birth to heat greatly, resistance toheat is stable.The present invention has not improved the gum content of rubber effectively when having improved rubber hardness, make rubber combination elasticity of the present invention excellent more, and is yielding or its distortion is very little.With the combination of other title complex of the present invention after, strengthen roads test card through platform experiment and 30,000 kilometers, height permanent loss amount all is not more than 10%, can be good at keeping himself deflection and is far smaller than within institute's use range.
Description of drawings
Fig. 1 is the structural representation of buffer block;
Fig. 2 is the synoptic diagram of buffer block internal structure.
Among the figure:
1, block rubber; 2, back up pad; 3, bolt.
Embodiment
For making the present invention more obviously understandable,, elaborate as follows now with preferred embodiment.
A kind of automobile is used the buffer block rubber combination, is processed by following raw material in weight part:
60 parts of SVR-3L;
40 parts of BR9000;
2 parts of N-sec.-propyl-N '-diphenyl-para-phenylene diamine (antioxidant 4010NA);
2,2,4-trimethylammonium-1,2 parts in 2-dichloride quinoline polymkeric substance (anti-aging agent RD);
1,900 2 parts of microcrystalline waxes;
5 parts of NOs;
50 parts of N-550;
5 parts of WB212;
10 parts of zinc methacrylates;
8 parts in zinc oxide;
3 parts of Triple Pressed Stearic Acid;
2 parts in sulphur;
1.6 parts of N tert butyl benzothiazole 2 sulfenamides (accelerator NS);
0.4 part of zinc dibutyl dithiocarbamate (accelerant B Z).
Preparation technology is:
(1) one section mixing: the Banbury mixer temperature is risen to 140 ± 10 ℃, SVR-3L, BR9000 and zinc methacrylate are dropped in the Banbury mixer carry out banburying, the banburying time is 5-8min.Then zinc oxide, Triple Pressed Stearic Acid, anti-aging agent, microcrystalline wax and WB212 are dropped into banburying in the Banbury mixer, the banburying time is 3-5min.Then carbon black N-550, NO are dropped in the Banbury mixer and carry out banburying,, the banburying time is 5-8min.Carry out slice after time arrives and park, the storage period was greater than 8 hours.
(2) two-stage mixing: one section rubber unvulcanizate is put into Banbury mixer soften; The softening time is 30 seconds; The Banbury mixer temperature is 65 ± 15 ℃, then sulphur, promotor is dropped in the Banbury mixer and one section rubber unvulcanizate banburying, and the banburying time is 3-5min; Then send into and carry out in the mill twice thin leading to, put thick slice then.
(3) park: will pass through rubber unvulcanizate that above-mentioned steps accomplishes and put into thermostatic chamber and park, the storage period was greater than 12 hours.
(4) sulfuration: is 160 ± 10 ℃ with the rubber unvulcanizate that parks in temperature, and pressure vulcanizes under the condition of 15Mpa, and curing time is 10-15min, promptly draws goods after the sulfuration.
A kind of automobile is used the buffer block rubber combination, is processed by following raw material in weight part:
70 parts of SVR-3L;
30 parts of BR9000;
5 parts in zinc oxide;
1 part of Triple Pressed Stearic Acid;
2,2,4-trimethylammonium-1,2.5 parts in 2-dichloride quinoline polymkeric substance (anti-aging agent RD);
1.5 parts of N-sec.-propyl-N '-diphenyl-para-phenylene diamine (antioxidant 4010NA);
1,900 4 parts of microcrystalline waxes;
20 parts of zinc methacrylates;
3 parts of WB212;
3 parts of NOs;
30 parts of N-550;
1.7 parts of N tert butyl benzothiazole 2 sulfenamides (accelerator NS);
0.3 part of zinc dibutyl dithiocarbamate (accelerant B Z);
1.5 parts in sulphur.
Preparation technology is with embodiment 1.
