Summary of the invention
For solving the problems of the technologies described above, the present invention proposes a kind of abrasion-resistant metal, drag reduction and the face of damage renovation agent, the wearing and tearing of can reducing friction have damage face repairing effect, improve the service precision and the safety of equipment, prolong service life of equipment, reduce maintenance cost.
The present invention provides the preparation method of above-mentioned abrasion-resistant metal, drag reduction and the face of damage renovation agent simultaneously.
Abrasion-resistant metal of the present invention, drag reduction and the face of damage renovation agent are processed by the raw material of following mass percent: 2 ~ 40% wear-resistant reparation powder, 45 ~ 95% lubricating oil and 3 ~ 20% atactic polyether.
Wherein:
Said wear-resistant reparation powder is made up of the raw material of following mass percent: organic-molybdenum 5 ~ 35%, lanthanum trifluoride 20 ~ 60%, nickel powder 2 ~ 28%, silicon dioxide powder 5 ~ 30% and boron nitride powder 3 ~ 15%.
Said atactic polyether is the condensed alcohols atactic polyether.
Also be added with hexa-atomic compound emulsifying agent, said hexa-atomic compound emulsifying agent accounts for 6 ~ 15% of wear-resistant reparation powder, lubricating oil and atactic polyether total mass.Hexa-atomic compound emulsifying agent has the good emulsifying performance, has solved the layering and the unsteady state of lubricating oil and wear-resistant reparation powder, and not with lubricating oil carrier generation chemical reaction, do not increase oil body, do not change other index of lubricating oil.
Said hexa-atomic compound emulsifying agent is made up of the raw material of following mass percent: nonyl polyoxyethylenated alcohol 3 ~ 40%, ethoxylated dodecyl alcohol 2 ~ 32%, ethoxylated dodecyl alcohol SULPHOSUCCINIC ACID ESTER 5 ~ 60%, Tween-60 7 ~ 20%, sodium hydrogencarbonate 10 ~ 35% and sodium hydroxide 10 ~ 35%.
The preparation method may further comprise the steps:
1) will meet the lubricating oil of ratio, wear-resistant reparation powder, atactic polyether is added to mix and mixes in transferring jar;
2) mixture that step 1) is obtained changes discharging after the grinding machine for grinding over to;
3) prepare hexa-atomic compound emulsifying agent, nonyl polyoxyethylenated alcohol, ethoxylated dodecyl alcohol, ethoxylated dodecyl alcohol SULPHOSUCCINIC ACID ESTER, Tween-60, sodium hydrogencarbonate and the sodium hydroxide that will meet ratio mix, and obtain hexa-atomic compound emulsifying agent;
The hexa-atomic compound emulsifying agent that 4) will meet ratio adds step 2) in the material that obtains, stir.
Wherein:
Mixing temperature is 50 ~ 60 ℃ in the step 1).
Step 2) milling time is 36 ~ 48 hours.
Controlled temperature is 60 ~ 80 ℃ in the step 3).
Performance of products index of the present invention:
Project |
Index |
Outward appearance |
The brownish black thick liquid |
PH value |
6—8 |
Zero pour |
≥-15 |
Flash-point |
≥180 |
Solid content |
≥10% |
The frictional coefficient reduced rate |
≥30% |
Size range |
≤1μm |
Stability |
>;=12 months |
Abrasion-resistant metal of the present invention, drag reduction and the face of damage renovation agent principle are:
The wear surface of friction pair precision " regeneration " phenomenon is based upon that betiding under the certain condition connects touches physics---the chemical process of a kind of uniqueness of friction area.And " friction surface regeneration techniques " its essence is: in the operational process of mechanical means, produce contact load between the friction pair.Under the sh effect, can produce unnecessary energy, what this unnecessary energy brought usually is the wearing and tearing of surface of friction pair.But this metal is wear-resisting when adding, behind drag reduction and the face of the damage renovation agent, just can set up in the sh zone so a kind ofly to utilize the new face of excess energy construction, rather than destroy the energy evolution pattern of old upper layer.With a friction surface is example, and surface of friction pair has than severe marking, and the atoms metal above it has uncompensated pair of key and connects.These atoms are easy to " being caught ", " becoming flexible " and from matrix, " are torn ".With the disengaging of surface atom, the degree of wear-out failure is constantly aggravated.Under the sh effect, isolated possibly no longer be several atoms, but catastrophic wearing and tearing have so just taken place in a monoblock atom group.In the operation process of equipment, seem such wear pattern and belong to normal wear, be summed up as normal circumstances following equipment life.And when abrasion-resistant metal, drag reduction and the face of damage renovation agent existed, it is different fully that situation just becomes, and the frictional energy that abrasion-resistant metal, drag reduction and the face of damage renovation agent utilize the friction pair motion to produce obtains new sintering metal in the metallic surface and repairs aspect.
