CN102785274A - Pretreatment method used before processing fast growing wood surface concave-convex textures - Google Patents

Pretreatment method used before processing fast growing wood surface concave-convex textures Download PDF

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Publication number
CN102785274A
CN102785274A CN2011101262510A CN201110126251A CN102785274A CN 102785274 A CN102785274 A CN 102785274A CN 2011101262510 A CN2011101262510 A CN 2011101262510A CN 201110126251 A CN201110126251 A CN 201110126251A CN 102785274 A CN102785274 A CN 102785274A
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fast growing
wood
solution
growing wood
present
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朱典想
王宏斌
朱捷
茆光华
李迎超
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Nanjing Forestry University
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Nanjing Forestry University
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Abstract

The invention relates to a pretreatment method used before processing fast growing wood surface concave-convex textures, wherein a purpose of the present invention is to overcome serious influence on strength and stiffness of fast growing wood due to traditional wood pretreatment chemical reagents such as strong acids and strong bases. The present invention provides a scheme for carrying out a softening pretreatment on Chinese redwood, paulownia, and pinus massoniana lamb by using a NH3.H2O solution separately providing an effect, wherein the Chinese redwood is treated for 2 hours at a temperature of 10 DEG C by using a 3% NH3.H2O solution, the paulownia is treated for 2 hours at a temperature of 30 DEG C by using a 2% NH3.H2O solution, and the pinus massoniana lamb is treated for 2 hours at a temperature of 30 DEG C by using a 2% NH3.H2O solution. The pretreatment method of the present invention has the following advantages that: strength of fast growing wood pretreated by the pretreatment process of the present invention is not significantly reduced; with processing, decorative solid wood boards with a large breadth and natural texture concave-convex effects are obtained; the product can be widely used in interior decorations and furniture manufacturing decorations; a new approach is developed for application of fast growing wood in engineering and industrial wood fields; no secondary pollution is generated, cost is low, and the processing method is easy to popularize.

