CN102779542B - Prevent the stolen method of CD and preparaton, device and system used in it - Google Patents

Abstract

The present invention discloses a kind of method preventing CD stolen, including：Interests refusal type anti-theft device is connected to the packaging for depositing described CD, wherein said anti-theft device includes destroying container and the destruction element that can destroy this container, be wherein packaged with the above-described container can baseplate material that is swelling or dissolving described CD preparaton；When without permission attempt remove or open described pack or removes from the package described CD or dismounting described anti-theft device when, by described destruction element, the described container that destroys is destroyed, thus packaged preparaton being discharged on the substrate surface of described CD and thus damaging described substrate surface, and make described CD unreadable；And preparaton, device and system used in it.According to the present invention it is possible to by being refused using the interests of chemical substance, scheme is simpler, inexpensively and more reliably prevent CD stolen in retail business, and effectively frightens thief.

Description

Prevent the stolen method of CD and preparaton, device and system used in it

Technical field

Present invention relates generally to prevent the stolen method of CD, and more particularly to by the profit using chemical substance Beneficial refusal scheme prevents the stolen method of CD and preparaton, device and system used in it.

Background technology

In retail business known have various for preventing the stolen methods, devices and systems of commodity, including label, for example Soft label and hard label, such as electronic article surveillance (EAS) label, ink label, EAS ink label；Magnetic clasp, such as ink magnetic Button；Protecting box etc..For example, WO2010/147915A1 discloses a kind of eas tag of Multiple techniques and system；CN 101918663A discloses a kind of improved eas tag.

The methods, devices and systems that refusing scheme by interests prevents commodity stolen are also as known in the art.Institute " the interests refusal scheme " of meaning refers to, when protected commodity are by unauthorized access, this commodity or the content included in it To be compromised, thus refusing unauthorized to obtain related interests.Generally, refuse the method for scheme using interests and do not adopt interests The method of refusal scheme is compared and more effectively can be tried to stop thief, thus it is stolen to be more reliably prevented from commodity.

Ink label is exactly a kind of anti-theft device by being refused using chemical substance offer of advantages, and it comprises ink, And make the fabric permanent stain of clothing when unauthorized attempt removes this label from clothing using ink, so that stolen thing Product are not worth.For example, disclose a kind of improved anti-theft ink tag in CN 101617095A；CN 1789344A is open A kind of improved commodity theft-proof dye.However, it is known that ink label just for textile development, be not particularly suited for Other commodity, including CD.

CD is also frequently referred to as " optical data media " or " optical medium " or " optical storage medium ", wherein can with optics Read mode stores data.Data by CD one or more layers in optical change and encode.CD is entirely supplied at it All easily stolen on chain.For example, CD is generally placed at retail and hires out on the shelf of mechanism, thus easily stolen.

The known method preventing CD stolen is usually such that light disk packing is difficult to open (for example by using protection Box, or mechanical lock is placed on described light disk packing or as the monitor device around this outer package)；In light disk packing Embedded eas tag or RFID (RF identification) label；Video monitoring is increased on supply chain；Or reduce consumer to article Unauthorized access (for example stop the reading of the catalogue of described CD by using light valve or light-sensitive material so that this CD not Readable) etc., such as CN 101495300A, DE 10301927A1, FR 2852439A1, JP 2010250887A, WO 97/ Disclosed in 26564A1, WO 2003/071056A3.

But, these are used for the theft protection method of CD or do not adopt interests refusal scheme, or using purely mechanic Interests refusal scheme, these methods still have relatively low reliability and are relatively easy to get around, thus thief can not effectively be tried to stop Abandon larceny, or more complicated, thus needing higher cost.

CN 1802705A discloses one kind permanently and general instantaneously destruction stores including at least in magnetic data The system and method for the data on medium.Here, preventing to being stored in magnetic by medium is destroyed using reactant chemical Property medium on data unauthorized use.The method of even now effectively can frighten thief, but adopts in the method Reactant chemical be corrosive (10% cerium ammonium nitrate+3.6% hydrochloric acid), large usage quantity (about 20cc), and ruining Data included in bad magnetic data storage medium.Therefore, such method is not suitable for the light in retail business as commodity Disk antitheft.

Accordingly, it would be desirable to be able to more reliably prevent the CD as commodity in retail business stolen by refusing scheme using interests The methods, devices and systems stolen, so as to more effective fright thief, dissuasion thief abandons larceny, simultaneously such Methods, devices and systems should be simply and cheap.

Content of the invention

Summary of the invention

The technical problem to be solved in the present invention is therefore to provide more reliably to prevent zero by refusing scheme using interests Sell in industry as the methods, devices and systems that the CD of commodity is stolen, so as to more effective fright thief, try to stop thief Abandon larceny, such methods, devices and systems should be simply and cheap simultaneously.

Prepared by swelling according to the energy of the present invention or baseplate material that dissolve described CD the theft protection for CD Agent, the interests refusal type anti-theft device, the inclusion according to the present invention that comprise such theft protection preparaton according to the present invention The anti-theft device of the present invention for preventing the stolen system of CD and according to the present invention using such theft protection The method that device prevents CD stolen solves above-mentioned technical problem.

