CN1027629C - Package for liquids - Google Patents
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- CN1027629C CN1027629C CN 89107192 CN89107192A CN1027629C CN 1027629 C CN1027629 C CN 1027629C CN 89107192 CN89107192 CN 89107192 CN 89107192 A CN89107192 A CN 89107192A CN 1027629 C CN1027629 C CN 1027629C
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- strip
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- packing container
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Abstract
A package containing from a quarter to three litres of a liquid, to be dissolved or dispersed in water, contained in an envelope of water soluble or dispersible material, the envelope having a flexible wall.
Description
The present invention relates to a kind of packing, it comprises a kind of liquid chemical or dissolving or is dispersed in chemicals in the organic liquid, and this liquid is encapsulated in the strip of paper used for sealing of water-soluble or water-dispersible material.
Usually making concentrated solution such as agricultural chemicals and herbicide chemicals and other potential hazardous material or they being dispersed in the organic liquid.In general, this chemicals is contained in the plastic container with helix closed metallo-or blowing.In order to use these chemical pesticides or herbicide, to measure the amount of condensed matter earlier from container, before being sprayed onto on processed place or the plant, mix then with big water gaging.This concentrated chemical solution is severe toxicity normally, thus in the process of they being measured and mixing, must take more care, in order to avoid the liquid chemical of splashing, and avoid the humans and animals to contact with concentrated solution or dispersion thing.
Make great efforts to attempt to make the design-calculated container in using container contain thing the time, the accidental danger of overflowing or splashing down is minimized, and also will be reduced the liquid residue that after use, remains in the container.Have and be convenient to inject the big mouthful of neck plastic container that liquid contains thing and be used.Blow-moulding plastic containers with hollow handle is manufactured, in this plastic container, the body portion of hollow handle and container from, in order to avoid in handle retain liquid.
However, the liquid that is easy to overflow the inside with the current packaging container in mixed process contains thing, the danger that there be the dangerous of contaminated environment in its result and contacted with humans and animals.And it is rare that vessel empty is really belonged to, and peasant and other user tend to unspent container is heaved around.These phenomenons exist bigger harm.Even use when being over when all liquid contains thing, the processing of empty receptacle also is difficult, scrubs container up hill and dale and the instrument scrubbing the metering concentrated solution or disperse thing difficulty especially.These devices have bigger harm to people and surrounding environment.
The container of the packing agrochemicals goods that proposed comprises that is suitable for being screwed into a threaded fittings of spraying on the water tank corresponding component.When only having the sealing arrangement of no leak liquid between water tank and container, the inclusion of container could overflow.Consider that the threaded fittings size needs normalisation, and when producing the possibility of leakage, so safety and use this equipment that practical difficulty is arranged widely as out of reach hydraulic seal.
Also propose solid chemical is packaged in the water-soluble container, and this container normally is full of, there are not particular difficulty in their manufacturing and use.
Proposed with water-soluble container package cargo length of schooling product, this container only with the chemicals of just overflowing after water contacts.Because the defective of known water-soluble container, for liquid chemical, this proposal is not adopted in practice.If the big quantity of fluid of splendid attire in the container, there is the tendency that is easy to break in this container.Proved already that it was difficult will avoiding the not satisfied vulnerable part of the container material of the pin hole of container heat seal joint and proximity thermal seal joint.
The present invention attempts to overcome the defective of known package container, and the packing container of on-aqueous liquid is provided, and packing container has the following advantageous characteristic:
The chemicals of packing only with just effusion after water contact, water is used for dissolving or disperseing chemicals, is reduced to bottom line thereby undiluted material contacted with environment or human or animal's chance.
Can provide to be suitable for chemicals water-reducible with scheduled volume, unit dosage form, needn't measure out undiluted chemicals.
The chemicals of packing is easy to use: before the use chemicals, a chemicals of packing is placed in the water simply and gets final product.
The safe handling process that proposes in order to wash the residue chemicals from container can be cancelled, and has avoided contaminated with the container that the chemicals of packing is contacted, so that they are handled.
Big quantity of fluid as greater than 1/4 liter liquid, can be packed under the dangerous situation that does not have packing container to leak basically or lost efficacy.
According to a packing container provided by the invention, can hold 1/4 and rise to 3 liters liquid, this liquid is a kind of chemicals or solution or the dispersion liquid of chemicals in organic liquid.Liquid is contained in the strip of paper used for sealing, and strip of paper used for sealing is to be made of water-soluble material or water-dispersible material undissolved in liquid and that do not disperse, and strip of paper used for sealing comprises a water-soluble or water dispersible flexible wall.
