CN102702669A - PC /ABS (poly carbonate/acrylonitrile butadiene styrene) laser etching electroplating material - Google Patents
PC /ABS (poly carbonate/acrylonitrile butadiene styrene) laser etching electroplating material Download PDFInfo
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- CN102702669A CN102702669A CN2012101977895A CN201210197789A CN102702669A CN 102702669 A CN102702669 A CN 102702669A CN 2012101977895 A CN2012101977895 A CN 2012101977895A CN 201210197789 A CN201210197789 A CN 201210197789A CN 102702669 A CN102702669 A CN 102702669A
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- acrylonitrile butadiene
- butadiene styrene
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Abstract
The invention relates to an alloy material, in particular to a PC /ABS (poly carbonate/acrylonitrile butadiene styrene) laser etching electroplating material, which comprises the following ingredients in parts by weight: 45 to 80 parts of PC, 30 to 35 parts of ABS, 0.1 to 10 parts of laser etching powder and 5 to 10 parts of methyl methacrylate, wherein rubber phase particles in the ABS are in a spherical shape, the particle size is 300 to 500nm, the particle distribution is regular, the interval is uniform, and the phase separation is clear. The alloy material has excellent heat stability and mechanical property, the marking color is pure, the contrast ratio with a bottom plate is high, meanwhile, the material can be electroplated, and in addition, the plating layer peeling strength is high.
Description
Technical field
The present invention relates to a kind of alloy material, be specifically related to a kind of PC/ABS radium carving plated material.
Background technology
Along with people's is to the increasingly high and false proof needs that require with artwork that beautify of product, and processing mode that the conventional plastic surface obtains pattern is like spray ink Printing, electrospark machining, and mechanical graduating with cutters etc. have been difficult to satisfy the demand, and radium carver skill is arisen at the historic moment.It is exactly the laser beam that utilizes high density energy that the radium carving has another name called laser labelling, is focused at workpiece surface target compound is carried out surface scan, makes the variation of material surface generation physics or chemistry, causes the variation of the reflective character of target surface, thereby obtains visible pattern.Compare with traditional technology, have the following advantages: one, it adopts Computer Control Technology, and the change tag content is very easy to, and adapts to modern production high-level efficiency, allegro requirement; Two, its adopts laser to do processing means, delineates meticulously, to the wide adaptability of material, can produce very fine mark on the surface of multiple material, and weather resistance is very good simultaneously; Three and workpiece between do not have the effect of operating force, guaranteed the original precision of workpiece, can be used as last procedure of production, save the precision work of making behind the mark; Four, processing mode is flexible, both can adapt to the needs that experiment cell-type single and mini-batch production is produced, and also can satisfy requirement of industrialized batch production; Five, do not have source of pollution, environment is not polluted.
But present laser engraving material bad mechanical property, radium carving DeGrain.The patent of CN101333325B discloses a kind of ABS laser engraving material and working method thereof, and this material comprises transparent ABS resin and/or ABS resin, TEB 3K, radium carving powder and other auxiliary agent etc.Yet ABS resin weathering resistance and UV resistant are relatively poor, and the PB of its resin surface layer contains the two keys of C=C; Chain rupture and crosslinked and become fragile be prone to take place in two keys in weathering process; Carrying out radium when carving, it is impure to occur marker color easily, and with the contrast gradient of base plate look phenomenon on the low side.
Summary of the invention
The objective of the invention is to solve phenomenons such as existing laser engraving material bad mechanical property, radium carving back color be impure, a kind of novel laser engraving material is provided, the plating performance of this material is good simultaneously.
For realizing above-mentioned purpose, the technical scheme that the present invention takes is: a kind of PC/ABS radium carving plated material by weight, comprises following component:
45 ~ 80 parts of PC
30 ~ 35 parts of ABS
0.1 ~ 10 part in radium carving powder
5 ~ 10 parts of TEB 3Ks
Said PC (polycarbonate) is a bisphenol A polycarbonate;
The rubber phase particles divinyl is spherical among the said ABS (acrylonitrile/butadiene/styrene multipolymer), and particle diameter is 300 ~ 500nm, and size distribution is neat, and evenly, it is clear to be separated at interval;
Said radium carving powder is a kind of in permanent white or the zinc sulfate.
