CN1027380C - Coal-fired detergent - Google Patents
Coal-fired detergent Download PDFInfo
- Publication number
- CN1027380C CN1027380C CN 91108658 CN91108658A CN1027380C CN 1027380 C CN1027380 C CN 1027380C CN 91108658 CN91108658 CN 91108658 CN 91108658 A CN91108658 A CN 91108658A CN 1027380 C CN1027380 C CN 1027380C
- Authority
- CN
- China
- Prior art keywords
- coal
- agent
- undesirable
- reducing smoke
- coal burning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003599 detergent Substances 0.000 title abstract 2
- 239000003245 coal Substances 0.000 claims abstract description 39
- 238000000034 method Methods 0.000 claims abstract description 16
- 239000000126 substance Substances 0.000 claims abstract description 11
- 150000001875 compounds Chemical class 0.000 claims abstract description 10
- 239000002808 molecular sieve Substances 0.000 claims abstract description 10
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 9
- 238000003618 dip coating Methods 0.000 claims abstract description 9
- 229910052751 metal Inorganic materials 0.000 claims abstract description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical group [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000654 additive Substances 0.000 claims abstract description 6
- 230000000996 additive effect Effects 0.000 claims abstract description 6
- 239000011248 coating agent Substances 0.000 claims abstract description 6
- 239000011777 magnesium Substances 0.000 claims abstract description 6
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- 239000000779 smoke Substances 0.000 claims description 12
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 10
- 239000012535 impurity Substances 0.000 claims description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- 239000000292 calcium oxide Substances 0.000 claims description 6
- 235000012255 calcium oxide Nutrition 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- JMANVNJQNLATNU-UHFFFAOYSA-N oxalonitrile Chemical compound N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 claims description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 4
- 239000004571 lime Substances 0.000 claims description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 3
- 239000005864 Sulphur Substances 0.000 claims description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 3
- 239000004568 cement Substances 0.000 claims description 3
- 229910000514 dolomite Inorganic materials 0.000 claims description 3
- 239000010459 dolomite Substances 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 230000004927 fusion Effects 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000001095 magnesium carbonate Substances 0.000 claims description 2
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 2
- 229960001708 magnesium carbonate Drugs 0.000 claims description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 150000007524 organic acids Chemical class 0.000 claims description 2
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 238000012216 screening Methods 0.000 claims description 2
- 235000017550 sodium carbonate Nutrition 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 2
- 239000000052 vinegar Substances 0.000 claims description 2
- 235000021419 vinegar Nutrition 0.000 claims description 2
- 238000000746 purification Methods 0.000 abstract description 4
- 230000008901 benefit Effects 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 239000004484 Briquette Substances 0.000 abstract description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004411 aluminium Substances 0.000 abstract description 2
- 229910052782 aluminium Inorganic materials 0.000 abstract description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 2
- 239000011575 calcium Substances 0.000 abstract description 2
- 229910052791 calcium Inorganic materials 0.000 abstract description 2
- 239000010703 silicon Substances 0.000 abstract description 2
- 229910052710 silicon Inorganic materials 0.000 abstract description 2
- 239000002671 adjuvant Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 4
- 239000003513 alkali Substances 0.000 description 2
- 238000005202 decontamination Methods 0.000 description 2
- 230000003588 decontaminative effect Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000002893 slag Substances 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003034 coal gas Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000003746 solid phase reaction Methods 0.000 description 1
- 238000010671 solid-state reaction Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Treating Waste Gases (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Abstract
The invention relates to a coal detergent, it is added chemical adjuvant by the compound and synthesized the reagent that can remove the harmful substance in the fire coal, the molecular sieve containing metallic element, it is a magnesium, calcium, silicon, aluminium type molecular sieve, the finished product is fine graininess, the consumption, can be regarded as additive to process the raw coal or regarded as the dip-coating agent to process the briquette coal, the fire coal supplies after the invention is processed are left naturally and used after 24 hours under the dry condition, the use temperature is 950 duC, the advantage of the invention is that the raw materials are easy to get, process simple, easy to use, cheap, process the supplies and carry on at room temperature, can reduce the discharge of the harmful substance in the fire coal effectively, the purification rate reaches 90%.