Should be appreciated that the liquid or solid chemicals can disperse in organic liquid, dispersion liquid can be such as a kind of emulsion or suspension.
Preferably the strip of paper used for sealing of splendid attire chemicals is carried out the part can, so that leave air space in strip of paper used for sealing, the space accounts for the strip of paper used for sealing volume of 2%-40% greatly, preferably accounts for the strip of paper used for sealing volume of 4%-10%.Can adopt bigger space, but so as if lack the coml attractive force.If strip of paper used for sealing stands vibrations, the strip of paper used for sealing of part can reduce the danger of breaking, and under the situation that temperature increases, can reduce the danger of breaking or leaking, and temperature can make the capsule bag expand or sweating.
The volume of carrying liquid is preferably from partly rising to 2 liters, partly to be upgraded to the best.
This packing has been avoided the difficulty that exists in the above-mentioned prior art.Use this packing, earlier an amount of water that measures is injected container, for example in the water tank of sprinkler, then the strip of paper used for sealing such as capsule or bag is taken out from container, such as the taking-up of tumbling, it is entirely put into the container that measures the water yield in advance is housed, and stir.At this moment, as the dissolving or when disperseing, the strip of paper used for sealing inclusion is just overflowed fully in containing the water of chemicals of the material of making capsule or bag.When chemicals mixes with big water gaging since it be in airtight always and the packages sealed state under, therefore do not exist chemicals to produce the possibility of sprinkling.When mixing, only when the diluted chemical goods, occur splashing, this point of generation is splashed or is unrestrained, does not cause the philtrum poison certainly or destroys environment.
The chemicals that can pack comprises that those have genotoxic potential or damaging or the material of infringement property is arranged to health of human body or to environment.They comprise as bactericidal agent, agricultural chemicals such as insecticide or herbicide is (as the hydroxy-phenylformonitrile herbicide, as Brominal or sulphur benzene nitrile or as the derivant of salt or lipid, as Heptanoates or Octanoates: a kind of compound that can use bromoxynil ester and sulphur benzonitrile ester), in general, they are dissolved or chemicalss of disperseing in big water gaging or in liquid, aqueous, metronidazole cmpd for example, be used for the anti-damaging object of aqueous industrial liquid, or add cmpd in the swimming pool to, photo supplies, ink, dyestuff, water-free organic acid and cement additire.Insecticide comprises as appending to the molluscicide in pond or the river.When the strip of paper used for sealing material was the PVA borate, chloride and chlorite can significantly cause the strip of paper used for sealing material rotten to a great extent, generally they can not be put into the liquid of packing, or the tamper seal leather material made it not be subjected to chloride and chloritic the influence.
Be insoluble to and be used to dissolve or disperse the suitable water-soluble or water-dispersible material of the organic solvent of chemicals to comprise polyoxyethylene or methylcellulose, but strip of paper used for sealing such as capsule or bag are preferably by polyvinyl alcohol film, be local alcoholysis or complete alcoholysis or hydrolysis, for example 40～99%, preferably the polyethylene acetate film of 70～92% alcoholysis or hydrolysis is made.
Polyvinyl alcohol film can be non-orientation, uniaxial orientation, biaxial orientation.Water-soluble material is best.The material that uses normally cold water solubles is separated, and the PVA that cold water solubles is separated is for best.Should be appreciated that when the liquid of packing dissolves in warm water or hot water or disperses, also can use other material.
The maximum tensile strength of strip of paper used for sealing material preferably reaches 20N/mm at least
2, the best is to 80N/mm from 30
2, breaking extension is preferably 200% to 380%, and the best is 220% to 350%, and measuring these numerical value is that 23 ℃ and relative humidity are to make under 50% the condition in temperature normally.The thickness of strip of paper used for sealing material is 10 to 500 microns, and the best is 20 to 100 microns.The strip of paper used for sealing material preferably has these physical property combination of features.
Polyvinyl alcohol material can be squeezed into pipe, makes its expansion by biaxial orientation then, or adopts the cast polyethylene process to make best.When the casting film method is thought desirable method, form pipe one end by film after, dress is irritated the chemicals of requirement.Above a certain amount of chemicals near strip of paper used for sealing, seal pipe again, formed a leak free capsule or bag.The air space that stays is preferably above the liquid in airtight strip of paper used for sealing, in addition, space and liquid in conjunction with volume preferably less than the volume of the maximum possible of strip of paper used for sealing so that make strip of paper used for sealing reach loose can, and can make its can be crooked.
