CN102690566A - Aqueous antistatic paint - Google Patents
Aqueous antistatic paint Download PDFInfo
- Publication number
- CN102690566A CN102690566A CN2012101788925A CN201210178892A CN102690566A CN 102690566 A CN102690566 A CN 102690566A CN 2012101788925 A CN2012101788925 A CN 2012101788925A CN 201210178892 A CN201210178892 A CN 201210178892A CN 102690566 A CN102690566 A CN 102690566A
- Authority
- CN
- China
- Prior art keywords
- toluene diisocyanate
- weight parts
- weight
- coating
- conductive filler
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention relates to aqueous antistatic paint which is made of conductive filler and a film forming material, wherein the conductive filler is composed of flake zinc powder and copper powder, and the film forming material is 2,4-toluene diisocyanate crosslinked modified polyvinyl alcohol. The 2,4-toluene diisocyanate crosslinked modified polyvinylalcohol is prepared by steps: adding 2,4-toluene diisocyanate into polyvinyl alcohol aqueous solution at 23-85 DEG C and reacting for at least one hour to obtain 2,4-toluene diisocyanate modified polyvinyl alcohol aqueous solution. The aqueous antistatic paint has excellent conductivity by using the flake zinc powder and copper powder as conductive filler, has excellent adhesive power and physical and mechanical performances, and is resistant to organic solvents and corrosion, high in water resistance and high in stability.
Description
Technical field
The present invention relates to paint field, be specifically related to a kind of aqueous antistatic coating.
Background technology
Coating plays the macromolecular material that protection, decoration etc. act on as a kind of article surface that is coated in, and is widely used in the covering with paint of hardware, upholstery, furniture etc.Common coating in use is prone to produce accumulation of static electricity because its electrical insulation capability is high.Might cause dust suction seriously to be difficult to purify and destroy the ultrapurification environment, thereby influence the operation of product appearance or precision instrument: static discharge can make various precision instruments, electronic devices and components are breakdown and scrap; In industries such as explosive, colliery, oil, chemical industry, weaving, static discharge causes the on fire or blast of inflammable and explosive substances, causes huge serious accident.The Application Areas of antistatic coating is expanded just year by year.
Antistatic coating is to be applied on the electrical insulator base material, makes it to have certain conduction current and the functional coating of eliminating static letter ability.Other technique means that obtains conductive layer such as antistatic coating and plating, vacuum sputtering etc. is compared, and has that equipment is simple, plurality of advantages such as easy construction, with low cost, applied range, especially is fit to the coating of various surfaces of complex shape.
CN 1389528A relates to a kind of aqueous antistatic coating and is made up of the conducting material of 1-60 part weight and the filmogen of 40-99 part weight; Said conducting material is a water-soluble poly styrene sulfonic acid doped polyaniline; Said filmogen is 2, the cross-linking modified Z 150PH of 4-toluene diisocynate vinegar; Said water-soluble poly styrene sulfonic acid doped polyaniline is obtained by carrying out oxidative polymerization at the aqueous solution by polystyrolsulfon acid, aniline, persulfuric acid; Said 2,4 one toluene diisocynate vinegar modified polyvinyl alcohols pass through with 2, and 4-toluene diisocynate vinegar carries out modified-reaction to Z 150PH and obtains.
Antistatic coating mainly is an addition type at present, and the conductive additive that is adopted mainly contains two types: one type is static inhibitor, and another kind of is various conductive filler materials.Mostly static inhibitor is the low-molecular-weight surfactant of polarity or ionic, like AS, quaternary, stearic phthalein amine propyl-dimethyl-beta-hydroxyethyl ammonium dihydrogen orthophosphate etc.They can only give material lower conductivity, and specific conductivity is generally less than 10-7S/cm, and work-ing life is short, and static inhibitor can move about and be consumed to the surface.Electroconductibility receives the influence of factors such as environment such as temperature, humidity, friction big.Conductive filler material comprises graphitized carbon black, graphite, charcoal fiber and metal or metal oxide powder etc.; Differing greatly of conductive filler material that uses at present and polymer architecture; Dispersed relatively poor; Be difficult to form homogeneous system, thereby influence physical and mechanical propertiess such as its electroconductibility and sticking power, shock strength.
Summary of the invention
The objective of the invention is to a series of problems of existing to prior art, proposes a kind of be solvent with water, sticking power is good, physical and mechanical properties is good, organic solvent-resistant, corrosion-resistant, have better water tolerance, a stable environment-friendly type aqueous antistatic coating.
