CN102732008A - Scented halogen-free flame retardant nylon composite material - Google Patents
Scented halogen-free flame retardant nylon composite material Download PDFInfo
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- CN102732008A CN102732008A CN2012101975616A CN201210197561A CN102732008A CN 102732008 A CN102732008 A CN 102732008A CN 2012101975616 A CN2012101975616 A CN 2012101975616A CN 201210197561 A CN201210197561 A CN 201210197561A CN 102732008 A CN102732008 A CN 102732008A
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- nylon matrix
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Abstract
Belonging to the technological field of high polymer materials, the invention relates to a scented halogen-free flame retardant nylon composite material. The material is composed of the following raw materials by weight: 42-47 parts of nylon 610 resin; 12-19 parts of rubber; 0.4-0.8 part of a coupling agent; 0.2-1.1 parts of a scented masterbatch; 5-11 parts of a filling material; 7-16 parts of a flame retardant; 0.2-0.6 part of an antioxidant; and 17-26 parts of a glass fiber. The nylon composite material provided by the invention has the advantages that: the tensile strength is more than 170MPa, the bending strength is over 200MPa, the izod notched impact strength is greater than 34kj/m<2>, the melt index is larger than 26g/10min, the flame retardance reaches V-0; and the appropriate scent of the material can improve the environment of a processing site.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of nylon composite materials with halogen-free flameproof of fragrance.
Background technology
Nylon material add tend to man-hour give out unpleasant offensive odour and when burning this smell more very.In addition, general nylon material has been owing to added halogen flame, thereby produces deleterious hydrogen halide when causing burning, is prone to the indicator of trapped personnel in the fire is caused the secondary injury.Therefore be necessary to improve.
Summary of the invention
Task of the present invention is to provide a kind of help to eliminate unpleasant strange taste and the nylon composite materials that helps significantly improving flame retardant effect and be of value to the halogen-free flameproof with fragrance of promoting intensity.
Task of the present invention is accomplished like this, a kind of halogen-free reinforced nylon matrix material with fragrance, and its raw material by following parts by weight is formed:
In one embodiment of the invention, described NYLON610 resin is a fusing point at 230 ℃ resin.
In another embodiment of the present invention, described rubber is the styrene-butadiene rubber(SBR) of powder.
In yet another embodiment of the present invention, described coupling agent is β-(3,4 epoxy cyclohexyl) ethyl trimethoxy silane.
In another embodiment of the present invention, described aroma agglomerate is spissated essence master batch.
Also have among the embodiment of the present invention, described filler is surface-treated Marinco H.
more of the present invention and among embodiment, described fire retardant is the trimeric cyanamide urate.
In of the present invention and then embodiment, described oxidation inhibitor is three [2,4 di-tert-butyl-phenyl] phosphorous acid ester.
Of the present invention again more and among embodiment, described spun glass is the alkali-free short glass fiber of length 3mm.
Halogen-free reinforced nylon matrix material with fragrance provided by the invention has following performance index, and tensile strength is greater than 170MPa, and flexural strength is greater than 200MPa, and the socle girder notched Izod impact strength is greater than 34kj/m
2, melting index is greater than 26g/10min, and flame retardant resistance reaches V-0 (UL-94-1.6 mm); Have suitable fragrance and use the environment that improves processing site.
Embodiment
Embodiment 1:
Fusing point is 42 parts of NYLON610 resins at 230 ℃ resin, and 12 parts in pulverous styrene-butadiene rubber(SBR), coupling agent are β-(3; 4 epoxy cyclohexyls) ethyl trimethoxy silane is 0.8 part; Spissated aroma agglomerate is 0.6 part of an essence master batch, and filler promptly passes through 5 parts of the Marinco Hs of activation treatment (being surface treatment), and fire retardant is 10 parts of trimeric cyanamide urates; Oxidation inhibitor i.e. 17 parts of the alkali-free short glass fibers of 0.6 part of three [2,4 di-tert-butyl-phenyl] phosphorous acid ester and length 3mm.
Embodiment 2:
Fusing point is 47 parts of NYLON610 resins at 230 ℃ resin, and 14 parts in pulverous styrene-butadiene rubber(SBR), coupling agent are β-(3; 4 epoxy cyclohexyls) ethyl trimethoxy silane is 0.4 part; Spissated aroma agglomerate is 0.2 part of an essence master batch, and filler promptly passes through 11 parts of the Marinco Hs of activation treatment (being surface treatment), and fire retardant is 7 parts of trimeric cyanamide urates; Oxidation inhibitor i.e. 20 parts of the alkali-free short glass fibers of 0.2 part of three [2,4 di-tert-butyl-phenyl] phosphorous acid ester and length 3mm.