Preparation technology of the present invention: according to the accurate weighing of formula constituent good after, behind the body material melt blending, adopt the dual-screw-stem machine extruding pelletization.
Beneficial effect of the present invention: compared with prior art, the present invention is because the introducing of PC, and the PC/ABS material possesses excellent thermostability and mechanical property, and the PC material be introduced in the pure degree that has improved marker color to a certain extent; Through the adding of radium carving powder, it is impure to have improved marker color, and with problems such as the contrast gradient of base plate look on the low side; Add TEB 3K among the present invention; Can strengthen the consistency of PC and ABS on the one hand; Have good toughening effect simultaneously, on the other hand, improved the section of PC/ABS alloy; The dispersion of ABS in the PC/ABS alloy material is more even, and this has also strengthened the coating stripping strength of PC/ABS material.
Embodiment
Embodiment 1
A kind of PC/ABS radium carving plated material by weight, comprises following component:
45 parts of PC
30 parts of ABS
1 part in radium carving powder
5 parts of TEB 3Ks
Embodiment 2
A kind of PC/ABS radium carving plated material by weight, comprises following component:
55 parts of PC
35 parts of ABS
3 parts in radium carving powder
5 parts of TEB 3Ks
Embodiment 3
A kind of PC/ABS radium carving plated material by weight, comprises following component:
80 parts of PC
35 parts of ABS
10 parts in radium carving powder
10 parts of TEB 3Ks
Above-mentioned 3 embodiment materials are carried out performance test, result such as following table:
| Project | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Tensile strength (MPa) | 48 | 50 | 43 |
| Flexural strength (MPa) | 82 | 85 | 78 |
| Shock strength (J/m) | 490 | 500 | 472 |
| Radium carving performance | Marker color is pure, and contrast gradient is high | Marker color is pure, and contrast gradient is high | Marker color is pure, and contrast gradient is high |
| Electroplate back coating stripping strength (MPa) | 4.7 | 5.0 | 4.3 |
Claims (1)
1. a PC/ABS radium is carved plated material, and it is characterized in that: according to the weight part meter, this material comprises 45 ~ 80 parts of following component: PC, 30 ~ 35 parts of ABS, 0.1 ~ 10 part in radium carving powder, 5 ~ 10 parts of TEB 3Ks;
Rubber phase particles is spherical among the said ABS, and particle diameter is 300 ~ 500nm; Said radium carving powder is a kind of in permanent white or the zinc sulfate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101977895A CN102702669A (en) | 2012-06-15 | 2012-06-15 | PC /ABS (poly carbonate/acrylonitrile butadiene styrene) laser etching electroplating material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101977895A CN102702669A (en) | 2012-06-15 | 2012-06-15 | PC /ABS (poly carbonate/acrylonitrile butadiene styrene) laser etching electroplating material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102702669A true CN102702669A (en) | 2012-10-03 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012101977895A Pending CN102702669A (en) | 2012-06-15 | 2012-06-15 | PC /ABS (poly carbonate/acrylonitrile butadiene styrene) laser etching electroplating material |
Country Status (1)
| Country | Link |
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| CN (1) | CN102702669A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105315580A (en) * | 2015-11-06 | 2016-02-10 | 博硕科技(江西)有限公司 | Laser etching polyvinyl chloride cable material and preparation method thereof |
