CN102643583A - Environment-friendly benzene-free painting and synthetic method thereof - Google Patents
Environment-friendly benzene-free painting and synthetic method thereof Download PDFInfo
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- CN102643583A CN102643583A CN201110170951XA CN201110170951A CN102643583A CN 102643583 A CN102643583 A CN 102643583A CN 201110170951X A CN201110170951X A CN 201110170951XA CN 201110170951 A CN201110170951 A CN 201110170951A CN 102643583 A CN102643583 A CN 102643583A
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Abstract
The invention relates to an environment-friendly benzene-free painting and a synthetic method thereof. The painting is formed by mixing an oil paint component with a diluting agent component according to the weight ratio being 100:(40-60); the oil paint component comprises the following components in parts by weight: 18-42 parts of acrylic resin, 4-15 parts of additive resin, 28-45 parts of organic pigment and 15-35 parts of solvent; and the diluting agent component comprises the following components in parts by weight: 40-70 parts of propylene glycol methyl ether acetate, 15-45 parts of n-butyl alcohol and 5-25 parts of n-butyl acetate. Compared with the prior art, the environment-friendly benzene-free painting disclosed by the invention has the advantages that the performances of products are excellent; the environment-friendly benzene-free painting can be used for spraying metal cross-linked by high temperature and is wide in application range; and especially, the environment-friendly benzene-free painting has no benzene substances and belongs to a general product of an environment-friendly benzene painting.
Description
Technical field
The present invention relates to a kind of coating and compound method thereof, especially relating to a kind of environment-friendly type does not have benzene coating and compound method thereof.
Background technology
Benzene (toluene, YLENE, trimethylbenzene, durene) is a kind of colourless, gas with special aromatic odour.Glue, paint, coating and tamanori are the main sources of benzene in air.Benzene and benzene series thing the cns anesthetic action can occur after being sucked by human body; Can suppress the human body hemopoietic function, make red blood corpuscle, white cell, thrombopenia, aplastic anemia trouble rate increases; Also can cause women's irregular menstruation, the birth defects of fetus etc.General in the market benzene painting majority is latex coating (water-based), and in the industrial high temperature lacquer system, environmental protection does not have benzene coating and monopolizes by European countries at home.This coating is through the high-temperature cross-linking filmogen by vinyl resin collocation aminoresin.Environmental protection does not have the benzene coating products and can be used for metal substrate external coatings such as aluminium wheel hub, medical machinery, electrical equipment.But, because the high temperature of domestic production paint benzol content does not all reach international standard, both can't with Japan and American-European competition among enterprises thereof, do not meet the slogan that " low-carbon environment-friendly " advocated in the world yet, restricted the development of domestic paint national industry greatly.
Summary of the invention
The object of the invention is exactly to provide a kind of not containing benezene material, extensive, the environmentally friendly environment-friendly type of the scope of application not to have benzene coating and compound method thereof for the defective that overcomes above-mentioned prior art existence.
The object of the invention can be realized through following technical scheme:
A kind of environment-friendly type does not have benzene coating, it is characterized in that, this coating by paint component and thinner composition by weight being 100: (40～60) are mixed and are obtained;
Described paint component comprises following composition and weight part content:
Vinyl resin 18～42, additive resin 4～15, pigment dyestuff 28～45, solvent 15～35;
Described thinner composition comprises following composition and weight part content:
1-Methoxy-2-propyl acetate 40～70, propyl carbinol 15～45, N-BUTYL ACETATE 5～25.
Form and weight part content below described paint component is preferred: vinyl resin 20～40, additive resin 5～10, pigment dyestuff 30～40, solvent 20～30.
Described additive resin is selected from one or more in acrylic acid modified alkyd resin or the epoxy resin.
Described pigment dyestuff is a rust-stabilising pigment, is selected from organic amido black, organic quinoline peptide ketone pigment, in the machine perylene grain or the organic pair of pyrrole pigment one or both are arranged.
Described solvent is selected from one or both in MIBK, mixing acid dimethyl ester, 1-Methoxy-2-propyl acetate or the propyl carbinol.
Form and weight part content below described thinner composition is preferred: 1-Methoxy-2-propyl acetate 50～60, propyl carbinol 25～40, N-BUTYL ACETATE 10～15.
