CN102738294B - Method for manufacturing multi-color drawing type solar cell - Google Patents

Method for manufacturing multi-color drawing type solar cell Download PDF

Info

Publication number
CN102738294B
CN102738294B CN201110091412.7A CN201110091412A CN102738294B CN 102738294 B CN102738294 B CN 102738294B CN 201110091412 A CN201110091412 A CN 201110091412A CN 102738294 B CN102738294 B CN 102738294B
Authority
CN
China
Prior art keywords
color
pattern
reflecting layer
paintings
solar cell
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201110091412.7A
Other languages
Chinese (zh)
Other versions
CN102738294A (en
Inventor
郭明锦
吴至升
蔡锦堂
陈添赐
欧乃天
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gintech Energy Corp
Original Assignee
Gintech Energy Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gintech Energy Corp filed Critical Gintech Energy Corp
Publication of CN102738294A publication Critical patent/CN102738294A/en
Application granted granted Critical
Publication of CN102738294B publication Critical patent/CN102738294B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/20Filters
    • G02B5/201Filters in the form of arrays
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/15Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on an electrochromic effect
    • G02F1/153Constructional details
    • G02F1/157Structural association of cells with optical devices, e.g. reflectors or illuminating devices
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1335Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133509Filters, e.g. light shielding masks
    • G02F1/133514Colour filters
    • G02F1/133516Methods for their manufacture, e.g. printing, electro-deposition or photolithography
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

Abstract

The invention provides a manufacturing method of a multicolor drawing type solar cell. Comprises the following steps of forming a photoelectric conversion layer on a substrate. And forming an anti-reflection layer above the photoelectric conversion layer according to a background color required by a picture. And etching the area of the first pattern of the anti-reflection layer to the thickness corresponding to the first color according to the first color of the first pattern required by the drawing. And etching the area of the second pattern of the anti-reflection layer to the thickness corresponding to the second color according to the second color of the second pattern required by the drawing.