| CN106751075A (en) * | 2016-11-28 | 2017-05-31 | 古道尔工程塑胶（深圳）有限公司 | Syndiotactic polytyrene polyhexamethylene adipamide flame-proof composite material |
| CN106751077A (en) * | 2016-11-28 | 2017-05-31 | 古道尔工程塑胶（深圳）有限公司 | Syndiotactic polytyrene flame-proof composite material |
| CN106751076A (en) * | 2016-11-28 | 2017-05-31 | 古道尔工程塑胶（深圳）有限公司 | Syndiotactic polytyrene composite |
| CN106751074A (en) * | 2016-11-28 | 2017-05-31 | 古道尔工程塑胶（深圳）有限公司 | Syndiotactic polytyrene polyhexamethylene adipamide composite |
| CN107936457A (en) * | 2017-11-24 | 2018-04-20 | 广东威林工程塑料股份有限公司 | Short fine reinforced ABS alloy material of a kind of scratch-resistant low gloss oil resistant and laser carving for mechanical keyboard and preparation method thereof |
| CN108003544A (en) * | 2016-11-01 | 2018-05-08 | 上海鼎事新材料科技有限公司 | A kind of TPU/TPE composite modification materials |
| CN109096722A (en) * | 2018-06-07 | 2018-12-28 | 广东聚石化学股份有限公司 | A kind of shock resistance laser carving PC/PBT alloy and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101113235A (en) * | 2006-07-28 | 2008-01-30 | 佛山市顺德区汉达精密电子科技有限公司 | PC/ABS modified alloy metal |
| CN101333325A (en) * | 2007-06-29 | 2008-12-31 | 美泰塑胶股份有限公司 | ABS laser engraving material and processing method thereof |
| CN101531801A (en) * | 2009-04-20 | 2009-09-16 | 四川长虹模塑科技有限公司 | Preparation method of scratch-resistant lacquer-free ABS moulding composition with high glaze |
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2012
- 2012-06-15 CN CN2012101977895A patent/CN102702669A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101113235A (en) * | 2006-07-28 | 2008-01-30 | 佛山市顺德区汉达精密电子科技有限公司 | PC/ABS modified alloy metal |
| CN101333325A (en) * | 2007-06-29 | 2008-12-31 | 美泰塑胶股份有限公司 | ABS laser engraving material and processing method thereof |
| CN101531801A (en) * | 2009-04-20 | 2009-09-16 | 四川长虹模塑科技有限公司 | Preparation method of scratch-resistant lacquer-free ABS moulding composition with high glaze |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105315580A (en) * | 2015-11-06 | 2016-02-10 | 博硕科技(江西)有限公司 | Laser etching polyvinyl chloride cable material and preparation method thereof |
| CN105315580B (en) * | 2015-11-06 | 2019-07-19 | 博硕科技(江西)有限公司 | A method of improving polyvinyl chloride cable material laser carving performance |
| CN108003544A (en) * | 2016-11-01 | 2018-05-08 | 上海鼎事新材料科技有限公司 | A kind of TPU/TPE composite modification materials |
| CN106751075A (en) * | 2016-11-28 | 2017-05-31 | 古道尔工程塑胶（深圳）有限公司 | Syndiotactic polytyrene polyhexamethylene adipamide flame-proof composite material |
| CN106751077A (en) * | 2016-11-28 | 2017-05-31 | 古道尔工程塑胶（深圳）有限公司 | Syndiotactic polytyrene flame-proof composite material |
| CN106751076A (en) * | 2016-11-28 | 2017-05-31 | 古道尔工程塑胶（深圳）有限公司 | Syndiotactic polytyrene composite |
| CN106751074A (en) * | 2016-11-28 | 2017-05-31 | 古道尔工程塑胶（深圳）有限公司 | Syndiotactic polytyrene polyhexamethylene adipamide composite |
| CN106751077B (en) * | 2016-11-28 | 2019-11-29 | 古道尔工程塑胶（深圳）有限公司 | Syndiotactic polytyrene flame retardant composite material |
| CN106751076B (en) * | 2016-11-28 | 2019-12-03 | 古道尔工程塑胶（深圳）有限公司 | Syndiotactic polytyrene composite material |
| CN107936457A (en) * | 2017-11-24 | 2018-04-20 | 广东威林工程塑料股份有限公司 | Short fine reinforced ABS alloy material of a kind of scratch-resistant low gloss oil resistant and laser carving for mechanical keyboard and preparation method thereof |
| CN109096722A (en) * | 2018-06-07 | 2018-12-28 | 广东聚石化学股份有限公司 | A kind of shock resistance laser carving PC/PBT alloy and preparation method thereof |
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Application publication date: 20121003 |