CN102730800A - Method and device for utilizing intermittent energy to electrolyze water - Google Patents
Method and device for utilizing intermittent energy to electrolyze water Download PDFInfo
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- CN102730800A CN102730800A CN2011100912386A CN201110091238A CN102730800A CN 102730800 A CN102730800 A CN 102730800A CN 2011100912386 A CN2011100912386 A CN 2011100912386A CN 201110091238 A CN201110091238 A CN 201110091238A CN 102730800 A CN102730800 A CN 102730800A
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Abstract
The invention discloses a method and a device for utilizing intermittent energy to electrolyze water. The method comprises: conducting voltage stabilization treatment to the electric energy generated by intermittent energy; detecting the voltage of the intermittent energy electric energy after the voltage stabilization treatment so as to obtain stabilized voltage; comparing the stabilized voltage with the rated voltage needed for operation of current electrolytic cells, and if the stabilized voltage is greater than the rated voltage, connecting an electrolytic cell that is parallel to and have the same rated voltage to the current electrolytic cells, then carrying out electrolysis of water; if the stabilized voltage is smaller than the rated voltage, decreasing the number of the current electrolytic cells, then carrying out electrolysis of water; and if the stabilized voltage is in the range of the rated voltage, utilizing the current electrolytic cells for electrolysis of water. The rated voltage is the voltage of the electrolytic cells operating in an ideal operation state. By applying the solution provided by the invention, the intermittent energy can be fully utilized, and at the same time the purpose of ensuring the electrolytic cells in an ideal operation state can be realized.
Description
Technical field
The present invention relates to technical field of new energies, particularly relate to a kind of method and device that utilizes the intermittent energy source brine electrolysis.
Background technology
Serious current of energy dilemma, new forms of energy such as sun power, wind energy, tidal energy owing to have renewable, cleaning, advantage such as abundant, have received extensive studies and exploitation.Because these renewable energy sources can produce the energy of instability (that is: intermittence) when many-sided factor affecting such as temperature, weather, region, so the intermittent energy source that is otherwise known as.
Utilize the intermittence energy to carry out brine electrolysis, obtain the mode of hydrogen and oxygen, be considered to a potential approach that utilizes intermittent energy source, but the intermittence of the energy can reduce electrolytic efficiency, thereby reduce the effective rate of utilization of intermittent energy source as power supply.A kind of mode of intermittent energy source brine electrolysis of utilizing of prior art is: the electric energy of intermittent energy source is exported with the mode of constant voltage or constant current, with the stable voltage of supply electrolyzer, thereby realized brine electrolysis, obtain hydrogen and oxygen.The advantage of this mode is the unstable electric energy of intermittent energy source is exported with stable manner, makes electrolyzer under stable voltage, work.But; This mode still can not make full use of intermittent energy source; For example: the electric energy that produces when intermittent energy source hour, though can reach the voltage of electrolyzer works better with the voltage of voltage stabilizing form output, more because of the electrolyzer quantity of load; In fact electrolyzer can't start, and intermittent energy source is underutilized like this.
Simultaneously, though the WV of electrolyzer is high more, electrolytic efficiency is high more, when the WV of electrolyzer is too high, and the work-ing life that can reduce electrolyzer.So electrolyzer just is in perfect condition when only in a voltage range, working, this moment, electrolytic efficiency was higher, and the life-span that helps improving electrolyzer.
Therefore, in the process of brine electrolysis, how to make full use of intermittent energy source, guarantee that simultaneously electrolyzer is in the ideal operation state, becomes important research project.
Summary of the invention
For solving the problems of the technologies described above, the invention provides a kind of method and device that utilizes the intermittent energy source brine electrolysis, to be implemented in the brine electrolysis process, make full use of intermittent energy source, and guarantee that electrolyzer is in the purpose of ideal operation state, technical scheme is following:
A kind of method of utilizing the intermittent energy source brine electrolysis comprises:
The electric energy that intermittent energy source produced is carried out voltage stabilizing to be handled;
Detect voltage stabilizing and handle the voltage of back intermittent energy source electric energy, obtain voltage of voltage regulation;
Said voltage of voltage regulation and the required voltage rating of current cell operation are compared, if after said voltage of voltage regulation greater than said voltage rating, then is the identical electrolyzer of said current electrolyzer parallel connection voltage rating, carry out brine electrolysis; If after said voltage of voltage regulation less than said voltage rating, then reduces the quantity of said current electrolyzer, carry out brine electrolysis; If said voltage of voltage regulation in the said range of nominal tension, then utilizes said current electrolyzer to carry out brine electrolysis;
Said voltage rating is the voltage of cell operation in desirable working order.
