CN102702610A - Method for preparing antirust master batch without nitrite - Google Patents
Method for preparing antirust master batch without nitrite Download PDFInfo
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- CN102702610A CN102702610A CN2012101585827A CN201210158582A CN102702610A CN 102702610 A CN102702610 A CN 102702610A CN 2012101585827 A CN2012101585827 A CN 2012101585827A CN 201210158582 A CN201210158582 A CN 201210158582A CN 102702610 A CN102702610 A CN 102702610A
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Abstract
The invention discloses a method for preparing an antirust master batch without nitrite, comprising the following steps: step 1, uniformly mixing 10%-40% of sebacic acid disodium salt, 20%-40% of molybdate, 10%-25% of cyclodextrin, 5%-15% of sodium benzoate (food grade) and 5%-15% of aromatizer (food grade) according to weight rate; step 2, and mixing the mixture obtained in the step 1 with LLDPE (linear low density polyethylene) by the weight rate of 1:2 for granulation. The components of the master batch do not include carcinogenic ingredients such as nitrite, so that the master batch does not bring damages to human bodies or environments in the use process.
Description
Technical field
The present invention relates to a kind of nitrite type anti-rust master batch method of manufacture that do not contain.
Background technology
The anti-rust master batch product of selling on the market now all is the prescription of external six the seventies; Quality is more stable; But all with nitrite as staple; Nitrite belongs to the carinogenicity compound, in blown film and use, human body is constituted potential and threatens, and HUMAN HEALTH and surrounding environment are caused certain harm.Domestic do not have the real nitrite prescription that do not contain to occur always, even serial problems such as also having the quality instability is arranged.For this reason, the applicant discloses a kind of prescription that does not contain the anti-rust master batch of objectionable impuritiess such as nitrite, thoroughly addresses the above problem.
Summary of the invention
Contain the nitrite composition for overcoming traditional master batch product, be prone to technical deficiency that human body and environment are worked the mischief, the invention provides a kind of steady quality, the harmless method of manufacture that does not contain nitrite type master batch.
For realizing above-mentioned technical purpose, the present invention adopts following technical scheme to realize: a kind of nitrite type anti-rust master batch method of manufacture that do not contain comprises following steps:
1, with certain herbaceous plants with big flowers two acid disodium salt 10%-40%, molybdate 20%-40%, Schardinger dextrins 10%-25%, Sodium Benzoate (food grade) 5%-15%, perfume compound (food grade) 5%-15%, mixes, and carry out the fine grinding oven dry by above-mentioned mass ratio;
2, the mixture of step 1 gained and LLDPE carry out mixing granulation by 1: 2 weight ratio, obtain anti-rust master batch at last.
Above-mentioned anti-rust master batch addition when blown film is 2%-4%, rust-proof effect well.
Optimum proportion in the step 1 is: certain herbaceous plants with big flowers two acid disodium salts 30%, molybdate 30%, Schardinger dextrins 20%, Sodium Benzoate (food grade) 15%, perfume compound (food grade) 5%.
The present invention has following beneficial effect: do not contain carcinogenic compositions such as nitrite in its component, in use can not bring harm to human body and environment.
Embodiment
Embodiment one
Step 1 mixes certain herbaceous plants with big flowers two acid disodium salt 30KG, molybdate 30KG, Schardinger dextrins 20KG, Sodium Benzoate (food grade) 15KG, perfume compound (food grade) 5KG, and carries out fine grinding oven dry, obtains the 100KG compound that becomes more meticulous;
Step 2 uses the mixture of step 1 gained and the LLDPE of 200KG to carry out mixing granulation, obtains anti-rust master batch at last.
The gained anti-rust master batch is pure white, and is cylindrical, and each grammes per square metre is between the 2-4 gram.
