CN102775100B - Convenient and fast construction type active powder concrete mixed superfine cement - Google Patents
Convenient and fast construction type active powder concrete mixed superfine cement Download PDFInfo
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- CN102775100B CN102775100B CN201210266936.XA CN201210266936A CN102775100B CN 102775100 B CN102775100 B CN 102775100B CN 201210266936 A CN201210266936 A CN 201210266936A CN 102775100 B CN102775100 B CN 102775100B
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- 239000004568 cement Substances 0.000 title claims abstract description 35
- 238000010276 construction Methods 0.000 title claims abstract description 8
- 239000004567 concrete Substances 0.000 title abstract description 46
- 239000000843 powder Substances 0.000 title abstract description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 42
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000004576 sand Substances 0.000 claims abstract description 25
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 239000000835 fiber Substances 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 12
- 239000006004 Quartz sand Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000011398 Portland cement Substances 0.000 claims description 2
- -1 during calculating Substances 0.000 claims 1
- 229910021487 silica fume Inorganic materials 0.000 abstract description 8
- 238000003756 stirring Methods 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 229910000831 Steel Inorganic materials 0.000 description 4
- 239000011083 cement mortar Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000011863 silicon-based powder Substances 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- 239000011374 ultra-high-performance concrete Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011372 high-strength concrete Substances 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 230000009191 jumping Effects 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 239000012258 stirred mixture Substances 0.000 description 1
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- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
掺超细水泥的施工便捷型活性粉末混凝土,属于混凝土技术领域。其原料组份包括超细水泥、砂、水、减水剂,其中超细水泥、砂、水、减水剂按重量计算的配合比为1:(0.7~1.5):(0.14~0.2):(0.01~0.05);超细水泥是以普通水泥或水泥熟料为原料,粉磨至规定细度后制得,其比表面积大于500m2/kg。发明可以提高活性粉末混凝土强度的增长速度,并使活性粉末混凝土摆脱对硅粉的依赖。The utility model relates to a convenient construction active powder concrete mixed with superfine cement, which belongs to the technical field of concrete. Its raw material components include ultrafine cement, sand, water, and water reducing agent. The mixing ratio of ultrafine cement, sand, water, and water reducing agent by weight is 1: (0.7~1.5): (0.14~0.2): (0.01~0.05); ultra-fine cement is made from ordinary cement or cement clinker, which is ground to a specified fineness, and its specific surface area is greater than 500m 2 /kg. The invention can increase the growth rate of the strength of the active powder concrete, and make the active powder concrete get rid of the dependence on silica fume.
Description
技术领域 technical field
本发明涉及一种活性粉末混凝土,尤其涉及一种掺超细水泥的施工便捷型活性粉末混凝土,属于混凝土技术领域。The invention relates to an active powder concrete, in particular to a convenient construction active powder concrete mixed with ultrafine cement, which belongs to the technical field of concrete.
技术背景 technical background
1993年,法国Bouygues公司的Richard等人以超细粒聚密水泥(DSP)与宏观无缺陷水泥(MDF)为基础,研制开发出一种超高性能水泥基复合材料——活性粉末混凝土(Reactive Powder Concrete,简称RPC),现在欧洲通常称之为超高性能混凝土(Ultra HighPerformance Concrete,简称UHPC)。该材料由活性粉末、水泥、细骨料、高强纤维等组分,通过级配设计优化,经高温养护等特定工艺制备而成,是一种高技术复合材料。In 1993, Richard et al. from Bouygues, France developed an ultra-high-performance cement-based composite material - Reactive Powder Concrete (Reactive Powder Concrete) based on ultra-fine-grained dense cement (DSP) and macro-defective cement (MDF). Powder Concrete, referred to as RPC), now Europe is usually called Ultra High Performance Concrete (Ultra High Performance Concrete, referred to as UHPC). The material is composed of active powder, cement, fine aggregate, high-strength fiber and other components, optimized through gradation design, and prepared through specific processes such as high temperature curing. It is a high-tech composite material.
活性粉末混凝土的基本配制原则包括:无粗骨料,掺加超细活性粉末,最大限度地减小缺陷尺寸;掺加钢纤维,增加韧性;使用高效减水剂,降低水胶比和孔隙率;高温养护,促进胶凝材料的水化反应。The basic preparation principles of reactive powder concrete include: no coarse aggregate, adding ultra-fine active powder to minimize defect size; adding steel fiber to increase toughness; using high-efficiency water reducing agent to reduce water-binder ratio and porosity ; High temperature curing, promote the hydration reaction of gelling materials.