Accordingly, the present invention also provides a kind of device that utilizes the intermittent energy source brine electrolysis, comprising:
Voltage stabilizing module, the electric energy that is used for that intermittent energy source is produced carry out voltage stabilizing to be handled;
Voltage detection module is used to detect the voltage of the intermittent energy source electric energy after said Voltage stabilizing module is handled, and obtains voltage of voltage regulation;
Comparison module is used for said voltage of voltage regulation and the required voltage rating of current cell operation are compared, and under the situation of said voltage of voltage regulation greater than said voltage rating, triggers the step-down module; Under the situation of said voltage of voltage regulation, trigger boost module less than said voltage rating; Under the situation of said voltage of voltage regulation in the said range of nominal tension, trigger the brine electrolysis module;
Said step-down module, be used to the identical electrolyzer of said current electrolyzer parallel connection voltage rating after, trigger said brine electrolysis module;
Said boost module after being used to reduce the quantity of said current electrolyzer, triggers said brine electrolysis module;
Said brine electrolysis module is used to utilize said current electrolyzer to carry out brine electrolysis.
In the scheme provided by the present invention, when utilizing intermittent energy source to carry out brine electrolysis for the electrolyzer power supply, after the electric energy voltage stabilizing processing that intermittent energy source produced, detect the voltage of intermittent energy source electric energy, determine voltage of voltage regulation as power supply; Judge that then whether said voltage of voltage regulation in the required range of nominal tension, according to judged result, is adjusted current electrolyzer, carries out follow-up brine electrolysis then when the electrolyzer works better.In this programme; According to the fluctuation size of intermittent energy source electric energy voltage of voltage regulation after the voltage stabilizing, confirm the electrolyzer of proper amt, make electrolyzer in the range of nominal tension, work; Make full use of intermittent energy source with this, and guarantee that simultaneously electrolyzer is in the ideal operation state.
Description of drawings
In order to be illustrated more clearly in the embodiment of the invention or technical scheme of the prior art; To do simple the introduction to the accompanying drawing of required use in embodiment or the description of the Prior Art below; Obviously, the accompanying drawing in describing below only is some embodiments of the present invention, for those of ordinary skills; Under the prerequisite of not paying creative work property, can also obtain other accompanying drawing according to these accompanying drawings.
Fig. 1 is a kind of first kind of schema that utilizes the method for intermittent energy source brine electrolysis provided by the present invention;
Fig. 2 utilizes the electric energy of the method for intermittent energy source brine electrolysis to handle synoptic diagram for the embodiment of the invention is a kind of;
Fig. 3 is a kind of second kind of schema that utilizes the method for intermittent energy source brine electrolysis of the embodiment of the invention;
Fig. 4 is a kind of the third schema that utilizes the method for intermittent energy source brine electrolysis of the embodiment of the invention;
Fig. 5 is a kind of structural representation that utilizes the device of intermittent energy source brine electrolysis of the embodiment of the invention.
Embodiment
In the prior art, when utilizing intermittent energy source as power supply source water electrolysis hydrogen production/oxygen, after the capable voltage stabilizing of unsettled electric energy, directly supply with electrolyzer and carry out brine electrolysis, the two ends of electrolyzer can produce hydrogen and oxygen respectively.Because the electric energy that intermittent energy source produces has unstable; So when the electric energy that produces hour; Maybe be because too much as the electrolyzer quantity of load; Make electrolyzer be in the more a spot of hydrogen/oxygen of work generation under the very low electric current, electrolyzer is not in the ideal operation state though intermittent energy source is fully used; Perhaps, the electric energy that produces when intermittent energy source has surpassed the required electric energy of fixed qty electrolyzer works better more, and additional electric energy will be wasted so, and this moment, intermittent energy source was not fully utilized, and electrolyzer is not in the ideal operation state.A kind of method of utilizing the intermittent energy source brine electrolysis provided by the present invention to be implemented in the brine electrolysis process, makes full use of intermittent energy source, guarantees that simultaneously electrolyzer is in the purpose of ideal operation state.
