CN102660749A - Phosphate-free degreasing agent - Google Patents

Phosphate-free degreasing agent Download PDF

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Publication number
CN102660749A
CN102660749A CN2012101383577A CN201210138357A CN102660749A CN 102660749 A CN102660749 A CN 102660749A CN 2012101383577 A CN2012101383577 A CN 2012101383577A CN 201210138357 A CN201210138357 A CN 201210138357A CN 102660749 A CN102660749 A CN 102660749A
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China
Prior art keywords
agent
phosphate
active agent
percent
tensio
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CN2012101383577A
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Chinese (zh)
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CN102660749B (en
Inventor
王伟
吴伏生
谢贇
杨维毅
郝赫
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SHENYANG PARKERIZING CO Ltd
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SHENYANG PARKERIZING CO Ltd
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Priority to CN201210138357.7A priority Critical patent/CN102660749B/en
Publication of CN102660749A publication Critical patent/CN102660749A/en
Application granted granted Critical
Publication of CN102660749B publication Critical patent/CN102660749B/en
Expired - Fee Related legal-status Critical Current
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Abstract

The invention provides a phosphate-free degreasing agent which is prepared through the components according to the following weight percents: 25 to 45 percent of carbonate, 30 to 50 percent of silicate, 10 to 25 percent of basic salt, 2 to 5 percent of chelating agent, and 5 to 10 percent of surface-active agent. The phosphate-free degreasing agent provided by the invention not only achieve the purpose of phosphate free, but also has the advantages of low using temperature, low foaming, high cleaning capability and the like.

Description

A kind of agent of non-phosphate degreasing
Technical field
The invention belongs to a kind of metallic material surface detergent, be specifically related to a kind of agent of non-phosphate degreasing.
Background technology
A large amount of grease-removing agents of selling on the market now are phosphorous grease-removing agent, and it can cause certain detrimentally affect to environment, and along with the day by day reinforcement of country to environment protection, using agent of non-phosphate degreasing is the first-selection of present most of enterprise.And the agent of non-phosphate degreasing that exists on the market mainly forms with highly basic and the assembly of exhibiting high surface promoting agent, also has the excessive problem of foam that thoroughly do not reach of cleaning.
Summary of the invention
The purpose of this invention is to provide a kind of agent of non-phosphate degreasing, easy control techniques requirement during use, cleansing power is strong, the generation foam is low.
Agent of non-phosphate degreasing provided by the invention, form by following substances in percentage by weight:
Carbonate 25 ~ 45%,
Silicate 30 ~ 50%,
Basic salt 10% ~ 25%,
Sequestrant 2 ~ 5%,
Tensio-active agent 5 ~ 10;
Wherein, Carbonate is the 1-2 kind in yellow soda ash, the sodium hydrogencarbonate; Water glass is the 1-2 kind of water glass, Starso; Basic salt is Pottasium Hydroxide or sodium hydroxide, and sequestrant is Sunmorl N 60S, EDTA Disodium or tetrasodium ethylenediamine tetraacetate, and tensio-active agent is low bubble property ethanol class surfactant B O-902 and alkyl polyoxyethylene polyethenoxy ether LG-299.
The preparation method of above-mentioned grease-removing agent is: in existing volume container, add component of inorganic salts according to part by weight and stir, add sequestrant and surface active agent composition again, integral body stirs and gets final product.
Advantage of the present invention is: easy control techniques requirement during use, and cleansing power is strong, and it is low to produce foam.
Embodiment
Embodiment 1:
Grease-removing agent is made up of following substances in percentage by weight:
Yellow soda ash 45%,
Starso 25%,
Sodium hydroxide 17%,
EDTA Disodium 5%,
Surfactant B O-902 5%,
Tensio-active agent LG-299 3%.
Above-mentioned low bubble property ethanol class surfactant B O-902 and alkyl polyoxyethylene polyethenoxy ether LG-299 are Ai Dike Shanghai trade Co., Ltd public offering product.
The preparation method is: in existing volume container, proportionally add component of inorganic salts and stir, add sequestrant and surface active agent composition again, integral body stirs and gets final product.
Embodiment 2
Grease-removing agent is made up of following substances in percentage by weight:
Yellow soda ash 35%,
Water glass 20%,
Starso 10%,
Sodium hydroxide 25%,
Tetrasodium ethylenediamine tetraacetate 3%,
Surfactant B O-902 4%,
Tensio-active agent LG-299 3%.
Preparing method: with embodiment 1.
Embodiment 3
Grease-removing agent is made up of following substances in percentage by weight:
Sodium hydrogencarbonate 25%,
Starso 42%,
Pottasium Hydroxide 24%,
Sunmorl N 60S 2%,
Surfactant B O-902 3%,
Tensio-active agent LG-299 4%.
Preparing method: with embodiment 1.
Embodiment 4
Grease-removing agent is made up of following substances in percentage by weight:
Yellow soda ash 30%,
Starso 36%,
Sodium hydroxide 20%,
Sunmorl N 60S 4%,
Surfactant B O-902 5%,
Tensio-active agent LG-299 5%.
Preparing method: with embodiment 1.
Embodiment 5
Grease-removing agent is made up of following substances in percentage by weight:
Yellow soda ash 30%,
Starso 35%,
Pottasium Hydroxide 24%,
Sunmorl N 60S 3%,
Surfactant B O-902 3%,
Tensio-active agent LG-299 5%.
Preparing method: with embodiment 1.
Embodiment 6
Grease-removing agent is made up of following substances in percentage by weight:
Yellow soda ash 20%,
Sodium hydrogencarbonate 10%,
Starso 35%,
Pottasium Hydroxide 24%,
Sunmorl N 60S 3%,
Surfactant B O-902 3%,
Tensio-active agent LG-299 5%.
With embodiment 1.
Experimental data
By the agent of non-phosphate degreasing product of the foregoing description preparation, clean the oil removing experiment in a large number according to the company standard of company, it is measured the result and all reaches more than 99%, meets the demands, and concrete data are following:
Figure 366171DEST_PATH_IMAGE001

