CN102719697A - Special alloy with function of paraffin inhibition and application thereof - Google Patents

Special alloy with function of paraffin inhibition and application thereof Download PDF

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Publication number
CN102719697A
CN102719697A CN2011100793476A CN201110079347A CN102719697A CN 102719697 A CN102719697 A CN 102719697A CN 2011100793476 A CN2011100793476 A CN 2011100793476A CN 201110079347 A CN201110079347 A CN 201110079347A CN 102719697 A CN102719697 A CN 102719697A
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China
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special alloy
alloy
wax
wax control
crude oil
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CN2011100793476A
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CN102719697B (en
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吕曼棋
张海峰
胡壮麒
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NAIR ENERGY EQUIPMENT Co Ltd
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Institute of Metal Research of CAS
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  • Manufacture And Refinement Of Metals (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

A special alloy with a function of paraffin inhibition is characterized in that the special alloy contains the following elements of: by weight, 65-95% of Cu, 3-30% of Ni, 1.0-5.0% of Co and 0.1-0.5% of RE, wherein RE is rare earth element. With the application of the special alloy in crude oil production wax inhibitor/removal technology, crude oil production efficiency is not only raised, but pollution caused by hot washing/chemistry-flushing well is also avoided. Therefore, the special alloy has obvious social and economic values. The paraffin inhibition special alloy is a novel functional material and has a good subject research value and a development prospect for the research on interaction effect of a metal material and a liquid and the development of a novel functional material by its electrocatalysis effect of crude oil composition and a special function of changing wax deposition agglomeration behavior.