At first a kind of method of intermittent energy source brine electrolysis of utilizing provided by the present invention is introduced below, this method comprises:
The electric energy that intermittent energy source produced is carried out voltage stabilizing to be handled;
Detect voltage stabilizing and handle the voltage of back intermittent energy source electric energy, obtain voltage of voltage regulation;
Said voltage of voltage regulation and the required voltage rating of current cell operation are compared, if after said voltage of voltage regulation greater than said voltage rating, then is the identical electrolyzer of said current electrolyzer parallel connection voltage rating, carry out brine electrolysis; If after said voltage of voltage regulation less than said voltage rating, then reduces the quantity of said current electrolyzer, carry out brine electrolysis; If said voltage of voltage regulation in the said range of nominal tension, then utilizes said current electrolyzer to carry out brine electrolysis;
Said voltage rating is the voltage of cell operation in desirable working order.
In the scheme provided by the present invention, when utilizing intermittent energy source to carry out brine electrolysis for the electrolyzer power supply, after the electric energy voltage stabilizing processing that intermittent energy source produced, detect the voltage of intermittent energy source electric energy, determine voltage of voltage regulation as power supply; Judge that then whether said voltage of voltage regulation in the required range of nominal tension, according to judged result, is adjusted current electrolyzer, carries out follow-up brine electrolysis then when the electrolyzer works better.In this programme; According to the fluctuation size of intermittent energy source electric energy voltage of voltage regulation after the voltage stabilizing, confirm the electrolyzer of proper amt, make electrolyzer in the range of nominal tension, work; Make full use of intermittent energy source with this, and guarantee that simultaneously electrolyzer is in the ideal operation state.
To combine the accompanying drawing in the embodiment of the invention below, the technical scheme in the embodiment of the invention is carried out clear, intactly description, obviously, described embodiment only is the present invention's part embodiment, rather than whole embodiment.Based on the embodiment among the present invention, those of ordinary skills are not making the every other embodiment that is obtained under the creative work prerequisite, all belong to the scope of the present invention's protection.
A kind of method of utilizing the intermittent energy source brine electrolysis provided by the present invention, as depicted in figs. 1 and 2, comprising:
S101 carries out voltage stabilizing to the electric energy that intermittent energy source produced and handles;
Because when utilizing intermittent energy source such as sun power, tidal energy, wind energy to generate electricity; The electric energy that is produced has unstable; So, handle so need carry out voltage stabilizing to the electric energy that intermittent energy source produced in order to guarantee in the brine electrolysis process that electrolyzer is worked under stable voltage.The mode that voltage stabilizing is handled can for: electric energy that intermittent energy source produced through stable-pressure device, is handled to carry out voltage stabilizing.The effect of said stable-pressure device: the unstable voltage that intermittent energy source produced is adjusted into rated output voltage.Those skilled in the art it is understandable that said stable-pressure device can adopt potentiostat, but are not limited to potentiostat.
S102 detects the voltage that back intermittent energy source electric energy is handled in voltage stabilizing, obtains voltage of voltage regulation;
In the present embodiment, the electrolyzer that is connected in the current circuit is called current electrolyzer.In the brine electrolysis process, said current electrolyzer is in running order.
Need to prove that current electrolyzer can be for one or more; When current electrolyzer was one, the two ends that directly are parallel to the stable-pressure device that is used for the voltage stabilizing processing got final product; When current electrolyzer is a plurality of, be parallelly connected between the electrolyzer, and parallelly connected with the stable-pressure device that is used for the voltage stabilizing processing.
When the electric energy after voltage stabilizing is handled carries out voltage detecting; Owing to be parallel connection between the current electrolyzer; And be connected in parallel on the stable-pressure device that is used for voltage stabilizing and handles (for example: two ends potentiostat), so detect the voltage that the voltage of electric energy after the voltage stabilizing just detects current electrolyzer two ends.
S103 compares said voltage of voltage regulation and the required voltage rating of current cell operation, if said voltage of voltage regulation greater than said voltage rating, is then carried out S104; If said voltage of voltage regulation less than said voltage rating, is then carried out S105; If said voltage of voltage regulation value in the said range of nominal tension, is carried out S106;
In the brine electrolysis process, when electrolyzer is worked, not only have the life-span that higher electrolytic efficiency can not influence electrolyzer simultaneously in certain voltage range, at this moment, electrolyzer is in the ideal operation state, and this voltage range is the voltage rating of electrolyzer.When WV during greater than the voltage rating of electrolyzer, electrolyzer has higher electrolytic efficiency, but can influence the life-span of electrolyzer; When WV during less than the voltage rating of electrolyzer, the electrolytic efficiency of electrolyzer is relatively low.