For reaching this purpose, the present invention adopts following technical scheme:
A kind of aqueous antistatic coating mainly is made up of the conductive filler material of 2 ~ 75 weight parts and the filmogen of 35 ~ 108 weight parts; Said conductive filler material is made up of zinc flake and copper powder, and said filmogen is the cross-linking modified Z 150PH of 2,4 toluene diisocyanate.
Conductive filler material commonly used has carbon black and conducting metal filler.The sooty particle diameter is more little, helps forming the chain type conductive structure more.The shape of conductive filler material has considerable influence to the conductivity of material, it is generally acknowledged that conducting particles is better in the form of sheets, and is spherical relatively poor.The present invention adopts zinc flake, and it is better to conductivity, because zinc powder and copper powder share, has reduced the oxidized possibility of copper powder simultaneously.Use 200 purpose copper powders in addition, its particle diameter is best selection, and it has good electroconductibility performance.The parts by weight of conductive filler material according to the invention may be selected to be 3 ~ 73, and 10 ~ 65,22 ~ 54,34 ~ 50,40 etc.
Filmogen is meant the independent material that can be formed with certain intensity, successive dry film, like inorganic substance such as various resins, dryness wet goods organic polymer material and water glass, is to form the requisite composition of filming.Color filler, some auxiliary agent play booster action filming when forming, they separately can not film forming, but their existence can make to film and more meet the requirement of effect, and film forming is had booster action.The parts by weight of filmogen of the present invention can select 36 ~ 105,45 ~ 90,53 ~ 80,62 ~ 73,68 etc.
Conductive filler material according to the invention is made up of the zinc flake of 1 ~ 32 weight part and the copper powder of 1 ~ 43 weight part; For example form by the zinc flake of 2 ~ 30 weight parts and the copper powder of 2 ~ 40 weight parts; Form by the zinc flake of 9 ~ 23 weight parts and the copper powder of 6 ~ 33 weight parts; Form by the zinc flake of 14 ~ 18 weight parts and the copper powder of 10 ~ 28 weight parts; Further preferably form, most preferably form by the zinc flake of 18 weight parts and the copper powder of 13 weight parts by the zinc flake of 10 ~ 25 weight parts and the copper powder of 8 ~ 20 weight parts.
2,4 toluene diisocyanate modified polyvinyl alcohol according to the invention is by 2,4 toluene diisocyanate Z 150PH to be carried out modified-reaction to obtain.
Coating according to the invention also comprises the resene tackiness agent.
Further; Said tackiness agent is the mixture of a kind of in polyurethane resin, resol, vinyl resin or the Synolac or at least two kinds; Polyurethane resin for example, resol/vinyl resin, vinyl resin/Synolac/polyurethane resin etc. all can be used for the present invention.
Further, in said resene tackiness agent, also can add carbon black disperser and coupling agent.
As most preferred technical scheme, aqueous antistatic coating according to the invention comprises following raw material by weight:
Of the present invention " mainly by ... constitute ", mean it except that said component, can also comprise other components, these other components are given said water-borne coatings different characteristic.In addition, of the present invention " mainly by ... constitute ", can also replace with enclosed " be " or " by ... composition ".
According to the invention 2; 4-tolylene diisocyanate modified polyvinyl alcohol prepares through following method: in polyvinyl alcohol water solution, add 2 under 23 ~ 85 ℃, 4-toluene diisocynate vinegar reacted 1 hour at least; Promptly obtain 2,4 toluene diisocyanate modified poly ethylene alcohol solution.
Raw materials in part by weight described in the above-mentioned preparation 2,4 toluene diisocyanate modified polyvinyl alcohol aqueous process is formed as follows:
Z 150PH 35 ~ 80
2,4 toluene diisocyanate 7 ~ 30
Water 720 ~ 950.
The parts by weight of said Z 150PH can select 36 ~ 78,42 ~ 72,50 ~ 68,60 etc.; The parts by weight of said 2,4 toluene diisocyanate can select 8 ~ 28,12 ~ 23,16 ~ 20,17 etc.; The parts by weight of said water are 722 ~ 947,750 ~ 920,773 ~ 905,780 ~ 856,820 etc.