For make or airtight packing container of the present invention in comprise the strip of paper used for sealing of liquid, when implementing heat seal, seal temperature is normally from 140 ℃ to 220 ℃, best 160 ℃ to 180 ℃.Intermediate plate pressure is generally 1 to 3 1/2 kg/cm
2, best 1 1/2 kg/cm
2To 2 1/2 kg/cm
2Dwell time is generally 200 milliseconds to 1.5 seconds, preferably 450 milliseconds to 1 second.
For guaranteeing the optimal process performance, be that 15 to 25 ℃ and relative humidity (RH) are to implement heat seal in 15% to 85% the scope normally in temperature.Relative humidity preferably 35% to 55% for obtaining suitable heat seal, need be made some routine tests according to the strip of paper used for sealing material, as selecting specific grade and the thickness of PVA.The leak free quality perhaps under the situation that does not have the liquid inclusion, can be tested by making capsule bag inflation by visualize zone of opacity or bubble.The defective of seal aspect can cause the deficiency of the water-soluble or water dispersible of leak free.Heat seal equipment by routine can be implemented the heat seal operation, and this heat seal equipment should allow to control and change the temperature of sealing intermediate plate, intermediate plate pressure and dwell time.
In practice, strip of paper used for sealing of the present invention about 10 minutes with the interior thing that contains that can overflow in it.When packing Plant Quarantine chemicals, the chemicals of packing will be placed in the conventional sprinkling case.Spray and do not fill the packing chemicals of water and adding in the case usually.When spraying case and have the device that stirs water, the capsule inclusion will overflow faster.Be preferably in and be less than 1 minute, as in 30 to 40 seconds, overflowing with interior effusion.Should be appreciated that the used time of effusion chemicals depends on many factors of removing beyond the capsule bag character, comprising the temperature and the stirring intensity of water.
When strip of paper used for sealing is a capsule or bag, wall thickness should remain to a minimum value, and for helping dissolving or dispersion rapidly in water, the wall thickness of capsule that provides or bag should have suitable intensity, although big sack may need thicker wall, the thickness that is approximately 30 microns is specially suitable.Wall is thick more, and is long more to the time of dissolving that wall material carried out or dispersion.Should be appreciated that strip of paper used for sealing of the present invention can comprise a wall district, this zone is easier to be more dissolved or disperse than remainder, so that contain thing in the strip of paper used for sealing of more promptly overflowing.
Suitable organic liquid solvent comprises petroleum-based solvent, for example ligroin, mineral oil, aliphatic hydrocarbon or aromatic hydrocarbon, as n-hexane, normal octane, thiacyclohexane, benzene, dimethylbenzene and naphthalene ball, halogenation aliphatics or aromatic hydrocarbon, for example amyl acetate, ketone, for example cyclohexanone, ether or high ethanol (low ethanol can move by above mentioned water-soluble or water-dispersible material: this can cause the product that comes across outside the strip of paper used for sealing) of carbon tetrachloride, methenyl choloride, Methochloride and chlorobenzene, lipid for example.Should understand, also can use solvent mixture, for example have the varsol compound of other solvent, for example copper or high ethanol.Organic liquid must be quite dry, and the representative type organic liquid contains and is less than 2% to 3% moisture content and unlikelyly leaks from strip of paper used for sealing prematurely to guarantee it.
Liquid in the strip of paper used for sealing contains thing and can be thickened or make its thixotroping.Stand mechanical shock as packing container, especially when strip of paper used for sealing comprised a flexible wall, the viscosity that the interior liquid of increase strip of paper used for sealing contains thing can reduce contingent strip of paper used for sealing and break.By adding inclusion, as close organic substance or amargosite, lecithin, poly-methylene acid or the silica gel of modification, the viscosity or the thixotroping that can strengthen the strip of paper used for sealing inclusion.
Term " modification parent organically " is meant parent organically (thereby dissolve each other with non-water content in the strip of paper used for sealing) and modification and make it to increase viscosity.
