Summary of the invention
The invention provides a kind of tower side line vapour phase and extract the device and method controlling gasoline blending component and do out, adopt multitower to carry out removing and cause the problems such as energy consumption is higher, floor space is comparatively large, investment is higher in order to overcome prior art.
For achieving the above object, the invention provides a kind of tower side line vapour phase and extracting the device controlling gasoline blending component and do out, comprising: weight-removing column, First Heat Exchanger, the second interchanger, the 3rd interchanger and return tank, wherein
First Heat Exchanger is connected with weight-removing column, and stable gasoline enters weight-removing column after First Heat Exchanger heating;
The overhead line of weight-removing column is connected with the second interchanger, second interchanger is connected with return tank by pipeline, return tank is connected with the first discharging pump, the light constituent of tower top enters return tank after overhead line also heat exchange cooling occurs in the second heat exchanger, cooled a part of light constituent is back to weight-removing column tower top through the first discharging pump, and rest part is as output of products;
Weight-removing column rectifying section side line and/or stripping section side line are connected with the 3rd interchanger, First Heat Exchanger successively, rectifying section sidedraw plate and/or stripping section sidedraw plate are provided with point for measuring temperature, control according to the temperature variation of point for measuring temperature the flow extracting gasoline blending component from rectifying section liquid phase and/or stripping section vapour phase, extract gasoline blending component out and export after the 3rd interchanger, First Heat Exchanger heat exchange cooling;
Be provided with the second discharging pump at the bottom of the tower of weight-removing column, the heavy constituent removed exports through the second discharging pump.
Further, overhead line is connected with one or more pipeline, one or more pipeline is connected with the overhead line before return tank after heating equipment.
Further, the second interchanger and the 3rd interchanger pass into coolant media respectively.
Further, the tower top pressure of weight-removing column is 0.05 ~ 15.0MPaG, and tower top temperature is 150 ~ 280 DEG C.
Further, said apparatus also comprises:
Other heating equipment, between being connected at the bottom of the export pipeline of the second discharging pump and the tower of weight-removing column, is delivered to weight-removing column using after a part of heavy constituent heating as thermal source.
For achieving the above object, present invention also offers a kind of tower side line vapour phase and extract the method controlling gasoline blending component and do out, the method comprises the following steps:
Stable gasoline is sent into weight-removing column after First Heat Exchanger heating, and wherein First Heat Exchanger is connected with weight-removing column;
The light constituent of tower top is sent into return tank after overhead line also heat exchange cooling occurs in the second heat exchanger, cooled a part of light constituent is back to weight-removing column tower top through the first discharging pump, rest part is as output of products, wherein the overhead line of weight-removing column is connected with the second interchanger, second interchanger is connected with return tank, and return tank is connected with the first discharging pump;
The flow extracting gasoline blending component from rectifying section liquid phase and/or stripping section vapour phase is controlled according to the temperature variation of point for measuring temperature on rectifying section sidedraw plate and/or stripping section sidedraw plate, extract gasoline blending component out to export after the 3rd interchanger, First Heat Exchanger heat exchange cooling, wherein weight-removing column rectifying section side line and/or stripping section side line are connected with the 3rd interchanger, First Heat Exchanger successively;
The heavy constituent removed is exported through the second discharging pump be arranged at the bottom of weight-removing column tower.
Further, overhead line is connected with one or more pipeline, one or more pipeline is connected with the overhead line before return tank after heating equipment.
Further, the second interchanger and the 3rd interchanger pass into coolant media respectively.
Further, the tower top pressure of weight-removing column is 0.05 ~ 15.0MPaG, and tower top temperature is 150 ~ 280 DEG C.
Further, aforesaid method is further comprising the steps of:
Weight-removing column is delivered to as thermal source after the heating equipment between at the bottom of the tower of the export pipeline and weight-removing column of a part of heavy constituent through being connected to the second discharging pump heats.