As optimal technical scheme, raw materials in part by weight is formed as follows described in the preparation 2,4 toluene diisocyanate modified polyvinyl alcohol aqueous process:
Z 150PH 53 ~ 70
2,4 toluene diisocyanate 12 ~ 26
Water 800 ~ 900;
As technical scheme most preferably, raw materials in part by weight described in the above-mentioned preparation method is formed as follows:
Z 150PH 60
2,4 toluene diisocyanate 23
Water 830.
Temperature of reaction of the present invention is 30 ~ 80 ℃, for example 31 ~ 78 ℃, and 36 ~ 72 ℃, 40 ~ 65 ℃, 43 ~ 60 ℃, 52 ℃ etc., further preferred 45 ~ 70 ℃, most preferably 65 ℃.
The described reaction times is 1 ~ 5h, 1.05 ~ 4.8h for example, 1.5 ~ 4.2h, 2 ~ 3.5h, 2.4 ~ 3h, 2.6h etc., further preferred 1.5 ~ 3h, most preferably 2h.
Above-mentioned conductive filler material is with after filmogen mixes, and conductive filler material homodisperse, specific conductivity in filmogen are 10
-8～10
-2The anti-static function coating of S/cm.
Coating of the present invention can add other auxiliary agents again according to performance and request for utilization, like skimmer, softening agent, oxidation inhibitor, UV light absorber etc.
Compare with the prior art scheme, the present invention has following beneficial effect:
The present invention compared with prior art has following advantage:
(1) the present invention adopts zinc flake, and it is better to conductivity, because zinc powder and copper powder share, has reduced the oxidized possibility of copper powder simultaneously.Use 200 purpose copper powders in addition, its particle diameter is best selection, and it has good electroconductibility performance.
(2) coating of the present invention has good anti-static function, and specific conductivity just can reach 10
-8S/cm; Paint film all has good sticking power, excellent physical and mechanical properties, organic solvent-resistant, corrosion-resistant, water resistance and satisfactory stability property preferably to glass, tinplate tin, concrete etc.
(3) solvent is a water, and save energy, resource are nuisanceless, pollution-free, abundant, inexpensive, the convenience of drawing materials of originating.Help environment protection on the one hand, meet global Green Chemistry conception development trend; On the other hand, also can bring bigger economic benefit.
(4) production process of the present invention is simple, does not need specific installation, has a good application prospect.Can be used for various productions or deposit the factory building of inflammable and explosive Chemicals and the Antistatic Paint of warehouse, electronic and electrical equipment factory building, glass, concrete product and buildings etc.
Down in the face of further explain of the present invention.But following instance only is a simple and easy example of the present invention, does not represent or limits rights protection scope of the present invention, and interest field of the present invention is as the criterion with claims.
Embodiment
For the present invention is described better, be convenient to understand technical scheme of the present invention, typical case of the present invention but non-restrictive example is following:
Embodiment 1
A kind of aqueous antistatic coating is made up of auxiliary agents such as the resol of the cross-linking modified Z 150PH of 2,4 toluene diisocyanate of the conductive filler material of 2 weight parts, 50 weight parts, 15 weight parts and an amount of carbon black disperser, coupling agents.Said conductive filler material is made up of the zinc flake of 1 weight part and the copper powder of 1 weight part.
Present embodiment described 2; The cross-linking modified Z 150PH of 4-tolylene diisocyanate obtains through following preparation method: the Z 150PH of 35 weight parts is added in the water of 800 weight parts and be made into polyvinyl alcohol water solution; In the above-mentioned aqueous solution, add 2 of 12 weight parts down at 23 ℃, 4-toluene diisocynate vinegar, reaction 1h; Promptly obtain 2,4 toluene diisocyanate modified poly ethylene alcohol solution.
Embodiment 2
A kind of aqueous antistatic coating is made up of auxiliary agents such as the cross-linking modified Z 150PH of 2,4 toluene diisocyanate of the conductive filler material of 75 weight parts, 35 weight parts, 22 parts by weight of acrylic resins and an amount of carbon black disperser, coupling agents.Said conductive filler material is made up of the zinc flake of 32 weight parts and the copper powder of 43 weight parts.
Present embodiment described 2; The cross-linking modified Z 150PH of 4-tolylene diisocyanate obtains through following preparation method: the Z 150PH of 70 weight parts is added in the water of 720 weight parts and be made into polyvinyl alcohol water solution; In the above-mentioned aqueous solution, add 2 of 30 weight parts down at 85 ℃, 4-toluene diisocynate vinegar, reaction 5h; Promptly obtain 2,4 toluene diisocyanate modified poly ethylene alcohol solution.
