CN102733248A - Method used for lowering release amounts of harmful components in main stream smoke and applied to cigarette paper containing rice paper pulp fibers - Google Patents
Method used for lowering release amounts of harmful components in main stream smoke and applied to cigarette paper containing rice paper pulp fibers Download PDFInfo
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- CN102733248A CN102733248A CN201210239310XA CN201210239310A CN102733248A CN 102733248 A CN102733248 A CN 102733248A CN 201210239310X A CN201210239310X A CN 201210239310XA CN 201210239310 A CN201210239310 A CN 201210239310A CN 102733248 A CN102733248 A CN 102733248A
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Abstract
The invention discloses a method used for lowering release amounts of harmful components in main stream smoke and applied to cigarette paper containing rice paper pulp fibers, and belongs to the technical field of reduction of tar and harmful components in the tobacco industry. The method is mainly and technically characterized in that 20%-35% of calcium carbonate stuffing, 1.0%-40% of rice paper pulp fibers, 10%-60% of hardwood pulp fibers and 5.0%-30% of softwood pulp fibers are evenly mixed by weight in a pulp preparing pool; the production is performed according to a normal cigarette paper production technology; 0.5%-5% of cigarette paper additives are added into the cigarette paper through a sizing machine; and then the cigarette paper containing rice paper pulp fibers is obtained and rolled up to form cigarettes. The release amounts of the harmful components in the main stream smoke, such as CO, crotonaldehyde, benzo[a]pyrene and NNK, can be effectively lowered.
Description
Technical field:
The present invention relates to the method that a kind of application contains the cigarette paper reduction cigarette mainstream flue gas harmful components burst size of rice paper paper pulp fiber, belong to the lowering harm and decreasing coking technical field of tobacco industry.
Background technology:
Present stage, tobacco business was faced with the multiple pressure of the World Health Organization and [Tobacco Control framework treaty]; On the other hand, along with improving constantly of living standard and quality of life, the contradiction between smoking and the health becomes increasingly conspicuous; To the cigarette security require increasingly high; Improve the cigarette security, the burst size that lowers harmful components in the cigarette smoke is the developing direction of international cigarette technology, also is the inevitable demand of development Chinese style cigarette.Seven kinds of harmful components carbon monoxide, hydrogen cyanide, Benzpyrene, phenol, crotonaldehyde, ammonia and 4-(methyl nitrosamino group) in the cigarette mainstream flue gas-4-(3-pyridine radicals)-1-butanone (NNK) burst size can effectively characterize cigarette mainstream flue gas biohazard property, and effectively reducing by seven kinds of harmful components is key problem in technology of realizing further harm reduction work.
Cigarette paper also is called cigarette bobbin paper, is the important materials of cigarette.Regular-size cigarette paper mainly is made up of inorganic filler in string and the structure thereof and combustionregulator.String commonly used has wood pulp fibre and linen fibre, and its consumption is generally the 65-75% of cigarette paper weight.Inorganic filler mainly is a calcium carbonate, and its consumption is the 25-35% of cigarette paper weight.Combustionregulator is generally organic acid alkali metal salt, after the paper moulding, adds, and its consumption is generally the 0.5-3% of cigarette paper weight.Cigarette paper is as the main auxiliary material of cigarette, mainly plays the effect of parcel pipe tobacco, but its compare with yew paper with forming paper, topmost characteristics are exactly that cigarette paper will be participated in the burning of whole cigarette.Undoubtedly, the physicochemical characteristics of cigarette paper will produce significant effects to the formation of harmful components in the cigarette smoke.