A kind of automobile is used the buffer block rubber combination, is processed by following raw material in weight part:
60 parts of SVR-3L;
40 parts of BR9000;
6 parts in zinc oxide;
2 parts of Triple Pressed Stearic Acid;
2,2,4-trimethylammonium-1,1.5 parts in 2-dichloride quinoline polymkeric substance (anti-aging agent RD);
2.5 parts of N-sec.-propyl-N '-diphenyl-para-phenylene diamine (antioxidant 4010NA);
1,900 3 parts of microcrystalline waxes;
15 parts of zinc methacrylates;
4 parts of WB212;
4 parts of NOs;
40 parts of N-550;
1.8 parts of N tert butyl benzothiazole 2 sulfenamides (accelerator NS);
0.2 part of zinc dibutyl dithiocarbamate (accelerant B Z);
2.5 parts in sulphur.
Preparation technology is with embodiment 1.
Embodiment 4
A kind of automobile is used the buffer block rubber combination, is processed by following raw material in weight part:
65 parts of SVR-3L;
35 parts of BR9000;
7 parts in zinc oxide;
2 parts of Triple Pressed Stearic Acid;
2,2,4-trimethylammonium-1,2.5 parts in 2-dichloride quinoline polymkeric substance (anti-aging agent RD);
2.5 parts of N-sec.-propyl-N '-diphenyl-para-phenylene diamine (antioxidant 4010NA);
1,900 2 parts of microcrystalline waxes;
18 parts of zinc methacrylates;
4 parts of WB212;
5 parts of NOs;
50 parts of N-550;
1.5 parts of N tert butyl benzothiazole 2 sulfenamides (accelerator NS);
0.5 part of zinc dibutyl dithiocarbamate (accelerant B Z);
1.5 parts in sulphur.
Preparation technology is with embodiment 1.
The material of embodiment 1-4 preparation is carried out performance test, and testing data is following:
Table 1
The material that embodiment 1-4 makes is processed buffer block, carry out the stand long duration test, test-results is following:
Table 2
Claims (13)
1. an automobile is used the buffer block rubber combination, it is characterized in that, is processed by following raw material in weight part:
Tree elastomer 60-70 weight part;
Cis-1,4-polybutadiene rubber 30-40 weight part;
P phenylenediamine type antioxidant 1.5-2.5 weight part;
Dihyaroquinoline class anti-aging agent 1.5-2.5 weight part;
Physical antioxidant 2-4 weight part;
Agent 3-5 weight part is uniformly dispersed;
Strengthening agent 30-50 weight part;
Softening agent 3-5 weight part;
Zinc methacrylate 10-20 weight part;
Vulcanizing agent 1.5-2.5 weight part;
Promoting agent 5-8 weight part;
Triple Pressed Stearic Acid 1-3 weight part;
Promotor 1.6-2.0 weight part.
2. a kind of automobile according to claim 1 is used the buffer block rubber combination, it is characterized in that, described tree elastomer is Vietnam SVR-3L.
3. a kind of automobile according to claim 1 is used the buffer block rubber combination, it is characterized in that, described cis-butadiene cement is the BR9000 of Shanghai Gaoqiao Chemical Manufacture.
4. a kind of automobile according to claim 1 is used the buffer block rubber combination, it is characterized in that, described p phenylenediamine type antioxidant is N-sec.-propyl-N '-diphenyl-para-phenylene diamine.
5. a kind of automobile according to claim 1 is used the buffer block rubber combination, it is characterized in that, described dihyaroquinoline class anti-aging agent is 2,2,4-trimethylammonium-1,2-dichloride quinoline polymkeric substance.
6. a kind of automobile according to claim 1 is used the buffer block rubber combination, it is characterized in that, described physical antioxidant is a microcrystalline wax 1900.
7. a kind of automobile according to claim 1 is used the buffer block rubber combination, it is characterized in that, described softening agent is a NO.
8. a kind of automobile according to claim 1 is used the buffer block rubber combination, it is characterized in that, described strengthening agent is carbon black N-550.
