CN102634112A - Carbon plastic synthetic heat exchange material - Google Patents
Carbon plastic synthetic heat exchange material Download PDFInfo
- Publication number
- CN102634112A CN102634112A CN2012100966893A CN201210096689A CN102634112A CN 102634112 A CN102634112 A CN 102634112A CN 2012100966893 A CN2012100966893 A CN 2012100966893A CN 201210096689 A CN201210096689 A CN 201210096689A CN 102634112 A CN102634112 A CN 102634112A
- Authority
- CN
- China
- Prior art keywords
- heat exchange
- carbon
- exchange material
- synthetic heat
- banburying
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000463 material Substances 0.000 title claims abstract description 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 18
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 17
- 239000004033 plastic Substances 0.000 title abstract description 4
- 229920003023 plastic Polymers 0.000 title abstract description 4
- 238000002360 preparation method Methods 0.000 claims description 8
- 238000003490 calendering Methods 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 238000005303 weighing Methods 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 6
- 239000003963 antioxidant agent Substances 0.000 abstract description 5
- 230000003078 antioxidant effect Effects 0.000 abstract description 5
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 4
- 230000005484 gravity Effects 0.000 abstract description 3
- 238000007254 oxidation reaction Methods 0.000 abstract description 2
- 230000015556 catabolic process Effects 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 238000006731 degradation reaction Methods 0.000 abstract 1
- 239000004020 conductor Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 235000006708 antioxidants Nutrition 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 238000010525 oxidative degradation reaction Methods 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- 229920002449 FKM Polymers 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000003916 acid precipitation Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000002990 reinforced plastic Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a carbon plastic synthetic heat exchange material which is corrosion-resistant, light in specific gravity, antioxidant and low temperature resistant, and has a heat conduction effect being superior to that of similar products on the market at present; furthermore, the fluidity is improved technically; and carbon plastic synthetic heat exchange material overcomes the defects of easy oxidization and degradation.
Description
Technical field
The present invention relates to a kind of heat exchange material, particularly relate to a kind of carbon and mould synthetic heat exchange material.
Background technology
Relate to required water heat exchange, aqueous vapor heat exchange or air heat exchange below 100 ℃ and the solar water heater heat-collecting devices in field such as building worker's heating, new forms of energy, thermal power generation, electronic engineering, fuel oil, gas power engineering at present; Need metallic substance manufacturings such as copper, aluminium, steel; Change (leading) hot merit ability though have necessarily; But not corrosion-resistant, cost is high, technology is loaded down with trivial details and energy consumption is high, the zero release that does not reach refuse, contaminate environment.The patented claim of China disclosure of the Invention CN101024763; Though the heat exchange material of its announcement; Heat exchange material result than metallic substance such as copper, aluminium on heat-conducting effect and hot strength is obvious, but its anti-oxidant, low temperature resistant effect low (having born of the same parents to split phenomenon under 20 ℃), and that is that all right is ripe for its technology.
Summary of the invention
The object of the invention is exactly the deficiency that overcomes prior art, provides a kind of carbon to mould synthetic heat exchange material.This carbon moulds that synthetic heat exchange material is corrosion-resistant, light specific gravity, anti-oxidant, low temperature resistant and heat-conducting effect are superior to like product in the market, and has on its technology and increased flowability.Overcome the shortcoming of easy oxidative degradation.
An object of the present invention is to provide a kind of carbon and mould synthetic heat exchange material.
Another object of the present invention provides said carbon and moulds synthetic heat exchange preparation methods.
The objective of the invention is to realize through following technical scheme:
A kind of carbon is moulded synthetic heat exchange material, and it is formed by the feedstock production that comprises following parts by weight;
Preferably, a kind of carbon is moulded synthetic heat exchange material, and it is formed by the feedstock production that comprises following parts by weight;
Graphite Powder 99 according to the invention: this powder tool thermal conductivity is good, chemicalstability good, erosion resistance is strong, electromagnetic shielding property is good.
Mixed rare-earth oxide: mainly molten through peracid by the adsorptivity ore deposit, oxalic acid precipitation calcination becomes mixed rare-earth oxide.Be the dark-brown powder, water insoluble, dissolve in acid.Be used to produce norium, single rare earth product.