Said voltage rating is relevant with the electrolyzer self characteristics.Wherein, have different ionogen, electrode, electrolyser construction, the pairing voltage rating of the electrolyzer of other critical materials or working temperature is different.In order to reach good electrolysis effectiveness, in the present embodiment, said current electrolyzer can be the solid polymer electrolyte electrolyzer.
Need to prove that the voltage of voltage regulation that obtains when detection can show that current electrolyzer has made full use of intermittent energy source during less than the rated output voltage of stable-pressure device.Therefore, in order to confirm that electric energy that intermittent energy source is produced is fully utilized and guarantee that current electrolyzer can work that in the range of nominal tension rated output voltage of said stable-pressure device should be slightly larger than the voltage rating of electrolyzer.Wherein, said rated output voltage exceeds the concrete numerical value of said voltage rating, decides according to practical situation.
After electric energy that intermittent energy source produced is handled through voltage stabilizing, detect the voltage of voltage regulation that obtains and whether be the standard adjusting current electrolyzer of judging whether in the range of nominal tension.This be because:
The voltage of voltage regulation (that is: the WV of electrolyzer) that obtains when detection is in the range of nominal tension time, and current electrolyzer has made full use of intermittent energy source, and the electrolytic efficiency of current electrolyzer is higher, produces more hydrogen/oxygen, is in the ideal operation state;
The voltage of voltage regulation (that is: the WV at electrolyzer two ends) that obtains when detection is when equaling the rated output voltage of stable-pressure device, and this moment, intermittent energy source was not fully utilized, and electrolyzer is not in the ideal operation state simultaneously; It is understandable that; When the output rating of intermittent energy source just equates with the power of electrolyzer, also the rated output voltage that voltage of voltage regulation equals stable-pressure device can appear, and this moment, intermittent energy source was fully utilized; But in practical application, the probability that this situation occurs is minimum.
The voltage of voltage regulation (that is: the WV of electrolyzer) that obtains when detection during less than said rated output voltage, explain that current electrolyzer has made full use of the electric energy that intermittent energy source produces, but current electrolyzer is not in the ideal operation state greater than voltage rating;
The voltage of voltage regulation (that is: the WV of electrolyzer) that obtains when detection is when being slightly less than voltage rating; Current electrolyzer is worked under very little electric current; Though this moment, current electrolyzer can make full use of the electric energy that intermittent energy source produces, electrolyzer is not in the ideal operation state;
The voltage of voltage regulation (that is: the WV of electrolyzer) that obtains when detection is very little the voltage rating relatively, this moment excessive electrolyzer as load, make voltage pole low, cause current electrolyzer to start, intermittent energy source can not be fully used.
For example:
Required voltage rating is U1-U2 when supposing cell operation, and its corresponding rated output is W1-W2; The rated output voltage of the stable-pressure device that utilized of hypothesis is the U3 a little more than U2 simultaneously, and the power that electrolyzer is corresponding under said rated output voltage is W3 and W3＞W2; Set n above-mentioned electrolyzer parallel connection:
When (1) voltage after detecting the intermittent energy source voltage stabilizing was U3, the operating power W of current electrolyzer equaled nW3, and at this moment, intermittent energy source is not fully utilized, and current electrolyzer is not in the ideal operation state;
When (2) voltage after detecting the intermittent energy source voltage stabilizing was U2-U3, the operating power W of current electrolyzer was: nW2＜W＜nW3, and at this moment, intermittent energy source is fully used, but current electrolyzer is not in the ideal operation state;
When (3) voltage after detecting the intermittent energy source voltage stabilizing was U1-U2, the operating power W of current electrolyzer was: nW1＜W＜nW2, and at this moment, intermittent energy source is fully used, and current electrolyzer is in the ideal operation state;
When (4) voltage after detecting the intermittent energy source voltage stabilizing is slightly less than U1; Current electrolyzer is worked under less current, at this moment, and the electric energy that too much electrolyzer utilizes intermittent energy source to produce; Intermittent energy source is fully used, but electrolyzer is not in the ideal operation state;
When (5) voltage after detecting the intermittent energy source voltage stabilizing was very little with respect to U1, caused intermittent energy source can not be utilized because the electrolyzer of excessive number can't start this moment.
