CN102755875A - Regenerating method of activated carbon after absorbing organic matters - Google Patents
Regenerating method of activated carbon after absorbing organic matters Download PDFInfo
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- CN102755875A CN102755875A CN2012102287933A CN201210228793A CN102755875A CN 102755875 A CN102755875 A CN 102755875A CN 2012102287933 A CN2012102287933 A CN 2012102287933A CN 201210228793 A CN201210228793 A CN 201210228793A CN 102755875 A CN102755875 A CN 102755875A
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Abstract
The invention relates to a waste activated carbon regenerating method, and discloses a regenerating method of activated carbon after absorbing organic matters. The regenerating method comprises the following steps: a, adding ferrous sulfate solution into a container holding waste activated carbon which is not dried; b, adjusting the pH value of the ferrous sulfate solution to be 2 to 4 with sulfuric acid solution; c, quickly adding hydrogen peroxide into a container holding ferrous sulfate and waste activated carbon; d, quickly stirring the container, performing reaction for 30 to 120 minutes; e, settling after stirring, and discharging liquid supernatant so as to obtain regenerated activated carbon. The method is simple to operate; the loss amount of activated carbon is small during a regenerating process; Fenton reagent can thoroughly oxidize and decompose the organic matters absorbed in the activated carbon, so that secondary pollution is effectively avoided during the regenerating process; and the regenerating method has good economic benefit.
Description
Technical field
The present invention relates to the waste active carbon regeneration techniques, related in particular to the renovation process of the active carbon behind a kind of adsorb organic compound.
Background technology
Active carbon has powerful adsorption capacity because of having flourishing pore structure and huge specific area, stable in properties, and water insoluble and organic solvent can acid and alkali resistance, and can stand that water is wet, the effect of high temperature and high pressure.Above plurality of advantages makes active carbon be widely used in production, various fields in life as a kind of important adsorbent and catalyst carrier.Along with the rapid rising of active carbon consumption, how waste active carbon effectively being regenerated also causes people's attention day by day." waste active carbon " be meant and be used for wastewater treatment, use a period of time after, the active carbon that adsorption capacity descends or completely loses.Fact proved that through suitable Regeneration Treatment the adsorption capacity of waste active carbon can part even recovery fully.Therefore waste active carbon will cause the serious waste of secondary pollution and resource as directly abandoning without regeneration.The regeneration of active carbon be exactly with physics, chemistry or biological method under the prerequisite of not destroying its original structure, remove and be adsorbed in the adsorbate on the active carbon, recover its absorption property, so that reusable process.
The method that is used for regeneration of activated carbon has at present mainly contained hot method of reproduction, bio-regeneration method, microwave radiation regeneration method, electrochemical regeneration method etc.; Wherein hot renewable hair be use at present at most, the most ripe regeneration of activated carbon method in the industry, but hot method of reproduction exists that power consumption is big, the charcoal loss is big, be prone to cause shortcoming such as secondary pollution.
Summary of the invention
It is simple to the purpose of this invention is to provide a kind of method, need not preliminary treatment, and the active carbon loss amount is few in the regenerative process, has avoided the renovation process of the active carbon behind the adsorb organic compound of secondary pollution of regenerative process.
In order to solve the problems of the technologies described above, the present invention is able to solve through following technical proposals:
The renovation process of the active carbon behind a kind of adsorb organic compound, method is following:
A. copperas solution is joined in the container of the waste active carbon that fills undried;
B. regulate copperas solution pH=2-4 with sulfuric acid solution;
C. add hydrogen peroxide solution fast in the container that fills ferrous sulfate and useless activated carbon;
D. fast container is stirred reaction 30-120min;
E. stir postprecipitation, discharge supernatant, the active carbon after can obtaining regenerating.
As preferably, waste active carbon in the container among the described step c: ferrous sulfate: hydrogen peroxide solution=1.0g: (0.3-1.2) mmol: (6-24) mmol.
As preferably, the control temperature is 50 ℃ in the described whipping process; Stir speed (S.S.) is 200r/min.
As preferably, described hydrogen peroxide solution is 30% hydrogen peroxide solution.
The present invention has significant technique effect owing to adopted above technical scheme:
The present invention is the direct Fenton reagent method of reproduction that the waste active carbon of the undried of collecting is carried out, and need not carry out preliminary treatment.Add the regeneration of Fenton reagent, the organic matter exhaustive oxidation that can will be adsorbed in the active carbon decomposes, and little to the activated carbon surface structure influence, thereby recovers the absorption property of active carbon, reaches the purpose of regenerated carbon.
The inventive method is simple to operate, and the active carbon loss amount is few in the regenerative process, and adsorbed organic matter in the Fenton reagent ability exhaustive oxidation degrading activity charcoal has effectively been avoided the secondary pollution of regenerative process, has favorable economic benefit.
In addition, this method can be used for repeatedly cyclic regeneration active carbon, has improved the utilization ratio of active carbon.