It has been found that the preparaton of the present invention, devices, systems and methods allow to effectively frighten thief, effectively advise Resistance thief abandons larceny, therefore can be reliably prevented the CD as commodity in retail business stolen, so simultaneously Preparaton, devices, systems and methods simple and cheap.

It has furthermore been found that the preparaton of the present invention can with considerably less volumetric usage be very easy to and rapidly (moment, Or about several seconds, but it is no longer than 5 minutes) damage the substrate surface of CD to cause this CD unreadable and thus effectively to frighten theft Person, thus reliably and effectively preventing described CD stolen, and these chemical formulation agent are noninflammable or low inflammabilities And non-hazardous or less harmful, therefore can be safely used for the interests refusal of the CD as commodity in retail business Type theft-prevention applications.

Therefore, in the first aspect, the present invention provides and prevents the stolen method of CD, including：

Interests refusal type anti-theft device is connected to the packaging for depositing described CD, described anti-theft device bag Include the destruction element that can destroy container and this container can be destroyed, be wherein packaged with the above-described container can swelling or dissolving described The preparaton of the baseplate material of CD；

When without permission attempt remove or open described pack or removes from the package described CD or dismounting described antitheft When stealing device, by described destruction element, the described container that destroys is destroyed, thus packaged preparaton is discharged to described On the substrate surface of CD.

In another aspect, the present invention also provides the interests refusal type anti-theft device for CD.

In another aspect, the present invention also provides for preventing the stolen system of CD, including for depositing described light The packaging of disk and the interests refusal type anti-theft device according to the present invention being connected in described packaging.

In another aspect, the present invention also provides the theft protection preparaton for CD, and described preparaton can be swelling or molten Solve the baseplate material of described CD, and be substantially made up of the mixture of butyl acetate and tetrachloroethylene；Or substantially by acetic acid The mixture composition of butyl ester, ethanol, glycerol and water.

In another aspect, the present invention also provides the theft protection preparaton for CD, and described preparaton can be swelling or molten Solve the baseplate material of described CD, and described preparaton be comprise emulsifying agent, water and at least one selected from following material Emulsion form：Ketone, ester, aromatic hydrocarbon, halogenated aliphatic hydrocarbon, amide, nitrile and cyanoacrylate.

Brief description

Fig. 1 is to show the photo that a pentyl acetate is applied to the substrate surface through damaging after DVD substrate surface；

Fig. 2 is to show for an emulsion being appointed as preparaton 8 to be applied to the substrate through damaging after DVD substrate surface The photo on surface.

Detailed Description Of The Invention

In the first aspect, the present invention provides and prevents the stolen method of CD, including：

Interests refusal type anti-theft device is connected to the packaging for depositing described CD, described anti-theft device bag Include the destruction element that can destroy container and this container can be destroyed, be wherein packaged with the above-described container can swelling or dissolving described The preparaton of the baseplate material of CD；

When without permission attempt remove or open described pack or removes from the package described CD or dismounting described antitheft When stealing device, by described destruction element, the described container that destroys is destroyed, thus packaged preparaton is discharged to described On the substrate surface of CD.

According to the present invention, the described preparaton being discharged on optic disc base board surface can damage described substrate surface so that institute State CD unreadable.

For the present invention, described " unreadable " refers to that optics is unreadable, such as when inserting the disc into PC (individual calculus Machine) CD-ROM drive or CD player in when, the data in CD can not read.

CD is often also called " optical data media " or " optical medium " or " optical storage medium ".

The form of CD includes read-only format, such as CD-Audio, CD-Video, CD-DA (digital audio compression disk), CD-ROM (CD read only memory), DVD (digital universal disc or digital video disc)-Audio, DVD-Video, DVD-ROM, indigo plant Light ROM media；Write once and read repeatedly (WORM) form (recordable type), such as CD-R (recordable CD), CD-RW, DVD-R (can Record DVD), DVD+R, DVD+RW, DVD-RAM, DVD-dual layer+R；And rewritable form, such as magneto-optic (MO) disk, CD-RW (rewritable CD), DVD-RAM (DVD random access memory media), DVD-RW or DVD+RW (rewritable DVD), PD (Panasonic's Phase transformation double plate), blue light RE and other phase change discs.

The CD of CD, DVD and blu-ray type is otherwise varied in structure each other, but the CD of these types is main Structural principle is consistent.And read-only CD CD and recordable CD CD are as broad as long in structure, their main distinctions In the application of material and the difference of some manufacturing processes, DVD aspect is also same reason.For example, CD CD is mainly by five layers Constitute, including substrate, recording layer, reflecting layer, protective layer, printing layer.When from the one side of CD smoother (laser head towards When simultaneously) observing CD, one layer of most surface is exactly substrate.In terms of substrate, it is as broad as long between CD, CD-R and CD-RW 's.

The substrate of CD be each functional structure (as groove etc.) carrier and be overall CD physical enclosure.Known The material of the substrate for CD can be selected from Merlon (PC), polymethyl methacrylate, epoxy resin, glass and non- Crystal formation polyolefin, preferably Merlon.