Description

Preprocess method before the processing of fast growing wood concavo-convex veining on surface
One, affiliated technical field
The present invention relates to the preceding surperficial softening method of a kind of wood surface Z-Correct bump mapping Z-correct processing to timber; Especially to the softening preliminary treatment in the surface of the metasequoia that processes Z-Correct bump mapping Z-correct in the fast growing wood easily, paulownia, masson pine; On this basis, easily fast growing wood is processed into the decorative timber that the surface has Z-Correct bump mapping Z-correct.
Two, background technology
At present; In Chinese Wenzhou, there are the timeworn furniture that process is used for a long time, the defective that some surperficial early wood local shedding occur in Shanxi, ground such as Beijing; Necessarily the panel process strong base solution or the strong acid solution preliminary treatment of ' defective ' are arranged to these; Be processed into panel then, be made into pseudo-classic furniture, make year furniture of a specified duration can show historical graceful bearing and modern elegance through refilling after the operations such as paint polishing with Z-Correct bump mapping Z-correct.In these areas; Also have in pseudo-classic furniture manufacturing process the big timber of density is used alkali treatment; Go out to have the sheet material of Z-Correct bump mapping Z-correct then through manual processing and fabricating, the more pretreated chemical experiment chemical materials of their used timber are highly basic, strong acid or oxidant mostly.Analyze in the face of many sulfuric acid (strong acid), caustic soda (highly basic) and the hydrogen peroxide (oxidant) used in the traditional timber preliminary treatment down:
1. sulfuric acid (H 2SO 4) as strong acid, because its density is bigger, H behind obtain solution 2SO 4Easy deposition is along with soaking the increase of timber time, owing to container leaves standstill, serious relatively in the wood corrosion of bottom when handling timber.And solution has pollution to environment.Transportation (according to hazardous materials transportation regulation transportation), to store near (avoid contact with reducing agents such as organic matter, metal dusts, forbid unlimited concentrated acid container smoking during storing or employ naked light) requirement very high.To red stain is generally all arranged after the timber preliminary treatment.
2. caustic soda (NaOH) physicochemical properties: belong to highly basic, have strong corrosivity, 30% caustic soda is a liquid under the normal temperature.Contact with acid vigorous reaction can take place, emit a large amount of heat, can corroding metal, some plastics of etch, rubber and coating.
3. hydrogen peroxide (is commonly called as hydrogen peroxide solution, molecular formula, H 2O 2) strong oxidizing property is arranged, though itself is not flammable, the oxygen that produces when decomposing can be combustion-supporting consumingly, and can set off an explosion bump, friction and the danger of combustion explosion is arranged when shaking after combustibles, organic matter contacts.
Because the strength and stiffness of fast growing material own are smaller, had a strong impact on its direct application in engineering and industry, can open up its range of application greatly and it is manufactured a kind of dalle with concavo-convex veining on surface of characteristic modelled after an antique.To carry out preliminary treatment to wood surface in wood surface Z-Correct bump mapping Z-correct first being processed; Promptly in order to process the sheet material that the surface has Z-Correct bump mapping Z-correct; Making early at first as far as possible, the late wood distinguishes; So that process the decorative wooden sheet material that the surface that meets the requirements has the natural texture concave-convex sense, be the basis that goes out Z-Correct bump mapping Z-correct in its Surface Machining so fast growing wood is softened preliminary treatment.
Employed chemical reagent strong acid in traditional timber preprocess method, highly basic are very high to the rate of corrosion of fast growing wood cell membrane; And wood cell wall is elementary cell and the basis that constitutes strength of wood and rigidity, then influences very big with traditional timber preliminary treatment chemical reagent strong acid, highly basic preliminary treatment fast growing wood to its strength and stiffness.So the damage to its cell membrane in the process of preliminary treatment fast growing wood should be paid close attention especially.
Three, summary of the invention
(1) the present invention's technical problem that will solve
Have a strong impact on fast growing material strength and stiffness in order to overcome with traditional timber preliminary treatment chemical reagent strong acid, highly basic; The technical problem that the present invention will solve provides a kind of acting on separately with ammonia spirit metasequoia, paulownia, masson pine is carried out the softening pretreated scheme in surface; Make whole preprocessing process very little to the influence of fast growing material strength and stiffness; On this basis, process the dalle that the surface that meets the requirements has Z-Correct bump mapping Z-correct easily.
(2) the technical solution adopted for the present invention to solve the technical problems
The present invention provides a kind of desirable preceding preprocess method of fast growing wood concavo-convex veining on surface processing: use 3%NH 3.H 2O solution is handled metasequoia 2h, is used 2%NH in the time of 10 ℃ 3.H 2O solution is handled paulownia 2h, is used 2%NH in the time of 30 ℃ 3.H 2O solution is handled masson pine 2h under 30 ℃ of conditions.
(3) know-why of the present invention
Ammoniacal liquor is alkalescent, to forming the wooden certain dissolubility that have of one of plant cell wall main component, again because NH 3.H 2O solution shows alkalescent, so very faint with the chemical action of lignin.And lignin is the factor that forms cell wall density and intensity, and cell membrane is again the key factor that influences strength of wood, and it is very little to its intensity effect then to act on the preliminary treatment fast growing wood separately with ammoniacal liquor.
(4) beneficial effect of the present invention
Like table 1,2, shown in 3: in the pretreating scheme provided by the present invention, metasequoia, paulownia, the masson pine rate of corrosion of wood cell wall separately are minimum.Because cell membrane is the key factor that influences strength of wood, so the intensity of metasequoia, masson pine itself does not reduce after preprocessing process of the present invention and preliminary treatment, the paulownia Strength Changes is very little.Timber preprocess method of the present invention is the basis that processing obtains having than large format the decorative wooden sheet material of natural texture concave-convex sense.
The present invention has overcome with strong acid, highly basic the pretreated a series of shortcomings of timber, promptly influences fast growing wood intensity hardly, does not produce secondary pollution, cost is low, processing method is easy to promote.Through the pretreated metasequoia of the present invention, paulownia, masson pine; Can access desirable Z-Correct bump mapping Z-correct through its surface after the machining; Product can be widely used in interior decoration and the furniture manufacturing decoration, for the fast growing material has been opened up new way in engineering and industrial cut stock field.
Table 1 metasequoia cell membrane rate of corrosion test arrangement
Table?1?corroded?rate?of?cell?wall?of?Met?sequoia
Figure BSA00000496782700021
Table 2 paulownia wood surface treatment test arrangement
Table?2?intact?rate?of?Pawlownia?cell?wall?statistics
Figure BSA00000496782700022
Table 3 masson pine processing method test arrangement
Table?3?intact?rate?of?Masson?pine?cell?wall?statistics
Four, description of drawings
Fig. 1 is with change color situation behind acid, neutral solution, the alkali lye processing timber;
Fig. 2 cuts the paulownia wood of processing for manual brush after the preliminary treatment;
Fig. 3 cuts the metasequoia timber of processing for manual brush after the preliminary treatment;
Fig. 4 makes Wine packing box for having the natural texture paulownia wood.
Explanation obtains having in the timber of nature Z-Correct bump mapping Z-correct through processing among Fig. 1, and the timber test specimen is with the preliminary treatment of strong acid liquid, and timber has tangible red stain.Preliminary treatment in akaline liquid, wood color tarnishes.Preliminary treatment in neutral liquid, the same timber that obtains having the nature Z-Correct bump mapping Z-correct through processing.Timber does not have obvious color to change, but moisture content changes obviously.
Accompanying drawing 2, accompanying drawing 3, the product design sketch of accompanying drawing 4 for having Z-Correct bump mapping Z-correct by the surface that obtains through processing behind the pretreating scheme of the present invention.
Five, the specific embodiment
1, metasequoia is used 3%NH 3.H 2O solution, in the time of 10 ℃, handle 2h;
2, paulownia are used 2%NH 3.H 2O solution, in the time of 30 ℃, handle 2h;
3, masson pine is used 2%NH 3.H 2O solution, under 30 ℃ of conditions, handle 2h.