A kind of environment-friendly type does not have the compound method of benzene coating, it is characterized in that, this method may further comprise the steps:
(1) paint component is synthetic
A, get the raw materials ready according to following composition and weight part content:
Vinyl resin 18～42, additive resin 4～15, pigment dyestuff 28～45, solvent 15～35;
B, by prescription requirements earlier with in whole solvents input reaction kettles, and be heated to 20～40 ℃ and stir;
C, maintenance are stirred and vinyl resin are dropped in the reaction kettle stirring and dissolving 1～2.5h successively;
D, treat that vinyl resin dissolves fully after, additive resin is slowly dropped in the reaction kettle and continues stirring and dissolving;
E, after all solids dissolving and mixing, grind after pigment dyestuff stirs to wherein dropping into, and adjustment viscosity is to the qualified paint component that promptly obtains;
(2) thinner composition is synthetic
A, get the raw materials ready according to following composition and weight part content:
1-Methoxy-2-propyl acetate 40～70, propyl carbinol 15～45, N-BUTYL ACETATE 5～25;
B, by the prescription requirement propyl carbinol is dropped in the reaction kettle;
C, maintenance are stirred, and 1-Methoxy-2-propyl acetate and N-BUTYL ACETATE are dropped in the reaction kettle, continue to stir 0.5～1h dissolving extremely fully;
After d, said components are dissolved fully, stop to stir, the moisture content that detects wherein is the qualified thinner composition that promptly obtains;
(3) environment-friendly type does not have the synthetic of benzene coating
With paint component and thinner composition by weight being 100: mix (40～60), and controlled temperature is 130～180 ℃, mixes 20～40min, and promptly obtaining environment-friendly type does not have benzene coating.
Adjustment viscosity to qualified viscosity >=120 second in the step (1)/25 ℃ are coated with-4 glasss.
Moisture content is qualified moisture content≤0.03wt% in the step (2).
Compared with prior art, excellent product performance of the present invention: hardness>=2H, 0～1 grade of sticking power; Tanned by the sun 24 months in Hainan; After polishing, loss of gloss rate≤10-%, Δ E≤31000h should reach the level of tanning by the sun 24 months; Xenon lamp artificial accelerated aging: non-foaming, not efflorescence, non-corrosive, do not ftracture aberrations Δ E≤3.0 temperature-change resistances: (90 ℃～-40 ℃) do not have cracking.Humidity resistance (40 ℃, 480h) no change also has the following advantages in addition:
(1) the present invention can spray through hot crosslinked metal (iron material, phosphatization iron material, aluminium, copper material, zinc-plated phosphoric acid material, stainless steel); And can be used in aluminium wheel hub, medical machinery, lamp decoration, bike, plated item, DVD, surface metal applications such as microwave oven;
(2) scope of application is wider, in the temperature environment more than 10 ℃, can use;
(3) raw materials cost of the present invention's employing is lower, does not especially contain benzene class material, belongs to environmental protection benzene-free type coating, and belongs to the general purpose grade product, has wide range of applications.
Embodiment
Below in conjunction with specific embodiment the present invention is elaborated.
Embodiment 1
A kind of environment-friendly type does not have benzene coating and preparation method thereof, and this method comprises following process step:
A: paint component synthetic
(1), promptly in 15 kilograms of MIBKs, 20 kilograms of input reaction kettles of propyl carbinol, and is heated to 40 ℃ and stirs earlier with whole solvents;
(2) keep stirring and 40 kilograms of vinyl resins, epoxy resin being dropped in the reaction kettle as 5 kilograms of additive resins successively, stirred 1 hour;
(3) to be mixedly slowly drop in the reaction kettle acrylic acid modified alkyd resin for 10 kilograms after evenly;
(4) after all solids dissolving and mixing, shut down slaking more than 12 hours;
(5) measure solid content, and be adjusted to theoretical value, make solids content >=50wt%;
(6) drop into rust-stabilising pigment, grind after stirring;
(7) to the discharging of the qualified back of fineness, with 1-Methoxy-2-propyl acetate adjustment viscosity to qualified, the viscosity requirement is coated with-4 glasss for >=120 seconds/25 ℃, promptly obtains paint component, weighing and bagging.