The chemical formulation agent of the present invention can swelling or dissolving CD baseplate material, thus damaged substrate surface is to cause light Disk is unreadable, and so that stolen CD loses value and effectively frightens thief.

Simultaneously as the chemical formulation agent of the present invention is only capable of swelling or dissolving CD baseplate material, therefore this chemistry is joined Preparation can hardly damage other layers, particularly recording layer, such that it is able to simple, gentle and safely application in retail business.

Any energy is swelling or the material of baseplate material of dissolving CD may be used in the preparaton of the present invention.

Preferably the material of baseplate material of swelling or dissolving CD can include ketone, ester, aromatic hydrocarbon, halogenated aliphatic hydrocarbon, acyl Amine, nitrile and cyanoacrylate, and its mixture.

For example, for using Merlon as the CD of baseplate material for, preferably can be swelling or dissolving CD The material of baseplate material is selected from least one in following material：Acetone, butanone, butyl acetate, pentyl acetate, benzene, toluene, Dimethylbenzene, styrene, tetrachloroethylene, chloroform, dimethylformamide, acrylonitrile and cyanoacrylate.Comprise above-mentioned substance Preparaton energy Rapid Damage optic disc base board surface is so that this CD is unreadable.

Described preparaton can be solvent version, but can also be preferably solution or emulsion form so that preparaton tool There is the stability of lower hazardness or inflammability or higher.

Described energy is swelling or the material ratio in the formulation of the baseplate material of dissolving CD is preferably from about 10 volumes %- About 100 volumes %, the cumulative volume based on preparaton.

Preferably, described preparaton is substantially made up of pure tetrachloroethylene；Or substantially by butyl acetate and tetrachloroethylene Mixture forms, and volume ratio preferably between the two is about (1-20%): about (80-99%), particularly from about 10%: about 90%.

Herein, described " substantially by ... form " refers to comprise the involved material of about 90-100 volume %.

Preferably, described preparaton additionally comprises at least one in water, ethanol and glycerol, preferably two kinds, more preferably three kinds. Preferably, described preparaton is substantially made up of the mixture of butyl acetate, ethanol, G ＆ W, and preferably second in the formulation The ratio of acid butyl ester is about 10- about 30 volume %, and the ratio of ethanol is about 10- about 30 volume %, the ratio of glycerol be about 10- about 30 volumes %, the ratio of water is about 10- about 70 volume %, and the particularly preferably volume ratio between these materials is about 1: 1: 1: 2. Such preparaton still can Rapid Damage optic disc base board surface, there is lower inflammability and hazardness simultaneously, thus it can More safely it is applied in retail business.

Preferably, described preparaton additionally comprises at least one additive, such as surfactant, is used for so that preparaton It is easier to optic disc base board moistened surface, thus preferably interacting with baseplate material；Stabilizer, be used for so that preparaton more Stable；And dyestuff, be used for so that preparaton more attractive or more visible so that so that thief can easily notice that comprises so The presence of the anti-theft device of preparaton and abandon larceny.

Applicable surfactant is nonionic surfactant, preferably polyoxyethylene-type, polyol type, alkanolamide Type, non-ionic fluorocarbon type or polyvinyl alcohol type.

Polyoxyethylene nonionic surfactant for example includes alkylphenol polyoxyethylene, such as OP series, TX system Row, Triton X series and NP range of commercial products, particularly Triton X-100 (triton x-100, octyl phenyl polyoxyethylene Ether), OP-10 (alkylphenol polyoxyethylene) or NP-10 (NPE)；High-carbon fatty alcohol polyoxyethylene ether, example Adduct as oleyl alcohol and 15-20 oxirane；Polyoxyethylene carboxylate；Polyoxyethylene amine；The epoxy of poly(propylene oxide) Ethane adduct；Polyoxyethylated ionic surfactant, such as by fatty alcohol-polyoxyethylene ether or alkyl phenol polyoxy second There are those of esterification preparation with sulphuric acid or phosphoric acid in the hydroxyl in alkene ether molecular end.

Polyol type nonionic surfactant is the organic compound containing multiple hydroxyls, for example ethylene glycol, glycerol, Tetramethylolmethane, anhydrous sorbitol and sucrose, the ester being formed with higher fatty acids, such as Span and Tween range of commercial products.

Applicable stabilizer includes light stabilizer, UV stabilizer, antioxidant, antifreeze etc..

Applicable dyestuff includes dissolving in described preparaton or scattered any dyestuff.

Preferably, described preparaton is the emulsion form comprising emulsifying agent and water.Such preparaton has especially low danger Do harm to property and inflammability and especially there is higher stability and wettability on the surface of the substrate.

Described emulsifying agent is preferably nonionic emulsifier.Nonionic surfactant mentioned above is also suitable effect Nonionic emulsifier in such emulsion.