In the above-described embodiments, control gasoline blending component by single tower to do, equipment institute floor space is less, it is less to invest, simultaneously by making full use of the heat energy that each component is carried, reduce the energy consumption of device, and control to extract gasoline blending component out according to the extraction plate temperature change that the point for measuring temperature that sidedraw plate is arranged detects to do, gasoline blending component yield is higher.
Embodiment
Below in conjunction with the accompanying drawing in the embodiment of the present invention, be clearly and completely described the technical scheme in the embodiment of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not paying the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Fig. 2 is that the tower side line vapour phase of one embodiment of the invention extracts the schematic flow sheet controlling gasoline blending component and do out.As shown in Figure 2, this device comprises: weight-removing column 201, First Heat Exchanger 202, second interchanger 203, the 3rd interchanger 205 and return tank 204, wherein
First Heat Exchanger 202 is connected with weight-removing column 201, and stable gasoline enters weight-removing column 201 after First Heat Exchanger 202 heats;
The overhead line of weight-removing column 201 is connected with the second interchanger 203, second interchanger 203 is connected with return tank 204, return tank 204 is connected with the first discharging pump 208, the light constituent of tower top through overhead line and occur in the second interchanger 203 heat exchange cooling after enter return tank 204, cooled a part of light constituent is back to weight-removing column 201 tower top after the first discharging pump 208, and rest part is as output of products;
Weight-removing column rectifying section side line (selecting whether to arrange according to the distribution situation of gasoline blending component in weight-removing column) and/or stripping section side line are connected with the 3rd interchanger 205, First Heat Exchanger 202 successively, rectifying section sidedraw plate and/or stripping section sidedraw plate are provided with point for measuring temperature, control according to the temperature variation of point for measuring temperature the flow extracting gasoline blending component from rectifying section liquid phase and/or stripping section vapour phase, extract gasoline blending component out and export after the 3rd interchanger 205, First Heat Exchanger 202 heat exchange cooling;
Be provided with the second discharging pump 207 at the bottom of the tower of weight-removing column 201, the heavy constituent removed exports through the second discharging pump 207.
In fig. 2, arrow B 1 is stable gasoline, and arrow B 2 is that the 3rd interchanger changes thermogenetic steam, arrow B 3 is de-oxygenised water, and arrow B 6 is that the second interchanger changes thermogenetic steam, and arrow B 7 is de-oxygenised water, arrow B 10 is light constituent, and arrow B 11 is heavy constituent, and arrow B 12 is gasoline blending component.
In the above-described embodiments, control gasoline blending component by single tower to do, equipment institute floor space is less, it is less to invest, simultaneously by making full use of the heat energy that each component is carried, reduce the energy consumption of device, and control to extract gasoline blending component out according to the extraction plate temperature change that the point for measuring temperature that sidedraw plate is arranged detects to do, gasoline blending component yield is higher.
Such as, the heat energy that the light constituent flowed out for making full use of tower top carries, overhead line is connected with one or more pipeline, one or more pipeline is connected with the overhead line before return tank after heating equipment, the heat energy that light constituent is carried as miscellaneous equipment thermal source and produce low-pressure steam, reach energy-conservation object.As heating equipment 1 is gone in arrow B in Fig. 24 instruction, heating equipment 2 is gone in arrow B 5 instruction, and arrow B 8, B9 instruction returns overhead line by heating equipment 1,2.
Such as, the second interchanger and the 3rd interchanger pass into coolant media (as deaerated water), respectively there is steam.
For ensureing the quality requirements of overhead stream, according to different cut split requirements or overhead product requirement, can select different temperature, pressure control strategy, such as, the tower top pressure of weight-removing column can be 0.05 ~ 15.0MPaG, and tower top temperature is 150 ~ 280 DEG C.
The gasoline component of C8 aromatic hydrocarbons and heavy aromatics component is rich in continuous catalytic reforming, does and does not meet Standard, can apply the present invention and produce qualified gasoline blending component.Illustrative example is given technology provided by the present invention and being further illustrated below, but not thereby limiting the invention.