At present, develop the research focus that the cigarette paper with harm reduction function has become current tobacco science and technology.Like application number is 201010197011.5 Chinese invention patent application once open " a kind of method of improving quality of cigarette paper "; The mass ratio of malic acid by mass ratio 0.1%-25% is dissolved in the mixed solution of water or second alcohol and water; Then with the ratio of the solution that mixes in 0.01%-5%; Cigarette paper is carried out the roll extrusion coating, and the cigarette paper that makes after the drying can improve the suction quality of cigarette, reduces the burst size of the ammonia in the cigarette mainstream flue gas.Application number is 201110123677.0 Chinese invention patent application once open " a kind of functional cigarette paper and preparation method "; At surface sprinkling of regular-size cigarette paper or a kind of minute ascus formed material of dip-coating layer, can effectively reduce harmful substances such as carbon monoxide and nitrosamine in the cigarette smoke.Application number is that 201110250573.6 Chinese invention patent application discloses " a kind of cigarette paper additive and application thereof "; With chrysanthemum and bluish dogbane, lophatherum gracile, rosemary,, a kind of or any several kinds of mixed extracts in Huang Shi, dandelion or the long-noded pit viper glossal canal are with after slaine mixes; Mode with coating or dip-coating is carried out the single or double applying glue on cigarette scraps of paper base; Harmful components in the ability selectivity reducing cigarette main flume, wherein, crotonaldehyde reduces 20%-40%; Phenols lowers 15-25%, and hydrogen cyanide reduces 15-30%.Application number is that 201010110006.6 Chinese invention patent application discloses " a kind of cigarette paper additive "; The compounding agent solution that will contain potassium phosphate, potassium citrate, potassium malate, glucose and citric acid makes an addition on the cigarette paper with the mode of applying glue; Can effectively reduce the carbon monoxide in the main flume, and promote the cigarette smoking quality.Application number is that 200810189920.7 Chinese invention patent discloses " a kind of cigarette paper and preparation thereof that reduces harmful substance contents such as carbon monoxide in the cigarette smoke, oxynitrides and phenols "; A kind of double wrap of patent report has the internal layer cigarette paper of metal oxide, composite oxide of metal, metal hydroxides or metallic hydrogen oxidation oxide and is wrapped in the outer outer cigarette paper of internal layer cigarette paper and constitute by being wrapped in the outer load of pipe tobacco.This cigarette paper can effectively reduce content of harmful in the cigarette smoke, reduces carbon monoxide greater than 10%, and nitrogen oxide is greater than 15%, and phenols is greater than 10%.Application number is that the Chinese invention patent application of 200610010731.X discloses " reducing cigarette paper with low-quantitation and high-transparent of carbon monoxide in flue gas and preparation method thereof "; To adhere to as processing aid by the mixture that inorganic filler, dispersant and combustion adjuvant constitute or be immersed on the cigarette paper; Obtained cigarette paper has quantitatively low and high airtight degree characteristic, and can effectively reduce the carbon monoxide in the flue gas.
It should be noted that above disclosed method all is through in cigarette paper, adding exogenous chemical substances to reach the purpose that reduces harmful components in the cigarette smoke.Up to now, prepare cigarette paper about the technological means of utilizing the special pulps fiber and do not see any report as yet with tar and harm reducing function.
Summary of the invention:
For overcoming the defective of prior art, the object of the present invention is to provide simple, the steady quality of a kind of production technology, can effectively reduce the method for cigarette mainstream flue gas harmful components burst size.
Technical solution problem of the present invention adopts following technical scheme:
Application contains the method for the cigarette paper reduction cigarette mainstream flue gas harmful components burst size of rice paper paper pulp fiber; By mass ratio the softwood pulp fiber of rice paper paper pulp fiber, 10-60% hardwood pulp fiber and the 5.0-30% of the pearl filler of 20-35%, 1.0-40% is mixed joining stock tank; Produce by normal cigarette paper production technology; The cigarette paper auxiliary agent of 0.5-5% adds in the cigarette paper through sizing applicator, promptly obtains adopting the cigarette paper of rice paper paper pulp fiber, and cigarette becomes cigarette to prop up then.
Described rice paper paper pulp fiber is the mixture that wingceltis pulp fiber and Shatian straw pulp fiber are formed by mass ratio 1:5~1.
Said cigarette paper auxiliary agent is potassium citrate or natrium citricum, or potassium citrate and natrium citricum are pressed the mixture that mass ratio 3~1:1 forms.
Compared with present technology, beneficial effect of the present invention is embodied in:
1, harm reduction effect is obvious.Compare with regular-size cigarette paper, the cigarette that utilizes the cigarette paper cigarette that contains the rice paper paper pulp fiber according to the invention to form props up, and can reduce harmful components CO in the cigarette mainstream flue gas, crotonaldehyde, benzo [a] pyrene and NNK more than 25%.
2, the present invention does not have negative effect to the smoking property of cigarette quality;
3, the preparation implementation is simple.In whole process of preparation, need not increase any production equipment, can not change existing production of cigarettes processing technology yet, technical implementation way is simple.