Preferably, the energy comprising in described emulsion swelling or dissolving CD baseplate material material be selected from butyl acetate, second At least one in sour pentyl ester and dimethylbenzene.Preferably, in described emulsion can swelling or dissolving CD the material of baseplate material Consumption is at least about 10 volumes %, preferably from about 10 volume %- about 90 volume %, more preferably from about 30 volumes %.Preferably, described breast In liquid, emulsifying agent (such as triton x-100) volume ratio and water between is about 3: 1 to about 1: 4.

Described emulsion can be prepared by conventional method known in the art.Preferably method include first by emulsifying agent with Water mix, and and then be added to can swelling or dissolving CD baseplate material material.

In the methods of the invention, by optic disc storage within a package, described packaging be connected with the present invention interests refusal type prevent Theft device.The anti-theft device of the present invention includes the destruction element that can destroy container and can destroy this container, wherein in institute State be packaged with container can swelling or dissolve described CD baseplate material preparaton；When trial is removed or opened without permission The described packaging for storing CD or from described packaging remove described CD or remove described anti-theft device when, by institute State destruction element to destroy the described container that destroys, thus packaged preparaton is discharged on the substrate surface of described CD And thus damage described substrate surface so that this CD is unreadable.

The interests refusal type anti-theft device of the present invention can be label, preferably hard label, more preferably electronic article surveillance (EAS) label；Magnetic clasp；Protecting box；Or a combination thereof form.

Described anti-theft device can be connected to the described packaging for storing CD by attachment structure, or is fitted to Described in the packaging of storing CD, or be incorporated in the described packaging for storing CD.

Described packaging is preferably optical disk cartridge.Optical disk cartridge generally comprise protecgulum, bonnet, opening structure and protecgulum and/or after The interior axle being formed by indented region in lid, wherein by the central opening of CD is placed on fixing light above described interior axle Disk.The anti-theft device of the present invention can be connected to the protecgulum of optical disk cartridge, bonnet, be opened region or interior axle by attachment structure Inner side or outside, or be fitted in these structures, or be incorporated in these structures, as long as ought attempting without permission removing or opening Described optical disk cartridge or when removing described CD from optical disk cartridge or removing described anti-theft device, by described destruction element by institute State and can destroy container destruction, thus packaged preparaton is discharged on the substrate surface of described CD and thus by this substrate Damaged surfaces are so that this CD is unreadable.It is for instance possible to use the applying date is pending trial while submission on November 10th, 2009 The method being connected to ink label in optical disk cartridge interior axle described in U.S. Patent application 12/615582 is by assembly of the invention It is connected on optical disk cartridge, the document is hereby incorporated herein by reference with it.

The anti-theft device of the present invention can comprise one or more to destroy container, preferably fragile container.Such appearance Device is it is known in the art that the pipe that is for example made up of glass or rigid plastics or bottle.For example, described container can include one Housing, this housing is fixed on light disk packing by a type of attachment structure (such as hobnail), and this attachment structure can Removed by the special releasing device of authorized librarian use.When a destruction element is bent and so that bottle is crushed, it is included in Preparaton within these bottles is discharged on optic disc base board surface, thus damaging this substrate surface so that CD is unreadable.

For example, described anti-theft device can be assembled by the cylindrical glass vials of two sealings, in these bottles Comprise the preparaton of the present invention, each bottle lies in the side of this hobnailed vertical axis and needs to be attached to fluting Hobnail (nail) above and along the top of these bottles or round one that they keep flat destroys plate, and its mode is when this is opened The hobnail of groove or nail transfer more than makes bottle crush with pressure during a compression stress of this bottle intensity.

Described anti-theft device can also be inlaid in in the packaging of storing CD, being such as inlaid in unlatching region, when When unauthorized opens this light disk packing, open pressure applied and promote destruction element (such as hobnail or plate), thus by institute State can destroy container destroy and discharge the preparaton of encapsulation, thus damaging optic disc base board surface to cause CD unreadable.

Described anti-theft device can also be integrated into in the packaging of storing CD, when unauthorized opens this packaging, Open pressure applied and promote destruction element (such as hobnail or plate), thus discharge encapsulation by container can be destroyed to destroy Preparaton, thus damage optic disc base board surface to cause this CD unreadable.For such anti-theft device, authorized person can Only to remove destruction element by special releasing device, described container can be protected together with the containment vessel of this external container Stay in be integrated into light disk packing as ornament.

In a still further aspect thereof, the present invention also provide for as described above be used for CD interests refusal type prevent Theft device.

In a still further aspect thereof, the present invention also provide for a kind of for preventing the stolen system of CD, including use In the packaging depositing described CD and the interests refusal type anti-theft device as described above being connected in described packaging.

In a still further aspect thereof, the present invention also provides the theft protection preparaton for CD, described preparaton energy Baseplate material that is swelling or dissolving described CD, and be substantially made up of the mixture of butyl acetate, ethanol, glycerol and water, its In in this preparaton the ratio of butyl acetate be preferably from about 10- about 30 volume %, the ratio of ethanol is preferably from about 10- about 30 body Long-pending %, the ratio of glycerol is preferably from about 10- about 30 volume %, and the ratio of water is preferably from about 10- about 70 volume %, particularly these Volume ratio between material is about 1: 1: 1: 2；Or substantially it is made up of the mixture of butyl acetate and tetrachloroethylene, preferably Volume ratio between the two is about (1-20%): (80-99%), particularly from about 10%: about 90%.