Embodiment 3
A kind of aqueous antistatic coating, auxiliary agents such as the cross-linking modified Z 150PH of 2,4 toluene diisocyanate of the conductive filler material of 30 weight parts, 108 weight parts, the Synolac of 8 weight parts and an amount of carbon black disperser, coupling agent constitute.Said conductive filler material is made up of the zinc flake of 10 weight parts and the copper powder of 20 weight parts.
Present embodiment described 2; The cross-linking modified Z 150PH of 4-tolylene diisocyanate obtains through following preparation method: the Z 150PH of 80 weight parts is added in the water of 950 weight parts and be made into polyvinyl alcohol water solution; In the above-mentioned aqueous solution, add 2 of 26 weight parts down at 80 ℃, 4-toluene diisocynate vinegar, reaction 3h; Promptly obtain 2,4 toluene diisocyanate modified poly ethylene alcohol solution.
Embodiment 4
A kind of aqueous antistatic coating is made up of auxiliary agents such as the polyurethane resin of the cross-linking modified Z 150PH of 2,4 toluene diisocyanate of the conductive filler material of 33 weight parts, 46 weight parts, 10 weight parts and an amount of carbon black disperser, coupling agents.Said conductive filler material is made up of the zinc flake of 25 weight parts and the copper powder of 8 weight parts.
Present embodiment described 2; The cross-linking modified Z 150PH of 4-tolylene diisocyanate obtains through following preparation method: the Z 150PH of 53 weight parts is added in the water of 900 weight parts and be made into polyvinyl alcohol water solution; In the above-mentioned aqueous solution, add 2 of 7 weight parts down at 70 ℃, 4-toluene diisocynate vinegar, reaction 1.5h; Promptly obtain 2,4 toluene diisocyanate modified poly ethylene alcohol solution.
Embodiment 5
A kind of aqueous antistatic coating is made up of auxiliary agents such as the polyurethane resin of the cross-linking modified Z 150PH of 2,4 toluene diisocyanate of the conductive filler material of 57 weight parts, 39 weight parts, 30 weight parts and an amount of carbon black disperser, coupling agents.Said conductive filler material is made up of the zinc flake of 32 weight parts and the copper powder of 25 weight parts.
Present embodiment described 2; The cross-linking modified Z 150PH of 4-tolylene diisocyanate obtains through following preparation method: the Z 150PH of 42 weight parts is added in the water of 832 weight parts and be made into polyvinyl alcohol water solution; In the above-mentioned aqueous solution, add 2 of 14 weight parts down at 45 ℃, 4-toluene diisocynate vinegar, reaction 3h; Promptly obtain 2,4 toluene diisocyanate modified poly ethylene alcohol solution.
Embodiment 6
A kind of aqueous antistatic coating is made up of the conductive filler material of 33 weight parts, the cross-linking modified Z 150PH of 2,4 toluene diisocyanate of 83 weight parts, the Synolac of 27 weight parts and the carbon black disperser of 11 weight parts, the auxiliary agents such as coupling agent of 7 weight parts.Said conductive filler material is made up of the zinc flake of 20 weight parts and the copper powder of 13 weight parts.
Present embodiment described 2; The cross-linking modified Z 150PH of 4-tolylene diisocyanate obtains through following preparation method: the Z 150PH of 60 weight parts is added in the water of 830 weight parts and be made into polyvinyl alcohol water solution; In the above-mentioned aqueous solution, add 2 of 23 weight parts down at 65 ℃, 4-toluene diisocynate vinegar, reaction 2h; Promptly obtain 2,4 toluene diisocyanate modified poly ethylene alcohol solution.
Applicant's statement; The person of ordinary skill in the field is on the basis of the foregoing description, and is with the concrete content point value of the foregoing description component, combined with the technical scheme of summary of the invention part; Thereby the new numerical range that produces; Also be one of record scope of the present invention, the application is no longer enumerated these numerical ranges for making specification sheets simple and clear.
Applicant's statement, the present invention explains preparation process of the present invention through the foregoing description, but the present invention is not limited to above-mentioned preparation process, does not mean that promptly the present invention must rely on above-mentioned preparation process and could implement.The person of ordinary skill in the field should understand, and to any improvement of the present invention, to the interpolation of the equivalence replacement of raw material that the present invention selects for use and ancillary component, the selection of concrete mode etc., all drops within protection scope of the present invention and the open scope.