Below, the present invention is described further through the specific embodiment.
The specific embodiment:
Embodiment 1:
By mass ratio the softwood pulp fiber of 20% pearl filler, 40% the rice paper paper pulp fiber of being made up of by mass ratio 1:5 wingceltis pulp fiber and Shatian straw pulp fiber, 10% hardwood pulp fiber and 25% is mixed joining stock tank; Produce by normal cigarette paper production technology; 5% natrium citricum adds in the cigarette paper through sizing applicator; Make the cigarette paper that contains the rice paper paper pulp fiber, cigarette becomes cigarette to prop up.Connect the cigarette Zhi Weiwei control sample that forms with the regular-size cigarette paper roll; On smoking machine, carry out the cigarette smoking test according to the standard aspiration condition, and carry out the detection of main flume CO, crotonaldehyde, benzo [a] pyrene and NNK burst size according to standard GB/T23356-2009, YC/T254-2008, GB/T21130-2007 and GB/T 23228-2008.Analysis result is seen table 1.
Embodiment 2:
By mass ratio the softwood pulp fiber of 35% pearl filler, 1% the rice paper paper pulp fiber of being made up of by mass ratio 1:1 wingceltis pulp fiber and Shatian straw pulp fiber, 40% hardwood pulp fiber and 20% is mixed joining stock tank; Produce by normal cigarette paper production technology; 4% potassium citrate adds in the cigarette paper through sizing applicator; Make the cigarette paper that contains the rice paper paper pulp fiber, cigarette becomes cigarette to prop up.Connect the cigarette Zhi Weiwei control sample that forms with the regular-size cigarette paper roll; On smoking machine, carry out the cigarette smoking test according to the standard aspiration condition, and carry out the detection of main flume CO, crotonaldehyde, benzo [a] pyrene and NNK burst size according to standard GB/T23356-2009, YC/T254-2008, GB/T21130-2007 and GB/T 23228-2008.Analysis result is seen table 1.
Embodiment 3:
By mass ratio the softwood pulp fiber of 28% pearl filler, 10% the rice paper paper pulp fiber of being made up of by mass ratio 1:3 wingceltis pulp fiber and Shatian straw pulp fiber, 45% hardwood pulp fiber and 15% is mixed joining stock tank; Produce by normal cigarette paper production technology; The mixture that 2% potassium citrate and natrium citricum are formed by mass ratio 3:1 mixes the back to be added in the cigarette paper through sizing applicator; Make the cigarette paper that contains the rice paper paper pulp fiber, cigarette becomes cigarette to prop up.Connect the cigarette Zhi Weiwei control sample that forms with the regular-size cigarette paper roll; On smoking machine, carry out the cigarette smoking test according to the standard aspiration condition, and carry out the detection of main flume CO, crotonaldehyde, benzo [a] pyrene and NNK burst size according to standard GB/T23356-2009, YC/T254-2008, GB/T21130-2007 and GB/T 23228-2008.Analysis result is seen table 1.
Embodiment 4:
By mass ratio the softwood pulp fiber of 20% pearl filler, 14.5% the rice paper paper pulp fiber of being made up of by mass ratio 1:2 wingceltis pulp fiber and Shatian straw pulp fiber, 60% hardwood pulp fiber and 5% is mixed joining stock tank; Produce by normal cigarette paper production technology; 0.5% potassium citrate and natrium citricum mix the back by mass ratio 2:1 to be added in the cigarette paper through sizing applicator; Make the cigarette paper that contains the rice paper paper pulp fiber, cigarette becomes cigarette to prop up.Connect the cigarette Zhi Weiwei control sample that forms with the regular-size cigarette paper roll; On smoking machine, carry out the cigarette smoking test according to the standard aspiration condition, and carry out the detection of main flume CO, crotonaldehyde, benzo [a] pyrene and NNK burst size according to standard GB/T23356-2009, YC/T254-2008, GB/T21130-2007 and GB/T 23228-2008.Analysis result is seen table 1.