Such preparaton may be preferably used in the method for the present invention.

The described Optical disk and substrate of the same material referring in this regard is identical with those referring in the inventive method aspect.

Preferably, described preparaton additionally comprise at least one selected from following material：Surfactant as described above, Stabilizer and dyestuff.

In a still further aspect thereof, the present invention also provides the theft protection preparaton for CD, described preparaton energy Baseplate material that is swelling or dissolving described CD, and described preparaton is to comprise emulsifying agent, water and at least one selected from as follows Energy swelling or dissolve described CD the material of baseplate material emulsion form：Ketone, ester, aromatic hydrocarbon, halogenated aliphatic hydrocarbon, acyl Amine, nitrile and cyanoacrylate.Carry in the described Optical disk and substrate of the same material referring in this regard and the inventive method aspect And those are identical.

For using Merlon as the CD of baseplate material, suitable preparaton comprises at least one being selected from such as Under material as can swelling or dissolve described CD baseplate material material：Acetone, butanone, butyl acetate, acetic acid penta Ester, benzene,toluene,xylene, styrene, tetrachloroethylene, chloroform, dimethylformamide, acrylonitrile and cyanoacrylate.

Such preparaton may be preferably used in the method for the present invention.

Preferably, described emulsifying agent is nonionic emulsifier, such as in terms of the inventive method in be directed to nonionic emulsifying As agent refers to, i.e. those for nonionic surfactant specific descriptions.

Preferably, the energy comprising in described emulsion swelling or dissolving CD baseplate material material be selected from butyl acetate, second At least one in sour pentyl ester and dimethylbenzene.Preferably, in described emulsion can swelling or dissolving CD the material of baseplate material Consumption is at least about 10 volumes %, preferably from about 10 volume %- about 90 volume %, more preferably from about 30 volumes %.Preferably, described breast In liquid, emulsifying agent (such as triton x-100) volume ratio and water between is about 3: 1 to about 1: 4.

Described emulsion can be prepared by conventional method known in the art.Preferably method include first by emulsifying agent with Water mix, and and then be added to can swelling or dissolving CD baseplate material material.

Preferably, described preparaton additionally comprise at least one selected from following material：Ethanol, glycerol, stabilizer and dyestuff. Described stabilizer and dyestuff are as described above.

The theft protection preparaton of the present invention, anti-theft device and theft protection system are highly suitable for conduct in retail business The various CDs of the commodity of commodity, particularly self service, highly reliably to prevent it stolen.

Hereinafter the present invention will be further illustrated by embodiment, and have no intention thus to limit the present invention.

Specific embodiment

Embodiment

Optic disc base board damaged surfaces test operation program：

In testing every time, prepare a DVD and (be purchased from imperial examinations foundation Science and Technology Ltd. of BeiJing, China；Its substrate Material is Merlon)；The chemical substance that one (about 0.05ml) is tested is applied on described optic disc base board surface；Range estimation is seen Whether readable examine detection CD in CD insertion PC (personal computer) CD-ROM drive after damaging effect and damaging；And record knot Really, shown in following Table I.

Table I, the chemical substance of test and its damage effect to optic disc base board surface

Triton x-100：Octyl phenyl polyoxyethylene ether, is purchased from Chinese Shanghai Chemical Reagent Co., Ltd., Sinopharm Group

It can be seen from fig. 1 and fig. 2 that the emulsion formulation 8 shown in a pentyl acetate or a table 1 is being applied to After on DVD substrate surface, DVD substrate surface significantly white " spot " quickly, and it shows DVD substrate Surface is damaged.CD after such damage is inserted in the CD-ROM drive of a personal computer, finds the light after these damages Disk is all unreadable.

As from Table I, only with a pure acetone, butyl acetate, pentyl acetate, dimethylbenzene and tetrachloroethylene with regard to energy Enough transient breakdown optic disc base board surfaces, and make these CDs unreadable.

In addition, the described two mixture (preparaton 3 and 6) shown in Table I and seven kinds of emulsions (preparaton 8 to 14) All damage optic disc base board surface immediately, and make these CDs unreadable.

As can be seen here, using the above-mentioned preparaton of the present invention can be considerably less volumetric usage rapidly damage CD base Plate surface, and make CD unreadable, therefore these preparatons can simply, at a low price and be reliably used for adopting interests Refusal scheme prevents CD stolen, and effectively frightens thief.

In addition, the described two mixture (preparaton 3 and 6) shown in Table I and seven kinds of emulsions (preparaton 8 to 14) are all Nonflammable and there is less harmful, therefore can be safely used in retail business.

The specific detail with reference to particular of the present invention describes the present invention.But it is undesirable to these details It is considered as limitation of the scope of the invention, unless they are included in the appended claims.It should also be understood that can be In the case of the spirit and scope of the invention, other are carried out to the embodiment above and is altered or modified.In addition, this explanation The all lists of references quoted in book are incorporated herein by with entire contents.