Embodiment 3:
Fusing point is 43 parts of NYLON610 resins at 230 ℃ resin, and 19 parts in pulverous styrene-butadiene rubber(SBR), coupling agent are β-(3; 4 epoxy cyclohexyls) ethyl trimethoxy silane is 0.5 part; Spissated aroma agglomerate is 0.9 part of an essence master batch, and filler promptly passes through 7 parts of the Marinco Hs of activation treatment (being surface treatment), and fire retardant is 10 parts of trimeric cyanamide urates; Oxidation inhibitor i.e. 23 parts of the alkali-free short glass fibers of 0.4 part of three [2,4 di-tert-butyl-phenyl] phosphorous acid ester and length 3mm.
Embodiment 4:
Fusing point is 45 parts of NYLON610 resins at 230 ℃ resin, and 16 parts in pulverous styrene-butadiene rubber(SBR), coupling agent are β-(3; 4 epoxy cyclohexyls) ethyl trimethoxy silane is 0.6 part; Spissated aroma agglomerate is 1.1 parts of essence master batches, and filler promptly passes through 9 parts of the Marinco Hs of activation treatment (being surface treatment), and fire retardant is 6 parts of trimeric cyanamide urates; Oxidation inhibitor i.e. 26 parts of the alkali-free short glass fibers of 0.5 part of three [2,4 di-tert-butyl-phenyl] phosphorous acid ester and length 3mm.
The halogen-free reinforced nylon matrix material with fragrance that embodiments of the invention 1 to 4 obtain has the technique effect shown in the following table through test:
Claims (9)
1.
A kind of halogen-free reinforced nylon matrix material with fragrance is characterized in that its raw material by following parts by weight forms:
42～47 parts of NYLON610 resins;
12～19 parts of rubber;
0.4～0.8 part of coupling agent;
0.2～1.1 part of aroma agglomerate;
5～11 parts of fillers;
7～16 parts of fire retardants;
0.2～0.6 part in oxidation inhibitor;
17～26 parts in
spun glass.
2.
halogen-free reinforced nylon matrix material with fragrance according to claim 1 is characterized in that described NYLON610 resin is a fusing point at 230 ℃ resin.
3.
halogen-free reinforced nylon matrix material with fragrance according to claim 1 is characterized in that described rubber is the styrene-butadiene rubber(SBR) of powder.
4.
halogen-free reinforced nylon matrix material with fragrance according to claim 1 is characterized in that described coupling agent is β-(3,4 epoxy cyclohexyl) ethyl trimethoxy silane.
5.
halogen-free reinforced nylon matrix material with fragrance according to claim 1 is characterized in that described aroma agglomerate is spissated essence master batch.
6.
halogen-free reinforced nylon matrix material with fragrance according to claim 1 is characterized in that described filler is surface-treated Marinco H.
7.
halogen-free reinforced nylon matrix material with fragrance according to claim 1 is characterized in that described fire retardant is the trimeric cyanamide urate.
8.
halogen-free reinforced nylon matrix material with fragrance according to claim 1 is characterized in that described oxidation inhibitor is three [2,4 di-tert-butyl-phenyl] phosphorous acid ester.
9.
Halogen-free reinforced nylon matrix material with fragrance according to claim 1 is characterized in that described spun glass is the alkali-free short glass fiber of length 3mm
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101975616A CN102732008A (en) | 2012-06-15 | 2012-06-15 | Scented halogen-free flame retardant nylon composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101975616A CN102732008A (en) | 2012-06-15 | 2012-06-15 | Scented halogen-free flame retardant nylon composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102732008A true CN102732008A (en) | 2012-10-17 |
Family
ID=46988347
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012101975616A Pending CN102732008A (en) | 2012-06-15 | 2012-06-15 | Scented halogen-free flame retardant nylon composite material |
Country Status (1)
| Country | Link |
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| CN (1) | CN102732008A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1800259A (en) * | 2004-12-31 | 2006-07-12 | 山东春潮色母料有限公司 | Aroma agglomerate for plastics and its preparation method |
| CN101760005A (en) * | 2008-12-26 | 2010-06-30 | 上海杰事杰新材料股份有限公司 | High-viscosity halogen-free flame-retardant polyamide composition |
| CN101798460A (en) * | 2010-02-08 | 2010-08-11 | 佛山市南海易乐工程塑料有限公司 | Composite flame retardant glass fibre reinforced nylon 66 insulating strip and preparation method thereof |
-
2012
- 2012-06-15 CN CN2012101975616A patent/CN102732008A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1800259A (en) * | 2004-12-31 | 2006-07-12 | 山东春潮色母料有限公司 | Aroma agglomerate for plastics and its preparation method |
| CN101760005A (en) * | 2008-12-26 | 2010-06-30 | 上海杰事杰新材料股份有限公司 | High-viscosity halogen-free flame-retardant polyamide composition |
| CN101798460A (en) * | 2010-02-08 | 2010-08-11 | 佛山市南海易乐工程塑料有限公司 | Composite flame retardant glass fibre reinforced nylon 66 insulating strip and preparation method thereof |
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| PB01 | Publication | ||
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Application publication date: 20121017 |