与普通混凝土和高强混凝土相比,活性粉末混凝土具有优异的物理力学性能:拥有很高的抗压强度、优异的抗折强度,并呈现出可观的抗拉性能,其极高的强度有利于降低结构自重和截面尺寸,充分利用各组成材料的力学性能,减少材料用量;掺加微细的钢纤维后能显著提高活性粉末混凝土的抗折强度、抗拉性能和吸收能量的能力,并延缓裂缝开裂,同时其抗压强度也有进一步提高;由于活性粉末混凝土内部孔隙率很小,材料缺陷低,所以有着优良的抗氯离子渗透、抗碳化、抗腐蚀、抗渗、抗冻及耐磨等耐久性;另外,冲击试验表明,活性粉末混凝土还具有优异的抗冲击性能。Compared with ordinary concrete and high-strength concrete, reactive powder concrete has excellent physical and mechanical properties: it has high compressive strength, excellent flexural strength, and exhibits considerable tensile properties, and its extremely high strength is conducive to reducing The self-weight and cross-sectional size of the structure make full use of the mechanical properties of the constituent materials and reduce the amount of materials; the addition of fine steel fibers can significantly improve the flexural strength, tensile properties and energy absorption capacity of reactive powder concrete, and delay cracks and cracks At the same time, its compressive strength has been further improved; due to the small internal porosity and low material defects of reactive powder concrete, it has excellent durability such as chloride ion penetration resistance, carbonation resistance, corrosion resistance, seepage resistance, frost resistance and wear resistance. ; In addition, the impact test shows that reactive powder concrete also has excellent impact resistance.
但是,活性粉末混凝土也存在一些问题:活性粉末混凝土的制备对硅粉需求量大,但我国硅粉资源匮乏,且硅粉产量有限,难以满足混凝土工程的需求;硅粉参与的是二次水化反应,因此,活性粉末混凝土的强度提高速度较为缓慢,这在常温养护的情况下表现尤为突出;活性粉末混凝土使用的掺合料过多会使配制过程过于繁琐,而且某些掺合物本身存在组成成分波动性大的问题,不利于活性粉末混凝土的规模化应用。However, there are also some problems in reactive powder concrete: the preparation of reactive powder concrete requires a large amount of silica fume, but my country's silica fume resources are scarce, and the production of silica fume is limited, which makes it difficult to meet the needs of concrete engineering; silica fume participates in secondary water Therefore, the strength of reactive powder concrete increases slowly, which is particularly prominent in the case of normal temperature curing; too many admixtures used in reactive powder concrete will make the preparation process too cumbersome, and some admixtures themselves There is a problem of large fluctuations in composition, which is not conducive to the large-scale application of reactive powder concrete.
发明内容 Contents of the invention
本发明目的是提供一种掺超细水泥的施工便捷型活性粉末混凝土,通过使用超细水泥来制备活性粉末混凝土并解决其相关问题。本发明可以提高活性粉末混凝土强度的增长速度,并使活性粉末混凝土摆脱对硅粉的依赖,可以简化生产,也易于控制材料的稳定性。The object of the present invention is to provide a convenient construction active powder concrete mixed with ultrafine cement, and to prepare active powder concrete and solve related problems by using ultrafine cement. The invention can improve the growth rate of the strength of the active powder concrete, and make the active powder concrete get rid of the dependence on silicon powder, simplify the production, and easily control the stability of the material.
为实现上述目的,本发明采取了如下技术方案:To achieve the above object, the present invention takes the following technical solutions:
一种掺超细水泥的施工便捷型活性粉末混凝土,其特征在于:原料组份包括超细水泥、砂、水、减水剂,其中超细水泥、砂、水、减水剂按重量计算的配合比为1:(0.7~1.5):(0.14~0.2):(0.01~0.05);A construction-friendly active powder concrete mixed with ultrafine cement, characterized in that: the raw material components include ultrafine cement, sand, water, and water reducing agent, wherein the ultrafine cement, sand, water, and water reducing agent are calculated by weight The mix ratio is 1: (0.7~1.5): (0.14~0.2): (0.01~0.05);
超细水泥作为一种灌浆材料,是以普通水泥或水泥熟料为原料,粉磨至规定细度后制得,其比表面积大于500m2/kg;通常在500~1000m2/kg,甚至更高;目前已有的各类普通水泥比表面积均小于500m2/kg。As a kind of grouting material, ultra - fine cement is made from ordinary cement or cement clinker and ground to a specified fineness. High; the specific surface area of various common cements currently available is less than 500m 2 /kg.