Usually, custom is used dissolving or is dispersed in concentrate pesticidal or herbicide in the organic liquid: in order to reduce the volume of each strip of paper used for sealing, can increase concentration.Can select any suitable orthobaric volume though people know, preferably each strip of paper used for sealing comprises the volume about 500 milliliters at least, and wishes preferably the inclusion of can splendid attire suitable orthobaric volume, for example 500 milliliters or 1 liter.
Preferably the strip of paper used for sealing after the can is packaged in the water repellant outer layer container; for example being called in our name has more detailed description in the application undetermined of " flexible package punch " (it relates to a kind of liquid package container; comprise the outer layer container that has damping base and comprise the water-soluble of liquid or water dispersible strip of paper used for sealing; it promptly protects strip of paper used for sealing to avoid the effect of water and too early dissolving, also plays the effect of second barrier layere simultaneously between virose liquid that concentrate and possible and operating personal and environment.Outer layer container can have the shape that can pack two or more strips of paper used for sealing that is made of plastics, and outer layer container can have sealing and leak free lid more again.Yet each strip of paper used for sealing preferably is packaged in the independent outer layer container separately.In the case, outer layer container preferably thermoplastic material is made, and annotates or blowing forms an outer layer container by mould, and it has one is flat flange top basically, a sidewall and a pedestal.Strip of paper used for sealing after the can places in the outer layer container, then paper tinsel system top seal to being on the flat flange top basically, thereby a complete fully enclosed and leak free outer layer container are provided.Representative type paper tinsel system top cover is made by aluminium foil, and is heat sealed on the top flange of outer layer container, but it also can be made by plastic foil or laminated paper, plastics and/or aluminium.
Preferably top seal is arrived the outer layer container top, if strip of paper used for sealing breaks, so that the good barrier layere of an anti-leak to be provided, it is the biggest slightly that top cover cans be compared to the top of outer layer container most, thereby so that provide an easy clamping to remove the flap of top cover.
Preferably as paper/aluminium/plastic lamination goods, wherein plastic layer can be heat-sealed on the top cover that gas tight seal is provided the lamination top cover.Aluminium lamination provides a barrier layere of any pin hole that prevents to occur on the plastic layer.Ply of paper has certain intensity and processing characteristics, and can print on ply of paper or bonding trade mark.Plastic material is polyethylene terephthalate (PET) preferably, this material provides a good barrier layere for preventing the leakage that may occur, and has a good heat seal, can remove top cover at an easy rate before using, when top cover is removed, it does not comprise the halogen to the environment structure potential damage, and can antidetonation.Also can use other plastic material, as polyvinylidene chloride (PVDC), polyvinyl alcohol, polypropylene or nylon.
Outer layer container preferably stamps the characteristic of information, guide for use and any other involved chemical of relevant strip of paper used for sealing inclusion and the warning of toxicity.These information can be stated from the paper tinsel system top cover or be attached on the trade mark of outer layer container sidewall.
The space of strip of paper used for sealing and outer layer container (preferably accounts for 5% of outer layer container volume at least greatly, this space preferably is not more than 30% of outer layer container volume, be preferably 20-25%: can take bigger space, but this may not possess commercial appeal, optimal selection accounts for 25% greatly).Best and the atmospheric isolation in space is for example in the dense envelope of the enterprising promoting the circulation of qi of outer layer container.Be that the relative humidity in the space preferably 45%-70%(is preferably 50-60% under 20 ℃ the condition in temperature, about 50% is good).When the strip of paper used for sealing material was the PVA film, the mechanical characteristics of film was subjected to the influence of its humidity, the humidity of film and in strip of paper used for sealing the humidity in the space between air space and strip of paper used for sealing and the outer layer container balance each other.Equilibrium point changes with temperature, thus storage period film not only can absorb moisture but also the moisture of can overflowing.Having found that, is under 20 ℃ the condition in temperature, and under the relative humidity of 45%-70%, the strip of paper used for sealing material can be kept best storage characteristics.
According to best manner of packing of the present invention, a crash-resistant double casing is provided, it can transport concentrated chemicals safely, and makes when handling the delayed toxicity pharmaceutical chemicals dangerous minimum to personnel and environment.
Following example illustrates the manufacture method of water soluble package of the present invention.
Use the equipment of conventional manufacturing capsule bag, adopt the PVA film to comprise the herbicidal capsule bag of liquid by following step manufacturing.
The PVA film that uses is a SYNTANA type KA cold water soluble PVA film, and its thickness is 40 microns, and has 88% gram-molecule saponification degree.