Continuous catalytic reforming device is rich in the gasoline component of C8 aromatic hydrocarbons and heavy aromatics component, need to produce the gasoline blending component meeting national standard and require, tower top produces C8 aromatic hydrocarbons, and stripping section side line vapour phase extracts gasoline blending component out, is the heavy aromatics component affecting gasoline endpoint removed at the bottom of tower.When being rich in C8 aromatic hydrocarbons and heavy aromatics component streams for the treatment of continuous catalytic reforming device, weight-removing column operational condition can design within the scope of tower top pressure 0.05 ~ 15.0MPaG and tower top temperature 150 ~ 280 DEG C.Now illustrate with example, weight-removing column feed stream composition is as table 1.
Table 1
Feed composition |
Composition (wt%) |
Toluene |
0.18 |
C8 alkane |
0.01 |
C8 aromatic hydrocarbons |
49.87 |
C9 alkane |
0.05 |
C9 aromatic hydrocarbons |
37.11 |
C9 cycloalkanes |
0.15 |
C10 aromatic hydrocarbons |
12.09 |
C11 aromatic hydrocarbons |
0.34 |
C12+ |
0.20 |
Add up to |
100.00 |
It is as shown in table 2 that the material balance needed is separated task, produces qualified C8 aromatic hydrocarbons and gasoline blending component.
Table 2
Charging |
Flow (kg/hr) |
Product |
Flow (kg/hr) |
Reformation C8+ component |
121104.20 |
C8 aromatic hydrocarbons |
59625.00 |
|
|
Gasoline blending component |
60995.50 |
|
|
Heavy aromatics |
483.70 |
Add up to |
121104.20 |
Add up to |
121104.20 |
Adopt the inventive method processing list 1 constitutive material, complete table 2 when requiring, the processing condition of weight-removing column are: inlet amount 121104.2kg/hr, tower top working pressure 0.526MPaG, tower top temperature 224.10 DEG C, tower top C8 aromatic hydrocarbons flow 59625kg/hr, gasoline blending component is from the 91st laminate (totally 101 layers of tower tray, from up to down number) top vapour phase extraction, extract gasoline blending composition flow rate 60995.5kg/hr out, do 199.64 DEG C.
And adopt traditional process processing list 1 constitutive material, complete table 2 when requiring, need two towers, C8 aromatic hydrocarbons tower (i.e. lightness-removing column amounts to 94 layers of column plate) and weight-removing column (altogether 38 layers of column plate).First raw material enters C8 aromatic hydrocarbons tower, and tower top obtains C8 aromatic hydrocarbons, and tower base stream is done 206.3 DEG C and exceeded Standard, as weight-removing column charging; Weight-removing column top obtains qualified gasoline blending component, is the heavy aromatics component affecting gasoline endpoint at the bottom of tower.C8 aromatic hydrocarbons tower inlet amount 121104.2kg/hr, tower top working pressure 0.526MPaG, tower top temperature 224.10 DEG C, tower top C8 aromatic hydrocarbons flow 59625kg/hr; Weight-removing column top working pressure 0.13MPaG, tower top temperature 217.40 DEG C, top gasoline blending composition flow rate 60995.5kg/hr, does 199.32 DEG C.
Above-mentioned two kinds of flow processs contrast situation is as shown in table 3:
Table 3
Such as, said apparatus also comprises: process furnace 206, between being connected at the bottom of the export pipeline of the second discharging pump 207 and the tower of weight-removing column 201, is delivered to weight-removing column using after a part of heavy aromatics component heating as thermal source.