Claims (1)

1. agent of non-phosphate degreasing is characterized in that being made up of following substances in percentage by weight:
Carbonate 25% ~ 45%,
Silicate 30% ~ 50%,
Basic salt 10% ~ 25%,
Sequestrant 2% ~ 5%,
Tensio-active agent 5% ~ 10%;
Wherein, Carbonate is the 1-2 kind in yellow soda ash, the sodium hydrogencarbonate; Water glass is the 1-2 kind of water glass, Starso; Basic salt is Pottasium Hydroxide or sodium hydroxide, and sequestrant is Sunmorl N 60S, EDTA Disodium or tetrasodium ethylenediamine tetraacetate, and tensio-active agent is low bubble property ethanol class surfactant B O-902 and alkyl polyoxyethylene polyethenoxy ether LG-299.
CN201210138357.7A 2012-05-08 2012-05-08 Phosphate-free degreasing agent Expired - Fee Related CN102660749B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201210138357.7A CN102660749B (en) 2012-05-08 2012-05-08 Phosphate-free degreasing agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201210138357.7A CN102660749B (en) 2012-05-08 2012-05-08 Phosphate-free degreasing agent

Publications (2)

Publication Number Publication Date
CN102660749A true CN102660749A (en) 2012-09-12
CN102660749B CN102660749B (en) 2014-02-12

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Country Status (1)