Embodiment 5:
Will be subsequent use after handling by the removal of impurities of rice paper paper pulp fiber, desanding, making beating that wingceltis pulp fiber and Shatian straw pulp fiber are formed by mass ratio 1:4; By mass ratio the softwood pulp fiber of 25% pearl filler, 5% rice paper paper pulp fiber, 35% hardwood pulp fiber and 30% is mixed joining stock tank then; Produce by normal cigarette paper production technology; 5% potassium citrate and natrium citricum mix the back by mass ratio 1:1 to be added in the cigarette paper through sizing applicator; Make the cigarette paper that contains the rice paper paper pulp fiber, cigarette becomes cigarette to prop up.Connect the cigarette Zhi Weiwei control sample that forms with the regular-size cigarette paper roll; On smoking machine, carry out the cigarette smoking test according to the standard aspiration condition, and carry out the detection of main flume CO, crotonaldehyde, benzo [a] pyrene and NNK burst size according to standard GB/T23356-2009, YC/T254-2008, GB/T21130-2007 and GB/T 23228-2008.Analysis result is seen table 1.
Embodiment 6:
By mass ratio the softwood pulp fiber of 20% pearl filler, 40% the rice paper paper pulp fiber of being made up of by mass ratio 1:1 wingceltis pulp fiber and Shatian straw pulp fiber, 10% hardwood pulp fiber and 25% is mixed joining stock tank; Produce by normal cigarette paper production technology; 5% natrium citricum adds in the cigarette paper through sizing applicator; Make the cigarette paper that contains the rice paper paper pulp fiber, cigarette becomes cigarette to prop up.Connect the cigarette Zhi Weiwei control sample that forms with the regular-size cigarette paper roll; On smoking machine, carry out the cigarette smoking test according to the standard aspiration condition, and carry out the detection of main flume CO, crotonaldehyde, benzo [a] pyrene and NNK burst size according to standard GB/T23356-2009, YC/T254-2008, GB/T21130-2007 and GB/T 23228-2008.Analysis result is seen table 1.
Claims (3)
1. use the method that the cigarette paper that contains the rice paper paper pulp fiber reduces cigarette mainstream flue gas harmful components burst size; It is characterized in that; By mass ratio the softwood pulp fiber of rice paper paper pulp fiber, 10-60% hardwood pulp fiber and the 5.0-30% of the pearl filler of 20-35%, 1.0-40% is mixed joining stock tank; Produce by normal cigarette paper production technology; The cigarette paper auxiliary agent of 0.5-5% adds in the cigarette paper through sizing applicator, promptly obtains adopting the cigarette paper of rice paper paper pulp fiber, and cigarette becomes cigarette to prop up then.
2. application according to claim 1 contains the method for the cigarette paper reduction cigarette mainstream flue gas harmful components burst size of rice paper paper pulp fiber; It is characterized in that described rice paper paper pulp fiber is the mixture that wingceltis pulp fiber and Shatian straw pulp fiber are formed by mass ratio 1:5~1.
3. application according to claim 1 contains the method for the cigarette paper reduction cigarette mainstream flue gas harmful components burst size of rice paper paper pulp fiber; It is characterized in that; Said cigarette paper auxiliary agent is potassium citrate or natrium citricum, or potassium citrate and natrium citricum are pressed the mixture that mass ratio 3~1:1 forms.
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Cited By (3)
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CN108158035A (en) * | 2018-01-11 | 2018-06-15 | 云南中烟工业有限责任公司 | A kind of wingceltis skin, sugarcane fiber composite paper filter material and its preparation method and application |
CN108425269A (en) * | 2018-02-08 | 2018-08-21 | 河南中烟工业有限责任公司 | A kind of cigarette paper and preparation method thereof added with tangerine peel powder |
CN109056399A (en) * | 2018-09-20 | 2018-12-21 | 中国宣纸股份有限公司 | A kind of stock mixing system of rice paper slurry |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108158035A (en) * | 2018-01-11 | 2018-06-15 | 云南中烟工业有限责任公司 | A kind of wingceltis skin, sugarcane fiber composite paper filter material and its preparation method and application |
CN108158035B (en) * | 2018-01-11 | 2020-10-27 | 云南中烟工业有限责任公司 | Sanders and bagasse fiber composite paper filter material and preparation method and application thereof |
CN108425269A (en) * | 2018-02-08 | 2018-08-21 | 河南中烟工业有限责任公司 | A kind of cigarette paper and preparation method thereof added with tangerine peel powder |
CN109056399A (en) * | 2018-09-20 | 2018-12-21 | 中国宣纸股份有限公司 | A kind of stock mixing system of rice paper slurry |
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