The liquid herbicide is the Brominal that dissolves in the naphthalene ball solvent and the compound of ioxynil lipid.The moisture that comprises in the liquid is less than 3%.
Opened type capsule bag is by the PVA thin film fabrication, by forming a shoulder, the bottom of simultaneous hot-sealing capsule bag and side then around the PVA film.The intermediate plate pressure that uses is 2kg/cm
2, the intermediate plate temperature is 160 ℃, the dwell time is 1 second.Ambient temperature is 18 ℃, and relative temperature is 35%.
Then, 500 milliliters of liquid herbicide are dispensed in the capsule bag, it is 4%～5% space that the capsule planted agent leaves volume, sealed pouch top afterwards, and the size of each capsule bag is 120mm * 250mm, per minute is made 10 capsule bags.
After putting into liquid, the capsule bag top after each can is sealed, leave the space of 4% to 5% volume in the capsule bag, the liquid of can 80% in the capsule.Therefore do not fill fully in the capsule, air space is left in the liquid top.
Each capsule bag is put into outer layer container by shown in the accompanying drawing.The outer layer container material is a polypropylene.Each outer layer container is with comprising PET(polyethylene terephthalate), the lamination top seal of aluminium and ply of paper.Pet layer is heat sealed on the apical margin of outer layer container, leaves air space between capsule bag and the outer layer container.When temperature was 20 ℃, the relative humidity in this space was 50%.
The detailed example of packing container of the present invention is described in conjunction with the accompanying drawings, wherein:
Fig. 1 is an entire package vessel side diagrammatic sketch.
Fig. 2 is the backplan of outer layer container.
Fig. 3 represents half longitudinal section by the entire package container.
Packing container comprises outer layer container 1, it have around with capsule of osed top strip of paper used for sealing 3(or the bag) paper tinsel system lid 2.Capsule or bag 3 are to be made by the polyvinyl alcohol film 4 of cold water soluble, film 4 is made up of the poly-vinyl acetate of 88% alcoholysis, the wall thickness of film 4 is 30 microns, and is heat-sealed into a sack shape, and this sack can 500 milliliters of dispersion things 5 that concentrate in organic liquid of splendid attire.Sack 3 is loaded in the outer layer container 1, and outer layer container 1 comprises it being straight apical margin 6 substantially, and apical margin 6 is connected with tapered sidewalls 8 by last collar portion 7.Outer layer container 1 also comprises base 9, and base 9 is connected by the least significant end of shock absorbing part 10 with sidewall 8.Fig. 2 has clearly illustrated that outer layer container has an approximate rectangular cross-sectional plane, and this rectangular cross section has radiused corners between adjacent side, and has the surface of outside bow action.The rectangle outer layer container is fit to a plurality of outer layer containers are packaging together quite effectively.Outer layer container also have as shown in Figure 1 to inferior pyramidal, be 3 ° to 4 ° with angle that vertical plane is in this case, when container is emptied,, can be sleeved on many outer layer containers together for ease of storing or handling.Taper also means and can move downward with prevention by the wall supporting sack of outer layer container.Outer layer container 1 is with having high melt flow index and have uniform wall thickness, as be about the 1mm wall thickness, block polymer polypropylene mould injection forming.Outer layer container is made semi-translucent, and is as described below, so that detect the leakage of sack under the situation that needn't open outer layer container.In alternative embodiment, only base is made semi-translucent, therefore can see leakage situation.In addition, polypropylene material is water repellant, and this makes outer layer container be easier to washing.In this embodiment, the material polypropylene of making shell has enough flintinesses, and it can support and protect sack, but it also has to a certain degree flexible, thisly flexiblely helps damping or is blow molded into packing container.
The cross section of bending constitutes usually the lower edge of sidewall 8 is connected to horizontal connection on the upper limb of base 9, and it can bend owing to the elasticity of thermoplastic material itself, allows to occur a little between base 9 and the sidewall 8 a bit relative moving up and down.This bending has absorbed the shock loads that is applied to outer layer container 1, as losing accidentally in transportation or lay days outer layer container.During transportation package holds, comprise the such packing container of a row by transported on trucks or even when being lifted up and down by fork truck, may fall or stand sizable shock loads at least.The shock absorbing part that forms between the sidewall of base and outer layer container is crooked also to absorb this shock loads, and partial buffer impose on load on the strip of paper used for sealing, simultaneously when applying this shock loads, can guarantee that container is unlikely splits.Equally, shift out packing container from any outer layer container after, before the container of unpacking was near strip of paper used for sealing, if packing container is lost on hardstand by accident, bumper can absorbing load.Especially occur on the base as falling of packing container, shock absorbing part has absorbed any shock loads that puts on the outer layer container.Equally, occur in the side wall of outer shell part if fall, the circular arc characteristic of sidewall means that the sidewall energy is also crooked and then absorbs any shock loads.In addition,, also can cause bending, with this absorbing vibration load if fall on the apical margin that occurs in outer layer container.
