CN102755842B - Preparation method of hollow fiber membranes for waste water treatment - Google Patents
Preparation method of hollow fiber membranes for waste water treatment Download PDFInfo
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- CN102755842B CN102755842B CN201210276475.4A CN201210276475A CN102755842B CN 102755842 B CN102755842 B CN 102755842B CN 201210276475 A CN201210276475 A CN 201210276475A CN 102755842 B CN102755842 B CN 102755842B
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- spinning
- attapulgite
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- 239000012528 membrane Substances 0.000 title claims abstract description 59
- 238000002360 preparation method Methods 0.000 title claims abstract description 29
- 238000004065 wastewater treatment Methods 0.000 title claims abstract description 11
- 239000012510 hollow fiber Substances 0.000 title abstract description 9
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 74
- 229960000892 attapulgite Drugs 0.000 claims abstract description 72
- 238000009987 spinning Methods 0.000 claims abstract description 57
- 239000002033 PVDF binder Substances 0.000 claims abstract description 34
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims abstract description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 49
- 239000007788 liquid Substances 0.000 claims description 44
- 239000000835 fiber Substances 0.000 claims description 43
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 30
- 239000012153 distilled water Substances 0.000 claims description 24
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 22
- 239000006228 supernatant Substances 0.000 claims description 20
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 16
- 238000003756 stirring Methods 0.000 claims description 16
- 230000010355 oscillation Effects 0.000 claims description 14
- 238000001556 precipitation Methods 0.000 claims description 14
- 238000001291 vacuum drying Methods 0.000 claims description 14
- 235000012489 doughnuts Nutrition 0.000 claims description 12
- 238000005266 casting Methods 0.000 claims description 11
- 235000011187 glycerol Nutrition 0.000 claims description 11
- 238000005406 washing Methods 0.000 claims description 11
- 230000001112 coagulating effect Effects 0.000 claims description 10
- 238000001891 gel spinning Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims description 8
- 238000005119 centrifugation Methods 0.000 claims description 7
- 125000004122 cyclic group Chemical group 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 238000007789 sealing Methods 0.000 claims description 7
- 238000000967 suction filtration Methods 0.000 claims description 7
- 238000000227 grinding Methods 0.000 claims description 2
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 21
- 150000002500 ions Chemical class 0.000 abstract description 17
- 238000001179 sorption measurement Methods 0.000 abstract description 13
- 238000000034 method Methods 0.000 abstract description 8
- 230000008901 benefit Effects 0.000 abstract description 6
- 230000008569 process Effects 0.000 abstract description 4
- 230000004907 flux Effects 0.000 abstract description 3
- 238000011068 loading method Methods 0.000 abstract description 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000009396 hybridization Methods 0.000 abstract 1
- 239000002202 Polyethylene glycol Substances 0.000 description 13
- 229920001223 polyethylene glycol Polymers 0.000 description 13
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 230000004048 modification Effects 0.000 description 7
- 238000012986 modification Methods 0.000 description 7
- 230000004888 barrier function Effects 0.000 description 6
- 238000009792 diffusion process Methods 0.000 description 6
- 238000013019 agitation Methods 0.000 description 5
- 238000004090 dissolution Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000004088 foaming agent Substances 0.000 description 5
- 235000016768 molybdenum Nutrition 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000002351 wastewater Substances 0.000 description 4
- 238000011161 development Methods 0.000 description 3
- 230000018109 developmental process Effects 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- -1 nickel Chemical class 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- 239000002734 clay mineral Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 241001062472 Stokellia anisodon Species 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- WLZRMCYVCSSEQC-UHFFFAOYSA-N cadmium(2+) Chemical compound [Cd+2] WLZRMCYVCSSEQC-UHFFFAOYSA-N 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 230000005183 environmental health Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- RVPVRDXYQKGNMQ-UHFFFAOYSA-N lead(2+) Chemical compound [Pb+2] RVPVRDXYQKGNMQ-UHFFFAOYSA-N 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 229910001453 nickel ion Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000005616 pyroelectricity Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
Description
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Priority Applications (1)
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CN201210276475.4A CN102755842B (en) | 2011-08-31 | 2012-08-04 | Preparation method of hollow fiber membranes for waste water treatment |