From the above, through detecting the fluctuation size of voltage of voltage regulation, can determine whether electric energy that intermittent energy source produces is fully utilized and electrolyzer whether under desirable working order.So in order to guarantee that intermittent energy source makes full use of and electrolyzer is in the ideal operation state, the voltage of voltage regulation that obtains when detection is carried out S104 during greater than said voltage rating, current electrolyzer is carried out step-down handle; The voltage of voltage regulation that obtains when detection is carried out S105 during less than said voltage rating, to the electrolyzer processing of boosting; And when detecting the voltage of voltage regulation obtain in the range of nominal tension time, needn't boost or step-down, directly carry out S106.
S104 behind the identical electrolyzer of said current electrolyzer parallel connection voltage rating, carries out brine electrolysis;
When said voltage of voltage regulation equaled the rated output voltage of said stable-pressure device, the intermittence energy was underutilized, and current electrolyzer is not in the ideal operation state; And but when said voltage of voltage regulation during greater than said voltage rating less than the rated output voltage of stable-pressure device, though the electric energy that intermittent energy source produced is fully used, current electrolyzer is not in the ideal operation state.
For above-mentioned two kinds of situation; Make current electrolyzer in desirable working order when guaranteeing to make full use of intermittent energy source; Can be through carrying out step-down for the mode of the subsequent use electrolyzer of current electrolyzer parallel connection; Make current electrolyzer in voltage rating work, so not only can make full use of intermittent energy source, guarantee that simultaneously current electrolyzer is in the ideal operation state.
Need to prove, in the brine electrolysis process, need preset a plurality of voltage ratings subsequent use electrolyzer identical with current electrolyzer voltage rating.In the time need carrying out step-down, then select electrolyzer suitable in the subsequent use electrolyzer to carry out parallel connection through the mode of parallelly connected electrolyzer.
It is understandable that the rated output of subsequent use electrolyzer is different with the rated output of current electrolyzer or identical.For example: suppose that current electrolyzer comprises 1 electrolyzer WA; 1 electrolyzer 2WA, 1 electrolyzer 5WA, the voltage rating of three electrolyzers is U1-U2; The rated output of electrolyzer WA is W1-W2; The rated output of electrolyzer 2WA is 2W1-2W2, and the rated output of electrolyzer 5WA is 5W1-5W2, and the rated output of default subsequent use electrolyzer can be K (K=1,2,5,10,20,50,100......) times of electrolyzer WA.Be fully used in order to guarantee the electric energy that intermittent energy source produces; Wherein the peak of K is provided with according to the peak power of the output of intermittent energy source size, makes the peak power of the peak power sum of all electrolyzers under voltage rating greater than intermittent energy source output.
In the present embodiment, the identical electrolyzer of said current electrolyzer parallel connection voltage rating, as shown in Figure 3, can be specially:
S104a, the subsequent use electrolyzer that will have maximum rated power carries out parallelly connected with current electrolyzer;
S104b, the voltage of the intermittent energy source electric energy after the detection voltage stabilizing is handled obtains reference voltage;
S104c compares said reference voltage and said voltage rating, if said reference voltage greater than said voltage rating, is then carried out S104a; If said reference voltage less than said voltage rating, is then carried out S104d; If said reference voltage in the said range of nominal tension, is then carried out S104e;
S104d breaks off the subsequent use electrolyzer of current parallel connection, and will less than subsequent use electrolyzer in the subsequent use electrolyzer of its rated output and current electrolyzer with maximum rated power carry out parallelly connected after, carry out S104b;
S104e, parallelly connected processing finishes.
In the above-mentioned parallel way in the present embodiment, carry out parallelly connected with current electrolyzer successively from big to small according to subsequent use electrolyzer rated output.The reference voltage (that is: the voltage at electrolyzer two ends) that obtains when detection is during still greater than said voltage rating; Then can continue to carry out parallelly connected with current electrolyzer the subsequent use electrolyzer of remaining maximum rated power; Continue to judge then and detect the reference voltage that obtains and the magnitude relationship of said voltage rating this moment, repeat corresponding processing according to magnitude relationship; The reference voltage that obtains when detection is less than said voltage rating; Then can break off the subsequent use electrolyzer parallelly connected with current electrolyzer; Reselecting other subsequent use electrolyzers carries out parallelly connected with current electrolyzer; When reselecting, still select according to subsequent use electrolyzer rated output order from big to small.