Claims (74)

1. prevent the stolen method of CD, including：

Interests refusal type anti-theft device is connected to the packaging for depositing described CD, wherein said anti-theft device bag Include the destruction element that can destroy container and this container can be destroyed, be wherein packaged with the above-described container can swelling or dissolving described The preparaton of the baseplate material of CD；

Described pack or remove from the package described CD or remove described theft protection and fill when attempting without permission removing or open When putting, by described destruction element, the described container that destroys is destroyed, thus packaged preparaton is discharged to described CD Substrate surface on.

2. method according to claim 1 is it is characterised in that described anti-theft device is label；Magnetic clasp；Protecting box；Or its group Conjunction form.

3. method according to claim 2 is it is characterised in that described label is hard label.

4. method according to claim 2 is it is characterised in that described label is electronic article surveillance tag.

5. method as claimed in one of claims 1-4 is it is characterised in that described anti-theft device is connected by attachment structure To the described packaging for storing CD, or it is fitted in the described packaging for storing CD, or be used for described in being incorporated into In the packaging of storing CD.

6. method as claimed in one of claims 1-4 it is characterised in that described CD be CD-Audio, CD-Video, CD-ROM, CD-DA, DVD-Audio, DVD-Video, DVD-ROM, CD-R, CD-RW, DVD-R, DVD+R, DVD+RW, DVD- RAM, DVD-dual layer+R, MO, PD, blue light ROM or blue light RE type CD.

7. method as claimed in one of claims 1-4 is it is characterised in that described baseplate material is selected from Merlon, poly- first Base acrylic acid methyl ester., epoxy resin, glass and armorphous polyolefin.

8. method according to claim 7 is it is characterised in that described baseplate material is Merlon.

9. method according to claim 1 it is characterised in that described preparaton comprise at least one selected from following energy swelling or Dissolve the material of the baseplate material of described CD：Ketone, ester, aromatic hydrocarbon, halogenated aliphatic hydrocarbon, amide, nitrile and cyanoacrylate.

10. method according to claim 8 it is characterised in that described preparaton comprise at least one swelling selected from following energy Or dissolve the material of the baseplate material of described CD：Acetone, butanone, butyl acetate, pentyl acetate, benzene,toluene,xylene, Styrene, tetrachloroethylene, chloroform, dimethylformamide, acrylonitrile and cyanoacrylate.

11. methods according to claim 9 or 10 it is characterised in that described energy swelling or dissolving CD baseplate material thing Matter ratio in the formulation is 10 volume %-100 volumes %, the cumulative volume based on preparaton.

12. methods according to claim 9 or 10 are it is characterised in that described preparaton is substantially made up of tetrachloroethylene；Or base It is made up of the mixture of butyl acetate and tetrachloroethylene in basis.

13. methods according to claim 12 are it is characterised in that acetic acid fourth in the mixture of described butyl acetate and tetrachloroethylene Volume ratio between ester and tetrachloroethylene is (1-20%)：(80-99%).

14. methods according to claim 9 or 10 are it is characterised in that described preparaton additionally comprises in water, ethanol and glycerol At least one.

15. methods according to claim 14 are it is characterised in that described preparaton additionally comprises in water, ethanol and glycerol extremely Few two kinds.

16. methods according to claim 14 are it is characterised in that described preparaton additionally comprises three in water, ethanol and glycerol Kind.

17. methods according to claim 14 it is characterised in that described preparaton substantially by butyl acetate, ethanol, glycerol and The mixture composition of water.

18. methods according to claim 17 it is characterised in that in this preparaton butyl acetate ratio be 10 volumes %- 30 volumes %, the ratio of ethanol is 10 volume %-30 volumes %, and the ratio of glycerol is 10 volume %-30 volumes %, the ratio of water Example is 10 volume %-70 volumes %.

19. methods according to claim 17 are it is characterised in that the volume ratio between butyl acetate, ethanol, G ＆ W is About 1:1:1:2.

20. methods according to claim 9 or 10 are it is characterised in that described preparaton additionally comprises at least one additive.

21. methods according to claim 20 are it is characterised in that described additive is selected from surfactant, stabilizer and dyestuff.

22. methods according to claim 21 are it is characterised in that described surfactant is nonionic surfactant.

23. methods according to claim 22 are it is characterised in that described surfactant is polyoxyethylene-type, polyol type, alkane Alkylolamides type, non-ionic fluorocarbon type or polyvinyl alcohol type nonionic surfactant.

24. methods according to claim 23 are it is characterised in that described Polyoxyethylene nonionic surfactant is selected from alkane Base phenol polyethenoxy ether；High-carbon fatty alcohol polyoxyethylene ether；Polyoxyethylene carboxylate；Polyoxyethylene amine；Poly(propylene oxide) Ethylene oxide adduct；Polyoxyethylated ionic surfactant.

OP is serial, TX is serial it is characterised in that described alkylphenol polyoxyethylene is selected from for 25. methods according to claim 24, Triton X series and NP range of commercial products.