Description

The manufacture method of multicolour paintings type solar cell
Technical field
The invention relates to a kind of photo-voltaic cell solar radiation energy being converted to electric energy, relate to the solar cell and manufacture method thereof with color adjusting and changing especially.
Background technology
Solar cell or photo-voltaic cell are electric energy by the luminous energy of sunlight by opto-electronic conversion mechanism transformation.In recent years, under the tide of Globalization protection, solar cell supply electric power is sent to great expectations, and actively carries out research and development, and the phase can obtain commercialization widely.Based on decoration demand or the factor of visual appearance, solar cell may need different appearance colours, such as: when by solar cell application on the roof of building or exterior wall time, if when considering that architectural design is attractive in appearance, even if need to do integral matching with the color of building or context.
And the technology of known manufacture multicolour solar cell mostly gives solar cell different colors by superimposed multi-layer anti-reflection layer, therefore need comparatively somewhat complex design or processing procedure.How to affect under the less prerequisite of solar power conversion efficiency, and multicolour solar cell person can obtained, for this reason needed for people in the industry.
Summary of the invention
Therefore, an object of the present invention is the manufacture method at the multicolour paintings type solar cell providing a kind of innovation (Multi-color crayoned solar cells).
According to above-mentioned object, a kind of manufacture method of multicolour paintings type solar cell, it comprises following steps.Form a photoelectric conversion layer on a base material.According to the background color needed for paintings, form an anti-reflecting layer above above-mentioned photoelectric conversion layer.First color of the first pattern needed for paintings, the thickness that region to the first Color pair etching the first pattern of anti-reflecting layer is answered.Second color of the second pattern needed for paintings, the thickness that region to the second Color pair etching the second pattern of anti-reflecting layer is answered.
According to one embodiment of the invention, anti-reflecting layer comprises silicon nitride or silica.
According to another embodiment of the present invention, the method for etching anti-reflecting layer more comprises formation one and etches glue on anti-reflecting layer, to etch anti-reflecting layer to required thickness.
According to another embodiment of the present invention, etching glue comprises hydrofluoride.
According to another embodiment of the present invention, above-mentioned manufacture method also comprises the 3rd color of the 3rd pattern needed for paintings, the thickness that the region etching the 3rd pattern of anti-reflecting layer is answered to the 3rd Color pair.
From the above, apply the manufacture method of multicolour paintings type solar cell of the present invention, background color first needed for paintings forms an anti-reflecting layer above above-mentioned photoelectric conversion layer, the shades of colour of the various patterns again needed for paintings, is etched to thickness corresponding to various pattern to realize multicoloured solar cell by anti-reflecting layer.This manufacture method is different from the known mode with laminated multi-layer anti-reflecting layer and realizes multicoloured means, and simplifies the complexity of known formation multi-layer anti-reflection layer.
Accompanying drawing explanation
For above and other objects of the present invention, feature, advantage and embodiment can be become apparent, appended accompanying drawing is described as follows:
Fig. 1-6 is flow process profiles of the manufacture method of a kind of multicolour paintings type solar cell illustrated according to an embodiment of the present invention.
[primary clustering symbol description]
100: solar cell
110: base material
111: photoelectric conversion layer
112:N type semiconductor layer
114:P-N junction
116: antireflection
120: the first patterns
122: the second patterns
124: the three patterns
126: electrode
128: electrode
D: thickness
D 1: thickness
D 2: thickness
D 3: thickness
Embodiment
Please refer to Fig. 1-6, it illustrates the flow process profile of the manufacture method of a kind of multicolour paintings type solar cell 100 according to an embodiment of the present invention.The n type semiconductor layer 112 that please refer to Fig. 1 is formed and is arranged on P type semiconductor base material 110, and is therebetween formed with P-N junction 114, so be formed with electric field at P-N junction 114 place.Therefore, when light exposes to now, electric field forms part and namely produces positive charge carriers (positive charge carriers) and negative charge carriers (negative charge carriers), thus generation current flows through P-N junction 114, and namely this be called opto-electronic conversion mechanism.In broad terms, the combination of P type semiconductor base material 110 and n type semiconductor layer 112, namely produces electric energy in order to construction photoelectric conversion layer 111 in order to change incident light.P type semiconductor layer 110 can be P-type silicon base material, and n type semiconductor layer 112 is deposited on above P-type silicon base material, is doped into P-type silicon base material and obtains via N-type impurity.In like manner, the combination of N type semiconductor base material and p type semiconductor layer, also can be used for construction photoelectric conversion layer.Broad sense and discussing, photoelectric conversion layer 111 can be made up of one or more semiconductor substances, and this semiconductor substance can be monocrystalline (single crystalline), polycrystalline (polycrystalline), the silicon of amorphous (amorphous) state, germanium or similar semi-conducting material.
As shown in Figure 2, transparent anti-reflecting layer 116 be formed be arranged at above photoelectric conversion layer 111, can be made up of silicon nitride (silicon nitride) or silica (silicon oxide) material, its formation method can be vapour deposition method (evaporation), mode that sputtering method (sputtering), print process (print screen), chemical vapour deposition technique (CVD) or other personage being familiar with this skill know.Anti-reflecting layer 116 is in order to reduce the light reflection loss (reflective loss) on battery unit surface.The thickness of anti-reflecting layer 116 also determines the color of solar cell 100 simultaneously.In the present embodiment, the background color first needed for multicolour paintings, forms an anti-reflecting layer 116 above above-mentioned photoelectric conversion layer 111.The thickness D of anti-reflecting layer 116 is background colors and determining needed for paintings.
As shown in Figure 3, the first pattern 120 of the first color is formed on anti-reflecting layer 116.The mode performed is the first color of the first pattern 120 needed for paintings, the thickness D that region to the first Color pair etching the first pattern 120 of anti-reflecting layer 116 is answered 1.In the present embodiment, the mode of etching anti-reflecting layer 116 is that wire mark one etches glue in the region of the first pattern 120, so as to etching anti-reflecting layer 116 to required thickness.Etching glue can be the etching glue of hydrofluoric acid containing salt etc., but is not limited to this.
As shown in Figure 4, the second pattern 122 of the second color is formed on anti-reflecting layer 116.The mode performed is the second color of the second pattern 122 needed for paintings, the thickness D that region to the second Color pair etching the second pattern 122 of anti-reflecting layer 116 is answered 2.In the present embodiment, the mode of etching anti-reflecting layer 116 is that wire mark one etches glue in the region of the first pattern 122, so as to etching anti-reflecting layer 116 to required thickness.Etching glue can be the etching glue of hydrofluoric acid containing salt etc., but is not limited to this.
As shown in Figure 5, the 3rd pattern 124 of the 3rd color is formed on anti-reflecting layer 116.The mode performed is the 3rd color of the 3rd pattern 124 needed for paintings, the thickness D that the region etching the 3rd pattern 124 of anti-reflecting layer 116 is answered to the 3rd Color pair 3.In the present embodiment, the mode of etching anti-reflecting layer 116 is that wire mark one etches glue in the region of the first pattern 124, so as to etching anti-reflecting layer 116 to required thickness.Etching glue can be the etching glue of hydrofluoric acid containing salt etc., but is not limited to this.
Above-mentioned paintings can according to the demand of designer, and the pattern of etching anti-reflecting layer to two kind, three kinds or more kind thickness, to realize the multicoloured possibility of paintings.Above-mentioned anti-reflecting layer thickness can because the material, process parameter etc. of anti-reflecting layer be different from the relation of pattern color, and have do not expect with anti-reflecting layer thickness and the corresponding relation of pattern color, therefore this case the relation of unlisted " thickness data " correspondence " pattern color ".
As shown in Figure 6, electrode (126,128) is formed respectively and is arranged at the corresponding surface of photoelectric conversion layer 111, the mode that its formation method can be vapour deposition method (evaporation), sputtering method (sputtering), print process (print screen), chemical vapour deposition technique (CVD) or other personage being familiar with this skill know.Fig. 6 is only the position of signal electrode (126,128) relative to photoelectric conversion layer 111, therefore omits the pattern illustrated in above-mentioned Fig. 2-5.Electrode 126 forms the front being arranged at photoelectric conversion layer 111, and run through anti-reflecting layer 116 and be electrically connected to photoelectric conversion layer 111; Electrode 128 formation arrange the back side of photoelectric conversion layer 111, and contact with P type semiconductor base material 110.Electrode (126,128) can be made up of layer gold or alloy, its material can be the similar substances such as gold, silver, aluminium, copper, platinum, can also be the such as transparent conductive oxide (transparent conductiveoxide) such as tin indium oxide (ITO) or zinc oxide (ZnO).
Electrode (126,128) namely becomes two electric terminals of photoelectric conversion layer 111.When solar cell 100 accepts solar light irradiation, electrode (126,128) is that the electric energy in order to produce photoelectric conversion layer 111 carries out charge and discharge operation.Preferably, electrode 128 can be arranged to various shape, such as concavo-convex fluctuating (concavo-convex) structure, assembles (light collection) in order to luminous energy.Moreover electrode 126 can form specific surface structure (surface-textured structure) and have rough surface, then for light energy and in the incident efficiency of photoelectric conversion layer 111, can promote to some extent.
On electrode (126,128), different protective layers (not being illustrated in drawing) can be covered on demand to increase the weatherability of solar cell 100.
From the invention described above execution mode, apply the manufacture method of multicolour paintings type solar cell of the present invention, background color first needed for paintings forms an anti-reflecting layer above above-mentioned photoelectric conversion layer, the shades of colour of the various patterns again needed for paintings, is etched to thickness corresponding to various pattern to realize multicoloured solar cell by anti-reflecting layer.This manufacture method is different from the known mode with laminated multi-layer anti-reflecting layer and realizes multicoloured means, and simplifies the complexity of known superimposed multi-layer anti-reflection layer.
Although the present invention discloses as above with execution mode; so itself and be not used to limit the present invention; anyly be familiar with this those skilled in the art; without departing from the spirit and scope of the present invention; when being used for a variety of modifications and variations, the scope that therefore scope of patent protection of the present invention must define depending on appending claims is as the criterion.