Description
The present invention relates to the purification techniques of objectionable impurities in a kind of fire coal, particularly a kind of coal burning agent for reducing smoke or undesirable.
At present, purification techniques development about objectionable impurities in the fire coal is very fast, especially aspect industrial furnace, use some refining plants, use some purifying methods to obtain very big progress, as in fire coal, adding compound oxidation magnesium (being commonly called as rhombspar), the widespread use of the certain methods of clay and citrate of lime, but these are to the sulfide in the fire coal, the tangible method of nitride decontamination effect improving, no matter be to adopt device also to be to use reagent, its comprehensive purifying effect is still unsatisfactory, because objectionable impurities just is discharged into outside the Working environment, still remain in the air, its influence still exists.And the facility investment of using is big, and reagent expense height is not easy to apply on a large scale, particularly applying aspect civil.
The objective of the invention is,, propose a kind of coal burning agent for reducing smoke or undesirable at above-mentioned the deficiencies in the prior art.
Technical solution of the present invention is, add the synthetic reagent that can remove objectionable impurities sulphur, nitrogen, cyanogen, fluorine cpd and carbon monoxide of chemical assistant by compound, it is characterized in that, this reagent is the sticking agent that contains the metallic element molecular sieve, by multiple natural inorganic mineral and organic acid is compound makes, perhaps add acid or the making of bases chemical assistant by compound, its finished product is a fine particulate.Using method of the present invention is to handle coal-fired material at normal temperature condition, makes additive, and the dip-coating agent is done in per kilogram additive and the fusion of 100-120 kilogram raw coal, the dip-coating agent that the hot water of per kilogram raw material and 5 kilograms 〉=70 ℃ is modulated thick pulpous state.Dip-coating 80-100 kilogram moulded coal, the entire treatment process is carried out under normal temperature condition, and coal-fired material after treatment leaves standstill naturally under drying conditions after 24 hours and to use, in 950 ℃ of the use temperatures.The present invention is applicable to the coal-fired material of sulfur-bearing≤3%.The invention belongs to a kind of magnesium, calcium, silicon, aluminium type molecular sieve.According to coal gas, solid phase physical and chemical principle, make the molecular adsorption in the molecular sieve of the metallic element that the gas molecule particulate of the objectionable impurities that discharges in the fire coal can contain with the present invention under the different temperature difference, conversion is gas phase, solid state reaction generates unhydrolyzed binary compound, get rid of with the waste residue behind the fired coal combustion, reduced emission of harmful substances amounts such as sulphur, cyanogen, fluorine, nitrogen compound and carbon monoxide effectively, reduced it for the erosion of human body and the pollution that causes to environment.
The invention has the advantages that, constitute raw material of the present invention and be easy to get that processing is simple, easy to use, cheap, handling coal-fired material is to carry out at normal temperatures.Both can handle with coal, can handle with coal commercial coal stove again Industrial Boiler, remove with the set fire coal in objectionable impurities, decontamination and deodorant, purification efficiency is up to 90%.Processing of the present invention and application process are all pollution-free, and its comprehensive benefit is better than, and known " single alkali " reaches " two alkali ".It is good to burn slag forming through the fire coal after the present invention's processing, the hardness height, its set material forms integument (being responding layer) with the burning slag, not only purified environment but also improved coal-fired heat utilization efficiency, effect is fairly obvious, also for comprehensive regulation environmental pollution with eliminate objectionable impurities in the fire coal and provide a kind of effective few product and method of spending to the erosion of human body.