Need to prove; When the subsequent use electrolyzer of a certain rated output with after current electrolyzer is parallelly connected; The reference voltage that detection obtains is less than said voltage rating, and then when reselecting subsequent use electrolyzer, other subsequent use electrolyzers identical with the subsequent use electrolyzer rated output of said parallel connection are not in range of choice; But select the maximum electrolyzer of rated output outside the identical subsequent use electrolyzer of said a plurality of rated output to carry out parallel connection, carry out follow-up detection, judgement then.
S105, reduce the quantity of said current electrolyzer after, carry out brine electrolysis;
When said voltage of voltage regulation is slightly less than the voltage rating of current electrolyzer, flow down work in small electric, though intermittent energy source is fully used, current electrolyzer is not in the ideal operation state; And when said voltage of voltage regulation with respect to the voltage rating of current electrolyzer hour, too much electrolyzer makes that the voltage pole at electrolyzer two ends is low, makes current electrolyzer to start, intermittent energy source can't obtain utilizing.
For above-mentioned two kinds of situation; Current electrolyzer is in desirable working order when guaranteeing to make full use of intermittent energy source; The mode of quantity that can be through reducing current electrolyzer is boosted; Make electrolyzer in voltage rating work, so not only can make full use of current electrolyzer of intermittent energy source while and be in the ideal operation state.
In the present embodiment, the quantity of the said current electrolyzer of said minimizing, as shown in Figure 4, can be specially:
S105a breaks off the electrolyzer that has maximum rated power in the said current electrolyzer;
S105b, the voltage of the intermittent energy source electric energy after the detection voltage stabilizing is handled obtains reference voltage;
S105c compares said reference voltage and said voltage rating, if said reference voltage less than said voltage rating, is then carried out S105a; If said reference voltage greater than said voltage rating, is then carried out S105d, if said reference voltage in the said range of nominal tension, is then carried out S105e;
S105d, the electrolyzer of parallelly connected current disconnection, and disconnection is again carried out S105b less than the electrolyzer with maximum rated power in the current electrolyzer of its rated output;
S105e breaks off processing and finishes.
In reducing the process of current electrolyzer quantity, according to rated output order from big to small in the current electrolyzer, break off electrolyzer and carry out judgment processing, after breaking off electrolyzer, detect the reference voltage that obtains in the range of nominal tension till.
S106 utilizes said current electrolyzer to carry out brine electrolysis.
When said voltage of voltage regulation is in the said range of nominal tension, directly utilizes the electrolyzer of current existence to carry out water electrolysis hydrogen production/oxygen and get final product.
In the scheme provided by the present invention, when utilizing intermittent energy source to carry out brine electrolysis for the electrolyzer power supply, after the electric energy voltage stabilizing processing that intermittent energy source produced, detect the voltage of intermittent energy source electric energy, determine voltage of voltage regulation as power supply; Judge that then whether said voltage of voltage regulation in the required range of nominal tension, according to judged result, is adjusted current electrolyzer, carries out follow-up brine electrolysis then when the electrolyzer works better.In this programme; According to the fluctuation size of intermittent energy source electric energy voltage of voltage regulation after the voltage stabilizing, confirm the electrolyzer of proper amt, make electrolyzer in the range of nominal tension, work; Make full use of intermittent energy source with this, and guarantee that simultaneously electrolyzer is in the ideal operation state.
Description through above method embodiment; The those skilled in the art can be well understood to the present invention and can realize by the mode that software adds essential general hardware platform; Can certainly pass through hardware, but the former is better embodiment under a lot of situation.Based on such understanding; The part that technical scheme of the present invention contributes to prior art in essence in other words can be come out with the embodied of software product; This computer software product is stored in the storage media; Comprise some instructions with so that computer equipment (can be Personal Computer, server, the perhaps network equipment etc.) carry out all or part of step of the said method of each embodiment of the present invention.And aforesaid storage media comprises: various media that can be program code stored such as ROS (ROM), random-access memory (ram), magnetic disc or CD.
Corresponding to top method embodiment, the embodiment of the invention also provides a kind of device that utilizes the intermittent energy source brine electrolysis, and is as shown in Figure 5, can comprise:
Said step-down module 140 is used to the identical electrolyzer of said current electrolyzer parallel connection voltage rating;
Said boost module 150 is used to reduce the quantity of said current electrolyzer;
Said brine electrolysis module 160 is used to utilize said current electrolyzer to carry out brine electrolysis.