At first, the friction surface regenerative process is from the beginning of overburden zone, and promptly the bigger zone of wearing and tearing because these zones have possessed regenerative process requisite excess energy takes place, and itself also has the more freedom key the atoms metal here.These free linkages are just as magnetic patch.Can directly catch the damage face renovation agent that is used to build cermet coating, and it firmly is fixed on the abrading section.Under the effect of load, constantly elongation growth is built new lattice.Like this, on original metal base, just formed new upper layer.Originally had the place of cut will generate the sintering metal patch, the abnormal activity source will disappear.After above-mentioned energy process is stable, the process of growth of resist also will stop automatically.
This product has the function of three aspects: the one, and the antifriction technology, i.e. minimizing or control cause the condition of wearing and tearing, for example use the lubricant of various functions; The 2nd, wear-resistant technology promptly improves the wear resisting property of surface of friction pair, like surface alloying, phosphatization, boronation processing etc.; The 3rd, damage face recovery technique is even apparatus diminishes the material of face repairing effect.
Compared with prior art, beneficial effect of the present invention is specific as follows:
1, the outstanding effect that has fuel-economizing, economize on electricity.The effect of abrasion-resistant metal, drag reduction and the face of damage renovation agent is through being carrier with lubricating oil, and this renovation agent is brought to friction surface, utilizes fricative energy, has formed the sintering metal reparation aspect of 3-12um on the pair of friction components surface.This repair layer hardness is high, and surface smoothness is high, and the metal denatured layer of 1-2um is arranged between the virgin metal basic unit, and is firm with the virgin metal underlying structure.Because of the reparation aspect is a cermet coating, has the ability of antiacid caustic corrosion; Because of repairing aspect high firmness and best bright finish, so have the effect that reduces frictional resistance, coefficient of friction generally between 0.06-0.03, has the outstanding effect of fuel-economizing, economize on electricity.
2, abrasion-resistant metal, drag reduction and the face of damage renovation agent not with lubricating oil generation chemical reaction, do not increase oil body, do not change other index of lubricating oil.And reduction engine exhaust emission index.
3, the prolonged mechanical ME cycle, improve the equipment running precision, reduction equipment operation noise.
4, easy to use, need not the maintenance that stops production.Abrasion-resistant metal, drag reduction and the face of damage renovation agent are added into lubricating oil with it under the situation that equipment does not disintegrate.Through equipment operation it is loaded onto friction surface, thereby realizes reparation equipment.
5, use validity period long.In a drain period of equipment regulation, need not replenish.Equipment can remain on comparatively ideal running condition.
6, abrasion-resistant metal, drag reduction and the face of damage renovation agent have good operability because the adding of hexa-atomic compound emulsifying agent can well mix with lubricated oil phase.
Embodiment
Specify the present invention below in conjunction with embodiment.
Embodiment 1
A kind of abrasion-resistant metal of the present invention, drag reduction and the face of damage renovation agent are processed by the raw material of following mass percent: 25% wear-resistant reparation powder, 60% lubricating oil and 15% atactic polyether;
Wherein, wear-resistant reparation powder is made up of the raw material of following mass percent: organic-molybdenum 18%, lanthanum trifluoride 28%, nickel powder 28%, silicon dioxide powder 20% and boron nitride powder 6%.
Also be added with hexa-atomic compound emulsifying agent, hexa-atomic compound emulsifying agent accounts for 10% of wear-resistant reparation powder, lubricating oil and atactic polyether total mass.