26. methods according to claim 25 are it is characterised in that described alkylphenol polyoxyethylene is triton x-100, OP- 10 or NP-10.

27. methods according to claim 24 are it is characterised in that described high-carbon fatty alcohol polyoxyethylene ether is oleyl alcohol and 15-20 The adduct of individual oxirane.

28. methods according to claim 24 are it is characterised in that described polyoxyethylated ionic surfactant is by fat There is esterification preparation with sulphuric acid or phosphoric acid in the hydroxyl on fat polyoxyethylenated alcohol or alkylphenol polyoxyethylene molecular end Those.

29. methods according to claim 23 are it is characterised in that described polyol type nonionic surfactant is containing many The ester that the organic compound of individual hydroxyl is formed with higher fatty acids.

30. methods according to claim 29 are it is characterised in that the described organic compound containing multiple hydroxyls is selected from second two Alcohol, glycerol, tetramethylolmethane, anhydrous sorbitol and sucrose.

31. methods according to claim 29 are it is characterised in that described ester is Span and Tween range of commercial products.

32. methods according to claim 21 are it is characterised in that described stabilizer is selected from light stabilizer, UV stabilizer, antioxidation Agent and antifreeze.

33. methods according to claim 21 are it is characterised in that described preparaton is the emulsion form comprising water and emulsifying agent.

34. according to the method for claim 33 it is characterised in that described emulsifying agent is nonionic emulsifier.

35. according to the method for claim 34 it is characterised in that described emulsifying agent is polyoxyethylene-type, polyol type, alkanol acyl Amine type, non-ionic fluorocarbon type or polyvinyl alcohol type nonionic emulsifier.

36. according to the method for claim 35 it is characterised in that described polyoxyethylene-type nonionic emulsifier is selected from alkyl phenol gathers Oxygen vinyl Ether；High-carbon fatty alcohol polyoxyethylene ether；Polyoxyethylene carboxylate；Polyoxyethylene amine；The epoxy second of poly(propylene oxide) Alkane adduct；Polyoxyethylated ionic surfactant.

37. according to the method for claim 36 it is characterised in that described alkylphenol polyoxyethylene be selected from OP series, TX series, Triton X series and NP range of commercial products.

38. according to the method for claim 37 it is characterised in that described alkylphenol polyoxyethylene is triton x-100, OP- 10 or NP-10.

39. according to the method for claim 36 it is characterised in that described high-carbon fatty alcohol polyoxyethylene ether is oleyl alcohol and 15-20 The adduct of individual oxirane.

40. according to the method for claim 36 it is characterised in that described polyoxyethylated ionic surfactant is by fat There is esterification preparation with sulphuric acid or phosphoric acid in the hydroxyl on fat polyoxyethylenated alcohol or alkylphenol polyoxyethylene molecular end Those.

41. according to the method for claim 35 it is characterised in that described polyol type nonionic emulsifier is containing multiple hydroxyls The ester that formed of organic compound and higher fatty acids.

42. according to the method for claim 41 it is characterised in that the described organic compound containing multiple hydroxyls is selected from second two Alcohol, glycerol, tetramethylolmethane, anhydrous sorbitol and sucrose.

43. according to the method for claim 41 it is characterised in that described ester is Span and Tween range of commercial products.

44. according to the method for claim 33 it is characterised in that the energy comprising in described emulsion is swelling or the substrate of dissolving CD The material of material is selected from least one in butyl acetate, pentyl acetate and dimethylbenzene.

45. according to the method for claim 44 it is characterised in that in described emulsion can swelling or dissolving CD baseplate material The consumption of material is at least 10 volumes %.

46. according to the method for claim 44 it is characterised in that in described emulsion can swelling or dissolving CD baseplate material The consumption of material is 10 volume %-90 volumes %.

47. according to the method for claim 44 it is characterised in that in described emulsion can swelling or dissolving CD baseplate material The consumption of material is about 30 volumes %.

48. according to the method for claim 44 it is characterised in that in described emulsion the volume ratio between emulsifying agent and water be 3:1 To 1:4.

49. according to the method for claim 48 it is characterised in that described emulsifying agent is triton x-100.

50. methods as claimed in one of claims 1-4 it is characterised in that described packaging is optical disk cartridge, it include protecgulum, after Lid, opening structure and the interior axle being formed by indented region in protecgulum and/or bonnet, wherein by putting the central opening of CD Put above described interior axle fixing CD, and described anti-theft device by attachment structure be connected to the protecgulum of optical disk cartridge, The inner side of bonnet, unlatching region or interior axle or outside, or be fitted in these structures, or be incorporated in these structures.

51. be used for CD interests refusal type anti-theft devices, its as defined in any one of claim 1-50, wherein institute State the destruction element that anti-theft device includes to destroy container and destroying this container, be wherein packaged with energy in the above-described container The preparaton of baseplate material that is swelling or dissolving described CD；When described packaging is removed or opened to trial or from packaging without permission In remove described CD or remove described anti-theft device when, by described destruction element by described destroy container destroy, from And packaged preparaton is discharged on the substrate surface of described CD.