Claims (10)
1. an aqueous antistatic coating is characterized in that, mainly is made up of the conductive filler material of 2 ~ 75 weight parts and the filmogen of 35 ~ 108 weight parts; Said conductive filler material is made up of zinc flake and copper powder, and said filmogen is the cross-linking modified Z 150PH of 2,4 toluene diisocyanate.
2. coating according to claim 1 is characterized in that, said conductive filler material is made up of the zinc flake of 1 ~ 32 weight part and the copper powder of 1 ~ 43 weight part, further preferably is made up of the zinc flake of 10 ~ 25 weight parts and the copper powder of 8 ~ 20 weight parts.
3. coating according to claim 1 and 2 is characterized in that, said 2,4 toluene diisocyanate modified polyvinyl alcohol is by 2,4 toluene diisocyanate Z 150PH to be carried out modified-reaction to obtain.
4. according to the described coating of one of claim 1-3, it is characterized in that said coating also comprises the resene tackiness agent;
Preferably, said tackiness agent is the mixture of a kind of in polyurethane resin, resol, vinyl resin or the Synolac or at least two kinds;
Preferably, in said resene tackiness agent, also can add carbon black disperser and coupling agent.
5. according to the described coating of one of claim 1-4, it is characterized in that, comprise following raw material by weight:
6. coating according to claim 5; It is characterized in that said 2,4 toluene diisocyanate modified polyvinyl alcohol prepares through following method: in polyvinyl alcohol water solution, add 2 under 23 ~ 85 ℃; 4-toluene diisocynate vinegar; Reacted at least 1 hour, and promptly obtained 2,4 toluene diisocyanate modified poly ethylene alcohol solution.
7. coating as claimed in claim 6 is characterized in that, said raw materials in part by weight is formed as follows:
Z 150PH 35 ~ 80
2,4 toluene diisocyanate 7 ~ 30
Water 720 ~ 950.
8. like claim 5 or 6 described coating, it is characterized in that said raw materials in part by weight is formed as follows:
Z 150PH 53 ~ 70
2,4 toluene diisocyanate 12 ~ 26
Water 800 ~ 900;
Or said raw materials in part by weight is formed as follows:
Z 150PH 60
2,4 toluene diisocyanate 23
Water 830.
9. like the described coating of one of claim 6-8, it is characterized in that described temperature of reaction is 30 ~ 80 ℃, further preferred 45 ~ 70 ℃, most preferably 65 ℃.
10. like the described coating of one of claim 6-9, it is characterized in that the described reaction times is 1 ~ 5h, further preferred 1.5 ~ 3h, most preferably 2h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101788925A CN102690566A (en) | 2012-06-01 | 2012-06-01 | Aqueous antistatic paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101788925A CN102690566A (en) | 2012-06-01 | 2012-06-01 | Aqueous antistatic paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102690566A true CN102690566A (en) | 2012-09-26 |
Family
ID=46856312
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012101788925A Pending CN102690566A (en) | 2012-06-01 | 2012-06-01 | Aqueous antistatic paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102690566A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104058694A (en) * | 2014-06-27 | 2014-09-24 | 无锡市崇安区科技创业服务中心 | Concrete material for road surface repair and construction method thereof |
| CN104403386A (en) * | 2014-12-16 | 2015-03-11 | 常熟市易安达电器有限公司 | Mineral comprehensive fallen-dust control box |
| CN108192428A (en) * | 2017-12-28 | 2018-06-22 | 青岛百川石墨有限公司 | Anti-static coatings and preparation method thereof |
| CN108504328A (en) * | 2018-03-29 | 2018-09-07 | 重庆渝茁科技有限公司 | Building heat preservation heat-barrier material hydrophober |
| CN109180895A (en) * | 2018-10-04 | 2019-01-11 | 南京航空航天大学溧水仿生产业研究院有限公司 | Bionical shell Materials with High Strength and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1389528A (en) * | 2002-06-21 | 2003-01-08 | 华南理工大学 | Water-thinned antistatic paint |
| CN1715350A (en) * | 2005-07-21 | 2006-01-04 | 浙江林学院 | Anti-static paint and its preparing method |
| CN101343497A (en) * | 2008-08-21 | 2009-01-14 | 上海正臣防腐科技有限公司 | Environment friendly corrosion protection antistatic coating |