Said hexa-atomic compound emulsifying agent is made up of the raw material of following mass percent: nonyl polyoxyethylenated alcohol 10%, ethoxylated dodecyl alcohol 32%, ethoxylated dodecyl alcohol SULPHOSUCCINIC ACID ESTER 8%, Tween-60 15%, sodium hydrogencarbonate 15% and sodium hydroxide 20%.
The preparation method may further comprise the steps:
1) will meet the lubricating oil of ratio, wear-resistant reparation powder, atactic polyether and be added to mix and transfer jar, under 55 ℃, mix;
2) mixture that step 1) is obtained changes grinding machine for grinding discharging in 48 hours over to;
3) prepare hexa-atomic compound emulsifying agent, nonyl polyoxyethylenated alcohol, ethoxylated dodecyl alcohol, ethoxylated dodecyl alcohol SULPHOSUCCINIC ACID ESTER, Tween-60, sodium hydrogencarbonate and the sodium hydroxide that will meet ratio mix, and stir and promptly get hexa-atomic compound emulsifying agent;
4) be under 70 ℃ of conditions, in temperature to step 2) add hexa-atomic compound emulsifying agent in the material that obtains, stir.
Embodiment 2
A kind of abrasion-resistant metal of the present invention, drag reduction and the face of damage renovation agent are processed by the raw material of following mass percent: 2% wear-resistant reparation powder, 95% lubricating oil and 3% atactic polyether;
Wherein, wear-resistant reparation powder is made up of the raw material of following mass percent: organic-molybdenum 25%, lanthanum trifluoride 25%, nickel powder 20%, silicon dioxide powder 20% and boron nitride powder 10%.
Also be added with hexa-atomic compound emulsifying agent, hexa-atomic compound emulsifying agent accounts for 6% of wear-resistant reparation powder, lubricating oil and atactic polyether total mass.
Said hexa-atomic compound emulsifying agent is made up of the raw material of following mass percent: nonyl polyoxyethylenated alcohol 18%, ethoxylated dodecyl alcohol 10%, ethoxylated dodecyl alcohol SULPHOSUCCINIC ACID ESTER 20%, Tween-60 7%, sodium hydrogencarbonate 10% and sodium hydroxide 35%.
The preparation method may further comprise the steps:
1) will meet the lubricating oil of ratio, wear-resistant reparation powder, atactic polyether and be added to mix and transfer jar, under 50 ℃, mix;
2) mixture that step 1) is obtained changes grinding machine for grinding discharging in 46 hours over to;
3) prepare hexa-atomic compound emulsifying agent, nonyl polyoxyethylenated alcohol, ethoxylated dodecyl alcohol, ethoxylated dodecyl alcohol SULPHOSUCCINIC ACID ESTER, Tween-60, sodium hydrogencarbonate and the sodium hydroxide that will meet ratio mix, and stir and promptly get hexa-atomic compound emulsifying agent;
4) be under 65 ℃ of conditions, in temperature to step 2) add hexa-atomic compound emulsifying agent in the material that obtains, stir.
Embodiment 3
A kind of abrasion-resistant metal of the present invention, drag reduction and the face of damage renovation agent are processed by the raw material of following mass percent: 40% wear-resistant reparation powder, 45% lubricating oil and 15% atactic polyether;
Wherein, wear-resistant reparation powder is made up of the raw material of following mass percent: organic-molybdenum 35%, lanthanum trifluoride 20%, nickel powder 17%, silicon dioxide powder 25% and boron nitride powder 3%.
Also be added with hexa-atomic compound emulsifying agent, hexa-atomic compound emulsifying agent accounts for 12% of wear-resistant reparation powder, lubricating oil and atactic polyether total mass.
Said hexa-atomic compound emulsifying agent is made up of the raw material of following mass percent: nonyl polyoxyethylenated alcohol 22%, ethoxylated dodecyl alcohol 20%, ethoxylated dodecyl alcohol SULPHOSUCCINIC ACID ESTER 8%, Tween-60 10%, sodium hydrogencarbonate 25% and sodium hydroxide 15%.
The preparation method may further comprise the steps:
1) will meet the lubricating oil of ratio, wear-resistant reparation powder, atactic polyether and be added to mix and transfer jar, under 60 ℃, mix;
2) mixture that step 1) is obtained changes grinding machine for grinding discharging in 44 hours over to;
3) prepare hexa-atomic compound emulsifying agent, nonyl polyoxyethylenated alcohol, ethoxylated dodecyl alcohol, ethoxylated dodecyl alcohol SULPHOSUCCINIC ACID ESTER, Tween-60, sodium hydrogencarbonate and the sodium hydroxide that will meet ratio mix, and stir and promptly get hexa-atomic compound emulsifying agent;
4) be under 60 ℃ of conditions, in temperature to step 2) add hexa-atomic compound emulsifying agent in the material that obtains, stir.
Embodiment 4
A kind of abrasion-resistant metal of the present invention, drag reduction and the face of damage renovation agent are processed by the raw material of following mass percent: 10% wear-resistant reparation powder, 80% lubricating oil and 10% atactic polyether;
Wherein, wear-resistant reparation powder is made up of the raw material of following mass percent: organic-molybdenum 10%, lanthanum trifluoride 60%, nickel powder 10%, silicon dioxide powder 11% and boron nitride powder 9%.
Also be added with hexa-atomic compound emulsifying agent, hexa-atomic compound emulsifying agent accounts for 9% of wear-resistant reparation powder, lubricating oil and atactic polyether total mass.
Said hexa-atomic compound emulsifying agent is made up of the raw material of following mass percent: nonyl polyoxyethylenated alcohol 5%, ethoxylated dodecyl alcohol 7%, ethoxylated dodecyl alcohol SULPHOSUCCINIC ACID ESTER 60%, Tween-60 8%, sodium hydrogencarbonate 10% and sodium hydroxide 10%.
The preparation method may further comprise the steps:
1) will meet the lubricating oil of ratio, wear-resistant reparation powder, atactic polyether and be added to mix and transfer jar, under 55 ℃, mix;
2) mixture that step 1) is obtained changes grinding machine for grinding discharging in 42 hours over to;
3) prepare hexa-atomic compound emulsifying agent, nonyl polyoxyethylenated alcohol, ethoxylated dodecyl alcohol, ethoxylated dodecyl alcohol SULPHOSUCCINIC ACID ESTER, Tween-60, sodium hydrogencarbonate and the sodium hydroxide that will meet ratio mix, and stir and promptly get hexa-atomic compound emulsifying agent;
4) be under 75 ℃ of conditions, in temperature to step 2) add hexa-atomic compound emulsifying agent in the material that obtains, stir.
Embodiment 5
A kind of abrasion-resistant metal of the present invention, drag reduction and the face of damage renovation agent are processed by the raw material of following mass percent: 18% wear-resistant reparation powder, 65% lubricating oil and 17% atactic polyether;
Wherein, wear-resistant reparation powder is made up of the raw material of following mass percent: organic-molybdenum 5%, lanthanum trifluoride 35%, nickel powder 15%, silicon dioxide powder 30% and boron nitride powder 15%.
Also be added with hexa-atomic compound emulsifying agent, hexa-atomic compound emulsifying agent accounts for 15% of wear-resistant reparation powder, lubricating oil and atactic polyether total mass.
Said hexa-atomic compound emulsifying agent is made up of the raw material of following mass percent: nonyl polyoxyethylenated alcohol 30%, ethoxylated dodecyl alcohol 2%, ethoxylated dodecyl alcohol SULPHOSUCCINIC ACID ESTER 40%, Tween-60 8%, sodium hydrogencarbonate 10% and sodium hydroxide 10%.
The preparation method may further comprise the steps:
1) will meet the lubricating oil of ratio, wear-resistant reparation powder, atactic polyether and be added to mix and transfer jar, under 60 ℃, mix;
2) mixture that step 1) is obtained changes grinding machine for grinding discharging in 40 hours over to;
3) prepare hexa-atomic compound emulsifying agent, nonyl polyoxyethylenated alcohol, ethoxylated dodecyl alcohol, ethoxylated dodecyl alcohol SULPHOSUCCINIC ACID ESTER, Tween-60, sodium hydrogencarbonate and the sodium hydroxide that will meet ratio mix, and stir and promptly get hexa-atomic compound emulsifying agent;
4) be under 80 ℃ of conditions, in temperature to step 2) add hexa-atomic compound emulsifying agent in the material that obtains, stir.
Embodiment 6
A kind of abrasion-resistant metal of the present invention, drag reduction and the face of damage renovation agent are processed by the raw material of following mass percent: 24% wear-resistant reparation powder, 70% lubricating oil and 6% atactic polyether;
Wherein, wear-resistant reparation powder is made up of the raw material of following mass percent: organic-molybdenum 14%, lanthanum trifluoride 55%, nickel powder 3%, silicon dioxide powder 16% and boron nitride powder 12%.
Also be added with hexa-atomic compound emulsifying agent, hexa-atomic compound emulsifying agent accounts for 13% of wear-resistant reparation powder, lubricating oil and atactic polyether total mass.
Said hexa-atomic compound emulsifying agent is made up of the raw material of following mass percent: nonyl polyoxyethylenated alcohol 10%, ethoxylated dodecyl alcohol 5%, ethoxylated dodecyl alcohol SULPHOSUCCINIC ACID ESTER 10%, Tween-60 20%, sodium hydrogencarbonate 30% and sodium hydroxide 25%.
The preparation method may further comprise the steps:
1) will meet the lubricating oil of ratio, wear-resistant reparation powder, atactic polyether and be added to mix and transfer jar, under 50 ℃, mix;
2) mixture that step 1) is obtained changes grinding machine for grinding discharging in 38 hours over to;
3) prepare hexa-atomic compound emulsifying agent, nonyl polyoxyethylenated alcohol, ethoxylated dodecyl alcohol, ethoxylated dodecyl alcohol SULPHOSUCCINIC ACID ESTER, Tween-60, sodium hydrogencarbonate and the sodium hydroxide that will meet ratio mix, and stir and promptly get hexa-atomic compound emulsifying agent;
4) be under 72 ℃ of conditions, in temperature to step 2) add hexa-atomic compound emulsifying agent in the material that obtains, stir.
Embodiment 7
A kind of abrasion-resistant metal of the present invention, drag reduction and the face of damage renovation agent are processed by the raw material of following mass percent: 33% wear-resistant reparation powder, 55% lubricating oil and 12% atactic polyether;
Wherein, wear-resistant reparation powder is made up of the raw material of following mass percent: organic-molybdenum 30%, lanthanum trifluoride 45%, nickel powder 8%, silicon dioxide powder 5% and boron nitride powder 12%.
Also be added with hexa-atomic compound emulsifying agent, hexa-atomic compound emulsifying agent accounts for 8% of wear-resistant reparation powder, lubricating oil and atactic polyether total mass.
Said hexa-atomic compound emulsifying agent is made up of the raw material of following mass percent: nonyl polyoxyethylenated alcohol 40%, ethoxylated dodecyl alcohol 15%, ethoxylated dodecyl alcohol SULPHOSUCCINIC ACID ESTER 15%, Tween-60 10%, sodium hydrogencarbonate 10% and sodium hydroxide 10%.
The preparation method may further comprise the steps:
1) will meet the lubricating oil of ratio, wear-resistant reparation powder, atactic polyether and be added to mix and transfer jar, under 52 ℃, mix;
2) mixture that step 1) is obtained changes grinding machine for grinding discharging in 36 hours over to;
3) prepare hexa-atomic compound emulsifying agent, nonyl polyoxyethylenated alcohol, ethoxylated dodecyl alcohol, ethoxylated dodecyl alcohol SULPHOSUCCINIC ACID ESTER, Tween-60, sodium hydrogencarbonate and the sodium hydroxide that will meet ratio mix, and stir and promptly get hexa-atomic compound emulsifying agent;
4) be under 68 ℃ of conditions, in temperature to step 2) add hexa-atomic compound emulsifying agent in the material that obtains, stir.
Abrasion-resistant metal, drag reduction and the face of damage renovation agent with embodiment 1 preparation are example, specify result of use of the present invention:
(1) the repair layer hardness of wear surface formation improves 1 ~ 2 times than matrix.
Adopt two blocks of 45# steel test block carrying out friction pair to do rotation, add No. 20 machine oil and abrasion-resistant metal, drag reduction and damage face renovation agent respectively, at voltage 220V to the experiment that rubs; Power 180W; Load 30N, under the rotating speed 515r/min condition, get system surface of friction metallographic specimen from following sample behind the operation 200h.On sample, choose A point and B point.
1, the microhardness of matrix 45# steel is lower, and numeric ratio is more approaching; The repair layer surface microhardness of handling through abrasion-resistant metal, drag reduction and the face of damage renovation agent improves a lot, but numerical fluctuations is bigger.Microhardness values at the B place reaches 405.0, brings up to 2 times than the hardness of matrix.
Table 1 specimen surface micro-hardness measurement value (HV)
2, with milscale wearing and tearing test block thickness is measured, measured 6 dot thickness at random, get its MV.The thickness average value of test block is 8.058 before the test, and test back average thickness value is 8.069.With the experiment before compare, sample thickness after test has increased 0.011mm.
Thickness measurements before and after the table 2 test block experiment
3, every dry at a distance from 15h, weigh, before the 15h up and down the weight of test block in time increase and reduce, major cause is not handle through reprocessing after the test block line cutting in the test; The surface has small burr to exist; Burr at first wears away in the process of the test, shows as the minimizing of test block weight, after the burr influence disappears; Because the existence of abrasion-resistant metal, drag reduction and the face of damage renovation agent; Generate repair layer at 45# steel surface of friction, show as the increase of test block weight, explain that abrasion-resistant metal, drag reduction and the face of damage renovation agent have repair to the 45# steel-steel pair.
Table 3 test block weight is with changing repair time
(2) can use lubricating oil, frictional coefficient descends significantly
Under load 200N condition, 120 minutes time, base oil is a tank 500CC machine oil, and the per-cent that the ratio of renovation agent and base oil is respectively every liter of base oil adding abrasion-resistant metal, drag reduction and the face of damage renovation agent is 2.5%, 5%, 10%, 20%.Adopt the multifunction friction wear trier to estimate the abrasion resistance of abrasion-resistant metal, drag reduction and the face of damage renovation agent: the frictional coefficient of base oil is higher; Be about 0.125; And after in base oil, adding abrasion-resistant metal, drag reduction and the face of the damage renovation agent of different content, frictional coefficient all obviously reduces.When content adds 2 grams in every liter of base oil (addition 10%), frictional coefficient is minimum, is about about 0.0487, and frictional coefficient is compared with base oil and reduced about 61% for this reason.
(3) the repair layer thickness >=5um of wear surface formation, the more untreated raising of gear hardness after renovation agent is handled is more than 50%.
After renovation agent was handled, to the lining, hardness was the graded that reduces gradually by table in the gear cross section.In surface to the distance scope of surperficial 40um; Handle back-geared average hardness through renovation agent and obviously improve and undressed gear, particularly on the surface less than 15um, the gear hardness after renovation agent is handled significantly increases; The gear that is untreated improves about 67%; And below the surperficial 40um, hardness is suitable, all near the hardness of matrix.
(4) use abrasion-resistant metal, drag reduction and the face of damage renovation agent, can make the noise of C0630 lathe reduce by 3 ~ 4.9bB.
Simultaneous test shows: each grade of the lathe average noise behind use abrasion-resistant metal, drag reduction and the face of the damage renovation agent work 1500h has reduced by 69.8%, 87.1% and 73.1% respectively, can reduce the operating noise of each grade of lathe very effectively.
Table 4 does not add each grade noise behind the lathe 1500h of abrasion-resistant metal, drag reduction and the face of damage renovation agent
Table 5 adds each grade noise behind the lathe 1500h of abrasion-resistant metal, drag reduction and the face of damage renovation agent
(5) behind the lathe operation 1500h of use abrasion-resistant metal, drag reduction and the face of damage renovation agent, the backlash plastisied dispersion is less; Abrasion-resistant metal, drag reduction and the face of damage renovation agent have the reparation gear function, can improve and keep the precision of lathe spindle.
The plastisied dispersion cartogram of table 6 backlash