As can be seen from Figure 2, base 9 has by the core around deep-slotted chip breaker 11 protuberances.Deep-slotted chip breaker provides collection some liquid of accidental spillage from sack before use.When outer layer container or when this part of outer layer container is semi-translucent at least; Open before the outer layer container, the user might check pedestal, and looks at whether sack leaks.Can avoid like this contacting with the chance of leakage.From Fig. 2 as seen, leave a space, formation leak free cavity when outer layer container places on the shelf below the core of base protuberance.This may produce some problems, because when sack bleeds outer layer container, the steam that concentrate this moment can enter cavity by the material of outer layer container, and steam is gathered in the cavity, and any coating on possibility etch shelf or the frame.Therefore, allow to have one at least radially towards the groove of base or the drafting apparatus of groove (not shown) in groove 11 downsides formation.
In this embodiment, dogleg section 10 also provides an interior annular shoulder of parking sack.The bending curved surface provides the smooth surface that does not make the sack tension or puncture sack.Therefore, on sack was supported at the bottom of the outer layer container, its result had further completely cut off mechanical shock.Sack also may be bent under state of stress and enter the damping space.
For easy to use, the inside of outer layer container is processed into very smooth surface specially, so that sack easily skids off from outer layer container.
In this embodiment, paper tinsel system lid 2 is made as polyethylene terephthalate/aluminium/paper laminate by the laminated material that can seal, and bigger than the external diameter of flange 6, and to stay the big flap around outer layer container, this flap can be used to tear lid.
Claims (21)
1, a kind of 1/4 packing container that rises to 3 liters of liquid that comprises, liquid is a kind of chemicals or solution or the dispersion liquid of chemicals in organic liquid, liquid is included in the strip of paper used for sealing, strip of paper used for sealing is, perhaps comprise, a kind of water-soluble or water-dispersible material, this material are insoluble to and are not scattered in liquid, and strip of paper used for sealing comprises a water-soluble or water dispersible flexible wall.
2,, it is characterized in that air space is arranged in the strip of paper used for sealing according to the packing container of claim 1.
3,, it is characterized in that the space in the strip of paper used for sealing is 4% to 10% of a strip of paper used for sealing volume according to the packing container of claim 2.
4,, it is characterized in that this container comprises partly to rise to 2 liters of liquid according to the packing container of claim 1 or 2 or 3.
5, according to the packing container of aforementioned any claim, the ultimate tensile strength that it is characterized in that the strip of paper used for sealing material is 20N/mm at least
2, breaking extension is 200% to 380%.
6, according to any packing container in the claim 1 to 4, the ultimate tensile strength that it is characterized in that the strip of paper used for sealing material is 30 to 80N/mm
2, breaking extension is 220% to 350%.
7, according to the packing container of aforementioned any claim, the thickness that it is characterized in that the strip of paper used for sealing material is 10 to 500 microns.
8, according to any packing container in the claim 1 to 6, the thickness that it is characterized in that the strip of paper used for sealing material is 10 to 100 microns.
9,, it is characterized in that the strip of paper used for sealing material comprises polyethylene oxide or methylcellulose according to the packing container of aforementioned any claim.
10, according to any packing container in the claim 1 to 8, it is characterized in that the strip of paper used for sealing material comprises polyvinyl alcohol.
11, according to the packing container of aforementioned any claim, it is characterized in that the strip of paper used for sealing inclusion be less than about 10 minutes after water contacts and overflowed.
12,, it is characterized in that the strip of paper used for sealing inclusion is less than about 1 minute and is overflowed according to the packing container of aforementioned any claim.
13,, it is characterized in that organic liquid comprises petroleum-based solvent, mineral oil, aliphatic hydrocarbon or aromatic hydrocarbon, the aliphatic hydrocarbon of halogenation or aromatic hydrocarbon, ester, copper, ether or high alcohol according to the packing container of aforementioned any claim.