Description

A kind of special alloy and application thereof with wax control function
Technical field
The present invention relates to metal material field, a kind of special alloy and application thereof with wax control function is provided especially.
Background technology
Generally all contain wax in the crude oil, there is the very high oil field of many wax contents in China.When oil producing operation; Crude oil constantly reduces owing to temperature from the process of subsurface to surface; Wax in the crude oil can be separated out after temperature reaches wax precipitation piont (generally about 40 ℃) and on sucker rod and tube wall, condensed, and the operation that finally causes pumping stops, and must remove the wax that solidifies through " well-flushing " and could continue oil pumping; Therefore, clear wax control becomes the important technical links of crude production.The most frequently used method of well-flushing is that heat is washed or paraffin removing with chemical method; Above method is no doubt effective, but just can restart the operation of pumping after must stopping oil producing operation and experiencing the drainage period of a couple of days, and the discharging of a large amount of chemical substances is arranged simultaneously; Had a strong impact on crude production efficient, and contaminate environment.In the ground system (oil pipeline and crude Treatment system) of crude production, also there is same clear wax control problem.
Summary of the invention
The object of the present invention is to provide a kind of separating out and the novel wax control alloy and the application thereof of the function of reuniting of wax in the crude oil for inhibiting that have; This alloy has special electrochemical activity; Effective the separating out, precipitate and reunite of wax in the crude oil for inhibiting, the wax control that can be used for the down-hole, oil field is handled.
A kind of special alloy provided by the invention with wax control function; It is characterized in that: described special alloy includes following component (weight percent wt%): Cu 65~95, and Ni 3~30, and Co 1.0~5.0; RE 0.1~0.5; Wherein, RE is a REE, and described REE is specially one of La, Ce, Pr, Nd, Gd or its combination.As preference, can also contain following component one or more (weight percent wt%) in the described special alloy: Ti 0.2~0.5, and B 0.03~0.10.
Special alloy with wax control function provided by the invention; Its concrete preparation method is following: adopt vacuum induction furnace melting under normal pressure, vacuum or Ar atmosphere protection; Adopt normal pressure or vacuum pouring, ingot mould fully is preheated to proper temperature has uniform macrostructure and microtexture to guarantee alloy; Then through forging, processing a material after rolling, the wire drawing; Or after mother alloy is processed in melting, to adopt the powder by atomization technology to process granularity be micron-sized alloy powder.
Special alloy with wax control function provided by the invention is when using; Alloy wire is used flame plating; Alloy powder is with plasma body or other spraying technology; Alloy powder is sprayed on the steel of making wax control instrument or the surface of other metallic substance, forms highly active surperficial wax control alloy layer, 0.1~30 micron of thickness.
Wax control alloy of the present invention is the electronegativity difference that utilizes paraffin in alloy and the crude oil; Make alloy in alloy-crude system, have the static catalytic activity, can change the electrostatic potential and the polarity of paraffin molecule from the crude oil that its surface current is crossed, make the wax of separating out in the crude oil be in the dispersive suspended state; Avoid wax to condense in the bulk of pipeline and wall; Wax is flowed out with crude oil liquid, reach the purpose of wax control, be applicable to all kinds of oil wells and ground, oil field crude oil transportation systems such as well on the beam, unloading well.
Special alloy with wax control function provided by the invention; Be to change the wax electronic structure of molecule and then change the brilliant reunion behavior of wax through electrochemical action; Effectively suppress and slow down the piece that condenses into of wax, impel the wax of separating out to float on a liquid and with liquid-flow, therefore with small crystal habit; Effectively prevent and delay wax condensing on tube wall, sucker rod, thereby prolong the clean-out service cycle of oil well.The wax control alloy except that improving crude production efficient, has also been avoided the pollution that hot washing/chemical well-flushing causes as the clear wax control The application of new technique of a kind of crude production, has tangible society and economic worth; The wax control special alloy is a kind of new function material; It is to the specific function of electrochemical catalysis effect with the deposition reunion behavior that changes wax of oil component; Interaction and development new function material to research metallic substance and liquid have good subject researching value and development prospect.
Special alloy with wax control function provided by the invention also has following advantage:
(1) wax control: after crude oil and the special alloy effect, the precipitation rate of the wax in the crude oil when temperature reduces significantly reduces, and the amount of separating out that is observed visually obviously reduces;
(2) improve crude production efficient: compare with using paraffin removal and control method machinery or physics, use the wax control special alloy to be used for oil well paraffin prevention, the snaking cycle can significantly be prolonged, significantly reduce the time of the operation that stops to pump;
(3) environmental protection: compare with common chemical paraffin removal method, oil well uses wax control alloy wax control, has avoided emission of harmful substances;
(4) inexpensive: the wax control alloy only plays katalysis, can life-time service.
Embodiment
Embodiment 1
A kind of special alloy with wax control function, the composition of alloy (weight percent wt%) as shown in the table:
Cu Ni Co Gd
88.0 10.5 1.0 0.5
Concrete preparation method is following: adopt vacuum induction furnace melting under normal pressure, adopt the normal pressure cast, through forging, process after rolling, the wire drawing material of φ 2; Process the wax control instrument with stainless steel, the wax control instrument is combined by porous inner cylinder and atresia urceolus, with flame plating spray coating alloy at the internal surface of inner core and the internal surface of outside surface and urceolus, 22 microns of thickness.Crude oil sprays entering urceolus entering oil pumping pipeline after flowing into inner core, and crude oil and alloy surface layer fully act on during this period.
1100 meters of oil well depths, 5.8 tons/day of oilwell produced fluid amounts, 2.3 tons/day of oil offtake; Water ratio 60%, wax content 14.5%, former employing hot-washing wax remover; Hot washing period 35 days, period of removing the wax extends to 274 days behind down-hole, the oil field wax control instrument that employing wax control alloy is processed, and wax control result is remarkable.
Embodiment 2
A kind of special alloy with wax control function, the composition of alloy (weight percent wt%) as shown in the table:
Cu Ni Co Ti Pr+Nd B
71.0 25.4 2.8 0.3 0.4 0.1
Concrete preparation method is following: adopt vacuum induction furnace melting under vacuum, adopt vacuum pouring, through forging, process after rolling, the wire drawing material of φ 2; Process the wax control instrument with stainless steel, the wax control instrument is combined by porous inner cylinder and atresia urceolus, with flame plating spray coating alloy at the internal surface of inner core and the internal surface of outside surface and urceolus, 16 microns of thickness.Crude oil sprays entering urceolus entering oil pumping pipeline after flowing into inner core, and crude oil and alloy surface layer fully act on during this period.
About 1500 meters of oil well depth, 7.8 tons/day of oilwell produced fluid amounts, 1.7 tons/day of produce oils; Water ratio 78%, wax content 21.1%, former employing hot-washing wax remover; Hot washing period 35 days, period of removing the wax extends to 234 days behind down-hole, the oil field wax control instrument that employing wax control alloy is processed, and wax control result is remarkable.
Embodiment 3
A kind of special alloy with wax control function, the composition of alloy (weight percent wt%) as shown in the table:
Cu Ni Co Ti La+Ce
91.0 7.0 1.1 0.4 0.5
Concrete preparation method is following: adopt vacuum induction furnace melting under the Ar gas shiled, adopt the normal pressure cast, become mother alloy after the pulverizing.Process the micron order alloy powder with atomising unit.Process the wax control instrument with stainless steel, the wax control instrument is combined by porous inner cylinder and atresia urceolus, is sprayed on the internal surface of inner core and the internal surface of outside surface and urceolus, 19 microns of thickness to alloy powder with plasma spraying.Crude oil sprays entering urceolus entering oil pumping pipeline after flowing into inner core, and crude oil and alloy surface layer fully act on during this period.
1100 meters of oil well depths, 5.8 tons/day of oilwell produced fluid amounts, 2.3 tons/day of oil offtake, water ratio 60%, wax content 14.5%, former employing hot-washing wax remover, hot washing period 35 days, period of removing the wax extends to 274 days behind the employing alloy tool, and wax control result is remarkable.