Country Link
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Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103205767A (en) * 2013-03-22 2013-07-17 沈阳帕卡濑精有限总公司 Non-phosphate two-component room temperature degreasing agent
CN104099621A (en) * 2014-06-24 2014-10-15 江门百得利包装材料有限公司 Weakly alkaline environment-friendly aluminum product surface degreasing agent and preparation method thereof
CN104233336A (en) * 2014-09-29 2014-12-24 无锡阳工机械制造有限公司 Dedicated alkaline rust removal liquid for nonferrous metals
CN104451752A (en) * 2014-11-19 2015-03-25 广东红日星实业有限公司 Oil removal powder for cleaning heavy oil stains and preparation method of oil removal powder
CN105755490A (en) * 2016-03-08 2016-07-13 湖南金裕环保科技有限公司 Normal-temperature phosphorus-free degreasing agent
CN106048632A (en) * 2016-07-04 2016-10-26 陈逸涵 Neutral non-phosphorus degreasing agent and preparation method thereof
CN106498421A (en) * 2016-09-23 2017-03-15 佛山市海明威生态科技有限公司 A kind of environmentally friendly double-component efficient cryogenic degreasing agent product and its production technology
CN106544684A (en) * 2016-09-28 2017-03-29 鞍钢未来钢铁研究院 A kind of cleaning surface of strip steel agent and its preparation and application
CN106811767A (en) * 2017-02-22 2017-06-09 李啸春 A kind of efficient degreasing agent and production method
CN106835166A (en) * 2016-12-02 2017-06-13 湖南德莱恩新材料科技有限公司 Low-temperature environment-friendly cleaning agent
CN107502453A (en) * 2017-07-25 2017-12-22 安徽胜利精密制造科技有限公司 A kind of notebook computer shell degreasing agent and application this degreasing agent progress ungrease treatment technique
CN108220979A (en) * 2017-12-29 2018-06-29 重庆全茂合渝科技有限公司 A kind of motorcycle double crosslinking gear shaft cleaning
CN108265308A (en) * 2018-03-12 2018-07-10 无锡市锡东橡塑机械有限公司 A kind of high-efficiency environment friendly degreasing agent and preparation method thereof and application method
CN108301007A (en) * 2018-03-12 2018-07-20 无锡市锡东橡塑机械有限公司 A kind of high-efficiency environment friendly steel tape degreasing agent and preparation method thereof and application method
CN108301008A (en) * 2018-03-12 2018-07-20 无锡市锡东橡塑机械有限公司 A kind of high-efficiency environment friendly Degreasant composition and preparation method thereof and application method
CN108505054A (en) * 2018-03-12 2018-09-07 无锡市锡东橡塑机械有限公司 A kind of high-efficiency environment friendly steel tape degreasing agent composition and preparation method thereof and application method
CN108707914A (en) * 2018-05-26 2018-10-26 厦门力九化工有限公司 A kind of agent of non-phosphate degreasing and preparation method thereof and application method
CN109267075A (en) * 2018-10-24 2019-01-25 上海优梓新材料科技有限公司 A kind of without phosphorus nitrogen-free industrial cleaning agent of environmental protection and energy saving
CN111793801A (en) * 2020-07-14 2020-10-20 沈阳帕卡濑精有限总公司 Acid pickling deslagging agent and preparation method and application thereof
CN113355679A (en) * 2021-04-15 2021-09-07 马鞍山佰斯予菲环保新材料科技有限公司 Environment-friendly degreasing agent and preparation method and application thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02219899A (en) * 1989-02-21 1990-09-03 Japan Organo Co Ltd Detergent
JP2005320598A (en) * 2004-05-10 2005-11-17 Nippon Paint Co Ltd Degreasing agent and degreasing method
CN1804130A (en) * 2006-01-11 2006-07-19 武汉钢铁(集团)公司 Cleaning agent for pretreatment of cold-rolling galvanization
CN101956200A (en) * 2010-11-03 2011-01-26 大连三达奥克化学股份有限公司 Non-phosphorus environment-friendly powdery degreasing agent and manufacturing method thereof
CN102002719A (en) * 2010-11-26 2011-04-06 张家港市森达外加剂有限公司 Low-temperature metal cleaning agent
CN102330102A (en) * 2011-10-17 2012-01-25 安徽师范大学 Phosphorus-free metal surface degreasing agent and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02219899A (en) * 1989-02-21 1990-09-03 Japan Organo Co Ltd Detergent
JP2005320598A (en) * 2004-05-10 2005-11-17 Nippon Paint Co Ltd Degreasing agent and degreasing method
CN1804130A (en) * 2006-01-11 2006-07-19 武汉钢铁(集团)公司 Cleaning agent for pretreatment of cold-rolling galvanization
CN101956200A (en) * 2010-11-03 2011-01-26 大连三达奥克化学股份有限公司 Non-phosphorus environment-friendly powdery degreasing agent and manufacturing method thereof
CN102002719A (en) * 2010-11-26 2011-04-06 张家港市森达外加剂有限公司 Low-temperature metal cleaning agent
CN102330102A (en) * 2011-10-17 2012-01-25 安徽师范大学 Phosphorus-free metal surface degreasing agent and preparation method thereof