52. are used for preventing the stolen system of CD, including for depositing the packaging of described CD and being connected to described packaging The interests refusal type anti-theft device according to claim 51.

The 53. theft protection preparatons being used for CD, described preparaton can baseplate material that is swelling or dissolving described CD, and substantially On be made up of the mixture of butyl acetate and tetrachloroethylene；Or substantially by butyl acetate, ethanol, G ＆ W mixture Composition.

54. according to the theft protection preparaton of claim 53 it is characterised in that the mixture of described butyl acetate and tetrachloroethylene Volume ratio between middle butyl acetate and tetrachloroethylene is (1-20%)：(80-99%).

55. according to the theft protection preparaton of claim 53 it is characterised in that in this preparaton the ratio of butyl acetate be 10 Volume %-30 volume %, the ratio of ethanol is 10 volume %-30 volumes %, and the ratio of glycerol is 10 volume %-30 bodies Long-pending %, the ratio of water is 10 volume %-70 volumes %.

56. according to the theft protection preparaton of claim 53 it is characterised in that body between butyl acetate, ethanol, G ＆ W Long-pending ratio is about 1:1:1:2.

57. according to the theft protection preparaton of claim 53 it is characterised in that described CD be CD-Audio, CD-Video, CD-ROM, CD-DA, DVD-Audio, DVD-Video, DVD-ROM, CD-R, CD-RW, DVD-R, DVD+R, DVD+RW, DVD- RAM, DVD-dual layer+R, MO, PD, blue light ROM or blue light RE type CD.

58. according to the theft protection preparaton of claim 53 it is characterised in that described baseplate material is selected from Merlon, poly- first Base acrylic acid methyl ester., epoxy resin, glass and armorphous polyolefin.

59. according to the theft protection preparaton of any one of claim 53-58 it is characterised in that described preparaton additionally comprises At least one selected from following material：Surfactant, stabilizer and dyestuff.

60. according to the theft protection preparaton of claim 59 it is characterised in that described surfactant such as claim 22-31 Any one of defined in.

61. according to the theft protection preparaton of claim 59 it is characterised in that described stabilizer to be selected from light stabilizer, UV stable Agent, antioxidant and antifreeze.

The 62. theft protection preparatons being used for CD, described preparaton can baseplate material that is swelling or dissolving described CD, and institute State the breast that preparaton is the material comprising emulsifying agent, water and at least one swelling selected from following energy or dissolving CD substrate material Liquid form：Ketone, ester, aromatic hydrocarbon, halogenated aliphatic hydrocarbon, amide, nitrile and cyanoacrylate.

63. according to the theft protection preparaton of claim 62 it is characterised in that described energy is swelling or dissolving CD substrate material Material be selected from acetone, butanone, butyl acetate, pentyl acetate, benzene,toluene,xylene, styrene, tetrachloroethylene, chloroform, two Methylformamide, acrylonitrile and cyanoacrylate.

64. according to the theft protection preparaton of claim 62 it is characterised in that described CD be CD-Audio, CD-Video, CD-ROM, CD-DA, DVD-Audio, DVD-Video, DVD-ROM, CD-R, CD-RW, DVD-R, DVD+R, DVD+RW, DVD- RAM, DVD-dual layer+R, MO, PD, blue light ROM or blue light RE type CD.

65. according to the theft protection preparaton of claim 62 it is characterised in that described baseplate material is selected from Merlon, poly- first Base acrylic acid methyl ester., epoxy resin, glass and armorphous polyolefin.

66. according to the theft protection preparaton of any one of claim 62-65 it is characterised in that described emulsifying agent such as right will Ask defined in any one of 34-43.

67. according to the theft protection preparaton of claim 66 it is characterised in that described emulsifying agent is triton x-100.

68. according to the theft protection preparaton of any one of claim 62-65 it is characterised in that the energy comprising in described emulsion The material of baseplate material that is swelling or dissolving CD is selected from least one in butyl acetate, pentyl acetate and dimethylbenzene.

69. according to the theft protection preparaton of claim 68 it is characterised in that in described emulsion can swelling or dissolving CD base The consumption of the material of panel material is at least 10 volumes %.

70. according to the theft protection preparaton of claim 68 it is characterised in that in described emulsion can swelling or dissolving CD base The consumption of the material of panel material is 10 volume %-90 volumes %.

71. according to the theft protection preparaton of claim 68 it is characterised in that in described emulsion can swelling or dissolving CD base The consumption of the material of panel material is about 30 volumes %.

72. according to the theft protection preparaton of claim 68 it is characterised in that the volume between emulsifying agent and water in described emulsion Ratio is 3:1 to 1:4.

73. according to the theft protection preparaton of any one of claim 62-65 it is characterised in that described preparaton additionally comprises At least one selected from following material：Ethanol, glycerol, stabilizer and dyestuff.

74. according to the theft protection preparaton of claim 73 it is characterised in that described stabilizer to be selected from light stabilizer, UV stable Agent, antioxidant and antifreeze.