Claims (6)

1. special alloy with wax control function, it is characterized in that: described special alloy includes following component (weight percent wt%): Cu 65~95, and Ni 3~30, and Co 1.0~5.0, and RE 0.1~0.5, and wherein, RE is a REE.
2. according to the described special alloy with wax control function of claim 1, it is characterized in that: described REE is one of La, Ce, Pr, Nd, Gd or its combination.
3. according to the described special alloy with wax control function of claim 1, it is characterized in that: one or more (weight percent wt%) that also contain following component in the described special alloy: Ti 0.2~0.5, and B 0.03~0.10.
4. according to the described special alloy of one of claim 1~3, it is characterized in that: special alloy is sprayed on the material surface of making the wax control instrument with plasma body or spraying technology, forms highly active surperficial wax control alloy layer with wax control function.
5. according to the described application with special alloy of wax control function of claim 4, it is characterized in that: described surperficial wax control alloy layer thickness is 0.1~30 micron.
6. one kind according to the described special alloy with wax control function of one of claim 1~3, and it is characterized in that: described special alloy is used for well on the beam, all kinds of oil wells of unloading well and ground, oil field crude oil transportation system.
CN2011100793476A 2011-03-31 2011-03-31 Special alloy with function of paraffin inhibition and application thereof Active CN102719697B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103775027A (en) * 2014-02-21 2014-05-07 江苏耐尔冶电集团有限公司 Pipeline type special metastable alloy anti-scale and anti-paraffin tool
CN111593228A (en) * 2020-05-25 2020-08-28 有研工程技术研究院有限公司 Champagne golden copper alloy material and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101126307A (en) * 2007-09-28 2008-02-20 王新虎 Wax-proof anti-scaling equipment and mating oil pipe short section
CN102676866A (en) * 2011-03-16 2012-09-19 中国科学院金属研究所 Special alloy for diesel engine on saving oil and reducing emission and application of special alloy

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101126307A (en) * 2007-09-28 2008-02-20 王新虎 Wax-proof anti-scaling equipment and mating oil pipe short section
CN102676866A (en) * 2011-03-16 2012-09-19 中国科学院金属研究所 Special alloy for diesel engine on saving oil and reducing emission and application of special alloy

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
高运宗等: "活泼金属合金棒快速清防蜡工艺技术研究", 《油气井测试》 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103775027A (en) * 2014-02-21 2014-05-07 江苏耐尔冶电集团有限公司 Pipeline type special metastable alloy anti-scale and anti-paraffin tool
CN103775027B (en) * 2014-02-21 2016-03-16 江苏耐尔冶电集团有限公司 A kind of pipeline type extraordinary metastable alloy antiscale wax control instrument
CN111593228A (en) * 2020-05-25 2020-08-28 有研工程技术研究院有限公司 Champagne golden copper alloy material and preparation method thereof
CN111593228B (en) * 2020-05-25 2021-09-03 有研工程技术研究院有限公司 Champagne golden copper alloy material and preparation method thereof

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