| CN102372969A (en) * | 2010-08-20 | 2012-03-14 | 苏州美亚美建筑涂料有限公司 | Antistatic coating |
-
2012
- 2012-06-01 CN CN2012101788925A patent/CN102690566A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1389528A (en) * | 2002-06-21 | 2003-01-08 | 华南理工大学 | Water-thinned antistatic paint |
| CN1715350A (en) * | 2005-07-21 | 2006-01-04 | 浙江林学院 | Anti-static paint and its preparing method |
| CN101343497A (en) * | 2008-08-21 | 2009-01-14 | 上海正臣防腐科技有限公司 | Environment friendly corrosion protection antistatic coating |
| CN102372969A (en) * | 2010-08-20 | 2012-03-14 | 苏州美亚美建筑涂料有限公司 | Antistatic coating |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104058694A (en) * | 2014-06-27 | 2014-09-24 | 无锡市崇安区科技创业服务中心 | Concrete material for road surface repair and construction method thereof |
| CN104058694B (en) * | 2014-06-27 | 2016-01-13 | 无锡市崇安区科技创业服务中心 | A kind of concrete material for pavement patching and constructional method thereof |
| CN104403386A (en) * | 2014-12-16 | 2015-03-11 | 常熟市易安达电器有限公司 | Mineral comprehensive fallen-dust control box |
| CN108192428A (en) * | 2017-12-28 | 2018-06-22 | 青岛百川石墨有限公司 | Anti-static coatings and preparation method thereof |
| CN108504328A (en) * | 2018-03-29 | 2018-09-07 | 重庆渝茁科技有限公司 | Building heat preservation heat-barrier material hydrophober |
| CN108504328B (en) * | 2018-03-29 | 2020-11-03 | 重庆渝茁科技有限公司 | Water repellent for building heat-insulating material |
| CN109180895A (en) * | 2018-10-04 | 2019-01-11 | 南京航空航天大学溧水仿生产业研究院有限公司 | Bionical shell Materials with High Strength and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102690566A (en) | Aqueous antistatic paint | |
| CN102627903B (en) | Environment-friendly water-based static electricity conductive corrosion-resistant coating and preparation method thereof | |
| CN104387908A (en) | Graphene anti-static floor coating and preparation method thereof | |
| CN111454641A (en) | Aqueous single-component conductive coating for insulator and preparation method thereof | |
| CN106590400B (en) | A kind of graphene modified water-soluble conductive coating and preparation method thereof | |
| CN103073970B (en) | The preparation method of solvent-free anti-electrostatic antibiotic epoxy self-leveling floor coating | |
| CN100348682C (en) | Anti-static paint and its preparing method | |
| CN108976977B (en) | Graphene in-situ polymerization modified conductive anticorrosion aqueous adhesive emulsion and preparation method thereof | |
| CN1203144C (en) | Water-thinned antistatic paint | |
| CN102702892A (en) | Conducting paint composition and preparation method thereof | |
| CN102702918A (en) | Conductive coating composition and preparation method thereof | |
| CN103131319A (en) | Bi-component nanometer polyaniline-epoxy acrylic resin/polyurethane interpenetrating network electric conduction and antistatic coating and preparation method | |
| CN107266911B (en) | polyaniline-based composite material and preparation method and application thereof | |
| CN104341877A (en) | Novel fireproof coating | |
| CN103666208A (en) | Antistatic paint suitable for polyethylene materials and preparation method thereof | |
| CN104513394A (en) | Coal-based polyaniline and anti-corrosive paint | |
| CN103232597A (en) | 2-mercapto benzimidazole/polyaniline anticorrosion composite material and preparation method thereof | |
| CN113736342B (en) | Environment-friendly coating and preparation method thereof | |
| CN103483934B (en) | A kind of Low-cost anticorrosive antirust primer and preparation method thereof | |
| CN110776823A (en) | Modified polyurethane coating and preparation method thereof | |
| CN104830224A (en) | Polyethersulfone antistatic anticorrosive paint, and preparation method and application thereof | |
| CN101265339A (en) | Method for preparing formable conducting polyaniline composite material | |
| CN106147121B (en) | A kind of preparation method of antiseptic fire-retardation dragging and squeezing glass fiber reinforced plastics crane span structure | |
| CN105507558B (en) | A kind of Antistatic PVC plastic floor | |
| KR101590092B1 (en) | Coating composition for insulated electric wire using bottom ash |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20120926 |