Claims (4)

1. a manufacture method for multicolour paintings type solar cell, is characterized in that, at least comprise:
Form a photoelectric conversion layer on a base material;
According to the background color needed for paintings, form an anti-reflecting layer above above-mentioned photoelectric conversion layer;
First color of the first pattern needed for these paintings, forms etching glue on this anti-reflecting layer, the thickness of answering to this first Color pair with the region etching this first pattern of this anti-reflecting layer; And
Second color of the second pattern needed for these paintings, forms etching glue on this anti-reflecting layer, the thickness of answering to this second Color pair with the region etching this second pattern of this anti-reflecting layer.
2. the manufacture method of multicolour paintings type solar cell according to claim 1, it is characterized in that, this anti-reflecting layer comprises silicon nitride or silica.
3. the manufacture method of multicolour paintings type solar cell according to claim 1, it is characterized in that, this etching glue comprises hydrofluoride.
4. the manufacture method of multicolour paintings type solar cell according to claim 1, is characterized in that, also comprise:
3rd color of the 3rd pattern needed for these paintings, the thickness that the region etching the 3rd pattern of this anti-reflecting layer is answered to the 3rd Color pair.
CN201110091412.7A 2011-03-29 2011-04-07 Method for manufacturing multi-color drawing type solar cell Expired - Fee Related CN102738294B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
TW100110802 2011-03-29
TW100110802A TWI435462B (en) 2011-03-29 2011-03-29 Manufacturing method for multi-color crayoned solar cells

Publications (2)

Publication Number Publication Date
CN102738294A CN102738294A (en) 2012-10-17
CN102738294B true CN102738294B (en) 2015-06-17

