CN102774084A - Uvioresistant antireflective coated layer with heat insulating function - Google Patents

Uvioresistant antireflective coated layer with heat insulating function Download PDF

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Publication number
CN102774084A
CN102774084A CN2012101334195A CN201210133419A CN102774084A CN 102774084 A CN102774084 A CN 102774084A CN 2012101334195 A CN2012101334195 A CN 2012101334195A CN 201210133419 A CN201210133419 A CN 201210133419A CN 102774084 A CN102774084 A CN 102774084A
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China
Prior art keywords
layer
uvioresistant
glass
heat insulating
antireflective coated
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Pending
Application number
CN2012101334195A
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Chinese (zh)
Inventor
王立新
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Universal Glass (shenzhen) Co Ltd
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Universal Glass (shenzhen) Co Ltd
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Application filed by Universal Glass (shenzhen) Co Ltd filed Critical Universal Glass (shenzhen) Co Ltd
Priority to CN2012101334195A priority Critical patent/CN102774084A/en
Publication of CN102774084A publication Critical patent/CN102774084A/en
Pending legal-status Critical Current

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Abstract

The invention discloses an uvioresistant antireflective coated layer with a heat insulating function. The uvioresistant antireflective coated layer with the heat insulating function is characterized in that four layers of compound antireflective coated layers are coated on common glass, wherein the antireflective coated layers from the surface of the common glass to upper side are sequentially as follows: a TiO2 or Nb2O5 layer; a first SiO2 layer; a ZnO and Al2O3 layer; and a second SiO2 layer. The uvioresistant antireflective coated layer with the heat insulating function provided by the invention has the function of reducing the reflectivity of visible lights on the surface of the glass so that the amount of visible lights through the common glass is promoted from 90% to 98%. The uvioresistant antireflective coated layer with the heat insulating function further has the uvioresistant effect, reduces the probability of ultraviolet through the glass, has the heat insulating effect and reduces infrared rays passing through the glass.

Description

A kind of uvioresistant also has the antireflective coatings of heat-blocking action
Technical field
The present invention relates to the coatings on a kind of glass surface, the antireflective coatings of especially a kind of antistatic uvioresistant and reflective infrared
Background technology
light has 4% light and is reflected away by the surface of glass through simple glass the time, positive and negative two surfaces of glass reflect away 8% light altogether, and light is had only about 90% through the amount of glass.
glass substrate itself is uvioresistant not, to ultrared reflection also very a little less than.At present antireflective coating is used for anti-ultravioletly not having basically.
Plating ITO (tin indium oxide) coating that present glass has; Have the electric conductivity and the transparency preferably; Can cut off harmful electron radiation, ultraviolet ray and far infrared, but ITO coating does not have the antireflective function, cost is also very high; Usually be not used in uvioresistant and subtract ultrared effect, and be mainly used in the touch-screen aspect.
Summary of the invention
the present invention seeks to: the antireflective coatings that a kind of glass surface is provided; Make the glass single face be reduced to 1% by 4% to the reflectivity of light; Behind the two sides plated film of glass, light is increased to about 98% through the amount of glass, when reducing to the visible light reflection; Increase reaches uvioresistant and anti-infrared function to ultraviolet ray and ultrared reflection and absorption.
Technical scheme of the present invention is:
A kind of antireflective coatings is characterized in that, can be on simple glass four layers of compound antireflective coatings of coating, said antireflective coatings from surface of ordinary glass up is successively: TiO 2 Or Nb 2 O 5 Layer; The one SiO 2 Layer; ZnO and Al 2 O 3 Layer; The 2nd SiO 2 Layer.
Preferably, said TiO 2 Or Nb 2 O 5 The thickness of layer is 10-50nm; The one SiO 2 The thickness of layer is 30-100nm; ZnO and Al 2 O 3 The thickness of layer is 20-200nm; The 2nd SiO 2 The thickness of layer is 80-150nm.
Preferably, said ZnO and Al 2 O 3 The content of ZnO in the layer is 0.9 ~ 0.999, Al 2 O 3 Content be 0.001 ~ 0.1.
said antireflective coatings utilizes the method for vacuum sputtering to be plated on glass surface; Every layer of coating uses different materials and thickness difference; Make visible light produce the interference of light, play the effect that reduces visible reflectance, improves its transmitance through the reverberation of different coating.(400 ~ 700nm), the reflectivity of antireflective coatings is≤1% in the scope of visible light.
Further, said ZnO and Al 2 O 3 Layer has electric conductivity, and face resistance is 5 ohm ~ 1 megaohm, and simultaneously to visible transparent, ZnO coating has strong absorption to ultraviolet light (wavelength is less than 380nm), and absorptivity is 50% ~ 90%.
are further set and the accurate thickness of each rete of control, make the reverberation interference effect reach best, thereby reduce the reflectivity of light, when reducing visible reflectance, increase ultraviolet ray and ultrared reflection.The radiation coefficient of rete is 0.1 ~ 0.5, and is high to ultrared reflection.
are further again, and outer field second silicon oxide layer is very hard, and its pencil hardness can reach 7H.Except that playing compound action, have protection and anti-scratch concurrently.
Advantage of the present invention is:
1. the present invention have the function of reduction visible light in the reflection of glass surface rate, make visible light be promoted to 98% through the amount of simple glass by 90%.
coating 2. of the present invention has the uvioresistant effect, can reduce ultraviolet ray and pass through glass.
3. the present invention have heat-blocking action, can reduce infrared ray and pass through glass.
4. the present invention have certain electrostatic-proof function, and cost is lower.
Description of drawings
Below in conjunction with accompanying drawing and embodiment the present invention is further described:
Fig. 1 is the structural representation of antireflective coatings of the present invention;
Fig. 2 is the reflectance test datagram of antireflective coatings of the present invention.
Wherein: 1, simple glass, 2, TiO 2 Or Nb 2 O 5 Layer, the 3, the one SiO 2 Layer, 4, ZnO and Al 2 O 3 Layer, the 5, the 2nd SiO 2 Layer.
The specific embodiment
Embodiment: as shown in Figure 1,
A kind of antireflective coatings, can be on simple glass 1 four layers of compound antireflective coatings of coating, said antireflective coatings from surface of ordinary glass up is successively: TiO 2 Or Nb 2 O 5 Layer 2; The one SiO 2 Layer 3; ZnO and Al 2 O 3 Layer 4; The 2nd SiO 2 Layer 5.
Said TiO 2 Or Nb 2 O 5 The thickness of layer 2 is 10-50nm; The one SiO 2 The thickness of layer 3 is 30-100nm; ZnO and Al 2 O 3 The thickness of layer 4 is 20-200nm; The 2nd SiO 2 The thickness of layer 5 is 80-150nm.
Said ZnO and Al 2 O 3 The content of ZnO in the layer 4 is 0.9 ~ 0.999, Al 2 O 3 Content be 0.001 ~ 0.1.
as can beappreciated from fig. 2, (400 ~ 700nm), reflectivity is≤1% to antireflective coatings of the present invention in the scope of visible light.
Manufacturing process: each coating is all accomplished with sputter plating method in vacuum chamber
Simple glass → cleaning → vacuum coating ground floor (titanium oxide TiO 2 Or niobium oxide Nb 2 O 5 Coating) → the vacuum coating second layer (silica SiO 2 Coating) → vacuum coating the 3rd layer of (zinc oxide ZnO and aluminium oxide: Al 2 O 3 Coating) → the 4th layer of (silica SiO of vacuum coating 2 Coating) → pasting protective film → packing warehouse-in.
Purposes more of the present invention:
1, museum preserve high-grade historical relic, can do antitheft (warning that glass is broken) by extraction electrode.
Exhibition such as 2, food show window, antireflective, well heat insulation, do not tie mist.
More than only is concrete exemplary applications of the present invention, and protection scope of the present invention is not constituted any limitation.Except that the foregoing description, the present invention can also have other embodiment.All employings are equal to the technical scheme of replacement or equivalent transformation formation, all drop within the present invention's scope required for protection.