Claims (2)

1. the preprocess method before a fast growing wood concavo-convex veining on surface is processed, it is characterized in that this method comprises following content: metasequoia is used 3%NH 3.H 2O solution, in the time of 10 ℃, handle 2h; Paulownia are used 2%NH 3.H 2O solution, in the time of 30 ℃, handle 2h; Masson pine is used 2%NH 3.H 2O solution, under 30 ℃ of conditions, handle 2h.
2. the preprocess method before the fast growing wood concavo-convex veining on surface processing according to claim 1 is characterized in that: use NH 3.H 2O solution effect separately carries out the softening preliminary treatment in surface to metasequoia, paulownia, masson pine fast growing material.
CN2011101262510A 2011-05-17 2011-05-17 Pretreatment method used before processing fast growing wood surface concave-convex textures Pending CN102785274A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108367451A (en) * 2015-12-07 2018-08-03 蒂莫泰·布瓦图泽特 The part delignification of ligno-cellulosic materials and the method for filling and the composite structure that can be obtained by this method
CN108890836A (en) * 2018-07-02 2018-11-27 浙江良友木业有限公司 A kind of manufacture craft of sandblasting ancient imitation floor board
US11656756B2 (en) 2018-02-09 2023-05-23 Sas Woodoo Touch detection device with touch interface made of composite material
US11820041B2 (en) 2017-06-07 2023-11-21 Sas Woodoo Process for supercritical or subcritical partial delignification and filling of a lignocellulosic material

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006082227A (en) * 2004-09-14 2006-03-30 Ninomiya Nosan:Kk Manufacturing method of flame-retardant and non-combustible wood for imparting digestion capacity to wood itself by impregnating wood with injection agent applying no load to environment in realizing flame-retardance and non-combustibility of wood
KR20060083241A (en) * 2005-01-14 2006-07-20 이구호 Wood flooring with natural paint and method of coating thereof
CN101700668A (en) * 2009-10-23 2010-05-05 南京林业大学 Wood compression carbonization sizing method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006082227A (en) * 2004-09-14 2006-03-30 Ninomiya Nosan:Kk Manufacturing method of flame-retardant and non-combustible wood for imparting digestion capacity to wood itself by impregnating wood with injection agent applying no load to environment in realizing flame-retardance and non-combustibility of wood
KR20060083241A (en) * 2005-01-14 2006-07-20 이구호 Wood flooring with natural paint and method of coating thereof
CN101700668A (en) * 2009-10-23 2010-05-05 南京林业大学 Wood compression carbonization sizing method

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108367451A (en) * 2015-12-07 2018-08-03 蒂莫泰·布瓦图泽特 The part delignification of ligno-cellulosic materials and the method for filling and the composite structure that can be obtained by this method
US11820041B2 (en) 2017-06-07 2023-11-21 Sas Woodoo Process for supercritical or subcritical partial delignification and filling of a lignocellulosic material
US11656756B2 (en) 2018-02-09 2023-05-23 Sas Woodoo Touch detection device with touch interface made of composite material
US11662899B2 (en) 2018-02-09 2023-05-30 Sas Woodoo Touch detection device with touch interface made of composite material
CN108890836A (en) * 2018-07-02 2018-11-27 浙江良友木业有限公司 A kind of manufacture craft of sandblasting ancient imitation floor board

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Application publication date: 20121121