所述的砂是天然砂、人工砂或石英砂,砂的粒径不大于5mm,按干砂的用量计算;若采用的砂为湿砂,应将湿砂中水的重量计入水的用量中;The sand mentioned is natural sand, artificial sand or quartz sand, and the particle size of the sand is not greater than 5mm, calculated according to the amount of dry sand; if the sand used is wet sand, the weight of water in the wet sand should be included in the amount of water middle;
所述的减水剂重量不包括减水剂中水的重量,如果减水剂含有水,计算时把其中的水折算到水的用量中。The weight of the water reducer does not include the weight of water in the water reducer. If the water reducer contains water, the water in the water reducer should be converted into the amount of water used in the calculation.
所述的水符合《混凝土拌合用水标准》JGJ 63-89的规定。Said water complies with the provisions of JGJ 63-89 "Standard for Concrete Mixing Water".
本发明的掺超细水泥的施工便捷型活性粉末混凝土,在使用时可通过添加纤维来进一步提高其性能,所述的纤维包括各种适用于活性粉末混凝土的纤维,如钢纤维,纤维掺量最大不超过活性粉末混凝土体积的6%。The convenient construction active powder concrete mixed with ultrafine cement of the present invention can further improve its performance by adding fibers during use. The fibers include various fibers suitable for active powder concrete, such as steel fibers, and the fiber content The maximum shall not exceed 6% of the volume of active powder concrete.
本发明的有益效果如下:The beneficial effects of the present invention are as follows:
该新型活性粉末混凝土采用超细水泥作为超细活性粉末组分,与掺入硅粉的活性粉末混凝土相比,由于超细水泥与水直接发生水化反应,因此可以提高活性粉末混凝土强度的增长速度。This new type of reactive powder concrete uses ultra-fine cement as the ultra-fine active powder component. Compared with the active powder concrete mixed with silica fume, the strength of the active powder concrete can be increased due to the direct hydration reaction between the ultra-fine cement and water. speed.
超细水泥易于生产,因此可使活性粉末混凝土摆脱对硅粉的依赖,利于活性粉末混凝土的制备。Ultrafine cement is easy to produce, so it can make active powder concrete get rid of the dependence on silica fume, which is beneficial to the preparation of active powder concrete.
在使用超细水泥制备活性粉末混凝土的过程中不用再掺入其它掺合料,从而达到简化生产的目的,也更易于控制材料的稳定性。In the process of using ultra-fine cement to prepare active powder concrete, there is no need to mix other admixtures, so as to achieve the purpose of simplifying production and make it easier to control the stability of materials.
具体实施方式 Detailed ways
下面结合实施例对本发明作进一步说明:The present invention will be further described below in conjunction with embodiment:
实施例:Example:
本发明采用的典型的材料配合比,以及对应的活性粉末混凝土的流动度和强度见下表:The typical material mix ratio that the present invention adopts, and the fluidity and strength of corresponding active powder concrete are shown in the following table:
所述的超细水泥为超细硅酸盐水泥,强度等级为52.5,密度3.07g/cm3,比表面积:568m2/kg;The ultra-fine cement is ultra-fine Portland cement with a strength grade of 52.5, a density of 3.07g/cm 3 , and a specific surface area of 568m 2 /kg;
所述的砂采用天然石英砂,粒径范围40目~70目;The sand is natural quartz sand with a particle size ranging from 40 mesh to 70 mesh;
所述的水符合《混凝土拌合用水标准》JGJ63-89的规定;The water mentioned complies with the provisions of JGJ63-89 of "Concrete Mixing Water Standard";
所述的减水剂主要成分为聚羧酸减水剂;The main component of the described water reducer is polycarboxylate water reducer;
所述的钢纤维长度8mm,直径0.12mm,抗拉强度不低于2850MPa。The steel fiber has a length of 8 mm, a diameter of 0.12 mm, and a tensile strength of not less than 2850 MPa.
其制作过程如下:Its production process is as follows:
将称量好的超细水泥和砂倒入搅拌锅中慢速搅拌1分钟,再慢速搅拌2分钟并在头30秒内将混合好的水与减水剂倒入搅拌锅中,快速搅拌3分钟后慢速搅拌1分钟停机,如果有纤维加入,在最后慢搅的1分钟内将纤维均匀地撒入搅拌锅内,之后再快速搅拌2分钟停机。采用的搅拌机符合《行星式水泥胶砂搅拌机》JC/T681-2005的要求。Pour the weighed ultra-fine cement and sand into the mixing pot and stir slowly for 1 minute, then stir slowly for 2 minutes and pour the mixed water and water reducer into the stirring pot within the first 30 seconds, and stir quickly After 3 minutes, stir slowly for 1 minute and stop. If there is fiber added, sprinkle the fiber evenly into the mixing pot during the last 1 minute of slow stirring, and then stir quickly for 2 minutes and stop. The mixer used meets the requirements of "Planetary Cement Mortar Mixer" JC/T681-2005.