The specific embodiment
Below in conjunction with embodiment the present invention is described in further detail:
Embodiment 1
The renovation process of the active carbon behind a kind of adsorb organic compound, method is following:
A. 6mmol/L copperas solution (100 ml) is joined in the iodine flask of the waste active carbon that fills undried;
B. regulate copperas solution pH=3 with 1 mol/L sulfuric acid solution;
C. add the 12mmol hydrogen peroxide solution fast in the iodine flask that fills ferrous sulfate and useless activated carbon;
D. fast iodine flask is put in the constant temperature shaking table and shaken, shaking table constant temperature is 50 ℃, and shaking speed is set at 200r/min, concussion reaction 70min;
E. take out iodine flask, carefully inclining supernatant, the active carbon after can obtaining regenerating.
COD with waste water after potassium dichromate method mensuration regenerated carbon and the fresh charcoal absorption calculates regeneration rate through following formula then.
Regeneration of activated carbon rate=(regenerated carbon is to the clearance/fresh active carbon of the waste water COD clearance to waste water COD) * 100%.The regeneration rate that draws active carbon can reach 82%.
In a word, the above is merely preferred embodiment of the present invention, and all equalizations of doing according to claim of the present invention change and modify, and all should belong to the covering scope of patent of the present invention.
Claims (4)
1. the renovation process of the active carbon behind the adsorb organic compound is characterized in that method is following:
A. copperas solution is joined in the container of the waste active carbon that fills undried;
B. regulate copperas solution pH=2-4 with sulfuric acid solution;
C. add hydrogen peroxide solution fast in the container that fills ferrous sulfate and useless activated carbon;
D. fast container is stirred reaction 30-120min;
E. stir postprecipitation, discharge supernatant again, the active carbon after can obtaining regenerating.
2. the renovation process of the active carbon behind the adsorb organic compound according to claim 1 is characterized in that: waste active carbon in the container among the described step c: ferrous sulfate: hydrogen peroxide solution=1.0g: (0.3-1.2) mmol: (6-24) mmol.
3. the renovation process of the active carbon behind the adsorb organic compound according to claim 1 is characterized in that: the control temperature is 50 ℃ in the described whipping process; Stir speed (S.S.) is 200r/min.
4. the renovation process of the active carbon behind the adsorb organic compound according to claim 1 and 2 is characterized in that: described hydrogen peroxide solution is 30% hydrogen peroxide solution.
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103212390A (en) * | 2013-04-12 | 2013-07-24 | 复旦大学 | In-situ regeneration method of trichloromethane-adsorbed saturating activated carbon |
CN103240067A (en) * | 2013-04-24 | 2013-08-14 | 复旦大学 | Persulfate composite solution for regeneration of phenol adsorption saturated activated carbon and preparation method and application thereof |
CN106693938A (en) * | 2017-01-25 | 2017-05-24 | 华东理工大学 | VOC Fenton degradation activated carbon oxidation regeneration method and device |
CN108176415A (en) * | 2016-12-08 | 2018-06-19 | 江苏瑞丰科技实业有限公司 | A kind of air purification raw material of wood-charcoal cleans regenerative use technology |
CN109550490A (en) * | 2018-11-28 | 2019-04-02 | 苏州清然环保科技有限公司 | The regeneration method of active carbon |
CN112875939A (en) * | 2021-04-09 | 2021-06-01 | 盐城工学院 | Integrated circulating sewage treatment device based on adsorption-Fenton |
CN113860564A (en) * | 2021-10-28 | 2021-12-31 | 武汉工程大学 | Fenton oxidation regeneration of active carbon and treatment method of refractory organic wastewater |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102276082A (en) * | 2011-06-12 | 2011-12-14 | 南昌航空大学 | Treatment method of high-salinity organic wastewater |
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Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102276082A (en) * | 2011-06-12 | 2011-12-14 | 南昌航空大学 | Treatment method of high-salinity organic wastewater |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103212390A (en) * | 2013-04-12 | 2013-07-24 | 复旦大学 | In-situ regeneration method of trichloromethane-adsorbed saturating activated carbon |
CN103212390B (en) * | 2013-04-12 | 2015-03-11 | 复旦大学 | In-situ regeneration method of trichloromethane-adsorbed saturating activated carbon |
CN103240067A (en) * | 2013-04-24 | 2013-08-14 | 复旦大学 | Persulfate composite solution for regeneration of phenol adsorption saturated activated carbon and preparation method and application thereof |
CN108176415A (en) * | 2016-12-08 | 2018-06-19 | 江苏瑞丰科技实业有限公司 | A kind of air purification raw material of wood-charcoal cleans regenerative use technology |
CN106693938A (en) * | 2017-01-25 | 2017-05-24 | 华东理工大学 | VOC Fenton degradation activated carbon oxidation regeneration method and device |
CN109550490A (en) * | 2018-11-28 | 2019-04-02 | 苏州清然环保科技有限公司 | The regeneration method of active carbon |
CN112875939A (en) * | 2021-04-09 | 2021-06-01 | 盐城工学院 | Integrated circulating sewage treatment device based on adsorption-Fenton |
CN113860564A (en) * | 2021-10-28 | 2021-12-31 | 武汉工程大学 | Fenton oxidation regeneration of active carbon and treatment method of refractory organic wastewater |
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Application publication date: 20121031 |