B: thinner composition synthetic
(1) first by the prescription requirement with in 15 kilograms of input reaction kettles of positive butyl ester solvent;
(2) keep stirring and 70 kilograms of 1-Methoxy-2-propyl acetates, N-BUTYL ACETATE to drop in the reaction kettle stirring and dissolving 0.5～1 hour for 15 kilograms successively;
(3) stop after waiting to dissolve stirring, detect and contain admittedly, and be adjusted to theoretical value, promptly obtain thinner composition, weighing and bagging.
C: environment-friendly type does not have the synthetic of benzene coating
By weight being to mix at 100: 50, controlled temperature is 150 ℃, mixes 30min with paint component and thinner composition, and promptly obtaining environment-friendly type does not have benzene coating.
Embodiment 2
A kind of environment-friendly type does not have the preparation method of benzene coating, and this method comprises following process step:
A: paint component synthetic
(1), promptly in 15 kilograms of MIBKs, 15 kilograms of input reaction kettles of propyl carbinol, and is heated to about 40 ℃ and stirs earlier with whole solvents;
(2) keep stirring and 20 kilograms in vinylformic acid, additive resin being dropped in the reaction kettle for 10 kilograms successively, stirred 1 hour;
(3) to be mixedly slowly drop in the reaction kettle acrylic acid modified alkyd resin for 5 kilograms after evenly;
(4) after all solids dissolving and mixing, shut down slaking more than 12 hours;
(5) measure solid content, and be adjusted to theoretical value;
(6) drop into rust-stabilising pigment and auxiliary agent, grind after stirring;
(7) to the discharging of the qualified back of fineness, with 1-Methoxy-2-propyl acetate adjustment viscosity to qualified, the viscosity requirement is coated with-4 glasss for >=120 seconds/25 ℃, promptly obtains paint component, weighing and bagging.
B: thinner composition synthetic
(1) first by the prescription requirement with in 70 kilograms of input reaction kettles of 1-Methoxy-2-propyl acetate solvent;
(2) keep stirring and 15 kilograms of propyl carbinols, N-BUTYL ACETATE to drop in the reaction kettle stirring and dissolving 0.5 hour for 15 kilograms successively;
(3) stop after waiting to dissolve stirring, detect and contain admittedly, and be adjusted to theoretical value, promptly obtain thinner composition, weighing and bagging.
C: environment-friendly type does not have the synthetic of benzene coating
By weight being to mix at 100: 55, controlled temperature is 140 ℃, mixes 30min with paint component and thinner composition, and promptly obtaining environment-friendly type does not have benzene coating.
Embodiment 3
A kind of environment-friendly type does not have the compound method of benzene coating, and this method may further comprise the steps:
(1) paint component is synthetic
A, get the raw materials ready according to following composition and content:
Vinyl resin 18kg, additive resin 4kg, pigment dyestuff 28kg, solvent 15kg; Wherein additive resin is acrylic acid modified alkyd resin; What pigment dyestuff adopted is the organic amido black of rust-stabilising pigment, and solvent is selected MIBK and mixing acid dimethyl ester mixture for use;
B, by prescription requirements earlier with in whole solvents input reaction kettles, and be heated to 20 ℃ and stir;
C, maintenance are stirred and vinyl resin are dropped in the reaction kettle stirring and dissolving 1h successively;
D, treat that vinyl resin dissolves fully after, additive resin is slowly dropped in the reaction kettle and continues stirring and dissolving;
E, after all solids dissolving and mixing, grind after pigment dyestuff stirs to wherein dropping into, and adjustment viscosity >=120 second/25 ℃ are coated with-4 glasss and promptly obtain paint component;
(2) thinner composition is synthetic
A, get the raw materials ready according to following composition and content:
1-Methoxy-2-propyl acetate 40kg, propyl carbinol 15kg, N-BUTYL ACETATE 5kg;
B, by the prescription requirement propyl carbinol is dropped in the reaction kettle;
C, maintenance are stirred, and 1-Methoxy-2-propyl acetate and N-BUTYL ACETATE are dropped in the reaction kettle, continue to stir 0.5h dissolving extremely fully;
After d, said components are dissolved fully, stop to stir, detect moisture content≤0.03wt% wherein, promptly obtain thinner composition;
(3) environment-friendly type does not have the synthetic of benzene coating
By weight being to mix at 100: 40, controlled temperature is 130 ℃, mixes 40min with paint component and thinner composition, and promptly obtaining environment-friendly type does not have benzene coating.