14,, it is characterized in that the interior liquid of strip of paper used for sealing contains thing and comprises the stringy additive of increase according to the packing container of aforementioned any claim.
15,, it is characterized in that liquid contains organic material of parent or amargosite that thing comprises modification, the silica of poly-methylene acid or increase viscosity according to the packing container of claim 14.
16,, it is characterized in that chemicals comprises that health or environment are had cmpd genotoxic potential or that destroy or damage according to the packing container of aforementioned any claim.
17,, it is characterized in that comprising agricultural chemicals according to the packing container of aforementioned any claim.
18,, it is characterized in that comprising bactericidal agent, insecticide or herbicide according to the packing container of aforementioned any claim.
19,, it is characterized in that chemicals comprises the hydroxy-phenylformonitrile herbicide according to the packing container of aforementioned any claim.
20,, it is characterized in that the hydroxy-phenylformonitrile herbicide comprises sulphur benzene nitrile and Brominal ester mixture according to the packing container of claim 19.
21,, it is characterized in that chemicals comprises and be used for the anti-cmpd that damages of aqueous industrial liquid, add cmpd, the cmpd that adds swimming pool to, chemicals, ink or the dyestuff of photograph usefulness, anhydrous organic acid or cement additire in the water-circulating of industry or civilian heating system to according to any packing container in the claim 1 to 16.
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB8814159.5 | 1988-06-15 | ||
| GB8814158.5 | 1988-06-15 | ||
| GB8814159.3 | 1988-06-15 | ||
| GB888814159A GB8814159D0 (en) | 1988-06-15 | 1988-06-15 | Packaging for chemicals |
| GB8903707A GB2230445B (en) | 1989-02-17 | 1989-02-17 | Package releasing its contents on contact with water |
| GB8903707.1 | 1989-02-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1040550A CN1040550A (en) | 1990-03-21 |
| CN1027629C true CN1027629C (en) | 1995-02-15 |
Family
ID=26294022
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 89105000 Expired - Lifetime CN1020880C (en) | 1988-06-15 | 1989-06-15 | Package for liquid products |
| CN 89107192 Expired - Lifetime CN1027629C (en) | 1988-06-15 | 1989-06-15 | Package for liquids |
| CN 89107193 Expired - Fee Related CN1026310C (en) | 1988-06-15 | 1989-06-15 | Packaging for liquids |
| CN 89107194 Expired - Fee Related CN1026311C (en) | 1988-06-15 | 1989-06-15 | Package for liquid products |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 89105000 Expired - Lifetime CN1020880C (en) | 1988-06-15 | 1989-06-15 | Package for liquid products |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 89107193 Expired - Fee Related CN1026310C (en) | 1988-06-15 | 1989-06-15 | Packaging for liquids |
| CN 89107194 Expired - Fee Related CN1026311C (en) | 1988-06-15 | 1989-06-15 | Package for liquid products |
Country Status (2)
| Country | Link |
|---|---|
| CN (4) | CN1020880C (en) |
| MA (1) | MA21572A1 (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU2008218794A1 (en) * | 2007-02-19 | 2008-08-28 | Syngenta Participations Ag | Multi-layer receptacle and residue removal method therefor |
| JP6710084B2 (en) * | 2016-03-30 | 2020-06-17 | テルモ株式会社 | Liquid bag and method of manufacturing liquid bag |
| CN111038752B (en) * | 2020-01-14 | 2022-01-14 | 天眼美哈(江苏)生物科技有限公司 | Disposable eye lotion and its preparing process |
-
1989
- 1989-06-14 MA MA21825A patent/MA21572A1/en unknown
- 1989-06-15 CN CN 89105000 patent/CN1020880C/en not_active Expired - Lifetime
- 1989-06-15 CN CN 89107192 patent/CN1027629C/en not_active Expired - Lifetime
- 1989-06-15 CN CN 89107193 patent/CN1026310C/en not_active Expired - Fee Related
- 1989-06-15 CN CN 89107194 patent/CN1026311C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1020880C (en) | 1993-05-26 |
| CN1040551A (en) | 1990-03-21 |
| CN1039227A (en) | 1990-01-31 |
| CN1026311C (en) | 1994-10-26 |
| CN1040552A (en) | 1990-03-21 |
| CN1026310C (en) | 1994-10-26 |
| CN1040550A (en) | 1990-03-21 |
| MA21572A1 (en) | 1989-12-31 |
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