Cited By (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103205767A (en) * 2013-03-22 2013-07-17 沈阳帕卡濑精有限总公司 Non-phosphate two-component room temperature degreasing agent
CN104099621A (en) * 2014-06-24 2014-10-15 江门百得利包装材料有限公司 Weakly alkaline environment-friendly aluminum product surface degreasing agent and preparation method thereof
CN104233336A (en) * 2014-09-29 2014-12-24 无锡阳工机械制造有限公司 Dedicated alkaline rust removal liquid for nonferrous metals
CN104451752A (en) * 2014-11-19 2015-03-25 广东红日星实业有限公司 Oil removal powder for cleaning heavy oil stains and preparation method of oil removal powder
CN105755490A (en) * 2016-03-08 2016-07-13 湖南金裕环保科技有限公司 Normal-temperature phosphorus-free degreasing agent
CN106048632A (en) * 2016-07-04 2016-10-26 陈逸涵 Neutral non-phosphorus degreasing agent and preparation method thereof
CN106498421A (en) * 2016-09-23 2017-03-15 佛山市海明威生态科技有限公司 A kind of environmentally friendly double-component efficient cryogenic degreasing agent product and its production technology
CN106544684A (en) * 2016-09-28 2017-03-29 鞍钢未来钢铁研究院 A kind of cleaning surface of strip steel agent and its preparation and application
CN106835166A (en) * 2016-12-02 2017-06-13 湖南德莱恩新材料科技有限公司 Low-temperature environment-friendly cleaning agent
CN106811767A (en) * 2017-02-22 2017-06-09 李啸春 A kind of efficient degreasing agent and production method
CN107502453A (en) * 2017-07-25 2017-12-22 安徽胜利精密制造科技有限公司 A kind of notebook computer shell degreasing agent and application this degreasing agent progress ungrease treatment technique
CN108220979A (en) * 2017-12-29 2018-06-29 重庆全茂合渝科技有限公司 A kind of motorcycle double crosslinking gear shaft cleaning
CN108265308A (en) * 2018-03-12 2018-07-10 无锡市锡东橡塑机械有限公司 A kind of high-efficiency environment friendly degreasing agent and preparation method thereof and application method
CN108301007A (en) * 2018-03-12 2018-07-20 无锡市锡东橡塑机械有限公司 A kind of high-efficiency environment friendly steel tape degreasing agent and preparation method thereof and application method
CN108301008A (en) * 2018-03-12 2018-07-20 无锡市锡东橡塑机械有限公司 A kind of high-efficiency environment friendly Degreasant composition and preparation method thereof and application method
CN108505054A (en) * 2018-03-12 2018-09-07 无锡市锡东橡塑机械有限公司 A kind of high-efficiency environment friendly steel tape degreasing agent composition and preparation method thereof and application method
CN108707914A (en) * 2018-05-26 2018-10-26 厦门力九化工有限公司 A kind of agent of non-phosphate degreasing and preparation method thereof and application method
CN109267075A (en) * 2018-10-24 2019-01-25 上海优梓新材料科技有限公司 A kind of without phosphorus nitrogen-free industrial cleaning agent of environmental protection and energy saving
CN111793801A (en) * 2020-07-14 2020-10-20 沈阳帕卡濑精有限总公司 Acid pickling deslagging agent and preparation method and application thereof
CN111793801B (en) * 2020-07-14 2022-10-14 沈阳帕卡濑精有限总公司 Acid pickling deslagging agent and preparation method and application thereof
CN113355679A (en) * 2021-04-15 2021-09-07 马鞍山佰斯予菲环保新材料科技有限公司 Environment-friendly degreasing agent and preparation method and application thereof

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