Now, embodiments of the invention are described:
Preparing quick lime, two kinds of compounds of calcium oxide with unslaked lime weight ratio 1%, they are mixed, levigate to 200 orders, as carrier, in carrier, add chemical assistant, wherein add the aluminium sesquioxide of vehicle weight 1%, 1.5% sodium silicoaluminate, 0.5% ferric oxide, 1% magnesiumcarbonate, 1% ethanol, 0.4% citric acid, 0.2% second two ammoniums, 1% acetic acid, even with carrier mix in mixing machine, duration of mixing 2 hours, the roasting 2 hours under 350 ℃ of temperature condition of material evenly, make the sticking agent that contains the metallic element molecular sieve, get 40 order screen underflows through screening and use as finished product.Using method of the present invention is, make additive, per kilogram reagent can be handled 100-120 kilogram raw coal, does the dip-coating agent, per kilogram reagent becomes the dip-coating agent of thick pulpous state with 5 kilograms 〉=70 ℃ hot water hybrid modulation, can dip-coating processing 80-100 kilogram moulded coal (for example honeycomb briquette).Using the present invention to handle coal-fired entire treatment process carries out at normal temperatures.The present invention is applicable to the fire coal of sulfur-bearing≤3% scope.Coal-fired material after the present invention handles needs leave standstill naturally under the drying conditions to re-use after (promptly 1 round the clock) in 24 hours, in 950 ℃ of the use temperatures.
Use magnesian lime, ground dolomite and magnesium cement to do carrier, interpolation chemical assistant salt, caustic soda or interpolation soda ash, vinegar are made the coal burning agent for reducing smoke or undesirable of the molecular sieve that contains metallic element also can use the method processing treatment fire coal that the present invention proposes, and its effect is fine.
Claims (5)
1, coal burning agent for reducing smoke or undesirable, can remove objectionable impurities sulphur by compound interpolation chemical assistant is synthetic, nitrogen, cyanogen, the reagent of fluorine cpd and carbon monoxide, it is characterized in that, this reagent is the sticking agent that contains the metallic element molecular sieve, by multiple natural inorganic mineral with organic acid is compound makes, perhaps add acid or the making of bases chemical assistant by compound, its finished product is a fine particulate, and the sticking agent that contains metallic element is by unslaked lime with by the aluminium sesquioxide of unslaked lime weight 1%, 1.5% sodium silicoaluminate, 0.5% ferric oxide, 1% magnesiumcarbonate, 1% ethanol, 0.4% citric acid, 0.2% second two ammoniums, 1% acetic acid is formed.
2, a kind of making method of coal burning agent for reducing smoke or undesirable according to claim 1, it is characterized in that, the material of coal burning agent for reducing smoke or undesirable will be formed, mix according to proportioning, make carrier to 200 orders with unslaked lime and alchlor are levigate, to put into the mixing machine mix even with other allotment materials again, and the material was evenly burnt 2 hours through 350 ℃ of temperature condition bakings, gets 40 order screen underflows through screening.
3, coal burning agent for reducing smoke or undesirable according to claim 1 is characterized in that, the sticking agent that contains the metallic element molecular sieve is made carrier by magnesian lime, ground dolomite, magnesium cement, adds salt and caustic soda and makes.
4, coal burning agent for reducing smoke or undesirable according to claim 1 is characterized in that, the sticking agent that contains the metallic element molecular sieve is made carrier by magnesian lime, ground dolomite, magnesium cement, and interpolation soda ash and vinegar make in carrier.
5, a kind of purposes of coal burning agent for reducing smoke or undesirable according to claim 1, it is characterized in that coal burning agent for reducing smoke or undesirable is used as additive, itself and raw coal fusion, per 1 kilogram of additive fusion 100-120 kilogram raw coal, use as the dip-coating agent, per kilogram coal burning agent for reducing smoke or undesirable and 5 kilograms 〉=70 ℃ hot water are modulated into thick pulpous state, dip-coating 80-100 kilogram moulded coal again, and the entire treatment process is carried out under normal temperature condition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91108658 CN1027380C (en) | 1991-08-26 | 1991-08-26 | Coal-fired detergent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91108658 CN1027380C (en) | 1991-08-26 | 1991-08-26 | Coal-fired detergent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1064501A CN1064501A (en) | 1992-09-16 |
| CN1027380C true CN1027380C (en) | 1995-01-11 |
Family
ID=4909400
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 91108658 Expired - Fee Related CN1027380C (en) | 1991-08-26 | 1991-08-26 | Coal-fired detergent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1027380C (en) |
-
1991
- 1991-08-26 CN CN 91108658 patent/CN1027380C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1064501A (en) | 1992-09-16 |
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|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |