CN102702927A - Nano modified epoxy antiseptic paint - Google Patents
Nano modified epoxy antiseptic paint Download PDFInfo
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- CN102702927A CN102702927A CN2012102081108A CN201210208110A CN102702927A CN 102702927 A CN102702927 A CN 102702927A CN 2012102081108 A CN2012102081108 A CN 2012102081108A CN 201210208110 A CN201210208110 A CN 201210208110A CN 102702927 A CN102702927 A CN 102702927A
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- modified epoxy
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- antifouling paste
- epoxy resin
- pigment
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Abstract
Nano modified epoxy antiseptic paint is prepared by the following raw materials in weight parts: 25-35 parts of epoxy resin, 0.5-1 part of coupling agent, 20-22 parts of pigment, 20-23 parts of filler, 10-15 parts of nano silicon, and 8-12 parts of solution. As the raw materials are adopted by the nano modified epoxy antiseptic paint, during the film-forming process, the nano silicon can automatically enters generated cavities, as a result, the compactness and impermeability effects are achieved at last, the penetration resistance to water and other media is improved, and further, the antiseptic performance of the whole paint film is improved, and the extraordinary technical effect is achieved.
Description
Technical field
The present invention relates to antifouling paste, be specifically related to a kind of nanometer modified epoxy antifouling paste.
Background technology
At present, epoxy anticorrosive paint is applicable to the Waterproofing/oilproofing chemical-resistant reagent of steel equipment and pipeline, does the usefulness of protection bottoming, also can do duraluminum, cementitious substrate bottoming or bottom surface unify the usefulness of protection.But existing epoxy anticorrosive paint antirust ability is strong, is prone to produce deposition, and construction process requirement is high.If construction wrong, rust-stabilising pigment is not fully utilized, and a little less than the anodic protection effect, paint film is prone to and returns the rust phenomenon, influences the long-term antiseptic property of epoxy anticorrosive paint.How improving the secular antiseptic property of epoxy anticorrosive paint, is the direction that epoxy anticorrosive paint is made great efforts.
Summary of the invention
Technical problem to be solved by this invention provides a kind of nanometer modified epoxy antifouling paste, and its paint film is fine and close, and shielding is good, and antiseptic property is superior and the anti-ability of soaking into is strong, thereby eliminates defective in the above-mentioned background technology.
For solving the problems of the technologies described above, technical scheme of the present invention is:
A kind of nanometer modified epoxy antifouling paste comprises that the feedstock production of following weight part forms:
Epoxy resin 25-35
Coupling agent 0.5-1
Pigment 20-22
Filler 20-23
Nano-silicon 10-15
Solvent 8-12.
The best proportioning of raw material is:
Epoxy resin 30
Coupling agent 0.8
Pigment 21
Filler 21
Nano-silicon 13
Solvent 10.
As a kind of improvement, said epoxy resin comprises E20 epoxy resin.
As a kind of improvement, said coupling agent comprises the polysilane coupling agent.
As a kind of improvement, said pigment comprises white titanium pigment, carbon black or iron oxide red powder; Said filler comprises at least a of process white, talcum powder and water-ground limestone.
As a kind of improvement, said solvent comprises at least a of YLENE, propyl carbinol.
As a kind of improvement, said nano-silicon comprises the nano silica fume of particle diameter 3-4 nanometer.
The present invention is prepared as follows step:
S1, obtain the epoxy resin, coupling agent, pigment, filler, nano-silicon and the solvent that weigh by weight; 1/2 epoxy resin, the coupling agent that weighs, pigment and the filler that weigh mixed; And high speed dispersion 25-35 minute, be uniformly dispersed, obtain mill base just;
S2, with the first mill base that obtains among the step S1, utilize sand mill to be ground to fineness 20-40um, obtain thick mill base;
S3, with the thick mill base that obtains among the step S2, added the epoxy resin that residue 1/2 weighs, the nano-silicon that weighs and solvent high-speed stirring 15-25 minute, the indexs such as viscosity, fineness, dryness of adjusting product are product.
Among the step S1, during high speed dispersion, stirring velocity is 1000-1500 rev/min.
Among the step S3, during high-speed stirring, stirring velocity is 1000-1500 rev/min.
Owing to adopted technique scheme, the invention has the beneficial effects as follows:
A kind of nanometer modified epoxy antifouling paste provided by the invention; Those skilled in the art have done a large amount of explorations: at first be to have selected effectively to improve the fine and close inadequately raw material of antifouling paste film forming; The antiseptic property and the impermeabilisation ability of epoxy anticorrosive paint have effectively been increased; Nanometer modified epoxy antifouling paste provided by the invention, wherein heavy flakey rust-stabilising pigment, zinc powder are evenly distributed in paint film, and physicals is even; And, causing dense form to reduce because the modified epoxy lacquer is certain to produce the hole in film process, the technician is when improving its performance; The unexpected discovery when adding nano-silicon in the raw material; Nano-silicon can be filled in the hole of generation automatically in the film process, finally plays fine and close effect of not passing through, and improves the impermeabilisation power to water and other media; Thereby improve whole paint film antiseptic property, this is those skilled in the art's beyong contemplations; Secondly, the invention provides each proportion of raw materials, the proportioning value draws through a large amount of experiment screenings repeatedly of technician; Especially the raw material that combines the present invention to select for use can make the paint film densification of nanometer modified epoxy antifouling paste, the advantage that shielding is good, antiseptic property is superior and the anti-ability of soaking into is strong perform to the best, has very high creativeness; For example: the consumption of coupling agent; If consumption is lower than 0.5 weight part, then product is prone to deposition, if consumption is higher than 1 weight part and then influences sticking power; The consumption of nano-silicon is lower than 10 weight parts, and then antiseptic property is not obvious, if be higher than 15 weight parts, the antiseptic property state that tends towards stability can cause the waste of nano-silicon.
In addition, in the preparation process that provides among the present invention, first mill base utilizes sand mill to be ground to fineness 20-40um; Adopting particle diameter simultaneously is the nano silica fume of 3-4 nanometer; And the speed that adopts 1000-1500 rev/min disperses and stirs, and under these processing condition, nano-silicon is best to the filling effect in hole; Make the film forming of nanometer modified epoxy antifouling paste the finest and close, it is best that overall performance reaches.
Nanometer modified epoxy antifouling paste according to raw material provided by the invention, proportioning preparation has excellent preservative property and impermeabilisation ability, the epoxy zinc rich primer that test makes; The modified epoxy zinc rich primer, the iron oxide red epoxy anticorrosion primer is behind the remodeling epoxy anticorrosion primer; By standard making sheet; Be salt spray resistance and water tolerance contrast experiment, result such as following table find out that from the result nanometer modified epoxy antifouling paste antiseptic property is superior to common epoxy anticorrosive paint.
Embodiment
For technique means, creation characteristic that the present invention is realized, reach purpose and effect and be easy to understand and understand, below in conjunction with specific embodiment, further set forth the present invention.
Embodiment 1
A kind of nanometer modified epoxy antifouling paste comprises that the feedstock production of following weight part forms:
Epoxy resin 30
Coupling agent 0.8
Pigment 21
Filler 21
Nano-silicon 13
Solvent 10.
Preparation process is following:
S1,15 weight part epoxy resin, 0.8 weight part coupling agent, 21 weight part pigment and 21 weight part fillers are mixed, and low whipping speed is 1500 rev/mins of following high speed dispersion 35 minutes, is uniformly dispersed, obtain mill base just;
S2, with the first mill base that obtains among the step S1, utilize sand mill to be ground to fineness 25um, obtain thick mill base;
S3, with the thick mill base that obtains among the step S2; Adding 15 parts by weight of epoxy resin, 13 weight part nano-silicons and 10 parts by weight solvent low whipping speeds is 1500 rev/mins of following high-speed stirring 25 minutes, and the index such as viscosity, fineness, dryness of adjusting product is product.
Adopt the antifouling paste of the present invention's preparation, film forming is fine and close, and salt fog resistance ability and water tolerance are stronger.
Embodiment 2
A kind of nanometer modified epoxy antifouling paste comprises that the feedstock production of following weight part forms:
E20 epoxy resin 30
Polysilane coupling agent 0.8
Titanium white powder pigment 21
Process white filler 21
Nano-silicon 13
Xylene solvent 10.
Preparation process is following:
S1, take by weighing the as above raw material of weight part; And the E20 epoxy resin of 15 weight parts, coupling agent and the titanium white powder pigment of 21 weight parts, the process white filler of 21 weight parts of 0.8 weight part mixed; And low whipping speed is 1500 rev/mins of following high speed dispersion 30 minutes; Be uniformly dispersed, obtain mill base just;
S2, with the first mill base that obtains among the step S1, utilize sand mill to be ground to fineness 30um, obtain thick mill base;
S3, with the thick mill base that obtains among the step S2; The E20 epoxy resin, the nano-silicon of 13 weight parts and the solvent low whipping speed of 10 weight parts that add residue 15 weight parts are 1500 rev/mins of following high-speed stirring 20 minutes, and the indexs such as viscosity, fineness, dryness of adjusting product are product.
Adopt the antifouling paste of the present invention's preparation, film forming is fine and close, and salt fog resistance ability and water tolerance are stronger.
Embodiment 3
A kind of nanometer modified epoxy antifouling paste comprises that following feedstock production forms:
E20 epoxy resin 25kg
Polysilane coupling agent 0.5kg
Carbon black pigment 20kg
Talcum powder 20kg
Nano-silicon 10kg
Propyl carbinol solvent 8kg.
Preparation process is following:
S1,12.5kgE20 epoxy resin, 0.5kg polysilane coupling agent, 20kg carbon black pigment and 20kg talcum powder are mixed, and low whipping speed is 1000 rev/mins of following high speed dispersion 25 minutes, is uniformly dispersed, obtain mill base just;
S2, with the first mill base that obtains among the step S1, utilize sand mill to be ground to fineness 40um, obtain thick mill base;
S3, with the thick mill base that obtains among the step S2, adding 12.5kgE20 epoxy resin, 10kg nano-silicon and 8kg propyl carbinol solvent low whipping speed is 1000 rev/mins of following high-speed stirring 15 minutes, the indexs such as viscosity, fineness, dryness of adjusting product are product.
Adopt the antifouling paste of the present invention's preparation, film forming is fine and close, and salt fog resistance ability and water tolerance are stronger.
Embodiment 4
A kind of nanometer modified epoxy antifouling paste comprises that the feedstock production of following weight part forms:
E20 epoxy resin 35
Polysilane coupling agent 1
Iron oxide red powder pigment 22
Talcum powder and heavy calcium carbonate filling 23
Nano-silicon 15
Propyl carbinol solvent 12.
Preparation process is following:
S1, with 17.5 weight part E20 epoxy resin, 1 weight part polysilane coupling agent, 22 weight part iron oxide red powder pigment; And talcum powder and heavy calcium carbonate filling totally 23 weight parts mix; And low whipping speed is 1300 rev/mins of following high speed dispersion 35 minutes, is uniformly dispersed, and obtains mill base just;
S2, with the first mill base that obtains among the step S1, utilize sand mill to be ground to fineness 20um, obtain thick mill base;
S3, with the thick mill base that obtains among the step S2; Adding 17.5 weight part E20 epoxy resin, 15 weight part nano-silicons and 12 weight part propyl carbinol solvent low whipping speeds is 1200 rev/mins of following high-speed stirring 25 minutes, and the index such as viscosity, fineness, dryness of adjusting product is product.
Adopt the antifouling paste of the present invention's preparation, film forming is fine and close, and salt fog resistance ability and water tolerance are stronger.
The present invention is not limited to above-mentioned embodiment, and all are based on technical conceive of the present invention, and the structural improvement of having done all falls among protection scope of the present invention.
Claims (10)
1. nanometer modified epoxy antifouling paste, it is characterized in that: the feedstock production that comprises following weight part forms:
Epoxy resin 25-35
Coupling agent 0.5-1
Pigment 20-22
Filler 20-23
Nano-silicon 10-15
Solvent 8-12.
2. a kind of nanometer modified epoxy antifouling paste as claimed in claim 1, it is characterized in that: the feedstock production that comprises following weight part forms:
Epoxy resin 30
Coupling agent 0.8
Pigment 21
Filler 21
Nano-silicon 13
Solvent 10.
3. according to claim 1 or claim 2 a kind of nanometer modified epoxy antifouling paste, it is characterized in that: said epoxy resin comprises E20 epoxy resin.
4. according to claim 1 or claim 2 a kind of nanometer modified epoxy antifouling paste, it is characterized in that: said coupling agent comprises the polysilane coupling agent.
5. according to claim 1 or claim 2 a kind of nanometer modified epoxy antifouling paste, it is characterized in that: said pigment comprises white titanium pigment, carbon black or iron oxide red powder.
6. according to claim 1 or claim 2 a kind of nanometer modified epoxy antifouling paste is characterized in that: said filler comprises at least a of process white, talcum powder, water-ground limestone.
7. according to claim 1 or claim 2 a kind of nanometer modified epoxy antifouling paste, it is characterized in that: said solvent comprises at least a of YLENE, propyl carbinol.
8. according to claim 1 or claim 2 a kind of nanometer modified epoxy antifouling paste, it is characterized in that: said nano-silicon comprises the nano silica fume of particle diameter 3-4 nanometer.
9. preparation method of nanometer modified epoxy antifouling paste according to claim 1 is characterized in that: comprise preparation process:
S1, obtain the epoxy resin, coupling agent, pigment, filler, nano-silicon and the solvent that weigh by weight, 1/2 epoxy resin, the coupling agent that weighs, pigment and the filler that weigh mixed, and high speed dispersion 25-35 minute, mill base just obtained;
S2, with the first mill base that obtains among the step S1, be ground to fineness 20-40um, obtain thick mill base;
S3, with the thick mill base that obtains among the step S2, added the epoxy resin that residue 1/2 weighs, the nano-silicon that weighs and solvent high-speed stirring 15-25 minute, the adjustment index is product.
10. the preparation method of nanometer modified epoxy antifouling paste as claimed in claim 9 is characterized in that: among the step S1, during high speed dispersion, stirring velocity is 1000-1500 rev/min; During high-speed stirring, stirring velocity is 1000-1500 rev/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102081108A CN102702927A (en) | 2012-06-22 | 2012-06-22 | Nano modified epoxy antiseptic paint |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102081108A CN102702927A (en) | 2012-06-22 | 2012-06-22 | Nano modified epoxy antiseptic paint |
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| CN102702927A true CN102702927A (en) | 2012-10-03 |
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| CN2012102081108A Pending CN102702927A (en) | 2012-06-22 | 2012-06-22 | Nano modified epoxy antiseptic paint |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109535804A (en) * | 2017-07-28 | 2019-03-29 | 李新念 | A kind of preparation method of waterborne antirust pigment |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1306052A (en) * | 2000-12-27 | 2001-08-01 | 中国科学院长春应用化学研究所 | Durably anticorrosion paint and its preparing process |
| CN1709988A (en) * | 2005-07-05 | 2005-12-21 | 北京国科京彪新材料科技有限公司 | High-temperature thermal-insulation anticorrosive nano coating and its preparing method |
| CN1317345C (en) * | 2005-07-05 | 2007-05-23 | 国家海洋局天津海水淡化与综合利用研究所 | Internal wall anticorrosive coating for sea water evaporating installation |
| CN100383205C (en) * | 2005-07-05 | 2008-04-23 | 孙启明 | Anticorrosive waterproof nano industrial coating and its preparing method |
| CN101148572B (en) * | 2007-11-12 | 2011-05-25 | 武汉市科达云石护理材料有限公司 | Epoxy group anti-skid glue and preparation method thereof |
-
2012
- 2012-06-22 CN CN2012102081108A patent/CN102702927A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1306052A (en) * | 2000-12-27 | 2001-08-01 | 中国科学院长春应用化学研究所 | Durably anticorrosion paint and its preparing process |
| CN1709988A (en) * | 2005-07-05 | 2005-12-21 | 北京国科京彪新材料科技有限公司 | High-temperature thermal-insulation anticorrosive nano coating and its preparing method |
| CN1317345C (en) * | 2005-07-05 | 2007-05-23 | 国家海洋局天津海水淡化与综合利用研究所 | Internal wall anticorrosive coating for sea water evaporating installation |
| CN100383205C (en) * | 2005-07-05 | 2008-04-23 | 孙启明 | Anticorrosive waterproof nano industrial coating and its preparing method |
| CN101148572B (en) * | 2007-11-12 | 2011-05-25 | 武汉市科达云石护理材料有限公司 | Epoxy group anti-skid glue and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109535804A (en) * | 2017-07-28 | 2019-03-29 | 李新念 | A kind of preparation method of waterborne antirust pigment |
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Application publication date: 20121003 |