CN102795883B - High-strength aerated concrete building block produced by using electrolysis manganese residues and preparation method thereof - Google Patents
High-strength aerated concrete building block produced by using electrolysis manganese residues and preparation method thereof Download PDFInfo
- Publication number
- CN102795883B CN102795883B CN201210321664.9A CN201210321664A CN102795883B CN 102795883 B CN102795883 B CN 102795883B CN 201210321664 A CN201210321664 A CN 201210321664A CN 102795883 B CN102795883 B CN 102795883B
- Authority
- CN
- China
- Prior art keywords
- manganese residues
- electrolytic manganese
- water
- building block
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical group [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title claims abstract description 65
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 238000005868 electrolysis reaction Methods 0.000 title abstract description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 49
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000000843 powder Substances 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002994 raw material Substances 0.000 claims abstract description 22
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 17
- 239000000292 calcium oxide Substances 0.000 claims abstract description 16
- 235000012255 calcium oxide Nutrition 0.000 claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 16
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000004568 cement Substances 0.000 claims abstract description 15
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000004576 sand Substances 0.000 claims abstract description 14
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 9
- MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 claims abstract description 8
- 239000002904 solvent Substances 0.000 claims abstract description 8
- 238000005406 washing Methods 0.000 claims abstract description 8
- 239000000654 additive Substances 0.000 claims abstract description 7
- 239000004411 aluminium Substances 0.000 claims description 14
- 229910052782 aluminium Inorganic materials 0.000 claims description 14
- 239000012752 auxiliary agent Substances 0.000 claims description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 9
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 9
- 238000000227 grinding Methods 0.000 claims description 9
- 239000004571 lime Substances 0.000 claims description 9
- 239000011572 manganese Substances 0.000 claims description 9
- 229910052748 manganese Inorganic materials 0.000 claims description 8
- -1 polyethylene Polymers 0.000 claims description 8
- 239000011344 liquid material Substances 0.000 claims description 6
- 239000002893 slag Substances 0.000 claims description 6
- 239000000758 substrate Substances 0.000 claims description 6
- 230000000996 additive effect Effects 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N Glycolaldehyde Chemical class OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 239000012298 atmosphere Substances 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 238000005187 foaming Methods 0.000 claims description 4
- 239000003292 glue Substances 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 4
- 238000005520 cutting process Methods 0.000 claims description 3
- 238000010790 dilution Methods 0.000 claims description 3
- 239000012895 dilution Substances 0.000 claims description 3
- 238000012423 maintenance Methods 0.000 claims description 3
- 238000002203 pretreatment Methods 0.000 claims description 3
- 230000000284 resting effect Effects 0.000 claims description 3
- 235000013599 spices Nutrition 0.000 claims description 3
- 239000004115 Sodium Silicate Substances 0.000 claims description 2
- 238000004090 dissolution Methods 0.000 claims description 2
- 238000009775 high-speed stirring Methods 0.000 claims description 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 9
- 238000003756 stirring Methods 0.000 abstract description 2
- 239000002002 slurry Substances 0.000 abstract 1
- 229940077386 sodium benzenesulfonate Drugs 0.000 abstract 1
- 238000004064 recycling Methods 0.000 description 7
- 230000033228 biological regulation Effects 0.000 description 5
- 229910052602 gypsum Inorganic materials 0.000 description 5
- 239000010440 gypsum Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 150000004683 dihydrates Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000010881 fly ash Substances 0.000 description 3
- 229960001866 silicon dioxide Drugs 0.000 description 3
- 101100513612 Microdochium nivale MnCO gene Proteins 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 206010000269 abscess Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
- 229910052918 calcium silicate Inorganic materials 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 239000010883 coal ash Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
Abstract
Description
Project | GB6566-2000 | Measured value |
Internal radiation index | re | ≤1 | 0.2 |
External radiation exposure index | r | ≤1 | 0.3 |
Sio 2 | Cao | Mgo | Mno | Fe 2o 3 | Al 2o 3 | Na 2o | K 2o | Other | loss | Add up to |
32.6 | 11.9 | 1.1 | 4.2 | 12.1 | 5.8 | 0.2 | 0.6 | On a small quantity | 16.8 | 85.3 |