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CN201110256477.2 | 2011-08-31 | ||
CN201110256477 | 2011-08-31 | ||
CN201210276475.4A CN102755842B (en) | 2011-08-31 | 2012-08-04 | Preparation method of hollow fiber membranes for waste water treatment |
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CN102755842A CN102755842A (en) | 2012-10-31 |
CN102755842B true CN102755842B (en) | 2014-10-29 |
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Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103480347A (en) * | 2013-10-11 | 2014-01-01 | 天津汉晴环保科技有限公司 | Preparation method of composite flat membrane for adsorbing heavy metal ions and product thereof |
CN103495349A (en) * | 2013-10-11 | 2014-01-08 | 天津汉晴环保科技有限公司 | Composite hollow fibrous membrane capable of adsorbing heavy metal ions and preparation method of composite hollow fibrous membrane |
CN104587848A (en) * | 2013-11-01 | 2015-05-06 | 贵阳时代沃顿科技有限公司 | A PVDF hollow fiber ultrafiltration membrane and a preparing method thereof |
CN104209018B (en) * | 2014-09-01 | 2016-06-29 | 淮阴师范学院 | A kind of attapulgite/polyvinylidene fluoride nanometer composite hyperfiltration membrane and preparation method thereof |
CN106582576A (en) * | 2016-12-31 | 2017-04-26 | 天津汉晴环保科技有限公司 | Heavy metal ion adsorption type hybrid hollow fiber film and production method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1772812A (en) * | 2005-11-17 | 2006-05-17 | 复旦大学 | Reinforced toughened antiwear composite polyimide material |
WO2006069131A1 (en) * | 2004-12-22 | 2006-06-29 | E. I. Du Pont De Nemours And Company | Polyester clay nanocomposites for barrier applications |
CN101544826A (en) * | 2009-05-08 | 2009-09-30 | 北京化工大学 | Polyimide/rod-like clay nano-composite film and preparation method thereof |
CN101711951A (en) * | 2009-11-23 | 2010-05-26 | 天津工业大学 | Method for preparing fiber separation film |
-
2012
- 2012-08-04 CN CN201210276475.4A patent/CN102755842B/en active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006069131A1 (en) * | 2004-12-22 | 2006-06-29 | E. I. Du Pont De Nemours And Company | Polyester clay nanocomposites for barrier applications |
CN1772812A (en) * | 2005-11-17 | 2006-05-17 | 复旦大学 | Reinforced toughened antiwear composite polyimide material |
CN101544826A (en) * | 2009-05-08 | 2009-09-30 | 北京化工大学 | Polyimide/rod-like clay nano-composite film and preparation method thereof |
CN101711951A (en) * | 2009-11-23 | 2010-05-26 | 天津工业大学 | Method for preparing fiber separation film |
Non-Patent Citations (2)
Title |
---|
改性凹凸棒土处理染化废水研究;王连军等;《南京理工大学学报》;19980630;第22卷(第3期);全文 * |
王连军等.改性凹凸棒土处理染化废水研究.《南京理工大学学报》.1998,第22卷(第3期),全文. |
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CN102755842A (en) | 2012-10-31 |
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C06 | Publication | ||
PB01 | Publication | ||
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SE01 | Entry into force of request for substantive examination | ||
ASS | Succession or assignment of patent right |
Owner name: GU YUNFENG Free format text: FORMER OWNER: LI JI Effective date: 20140918 |
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C41 | Transfer of patent application or patent right or utility model | ||
C53 | Correction of patent for invention or patent application | ||
CB03 | Change of inventor or designer information |
Inventor after: Gu Yunfeng Inventor before: Zhao Yiping Inventor before: Zhang Guifang Inventor before: Chen Li Inventor before: Shen Xiang Inventor before: Zhang Qiang Inventor before: Li Ji |
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COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 100079 FENGTAI, BEIJING TO: 310000 HANGZHOU, ZHEJIANG PROVINCE Free format text: CORRECT: INVENTOR; FROM: ZHAO YIPING ZHANG GUIFANG CHEN LI SHEN XIANG ZHANG QIANG LI JI TO: GU YUNFENG |
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TA01 | Transfer of patent application right |
Effective date of registration: 20140918 Address after: Hangzhou City, Zhejiang province 310000 City Building 2 unit 10 Fang Yuanyuan Room 202 Applicant after: Gu Yunfeng Address before: 100079, Beijing, Fengtai District, seven horizontal 44 square, south home building No. 1603, room 9 Applicant before: Li Ji |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20151207 Address after: Hangzhou City, Zhejiang province 310011 Gongshu District Dengyun Road No. 518 West Building 2 times constant policy center room 415 Patentee after: HANGZHOU YOUCHUANG ENVIRONMENTAL ENGINEERING TECHNOLOGY CO., LTD. Address before: Hangzhou City, Zhejiang province 310000 City Building 2 unit 10 Fang Yuanyuan Room 202 Patentee before: Gu Yunfeng |
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CP01 | Change in the name or title of a patent holder | ||
CP01 | Change in the name or title of a patent holder |
Address after: Hangzhou City, Zhejiang province 310011 Gongshu District Dengyun Road No. 518 West Building 2 times constant policy center room 415 Patentee after: Zhejiang friend Environment Technology Co., Ltd. Address before: Hangzhou City, Zhejiang province 310011 Gongshu District Dengyun Road No. 518 West Building 2 times constant policy center room 415 Patentee before: HANGZHOU YOUCHUANG ENVIRONMENTAL ENGINEERING TECHNOLOGY CO., LTD. |