9. a kind of automobile according to claim 1 is used the buffer block rubber combination, it is characterized in that, the described agent that is uniformly dispersed is WB212.
10. a kind of automobile according to claim 1 is used the buffer block rubber combination, it is characterized in that, described vulcanizing agent is a SULPHUR POWDER.
11. a kind of automobile according to claim 1 is used the buffer block rubber combination, it is characterized in that, described promoting agent zinc oxide.
12. a kind of automobile according to claim 1 is used the buffer block rubber combination, it is characterized in that, described promotor is dithiocarbamatetype accelerator.
13. a kind of automobile according to claim 1 is used the buffer block rubber combination, it is characterized in that, described dithiocarbamatetype accelerator is the mixture of zinc dibutyl dithiocarbamate and N tert butyl benzothiazole 2 sulfenamide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103475395A CN102827405A (en) | 2012-09-17 | 2012-09-17 | Buffer block rubber composition for automobile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012103475395A CN102827405A (en) | 2012-09-17 | 2012-09-17 | Buffer block rubber composition for automobile |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102827405A true CN102827405A (en) | 2012-12-19 |
Family
ID=47330734
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012103475395A Pending CN102827405A (en) | 2012-09-17 | 2012-09-17 | Buffer block rubber composition for automobile |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102827405A (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103483484A (en) * | 2013-09-08 | 2014-01-01 | 无为县大江橡塑制品有限公司 | Formula of engine cover buffer block |
| CN103724699A (en) * | 2013-12-16 | 2014-04-16 | 芜湖万润机械有限责任公司 | Buffer block rubber combination for automobile |
| CN104788743A (en) * | 2015-03-29 | 2015-07-22 | 安徽欧耐橡塑工业有限公司 | Abrasion-resistant cover rubber for steel wire rope core conveying belt |
| CN104837909A (en) * | 2013-01-09 | 2015-08-12 | 东洋橡胶工业株式会社 | Rubber composition for anti-vibration rubber |
| CN104927115A (en) * | 2015-06-29 | 2015-09-23 | 安徽中鼎减震橡胶技术有限公司 | Low-dynamic-ratio high-resistance rubber material and production method thereof |
| CN105694138A (en) * | 2016-01-29 | 2016-06-22 | 宁波远欣石化有限公司 | Elastic cushioning rubber material and preparation method thereof |
| CN106397864A (en) * | 2016-10-17 | 2017-02-15 | 上海众力投资发展有限公司 | Rubber composition for upper support of automobile shock absorber |
| CN106939089A (en) * | 2016-01-04 | 2017-07-11 | 江苏骆氏减震件有限公司 | A kind of elastomeric material, Preparation Method And The Use |
| CN110204798A (en) * | 2019-05-31 | 2019-09-06 | 安徽鼎连高分子材料股份有限公司 | A kind of Elevator roller rubber compound and manufacturing process for vertical lift elevator |
| CN114085433A (en) * | 2021-12-29 | 2022-02-25 | 江苏铁科新材料股份有限公司 | High-hardness rubber material suitable for injection molding and preparation process thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101649074A (en) * | 2009-09-17 | 2010-02-17 | 上海众力汽车部件有限公司 | Compression and fatigue resisting rubber composition |
| CN102341451A (en) * | 2009-08-07 | 2012-02-01 | 东海橡胶工业株式会社 | Vibration-damping rubber composition |
-
2012
- 2012-09-17 CN CN2012103475395A patent/CN102827405A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102341451A (en) * | 2009-08-07 | 2012-02-01 | 东海橡胶工业株式会社 | Vibration-damping rubber composition |
| CN101649074A (en) * | 2009-09-17 | 2010-02-17 | 上海众力汽车部件有限公司 | Compression and fatigue resisting rubber composition |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104837909A (en) * | 2013-01-09 | 2015-08-12 | 东洋橡胶工业株式会社 | Rubber composition for anti-vibration rubber |