此时可进行流动度测试。流动度测试方法按《水泥胶砂流动度测定方法》GB/T2419-2005进行,但是采用玻璃平板代替跳桌进行试验。At this point a fluidity test can be performed. The fluidity test method is carried out according to the "Measurement Method for Fluidity of Cement Mortar Sand" GB/T2419-2005, but a glass plate is used instead of a jumping table for the test.
将搅拌好的混合料按《水泥胶砂强度检验方法(ISO法)》GB/T17671-1999要求倒入40mm×40mm×160mm的标准试模中,在振动台上振动密实后移入在温度20±1℃相对湿度不低于90%的养护箱中养护1~2天,脱模后将试块移入混凝土加速养护箱中养护2天,养护箱温度控制在90±1℃。振动台频率2860次/分,震幅0.3~0.6mm。混凝土加速养护箱符合《混凝土加速养护箱》JG/T3027-1995的要求。Pour the stirred mixture into the standard test mold of 40mm×40mm×160mm according to the requirements of GB/T17671-1999 of "Cement Mortar Strength Test Method (ISO Method)" Curing in a curing box with a relative humidity of not less than 90% at 1°C for 1 to 2 days. After demoulding, move the test block into a concrete accelerated curing box for curing for 2 days. The temperature of the curing box is controlled at 90±1°C. The frequency of the vibrating table is 2860 times/min, and the amplitude is 0.3-0.6mm. The concrete accelerated curing box meets the requirements of "Concrete Accelerated Curing Box" JG/T3027-1995.
养护完毕的活性粉末混凝土试块按照《水泥胶砂强度检验方法(ISO法)》GB/T17671-1999要求进行抗压强度试验。The reactive powder concrete test block after curing is subjected to the compressive strength test according to the requirements of "Cement mortar strength test method (ISO method)" GB/T17671-1999.
已有的研究表明,采用硅粉的活性粉末混凝土在20℃的环境下养护28d后抗压强度比90℃蒸汽养护低20%~30%。但采用上表中的配合比进行对比试验发现,在不采用硅粉的情况下,材料20℃养护28d的抗压强度仅比90℃蒸汽养护低10%左右,证明若不采用硅粉,常温下活性粉末混凝土强度的增长速度得以明显提高。Existing studies have shown that the compressive strength of reactive powder concrete using silica fume cured at 20°C for 28 days is 20%-30% lower than that cured with steam at 90°C. However, using the mix proportions in the above table to conduct a comparative test, it is found that without using silicon powder, the compressive strength of the material cured at 20°C for 28 days is only about 10% lower than that of steam curing at 90°C, which proves that if silicon powder is not used, the material at room temperature The growth rate of the strength of the reactive powder concrete can be significantly improved.
最后说明的是,以上实施例仅用以说明本发明的技术方案而非限制,尽管参照较佳实施例对本发明进行了详细说明,本领域的普通技术人员应当理解,可以对本发明的技术方案进行修改或者等同替换,而不脱离本发明技术方案的宗旨和范围,其均应涵盖在本发明的权利要求范围当中。Finally, it is noted that the above embodiments are only used to illustrate the technical solutions of the present invention without limitation. Although the present invention has been described in detail with reference to the preferred embodiments, those of ordinary skill in the art should understand that the technical solutions of the present invention can be carried out Modifications or equivalent replacements without departing from the spirit and scope of the technical solution of the present invention shall be covered by the claims of the present invention.
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CN101437773A (en) * | 2006-05-05 | 2009-05-20 | 赢创德固赛有限责任公司 | Pulverulent composition comprising a hydraulic binder and a pyrogenic metal oxide |
CN102503310A (en) * | 2011-11-07 | 2012-06-20 | 西南交通大学 | Super-high early-strength grouting material for repairing ballastless track structure of high speed railway |
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CN101289302A (en) * | 2008-06-05 | 2008-10-22 | 北京中铁房山桥梁有限公司 | High-performance concrete material for prestressed component of ballastless track and method for preparing same |
CN102503310A (en) * | 2011-11-07 | 2012-06-20 | 西南交通大学 | Super-high early-strength grouting material for repairing ballastless track structure of high speed railway |
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