Embodiment 4
A kind of environment-friendly type does not have the compound method of benzene coating, and this method may further comprise the steps:
(1) paint component is synthetic
A, get the raw materials ready according to following composition and content:
Vinyl resin 20kg, additive resin 5kg, pigment dyestuff 30kg, solvent 20kg wherein add
Adding the agent resin is epoxy resin, and what pigment dyestuff adopted is the organic amido black of rust-stabilising pigment and organic quinoline peptide ketone pigment
Hybrid pigment, solvent is selected 1-Methoxy-2-propyl acetate for use;
B, by prescription requirements earlier with in whole solvents input reaction kettles, and be heated to 30 ℃ and stir;
C, maintenance are stirred and vinyl resin are dropped in the reaction kettle stirring and dissolving 2h successively;
D, treat that vinyl resin dissolves fully after, additive resin is slowly dropped in the reaction kettle and continues to stir
Mix dissolving;
E, after all solids dissolving and mixing, grind after pigment dyestuff stirs to wherein dropping into
Mill, and adjustment viscosity >=120 second/25 ℃ are coated with-4 glasss and promptly obtain paint component;
(2) thinner composition is synthetic
A, get the raw materials ready according to following composition and content:
1-Methoxy-2-propyl acetate 50kg, propyl carbinol 25kg, N-BUTYL ACETATE 10kg;
B, by the prescription requirement propyl carbinol is dropped in the reaction kettle;
C, maintenance are stirred, and 1-Methoxy-2-propyl acetate and N-BUTYL ACETATE are dropped in the reaction kettle, continue to stir 1h dissolving extremely fully;
After d, said components are dissolved fully, stop to stir, detect moisture content≤0.03wt% wherein, promptly obtain thinner composition;
(3) environment-friendly type does not have the synthetic of benzene coating
By weight being to mix at 100: 40, controlled temperature is 180 ℃, mixes 20min with paint component and thinner composition, and promptly obtaining environment-friendly type does not have benzene coating.
Embodiment 5
A kind of environment-friendly type does not have the compound method of benzene coating, and this method may further comprise the steps:
(1) paint component is synthetic
A, get the raw materials ready according to following composition and content:
Vinyl resin 40kg, additive resin 10kg, pigment dyestuff 40kg, solvent 30kg, wherein additive resin is an epoxy resin, and what pigment dyestuff adopted is rust-stabilising pigment You Ji perylene grain and the organic pair of hybrid pigment that pyrrole pigment constitutes, and solvent is selected propyl carbinol for use;
B, by prescription requirements earlier with in whole solvents input reaction kettles, and be heated to 30 ℃ and stir;
C, maintenance are stirred and vinyl resin are dropped in the reaction kettle stirring and dissolving 2h successively;
D, treat that vinyl resin dissolves fully after, additive resin is slowly dropped in the reaction kettle and continues stirring and dissolving;
E, after all solids dissolving and mixing, grind after pigment dyestuff stirs to wherein dropping into, and adjustment viscosity >=120 second/25 ℃ are coated with-4 glasss and promptly obtain paint component;
(2) thinner composition is synthetic
A, get the raw materials ready according to following composition and content:
1-Methoxy-2-propyl acetate 60kg, propyl carbinol 40kg, N-BUTYL ACETATE 15kg;
B, by the prescription requirement propyl carbinol is dropped in the reaction kettle;
C, maintenance are stirred, and 1-Methoxy-2-propyl acetate and N-BUTYL ACETATE are dropped in the reaction kettle, continue to stir 0.5h dissolving extremely fully;
After d, said components are dissolved fully, stop to stir, detect moisture content≤0.03wt% wherein, promptly obtain thinner composition;
(3) environment-friendly type does not have the synthetic of benzene coating
By weight being to mix at 100: 40, controlled temperature is 180 ℃, mixes 20min with paint component and thinner composition, and promptly obtaining environment-friendly type does not have benzene coating.
