CN102757753A - Highly elastic cotton spraying adhesive - Google Patents
Highly elastic cotton spraying adhesive Download PDFInfo
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- CN102757753A CN102757753A CN2012102793564A CN201210279356A CN102757753A CN 102757753 A CN102757753 A CN 102757753A CN 2012102793564 A CN2012102793564 A CN 2012102793564A CN 201210279356 A CN201210279356 A CN 201210279356A CN 102757753 A CN102757753 A CN 102757753A
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- resin
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- potassium persulphate
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
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Abstract
A highly elastic cotton spraying adhesive is composed of a resin component, a polymerizing and crosslinking component and an emulsifying additive component, wherein the resin component is composed of methyl methacrylate, styrene, acrylonitrile, ethyl acrylate, butyl acrylate and itaconic acid; the polymerizing and crosslinking component is composed of N-methylol acrylamide and potassium persulfate; the emulsifying additive component is composed of sodium dodecyl benzene sulfonate and 0S-15 and sodium hydrogen sulfite; and deionized water is adopted for a carrier component. An emulsion polymerization technology and a redox catalytic system are adopted for a synthesis process; an amount of deionized water, crosslinking agents, emulsifying agents and resin monomers are added firstly, residual materials are added dropwisely according to technical requirements after preparation of a seeded emulsion, and a finished product is obtained after stirring, heating up, heat preserving, cooling, PH adjusting, discharging and filtering.
Description
Technical field
The present invention relates to a kind of Spray Cotton Binder with High Elasticity, specifically refer to when be used for gum sprayed cotton makes fiber is risen the sticker of cohesive action, belong to the adhesive technology field.
Background technology
Gum sprayed cotton has been widely applied to the every aspect of people's life, and articles for use do not stay the figure of its existence nowhere to insulation garment or the like from the bed.Yet when same gum sprayed cotton is applied to different field, the requirement of its quality especially pliability is differed widely, the gum sprayed cotton of for example using as mattress is exactly to possess hardness sense high resilience again as much as possible to its requirement.Gum sprayed cotton whether possess hardness, be crucial as the resin structure of the spray celloidin of fiber caking agent, the spray celloidin that uses soft resin to make not only possesses the hardness sense but also whippy gum sprayed cotton comes in any case also can not do.
Summary of the invention
The present invention discloses a kind of Spray Cotton Binder with High Elasticity, is the main structure resin with rigid TEB 3K, vinylbenzene, cooperates fiber species to select, and making the gum sprayed cotton of processing is that the sense of tool hardness has good elasticity again.
The technical scheme that the present invention adopts is: Spray Cotton Binder with High Elasticity is made up of resin component, polymerization crosslinking component, emulsifying additive component; Resin Composition is made up of TEB 3K, vinylbenzene, vinyl cyanide, ethyl propenoate, Bing Xisuandingzhi, methylene-succinic acid; The polymerization crosslinking component is made up of N hydroxymethyl acrylamide, Potassium Persulphate; The emulsifying additive component is made up of X 2073,0S-15, and carrier component adopts deionized water.
Building-up process adopts emulsion polymerization technique and redox-catalyst system; With adding part deionized water, linking agent, emulsifying agent and resin monomer earlier; After the seed emulsion preparation; Drip surplus material by the technical requirements program, the discharging filtration is finished product behind stirring, intensification, insulation, cooling, the adjustment pH value.
The invention has the beneficial effects as follows: cooperate the selection of fiber species, the gum sprayed cotton that the spray celloidin of employing present technique is processed, product hardness is high, and rebound resilience is strong, and perviousness is big, water-tolerant.
Embodiment:
By weight percentage, the TEB 3K 25.5% of resin Composition, vinylbenzene 20.3%, vinyl cyanide 15.8%, ethyl propenoate 13.2%, Bing Xisuandingzhi 13.2%, methylene-succinic acid 12%; The N hydroxymethyl acrylamide 82% of polymerization crosslinking component, Potassium Persulphate 18%; The X 2073 62% of emulsification, binder component, 0S-15 are 38%; The sodium hydrogencarbonate of other additives is 0.1 ~ 0.5% of total component.Total ingredient proportion adopts resin Composition 40%, carrier component 60%, and emulsification, binder component are by 2.5% of total amount, and the polymerization crosslinking component is by 1.5 ~ 2% of total amount.
When practical implementation was synthesized, elder generation was with the mixed solution of deionized water, OS-15 and part Potassium Persulphate, 30% the TEB 3K and the mixed solution of other resin monomers; Drop in the reactor drum, adding an amount of Sodium phosphate, dibasic or sodium hydrogencarbonate adjusting pH value is about 6, when slowly being warmed up to 65 ℃; Insulation reaction for some time, make polymeric solution form seed emulsion after, begin to drip remaining 70% resin monomer mixed solution; And dripping the mixing solutions of Potassium Persulphate, N hydroxymethyl acrylamide continuously, the mixing solutions in that 3-4h adds resin monomer mixed solution and Potassium Persulphate, N hydroxymethyl acrylamide synchronously is warmed up to 80 ℃ then; Insulation reaction 1h is warmed up to 90 ℃ again, insulation 30min; Cool to then below 50 ℃, adjust pH is 6 ~ 7, and the after-filtration that cools is a finished product.