Wherein, said step-down module 140 comprises:
The parallel connection unit is used for the subsequent use electrolyzer with maximum rated power and current electrolyzer are carried out parallelly connected, and the current voltage of voltage regulation that 120 detections of said voltage detection module obtain is confirmed as reference voltage;
First comparing unit is used for said reference voltage and said voltage rating are compared, and under the situation of said reference voltage greater than said voltage rating, triggers said parallelly connected unit; Under the situation of said reference voltage, trigger first processing unit less than said voltage rating; When said reference voltage is in the said range of nominal tension, trigger brine electrolysis module 160;
Said first processing unit; Be used to break off the electrolyzer of current parallel connection; And will less than subsequent use electrolyzer in the subsequent use electrolyzer of its rated output and current electrolyzer with maximum rated power carry out parallelly connected after; Said voltage detection module 120 is detected the current voltage of voltage regulation that obtains confirm as reference voltage, trigger first comparing unit.
Wherein, said boost module 150 comprises:
Switching units is used for breaking off said current electrolyzer and has the maximum rated power electrolyzer, and said voltage detection module 120 is detected the current voltage of voltage regulation that obtains confirm as reference voltage;
Second comparing unit is used for said reference voltage and said voltage rating are compared, and under the situation of said reference voltage less than said voltage rating, triggers switching units; Under the situation of said reference voltage, trigger second processing unit greater than said voltage rating; When said reference voltage is in the said range of nominal tension, trigger brine electrolysis module 160;
Said second processing unit; The electrolyzer that is used for parallelly connected current disconnection again; And break off less than behind the electrolyzer in the current electrolyzer of its rated output with maximum rated power; Said voltage detection module 120 is detected the current voltage of voltage regulation that obtains confirm as reference voltage, trigger second comparing unit.
For device or system embodiment, because it is basically corresponding to method embodiment, so relevant part gets final product referring to the part explanation of method embodiment.Device described above or system embodiment only are schematic; Wherein said unit as the separating component explanation can or can not be physically to separate also; The parts that show as the unit can be or can not be physical locations also; Promptly can be positioned at a place, perhaps also can be distributed on a plurality of NEs.Can realize the purpose of present embodiment scheme according to the needs selection some or all of module wherein of reality.Those of ordinary skills promptly can understand and implement under the situation of not paying creative work.
In several embodiment provided by the present invention, should be understood that, the system that is disclosed, apparatus and method not surpassing in the application's the spirit and scope, can realize through other mode.Current embodiment is a kind of exemplary example, should be as restriction, and given particular content should in no way limit the application's purpose.For example, the division of said unit or subelement only is that a kind of logic function is divided, and during actual the realization other dividing mode can be arranged, and for example a plurality of unit or a plurality of subelement combine.In addition, a plurality of unit can or assembly can combine or can be integrated into another system, or some characteristics can ignore, or do not carry out.
In addition, institute's descriptive system, the synoptic diagram of apparatus and method and different embodiment, in the scope that does not exceed the application, can with other system, module, technology or method combine or are integrated.Another point, the coupling each other that shows or discuss or directly coupling or communication to connect can be through some interfaces, device or unitary indirect coupling or communication connect, and can be electrically, machinery or other form.The above only is an embodiment of the present invention; Should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the principle of the invention; Can also make some improvement and retouching, these improvement and retouching also should be regarded as protection scope of the present invention.
Claims (7)
1. a method of utilizing the intermittent energy source brine electrolysis is characterized in that, comprising:
The electric energy that intermittent energy source produced is carried out voltage stabilizing to be handled;
Detect voltage stabilizing and handle the voltage of back intermittent energy source electric energy, obtain voltage of voltage regulation;
Said voltage of voltage regulation and the required voltage rating of current cell operation are compared, if after said voltage of voltage regulation greater than said voltage rating, then is the identical electrolyzer of said current electrolyzer parallel connection voltage rating, carry out brine electrolysis; If after said voltage of voltage regulation less than said voltage rating, then reduces the quantity of said current electrolyzer, carry out brine electrolysis; If said voltage of voltage regulation in the said range of nominal tension, then utilizes said current electrolyzer to carry out brine electrolysis;
Said voltage rating is the voltage of cell operation in desirable working order.