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210321664.9A CN102795883B (en) | 2012-08-31 | 2012-08-31 | High-strength aerated concrete building block produced by using electrolysis manganese residues and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210321664.9A CN102795883B (en) | 2012-08-31 | 2012-08-31 | High-strength aerated concrete building block produced by using electrolysis manganese residues and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
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CN102795883A CN102795883A (en) | 2012-11-28 |
CN102795883B true CN102795883B (en) | 2014-03-26 |
Family
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Family Applications (1)
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CN201210321664.9A Expired - Fee Related CN102795883B (en) | 2012-08-31 | 2012-08-31 | High-strength aerated concrete building block produced by using electrolysis manganese residues and preparation method thereof |
Country Status (1)
Country | Link |
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CN (1) | CN102795883B (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103253920A (en) * | 2013-06-09 | 2013-08-21 | 赣州腾远钴业有限公司 | Method for preparing concrete block by utilizing wet smelting leached waste residues of cobalt |
CN103992070A (en) * | 2014-05-05 | 2014-08-20 | 松桃鼎进新型材料有限公司 | Preparing process of electrolytic manganese residue autoclaved brick |
CN103979997B (en) * | 2014-05-07 | 2015-09-23 | 桂林理工大学 | A kind of water-quenched manganese slag that utilizes prepares the method for high strength gas concrete as aggregate |
CN104072036B (en) * | 2014-05-29 | 2016-03-23 | 蚌埠华东石膏有限公司 | A kind of containing electrolytic manganese residues concrete and preparation method thereof |
CN105599110B (en) * | 2015-12-23 | 2018-05-04 | 广西大学 | The method that non-autoclaved and unburned manganese slag brick is prepared using manganese ore acid-soaked waste residue |
CN108129161A (en) * | 2018-02-02 | 2018-06-08 | 曲水标威新型建材有限公司 | Composite aerated brick and preparation method |
CN110981386B (en) * | 2019-11-28 | 2021-10-15 | 湖南绿生科技发展有限公司 | Aerated concrete block produced from vanadium smelting slag and preparation method thereof |
CN114409352A (en) * | 2021-10-24 | 2022-04-29 | 湖南绿生永固新材料有限公司 | Method for producing autoclaved aerated concrete from high-strength light manganese smelting slag micro powder |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101698586A (en) * | 2009-11-06 | 2010-04-28 | 贵州省建筑材料科学研究设计院 | Aerated concrete produced by electrolytic manganese slag and preparation method thereof |
CN101864823A (en) * | 2010-06-10 | 2010-10-20 | 湖北声荣环保节能科技有限公司 | Aerated concrete building block produced by heavy metal-removed manganese carbonate tailing and manufacturing method thereof |
KR101099074B1 (en) * | 2011-07-04 | 2011-12-27 | 주식회사 제트콘코리아 | Concrete constitution |
CN102584139A (en) * | 2012-01-18 | 2012-07-18 | 中国铁道科学研究院金属及化学研究所 | Self-densifying concrete as well as preparation method and application thereof |
-
2012
- 2012-08-31 CN CN201210321664.9A patent/CN102795883B/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101698586A (en) * | 2009-11-06 | 2010-04-28 | 贵州省建筑材料科学研究设计院 | Aerated concrete produced by electrolytic manganese slag and preparation method thereof |
CN101864823A (en) * | 2010-06-10 | 2010-10-20 | 湖北声荣环保节能科技有限公司 | Aerated concrete building block produced by heavy metal-removed manganese carbonate tailing and manufacturing method thereof |
KR101099074B1 (en) * | 2011-07-04 | 2011-12-27 | 주식회사 제트콘코리아 | Concrete constitution |
CN102584139A (en) * | 2012-01-18 | 2012-07-18 | 中国铁道科学研究院金属及化学研究所 | Self-densifying concrete as well as preparation method and application thereof |
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Publication number | Publication date |
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CN102795883A (en) | 2012-11-28 |
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Legal Events
Date | Code | Title | Description |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
DD01 | Delivery of document by public notice | ||
DD01 | Delivery of document by public notice |
Addressee: Patent person in charge Document name: Notification that Application Deemed not to be Proposed |
|
TR01 | Transfer of patent right |
Effective date of registration: 20181219 Address after: 418000 Hunan Zhongfang County Industrial Park Huaihua Yonggu Energy-saving Wall Material Co., Ltd. Patentee after: HUAIHUA YONGGU ENERGY SAVING WALL MATERIAL Co.,Ltd. Address before: 418000 Hunan Zhongfang County Industrial Park Huaihua Yonggu Energy-saving Wall Material Co., Ltd. Patentee before: Liu Qiaoxing |
|
TR01 | Transfer of patent right | ||
CP03 | Change of name, title or address |
Address after: 418000 Hunan Province China County Industrial Park Huaihua YONGGU energy-saving wall materials Co. Ltd. Patentee after: Hunan Lvsheng YONGGU New Material Co.,Ltd. Address before: 418000 Hunan Zhongfang County Industrial Park Huaihua Yonggu Energy-saving Wall Material Co., Ltd. Patentee before: HUAIHUA YONGGU ENERGY SAVING WALL MATERIAL Co.,Ltd. |
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CP03 | Change of name, title or address | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140326 Termination date: 20210831 |
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CF01 | Termination of patent right due to non-payment of annual fee |