Below for tower side line vapour phase extracts the method controlling gasoline blending component and do out, comprise the following steps:
Stable gasoline is sent into weight-removing column after First Heat Exchanger heating, and wherein First Heat Exchanger is connected with weight-removing column;
The light constituent of tower top is sent into return tank after overhead line also heat exchange cooling occurs in the second heat exchanger, cooled a part of light constituent is back to weight-removing column tower top through the first discharging pump, rest part is as output of products, wherein the overhead line of weight-removing column is connected with the second interchanger, second interchanger is connected with return tank, and return tank is connected with the first discharging pump;
Control (to select according to the distribution situation of gasoline blending component weight-removing column from rectifying section liquid phase according to the temperature variation of point for measuring temperature on rectifying section sidedraw plate and/or stripping section sidedraw plate, if need to extract a part from rectifying section liquid phase) and/or stripping section vapour phase extract the flow of gasoline blending component, extract gasoline blending component out through the 3rd interchanger, export after First Heat Exchanger heat exchange cooling, wherein weight-removing column rectifying section side line (selecting whether to arrange according to the distribution situation of gasoline blending component in weight-removing column) and/or stripping section side line successively with the 3rd interchanger, First Heat Exchanger is connected,
The heavy constituent removed is exported through the second discharging pump be arranged at the bottom of weight-removing column tower.
Such as, the heat energy that the light constituent flowed out for making full use of tower top carries, overhead line is connected with one or more pipeline, one or more pipeline is connected with the overhead line before return tank after heating equipment, the heat energy that light constituent is carried as miscellaneous equipment thermal source and produce low-pressure steam, reach energy-conservation object.As heating equipment 1 is gone in arrow B in Fig. 24 instruction, heating equipment 2 is gone in arrow B 5 instruction, and arrow B 8, B9 instruction returns overhead line by heating equipment 1,2.
Such as, the second interchanger and the 3rd interchanger pass into coolant media (as deaerated water), respectively there is steam.
For ensureing the quality requirements of overhead stream, according to different cut split requirements or overhead product requirement, can select different temperature, pressure control strategy, such as, the tower top pressure of weight-removing column can be 0.05 ~ 15.0MPaG, and tower top temperature is 150 ~ 280 DEG C.
Such as, aforesaid method is further comprising the steps of:
Weight-removing column is delivered to as thermal source after the heating equipment between at the bottom of the tower of the export pipeline and weight-removing column of a part of heavy constituent through being connected to the second discharging pump heats.
As can be seen from above-described embodiment, present invention achieves following beneficial effect:
(1) traditional double tower scheme general facilities consume and equipment number of units more than single tower scheme, cause energy consumption about increase by 8% and production cost about increase by 10%;
(2) traditional double tower planning device number of units is more than single tower scheme, and floor space approximately increases by 30%;
(3) each specialized material such as traditional double tower planning device number of units, occupation of land, pipeline, instrument, framework, cable is more than single tower scheme, and causing investing approximately increases by 24%;
Visible, above-described embodiment controls gasoline blending component by single tower and does, equipment institute floor space is less, it is less to invest, simultaneously by making full use of the heat energy that each component is carried, reduce the energy consumption of device, and control to extract gasoline blending component out according to the extraction plate temperature change that the point for measuring temperature that sidedraw plate is arranged detects to do, gasoline blending component yield is higher.
One of ordinary skill in the art will appreciate that: accompanying drawing is the schematic diagram of an embodiment, the module in accompanying drawing or flow process might not be that enforcement the present invention is necessary.
One of ordinary skill in the art will appreciate that: the module in the device in embodiment can describe according to embodiment and be distributed in the device of embodiment, also can carry out respective change and be arranged in the one or more devices being different from the present embodiment.The module of above-described embodiment can merge into a module, also can split into multiple submodule further.
Last it is noted that above embodiment is only in order to illustrate technical scheme of the present invention, be not intended to limit; Although with reference to previous embodiment to invention has been detailed description, those of ordinary skill in the art is to be understood that: it still can be modified to the technical scheme described in previous embodiment, or carries out equivalent replacement to wherein portion of techniques feature; And these amendments or replacement, do not make the essence of appropriate technical solution depart from the spirit and scope of embodiment of the present invention technical scheme.