2. method according to claim 1 is characterized in that, is the identical electrolyzer of said current electrolyzer parallel connection voltage rating, is specially:
A, the subsequent use electrolyzer that will have maximum rated power carries out parallelly connected with current electrolyzer;
B, the voltage of the intermittent energy source electric energy after the detection voltage stabilizing is handled obtains reference voltage;
C compares said reference voltage and said voltage rating, if said reference voltage greater than said voltage rating, is then carried out A; If said reference voltage, then breaks off the subsequent use electrolyzer of current parallel connection less than said voltage rating, and will less than subsequent use electrolyzer in the subsequent use electrolyzer of its rated output and current electrolyzer with maximum rated power carry out parallelly connected after, carry out B; If said reference voltage is in the said range of nominal tension, then parallelly connected processing finishes.
3. method according to claim 1 and 2 is characterized in that, the quantity of the said current electrolyzer of said minimizing is specially:
A breaks off the electrolyzer that has maximum rated power in the said current electrolyzer;
B, the magnitude of voltage of the intermittent energy source electric energy after the detection voltage stabilizing is handled obtains reference voltage;
C compares said reference voltage and said voltage rating, if said reference voltage less than said voltage rating, is then carried out A; If said reference voltage is greater than said voltage rating; The electrolyzer of parallelly connected current disconnection again then; And break off less than behind the electrolyzer in the current electrolyzer of its rated output with maximum rated power; Carry out B, finish if said reference voltage in the said range of nominal tension, then breaks off processing.
4. method according to claim 1 is characterized in that, said current electrolyzer is the solid polymer electrolyte electrolyzer.
5. a device that utilizes the intermittent energy source brine electrolysis is characterized in that, comprising:
Voltage stabilizing module, the electric energy that is used for that intermittent energy source is produced carry out voltage stabilizing to be handled;
Voltage detection module is used to detect the voltage of the intermittent energy source electric energy after said Voltage stabilizing module is handled, and obtains voltage of voltage regulation;
Comparison module is used for said voltage of voltage regulation and the required voltage rating of current cell operation are compared, and under the situation of said voltage of voltage regulation greater than said voltage rating, triggers the step-down module; Under the situation of said voltage of voltage regulation, trigger boost module less than said voltage rating; Under the situation of said voltage of voltage regulation in the said range of nominal tension, trigger the brine electrolysis module;
Said step-down module, be used to the identical electrolyzer of said current electrolyzer parallel connection voltage rating after, trigger said brine electrolysis module;
Said boost module after being used to reduce the quantity of said current electrolyzer, triggers said brine electrolysis module;
Said brine electrolysis module is used to utilize said current electrolyzer to carry out brine electrolysis.
6. device according to claim 5 is characterized in that, said step-down module comprises:
The parallel connection unit is used for the subsequent use electrolyzer with maximum rated power and current electrolyzer are carried out parallelly connected, and the current voltage of voltage regulation that the detection of said voltage detection module obtains is confirmed as reference voltage;
First comparing unit is used for said reference voltage and said voltage rating are compared, and under the situation of said reference voltage greater than said voltage rating, triggers said parallelly connected unit; Under the situation of said reference voltage, trigger first processing unit less than said voltage rating; Under the situation of said reference voltage in the said range of nominal tension, trigger the brine electrolysis module;
Said first processing unit; Be used to break off the electrolyzer of current parallel connection; And will less than subsequent use electrolyzer in the subsequent use electrolyzer of its rated output and current electrolyzer with maximum rated power carry out parallelly connected after; Said voltage detection module is detected the current voltage of voltage regulation that obtains confirm as reference voltage, trigger first comparing unit.
7. according to claim 5 or 6 described devices, it is characterized in that said boost module comprises:
Switching units is used for breaking off said current electrolyzer and has the maximum rated power electrolyzer, and said voltage detection module is detected the current voltage of voltage regulation that obtains confirm as reference voltage;
Second comparing unit is used for said reference voltage and said voltage rating are compared, and under the situation of said reference voltage less than said voltage rating, triggers switching units; Under the situation of said reference voltage, trigger second processing unit greater than said voltage rating; Under the situation of said reference voltage in the said range of nominal tension, trigger the brine electrolysis module;
Said second processing unit; The electrolyzer that is used for parallelly connected current disconnection again; And break off less than behind the electrolyzer in the current electrolyzer of its rated output with maximum rated power; Said voltage detection module is detected the current voltage of voltage regulation that obtains confirm as reference voltage, trigger second comparing unit.
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| CN1156125A (en) * | 1995-12-27 | 1997-08-06 | 日本恩迪克股份有限公司 | Device for producing electrolytic water |
| CN1530332A (en) * | 2003-03-11 | 2004-09-22 | 悦 郑 | Negative cost sea water desalination of wind-energy source or marine energy |
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