Embodiment 6
A kind of environment-friendly type does not have the compound method of benzene coating, and this method may further comprise the steps:
(1) paint component is synthetic
A, get the raw materials ready according to following composition and content:
Vinyl resin 42kg, additive resin 15kg, pigment dyestuff 45kg, solvent 35kg, wherein additive resin is an epoxy resin, and what pigment dyestuff adopted is the hybrid pigment that organic pair of pyrrole pigment constitutes, and solvent is selected propyl carbinol for use;
B, by prescription requirements earlier with in whole solvents input reaction kettles, and be heated to 40 ℃ and stir;
C, maintenance are stirred and vinyl resin are dropped in the reaction kettle stirring and dissolving 2.5h successively;
D, treat that vinyl resin dissolves fully after, additive resin is slowly dropped in the reaction kettle and continues stirring and dissolving;
E, after all solids dissolving and mixing, grind after pigment dyestuff stirs to wherein dropping into, and adjustment viscosity >=120 second/25 ℃ are coated with-4 glasss and promptly obtain paint component;
(2) thinner composition is synthetic
A, get the raw materials ready according to following composition and content:
1-Methoxy-2-propyl acetate 70kg, propyl carbinol 45kg, N-BUTYL ACETATE 25kg;
B, by the prescription requirement propyl carbinol is dropped in the reaction kettle;
C, maintenance are stirred, and 1-Methoxy-2-propyl acetate and N-BUTYL ACETATE are dropped in the reaction kettle, continue to stir 1h dissolving extremely fully;
After d, said components are dissolved fully, stop to stir, detect moisture content≤0.03wt% wherein, promptly obtain thinner composition;
(3) environment-friendly type does not have the synthetic of benzene coating
By weight being to mix at 100: 60, controlled temperature is 180 ℃, mixes 20min with paint component and thinner composition, and promptly obtaining environment-friendly type does not have benzene coating.
Claims (9)
1. an environment-friendly type does not have benzene coating, it is characterized in that, this coating by paint component and thinner composition by weight being 100: (40～60) are mixed and are obtained;
Described paint component comprises following composition and weight part content:
Vinyl resin 18～42, additive resin 4～15, pigment dyestuff 28～45, solvent 15～35;
Described thinner composition comprises following composition and weight part content:
1-Methoxy-2-propyl acetate 40～70, propyl carbinol 15～45, N-BUTYL ACETATE 5～25.
2. a kind of environment-friendly type according to claim 1 does not have benzene coating, it is characterized in that, forms and weight part content below described paint component is preferred: vinyl resin 20～40, additive resin 5～10, pigment dyestuff 30～40, solvent 20～30.
3. a kind of environment-friendly type according to claim 1 does not have benzene coating, it is characterized in that, described additive resin is selected from one or more in acrylic acid modified alkyd resin or the epoxy resin.
4. a kind of environment-friendly type according to claim 1 does not have benzene coating, it is characterized in that, described pigment dyestuff is a rust-stabilising pigment, is selected from organic amido black, organic quinoline peptide ketone pigment, in the machine perylene grain or the organic pair of pyrrole pigment one or both are arranged.
5. a kind of environment-friendly type according to claim 1 does not have benzene coating, it is characterized in that, described solvent is selected from one or both in MIBK, mixing acid dimethyl ester, 1-Methoxy-2-propyl acetate or the propyl carbinol.
6. a kind of environment-friendly type according to claim 1 does not have benzene coating, it is characterized in that, forms and weight part content below described thinner composition is preferred: 1-Methoxy-2-propyl acetate 50～60, propyl carbinol 25～40, N-BUTYL ACETATE 10～15.