| CN104837909B (en) * | 2013-01-09 | 2016-09-14 | 东洋橡胶工业株式会社 | Vibration-proof rubber rubber composition |
| CN103483484A (en) * | 2013-09-08 | 2014-01-01 | 无为县大江橡塑制品有限公司 | Formula of engine cover buffer block |
| CN103724699A (en) * | 2013-12-16 | 2014-04-16 | 芜湖万润机械有限责任公司 | Buffer block rubber combination for automobile |
| CN104788743A (en) * | 2015-03-29 | 2015-07-22 | 安徽欧耐橡塑工业有限公司 | Abrasion-resistant cover rubber for steel wire rope core conveying belt |
| CN104927115A (en) * | 2015-06-29 | 2015-09-23 | 安徽中鼎减震橡胶技术有限公司 | Low-dynamic-ratio high-resistance rubber material and production method thereof |
| CN106939089A (en) * | 2016-01-04 | 2017-07-11 | 江苏骆氏减震件有限公司 | A kind of elastomeric material, Preparation Method And The Use |
| CN105694138A (en) * | 2016-01-29 | 2016-06-22 | 宁波远欣石化有限公司 | Elastic cushioning rubber material and preparation method thereof |
| CN106397864A (en) * | 2016-10-17 | 2017-02-15 | 上海众力投资发展有限公司 | Rubber composition for upper support of automobile shock absorber |
| CN110204798A (en) * | 2019-05-31 | 2019-09-06 | 安徽鼎连高分子材料股份有限公司 | A kind of Elevator roller rubber compound and manufacturing process for vertical lift elevator |
| CN114085433A (en) * | 2021-12-29 | 2022-02-25 | 江苏铁科新材料股份有限公司 | High-hardness rubber material suitable for injection molding and preparation process thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102827405A (en) | Buffer block rubber composition for automobile | |
| CN101870777A (en) | High-hardness rubber composite for minitype automobile chassis buffer block | |
| CN102146169A (en) | High fatigue resistance rubber preparing raw material applied to automobile damping product | |
| CN102705411B (en) | Ozone-resisting supporting rubber vibration absorber of truck cab and preparation method of ozone-resisting supporting rubber vibration absorber | |
| CN103772758A (en) | Cushion for engine suspension system and preparation method thereof | |
| CN105754157B (en) | A kind of automobile chassis bush rubber composition | |
| CN103788505B (en) | A kind of sizing material of dynamic vibration absorber and preparation method thereof | |
| CN102634078A (en) | Tire shoulder pad rubber composition and preparation method | |
| CN101921413A (en) | Elastic side bearing body material for bogie of rail wagon | |
| CN104893125A (en) | Sponge rubber formula with good heat resistance and air tightness | |
| CN104987547B (en) | A kind of bushing of resistance to ozone stable and preparation method thereof | |
| CN109054117B (en) | Tread composition of low-rolling-resistance tire of all-steel truck | |
| CN111718521B (en) | Magnetic-sensitive rubber composition for rubber air spring and preparation method thereof | |
| CN106752403A (en) | One kind foaming nitrile rubber composite metal plate and preparation method thereof | |
| CN103788424A (en) | Formula for rubber used for automobile shock absorption products | |
| CN102134335B (en) | Intermediate supporting cushion rubber of transmission shaft | |
| CN106397864A (en) | Rubber composition for upper support of automobile shock absorber | |
| CN104877238A (en) | Rubber for locomotive torsion damper | |
| CN103205028A (en) | Organic clay rubber composite material for laminated rubber supporting seat and preparation process thereof | |
| CN101768294A (en) | Cord thread rubber compound for basic layer of automobile tire | |
| CN104927122A (en) | Dynamic fatigue resistant rubber | |
| CN102634082A (en) | Tire tread base rubber composition and preparation method | |
| CN101747537A (en) | Trend rubber for helicopter tires | |
| CN107759849A (en) | One kind combination material, sizing material and tire | |
| CN102093612A (en) | Truck engine mounting rubber preparation raw material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20121219 |