Claims (3)

1. A kind of uvioresistant also has the antireflective coatings of heat-blocking action, it is characterized in that, can be on simple glass four layers of compound antireflective coatings of coating, said antireflective coatings from surface of ordinary glass up is successively: TiO 2 Or Nb 2 O 5 Layer; The one SiO 2 Layer; ZnO and Al 2 O 3 Layer; The 2nd SiO 2 Layer.
2. Uvioresistant according to claim 1 also has the antireflective coatings of heat-blocking action, it is characterized in that said TiO 2 Or Nb 2 O 5 The thickness of layer is 10-50nm; The one SiO 2 The thickness of layer is 30-100nm; ZnO and Al 2 O 3 The thickness of layer is 20-200nm; The 2nd SiO 2 The thickness of layer is 80-150nm.
3. Uvioresistant according to claim 1 also has the antireflective coatings of heat-blocking action, it is characterized in that said ZnO and Al 2 O 3 The content of ZnO in the layer is 0.9 ~ 0.999, Al 2 O 3 Content be 0.001 ~ 0.1
CN2012101334195A 2012-05-02 2012-05-02 Uvioresistant antireflective coated layer with heat insulating function Pending CN102774084A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2012101334195A CN102774084A (en) 2012-05-02 2012-05-02 Uvioresistant antireflective coated layer with heat insulating function

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2012101334195A CN102774084A (en) 2012-05-02 2012-05-02 Uvioresistant antireflective coated layer with heat insulating function

Publications (1)

Publication Number Publication Date
CN102774084A true CN102774084A (en) 2012-11-14

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CN2012101334195A Pending CN102774084A (en) 2012-05-02 2012-05-02 Uvioresistant antireflective coated layer with heat insulating function

Country Status (1)

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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101055321A (en) * 2006-04-13 2007-10-17 达诺光电股份有限公司 High light transmittance ratio touch screen

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101055321A (en) * 2006-04-13 2007-10-17 达诺光电股份有限公司 High light transmittance ratio touch screen

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
李丽等: "Al掺杂ZnO薄膜的XPS谱及电学性质研究", 《微细加工技术》, no. 1, 15 February 2008 (2008-02-15) *
李丽等: "AZO薄膜的光学性质研究", 《重庆邮电大学学报(自然科学版)》, vol. 21, no. 6, 15 December 2009 (2009-12-15) *

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Application publication date: 20121114