When blown film, add anti-rust master batch by 2% consumption after, the anti-rust film of blowing does not have tangible irritating smell, and light fragrance is arranged, transparency improves very big, when making colourless anti-rust film and do not add the anti-rust master batch basically identical, has irritating smell to produce.Emerging salt-fog test was not seen corrosion in 72 hours in the rust-proof effect warp, and rust-proof effect is good, accomplishes the end in view.
Embodiment two
Step 1 mixes certain herbaceous plants with big flowers two acid disodium salt 40KG, molybdate 40KG, Schardinger dextrins 10KG, Sodium Benzoate (food grade) 5KG, perfume compound (food grade) 5KG, and carries out fine grinding oven dry, obtains the 100KG compound that becomes more meticulous;
Step 2 uses the mixture of step 1 gained and the LLDPE of 200KG to carry out mixing granulation, obtains anti-rust master batch at last.
The gained anti-rust master batch is pure white, and is cylindrical, and each grammes per square metre is between the 2-4 gram.
When blown film, add anti-rust master batch by 3% consumption after, the anti-rust film of blowing does not have tangible irritating smell, and light fragrance is arranged, transparency improves very big, when making colourless anti-rust film and do not add the anti-rust master batch basically identical, has irritating smell to produce.Emerging salt-fog test was not seen corrosion in 72 hours in the rust-proof effect warp, and rust-proof effect is good, accomplishes the end in view.
Embodiment three
Step 1 mixes certain herbaceous plants with big flowers two acid disodium salt 10KG, molybdate 35KG, Schardinger dextrins 25KG, Sodium Benzoate (food grade) 15KG, perfume compound (food grade) 15KG, and carries out fine grinding oven dry, obtains the 100KG compound that becomes more meticulous;
Step 2 uses the mixture of step 1 gained and the LLDPE of 200KG to carry out mixing granulation, obtains anti-rust master batch at last.
The gained anti-rust master batch is pure white, and is cylindrical, and each grammes per square metre is between the 2-4 gram.
When blown film, add anti-rust master batch by 4% consumption after, the anti-rust film of blowing does not have tangible irritating smell, and light fragrance is arranged, transparency improves very big, when making colourless anti-rust film and do not add the anti-rust master batch basically identical, has irritating smell to produce.Emerging salt-fog test was not seen corrosion in 72 hours in the rust-proof effect warp, and rust-proof effect is good, accomplishes the end in view.
Embodiment four
Step 1 mixes certain herbaceous plants with big flowers two acid disodium salt 40KG, molybdate 20KG, Schardinger dextrins 20KG, Sodium Benzoate (food grade) 10KG, perfume compound (food grade) 10KG, and carries out fine grinding oven dry, obtains the 100KG compound that becomes more meticulous;
Step 2 uses the mixture of step 1 gained and the LLDPE of 200KG to carry out mixing granulation, obtains anti-rust master batch at last.
The gained anti-rust master batch is pure white, and is cylindrical, and each grammes per square metre is between the 2-4 gram.
When blown film, add anti-rust master batch by 2% consumption after, the anti-rust film of blowing does not have tangible irritating smell, and light fragrance is arranged, transparency improves very big, when making colourless anti-rust film and do not add the anti-rust master batch basically identical, has irritating smell to produce.Emerging salt-fog test was not seen corrosion in 72 hours in the rust-proof effect warp, and rust-proof effect is good, accomplishes the end in view.
Claims (3)
1. one kind does not contain nitrite type anti-rust master batch method of manufacture; It is characterized in that; It comprises following steps: step 1; Certain herbaceous plants with big flowers two acid disodium salt 10%-40%, molybdate 20%-40%, Schardinger dextrins 10%-25%, Sodium Benzoate (food grade) 5%-15%, perfume compound (food grade) 5%-15% are mixed by above-mentioned mass ratio, and carry out the fine grinding oven dry; Step 2, the mixture of step 1 gained and LLDPE carry out mixing granulation by 1: 2 weight ratio, obtain anti-rust master batch at last.