7. an environment-friendly type as claimed in claim 1 does not have the compound method of benzene coating, it is characterized in that this method may further comprise the steps:
(1) paint component is synthetic
A, get the raw materials ready according to following composition and weight part content:
Vinyl resin 18～42, additive resin 4～15, pigment dyestuff 28～45, solvent 15～35;
B, by prescription requirements earlier with in whole solvents input reaction kettles, and be heated to 20～40 ℃ and stir;
C, maintenance are stirred and vinyl resin are dropped in the reaction kettle stirring and dissolving 1～2.5h successively;
D, treat that vinyl resin dissolves fully after, additive resin is slowly dropped in the reaction kettle and continues stirring and dissolving;
E, after all solids dissolving and mixing, grind after pigment dyestuff stirs to wherein dropping into, and adjustment viscosity is to the qualified paint component that promptly obtains;
(2) thinner composition is synthetic
A, get the raw materials ready according to following composition and weight part content:
1-Methoxy-2-propyl acetate 40～70, propyl carbinol 15～45, N-BUTYL ACETATE 5～25;
B, by the prescription requirement propyl carbinol is dropped in the reaction kettle;
C, maintenance are stirred, and 1-Methoxy-2-propyl acetate and N-BUTYL ACETATE are dropped in the reaction kettle, continue to stir 0.5～1h dissolving extremely fully;
After d, said components are dissolved fully, stop to stir, the moisture content that detects wherein is the qualified thinner composition that promptly obtains;
(3) environment-friendly type does not have the synthetic of benzene coating
With paint component and thinner composition by weight being 100: mix (40～60), and controlled temperature is 130～180 ℃, mixes 20～40min, and promptly obtaining environment-friendly type does not have benzene coating.
8. a kind of environment-friendly type according to claim 7 does not have the compound method of benzene coating, it is characterized in that, adjustment viscosity to qualified viscosity >=120 second in the step (1)/25 ℃ are coated with-4 glasss.
9. a kind of environment-friendly type according to claim 7 does not have the compound method of benzene coating, it is characterized in that, moisture content is qualified moisture content≤0.03wt% in the step (2).
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| Application Number | Priority Date | Filing Date | Title |
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| CN201110170951XA CN102643583A (en) | 2011-06-21 | 2011-06-21 | Environment-friendly benzene-free painting and synthetic method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201110170951XA CN102643583A (en) | 2011-06-21 | 2011-06-21 | Environment-friendly benzene-free painting and synthetic method thereof |
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| CN102643583A true CN102643583A (en) | 2012-08-22 |
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| Application Number | Title | Priority Date | Filing Date |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103805007A (en) * | 2013-10-18 | 2014-05-21 | 中山市大田汽车护理用品有限公司 | Benzene-free spray paint and preparation method thereof |
| CN107573775A (en) * | 2017-07-17 | 2018-01-12 | 江苏艺博防水防腐工程有限公司 | One kind is exempted to dry metallic conduit sprayed on material and its construction method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1048873A (en) * | 1990-06-05 | 1991-01-30 | 张展洪 | The production method of non-bezene acrylic acid resin baking finish and self-drying paint |
| CN1103419A (en) * | 1993-11-30 | 1995-06-07 | 广州市白云区白云精细化工研究所 | Method for producing fast low-temp. setting baking finish of acrylate resin without benzene toxicity |
| CN101392144A (en) * | 2008-11-12 | 2009-03-25 | 常州市普兰纳涂料有限公司 | Coating for wind power blade and preparation method thereof |
-
2011
- 2011-06-21 CN CN201110170951XA patent/CN102643583A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1048873A (en) * | 1990-06-05 | 1991-01-30 | 张展洪 | The production method of non-bezene acrylic acid resin baking finish and self-drying paint |
| CN1103419A (en) * | 1993-11-30 | 1995-06-07 | 广州市白云区白云精细化工研究所 | Method for producing fast low-temp. setting baking finish of acrylate resin without benzene toxicity |
| CN101392144A (en) * | 2008-11-12 | 2009-03-25 | 常州市普兰纳涂料有限公司 | Coating for wind power blade and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 吴义彪: "丙二醇醚的生产及在涂料中的应用", 《涂料工业》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103805007A (en) * | 2013-10-18 | 2014-05-21 | 中山市大田汽车护理用品有限公司 | Benzene-free spray paint and preparation method thereof |
| CN103805007B (en) * | 2013-10-18 | 2016-10-12 | 中山市大田汽车护理用品有限公司 | One is sprayed paint and preparation method thereof without benzene |
| CN107573775A (en) * | 2017-07-17 | 2018-01-12 | 江苏艺博防水防腐工程有限公司 | One kind is exempted to dry metallic conduit sprayed on material and its construction method |
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Application publication date: 20120822 |