Claims (2)
1. Spray Cotton Binder with High Elasticity; It is characterized in that: the spray celloidin is made up of resin component, polymerization crosslinking component, emulsifying additive component, and resin Composition is made up of TEB 3K 25.5%, vinylbenzene 20.3%, vinyl cyanide 15.8%, ethyl propenoate 13.2%, Bing Xisuandingzhi 13.2%, methylene-succinic acid 12%; The N hydroxymethyl acrylamide 82% of polymerization crosslinking component, Potassium Persulphate 18%; The X 2073 62% of emulsification, binder component, 0S-15 are 38%; The sodium hydrogencarbonate of other additives is 0.1 ~ 0.5% of total component; Total ingredient proportion adopts resin Composition 40%, carrier component 60%, and emulsification, binder component are by 2.5% of total amount, and the polymerization crosslinking component is by 1.5 ~ 2% of total amount.
2. Spray Cotton Binder with High Elasticity according to claim 1 is characterized in that: described spray celloidin is the mixed solution with deionized water, OS-15 and part Potassium Persulphate in polymerization process elder generation, the mixed solution of 30% resin monomer; Drop in the reactor drum, adding an amount of Sodium phosphate, dibasic or sodium hydrogencarbonate adjusting pH value is about 6, when slowly being warmed up to 65 ℃; Insulation reaction for some time, make polymeric solution form seed emulsion after, begin to drip remaining 70% resin monomer mixed solution; And dripping the mixing solutions of Potassium Persulphate, N hydroxymethyl acrylamide continuously, the mixing solutions in that 3-4h adds resin monomer mixed solution and Potassium Persulphate, N hydroxymethyl acrylamide synchronously is warmed up to 80 ℃ then; Insulation reaction 1h is warmed up to 90 ℃ again, insulation 30min; Cool to then below 50 ℃, adjust pH is 6 ~ 7, and the after-filtration that cools is a finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102793564A CN102757753A (en) | 2012-08-08 | 2012-08-08 | Highly elastic cotton spraying adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102793564A CN102757753A (en) | 2012-08-08 | 2012-08-08 | Highly elastic cotton spraying adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102757753A true CN102757753A (en) | 2012-10-31 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012102793564A Pending CN102757753A (en) | 2012-08-08 | 2012-08-08 | Highly elastic cotton spraying adhesive |
Country Status (1)
| Country | Link |
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| CN (1) | CN102757753A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110028616A (en) * | 2019-03-22 | 2019-07-19 | 广东银洋环保新材料有限公司 | High-elasticity acrylate adhesive for glue-sprayed cotton and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0590886A1 (en) * | 1992-10-01 | 1994-04-06 | Rohm And Haas Company | Laminating construction adhesive compositions with improved performance |
| CN102020933A (en) * | 2009-09-23 | 2011-04-20 | 葛小琴 | Polyester wadding adhesive |
| CN102191686A (en) * | 2010-03-08 | 2011-09-21 | 上海奇想青晨新材料科技股份有限公司 | Aqueous spray-bonded wadding glue and preparation method thereof |
-
2012
- 2012-08-08 CN CN2012102793564A patent/CN102757753A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0590886A1 (en) * | 1992-10-01 | 1994-04-06 | Rohm And Haas Company | Laminating construction adhesive compositions with improved performance |
| CN102020933A (en) * | 2009-09-23 | 2011-04-20 | 葛小琴 | Polyester wadding adhesive |
| CN102191686A (en) * | 2010-03-08 | 2011-09-21 | 上海奇想青晨新材料科技股份有限公司 | Aqueous spray-bonded wadding glue and preparation method thereof |
Non-Patent Citations (7)
| Title |
|---|
| 《印染助剂》 20040831 刘金树 "改性聚醋酸乙烯酯喷胶棉粘合剂的合成与研究" 2 第21卷, 第04期 * |
| 《粘接》 19990430 张洪涛等 "高弹性喷棉胶的研制" 1 第20卷, 第04期 * |
| 《粘接》 19990430 张洪涛等 "高弹性喷棉胶的研制" 2 第20卷, 第04期 * |
| 刘金树: ""改性聚醋酸乙烯酯喷胶棉粘合剂的合成与研究"", 《印染助剂》 * |
| 张洪涛、黄锦霞: "《聚合物胶乳配方与应用》", 31 January 2008, 化学工业出版社 * |
| 张洪涛等: ""高弹性喷棉胶的研制"", 《粘接》 * |
| 黄洪周: "《中国表面活性剂总览》", 30 September 2003, 化学工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110028616A (en) * | 2019-03-22 | 2019-07-19 | 广东银洋环保新材料有限公司 | High-elasticity acrylate adhesive for glue-sprayed cotton and preparation method thereof |
| CN110028616B (en) * | 2019-03-22 | 2021-03-02 | 广东银洋环保新材料有限公司 | High-elasticity acrylate adhesive for glue-sprayed cotton and preparation method thereof |
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: WANG WENTING Free format text: FORMER OWNER: WANG WENTAO Effective date: 20130613 |
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| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 210029 NANJING, JIANGSU PROVINCE TO: 362216 QUANZHOU, FUJIAN PROVINCE |
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| TA01 | Transfer of patent application right |
Effective date of registration: 20130613 Address after: 362216, No. 33, sunny sunny area, Jinjiang, Fujian, Quanzhou Applicant after: Wang Wenting Address before: Jianye District of Nanjing City, Jiangsu province 210029 4 Building No. 12 Nanyuan Qu Yuan Village Applicant before: Wang Wentao |
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20121031 |