2. a kind of nitrite type anti-rust master batch method of manufacture that do not contain as claimed in claim 1; It is characterized in that: the optimum proportion in the step 1 does, certain herbaceous plants with big flowers two acid disodium salts 30%, molybdate 30%, Schardinger dextrins 20%, Sodium Benzoate (food grade) 15%, perfume compound (food grade) 5%.
3. method is used in the described use that does not contain nitrite type anti-rust master batch of claim 1, and it is characterized in that: the addition when blown film is 2%-4%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210158582.7A CN102702610B (en) | 2012-05-22 | 2012-05-22 | One is not containing nitrous acid salt form anti-rust master batch manufacture method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210158582.7A CN102702610B (en) | 2012-05-22 | 2012-05-22 | One is not containing nitrous acid salt form anti-rust master batch manufacture method |
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| Publication Number | Publication Date |
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| CN102702610A true CN102702610A (en) | 2012-10-03 |
| CN102702610B CN102702610B (en) | 2015-10-14 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201210158582.7A Expired - Fee Related CN102702610B (en) | 2012-05-22 | 2012-05-22 | One is not containing nitrous acid salt form anti-rust master batch manufacture method |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104311973A (en) * | 2014-11-10 | 2015-01-28 | 青岛科技大学 | Organic amine borate antirust masterbatch and preparation method thereof as well as application thereof |
| CN104311971A (en) * | 2014-11-10 | 2015-01-28 | 青岛鑫盈鑫包装材料有限公司 | Multi-metal anti-rusting master batch as well as preparation method and application thereof |
| CN104311975A (en) * | 2014-11-10 | 2015-01-28 | 青岛鑫盈鑫包装材料有限公司 | Lauroyl diethanolamide borate VCI (Volatile Corrosion Inhibitor) masterbatch as well as preparation method and applications thereof |
| CN104761786A (en) * | 2014-12-26 | 2015-07-08 | 青岛科技大学 | Phytic-acid type gas-phase antirust masterbatch, and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101481476A (en) * | 2009-02-12 | 2009-07-15 | 中国人民解放军军械工程学院 | Preparation of conductive gas-phase anti-rust membrane |
| CN101643127A (en) * | 2009-06-20 | 2010-02-10 | 金福东 | Biodegradable gasified rust-proof bubble film and manufacturing method thereof |
| CN102391548A (en) * | 2011-09-07 | 2012-03-28 | 中国人民解放军军械工程学院 | Biodegradable starch-based molybdate gas-phase rust-preventing masterbatch |
-
2012
- 2012-05-22 CN CN201210158582.7A patent/CN102702610B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101481476A (en) * | 2009-02-12 | 2009-07-15 | 中国人民解放军军械工程学院 | Preparation of conductive gas-phase anti-rust membrane |
| CN101643127A (en) * | 2009-06-20 | 2010-02-10 | 金福东 | Biodegradable gasified rust-proof bubble film and manufacturing method thereof |
| CN102391548A (en) * | 2011-09-07 | 2012-03-28 | 中国人民解放军军械工程学院 | Biodegradable starch-based molybdate gas-phase rust-preventing masterbatch |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104311973A (en) * | 2014-11-10 | 2015-01-28 | 青岛科技大学 | Organic amine borate antirust masterbatch and preparation method thereof as well as application thereof |
| CN104311971A (en) * | 2014-11-10 | 2015-01-28 | 青岛鑫盈鑫包装材料有限公司 | Multi-metal anti-rusting master batch as well as preparation method and application thereof |
| CN104311975A (en) * | 2014-11-10 | 2015-01-28 | 青岛鑫盈鑫包装材料有限公司 | Lauroyl diethanolamide borate VCI (Volatile Corrosion Inhibitor) masterbatch as well as preparation method and applications thereof |
| CN104761786A (en) * | 2014-12-26 | 2015-07-08 | 青岛科技大学 | Phytic-acid type gas-phase antirust masterbatch, and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102702610B (en) | 2015-10-14 |
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