Family

ID=46993441

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201110091412.7A Expired - Fee Related CN102738294B (en) 2011-03-29 2011-04-07 Method for manufacturing multi-color drawing type solar cell

Country Status (3)

Country Link
KR (1) KR101250207B1 (en)
CN (1) CN102738294B (en)
TW (1) TWI435462B (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105023956A (en) * 2014-04-28 2015-11-04 陈彩惠 Solar panel structure with pattern
TWI611593B (en) 2014-08-07 2018-01-11 Chen Cai Hui Solar panel structure with illuminating pattern
EP3648174A1 (en) * 2018-10-31 2020-05-06 Total SA Photovoltaic assembly

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5725006A (en) * 1995-01-31 1998-03-10 Mitsubishi Denki Kabushiki Kaisha Solar battery cell, a solar battery module, and a solar battery module group
CN2733597Y (en) * 2004-09-27 2005-10-12 西安佳阳新能源有限公司 Color photovoltaic assembly
KR100952428B1 (en) * 2009-07-10 2010-04-14 주식회사 순에너지 Manufacturing method of color design solar cell
TW201037843A (en) * 2009-04-01 2010-10-16 Gintech Energy Corp High efficeency colored solar cell and manufacturing method thereof
CN101982889A (en) * 2010-10-11 2011-03-02 山东力诺太阳能电力股份有限公司 Manufacturing method of solar cell

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101728453B (en) * 2008-10-28 2011-10-05 昱晶能源科技股份有限公司 Method for manufacturing solar battery with differential doping

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5725006A (en) * 1995-01-31 1998-03-10 Mitsubishi Denki Kabushiki Kaisha Solar battery cell, a solar battery module, and a solar battery module group
CN2733597Y (en) * 2004-09-27 2005-10-12 西安佳阳新能源有限公司 Color photovoltaic assembly
TW201037843A (en) * 2009-04-01 2010-10-16 Gintech Energy Corp High efficeency colored solar cell and manufacturing method thereof
KR100952428B1 (en) * 2009-07-10 2010-04-14 주식회사 순에너지 Manufacturing method of color design solar cell
CN101982889A (en) * 2010-10-11 2011-03-02 山东力诺太阳能电力股份有限公司 Manufacturing method of solar cell

Also Published As

Publication number Publication date
TWI435462B (en) 2014-04-21
CN102738294A (en) 2012-10-17
KR101250207B1 (en) 2013-04-08
TW201240130A (en) 2012-10-01
KR20120111864A (en) 2012-10-11

Similar Documents

Publication Publication Date Title
EP2154727B1 (en) Solar cells provided with color modulation and method for fabricating the same
US8053665B2 (en) Truncated pyramid structures for see-through solar cells
JP5528809B2 (en) Template and method of use for three-dimensional thin film solar cell manufacturing
US8853521B2 (en) Truncated pyramid structures for see-through solar cells
JP2014150280A (en) Template for manufacturing three-dimensional thin-film solar cell and use method
WO2008045813A2 (en) Solar module structures and assembly methods for three-dimensional thin-film solar cells
US10978990B2 (en) Glass cover with optical-filtering coating for managing color of a solar roof tile
KR101161378B1 (en) Thin-film type solar cell having white reflective media layer and fabricating method thereof
CN102169195A (en) Method for manufacturing nanometer antireflection film or antireflection coating and optical or photoelectric device
WO2017090056A1 (en) Solar module with selective colored coating
CN102237441A (en) Method for realizing light transmission of thin film solar module by using vibrating mirror laser equipment
CN102738294B (en) Method for manufacturing multi-color drawing type solar cell
US8822259B2 (en) Methods for enhancing light absorption during PV applications
CN103367472A (en) T-type top electrode back-reflection thin film solar cell
US20090272428A1 (en) Insulating Glass Unit with Integrated Mini-Junction Device
US20100139753A1 (en) Semiconductor device and method of producing a semiconductor device
EP2711990A1 (en) Solar module and its production process
WO2015071708A1 (en) Photovoltaic device and method of manufacturing same
CN102064212B (en) Amorphous silicon film solar cell and preparation method thereof
CN111640802A (en) HIT battery without back silver electrode and manufacturing method thereof
CN215451422U (en) Solar energy assembly
CN113380903A (en) Solar energy assembly
CN111987225A (en) IBC solar cell structure and preparation process thereof
EP2194583A1 (en) Semiconductor device and method of producing a semiconductor device
WO2010063590A1 (en) Semiconductor device and method of producing a semiconductor device

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20150617

Termination date: 20160407