Coupling agent: but the strong combination of the use reinforced plastics of coupling agent and carbon graphite has improved the physical strength of product.
Antioxidant 1010: white crystalline powder, chemical property is stable, can be widely used in general-purpose plastics, engineering plastics, viton, fiber, hot melt adhesive, resin, oil product, ink is in the industries such as coating.With anti-oxidant DLTP and be used for Vestolen PP 7052 and the Vilaterm hybrid resin, can improve its thermostability significantly.
Toughner PPB-8101: be used to overcome the cold fragility and the process flowability of cold district, improve toughness, controlled the low temperature born of the same parents and split, toughner and Vilaterm and polyacrylic being used increase its end product on hot strength; Detected result: the material hot strength is 2.55;
Stablizer RWS: claim ester group tin heat stabilizer RWS-784 again, colourless to little yellow transparent liquid, the polyvinyl-chloride use thermo-stabilizer, good heat stability can prevent the oxidation of the course of processing and makes the material variation;
Nucleator WBG: claim WBG series Vestolen PP 7052 crystal formation properties-correcting agent again, it act as and has improved percent crystallization in massecuite in the present invention.Improve crystalline form, had the α type to become the β type, increased rigidity intensity.
The preparation method of a kind of environment-friendly type plastic-base heat conducting material of the present invention, it may further comprise the steps;
Take by weighing each raw material by formula ratio, mixed at high speed is evenly after banburying, calendering, cold cut become cylindrical particle to obtain.
Preferably, the described mixed at high speed time was controlled at 2 minutes.
More preferably, affiliated banburying is when the Banbury mixer temperature reaches 290 ± 5 ℃, keeps banburying 60-90 second.
Described calendering is after material gets into rolling press, to roll discharging into strips.
The present invention adopts above-mentioned special process method, has increased flowing property on its technology, has saved the energy; Roll after the cold cut step has changed and extruded the shortcoming that is prone to oxidative degradation in the fervent process of anti-granulation, thereby improved its mechanical property.
Environment-friendly type plastic-base heat conducting material of the present invention is a kind of thermally conductive material that is used to build fields such as worker's heating, new forms of energy, thermal power generation, electronic engineering, fuel oil, gas power engineering and solar water heater heat-collecting device.Various auxiliary agents in this plastic-base heat conducting material prescription have improved corrosion-resistant degree, hot strength reaches 2.55 standards above present like product hot strength 1.0-2.0 under low temperature environment; Light specific gravity, anti-oxidant, low temperature resistantly reach-33 ℃ and heat-conducting effect and be superior to like product in the market; Also help environmental protection and cost is low, be fit to promote the use of.
Embodiment
Below adopt embodiment to specify a kind of environment-friendly type plastic-base heat conducting material of the present invention and preparation method thereof.
Embodiment 1 (units)
Its preparation method is following:
Take by weighing each raw material by formula ratio, mixed at high speed gets into the Banbury mixer banburying after 2 minutes, 290 ℃ of temperature, and 80 seconds banburying time, through rolling press calendering discharging, last cold cut becomes cylindrical particle to obtain again.
Embodiment 2 (units)
Take by weighing each raw material by formula ratio, mixed at high speed gets into the Banbury mixer banburying after 2 minutes, 295 ℃ of temperature, and 60 seconds banburying time, through rolling press calendering discharging, last cold cut becomes cylindrical particle to obtain again.
Embodiment 3 (units)
Its preparation method such as embodiment 1.
Below process the effect behind the scatterer through the examining report explanation embodiment of the invention 1 environment-friendly type plastic-base heat conducting material.
Architectural environment inspection center of Tsing-Hua University
The radiator performance examining report
Claims (5)
1. a carbon is moulded synthetic heat exchange material, and it is formed by the feedstock production that comprises following parts by weight;
2. carbon as claimed in claim 1 is moulded synthetic heat exchange material, and it is formed by the feedstock production that comprises following parts by weight;
3. the described carbon of preparation claim 1 is moulded synthetic heat exchange material, and it may further comprise the steps; Take by weighing each raw material by formula ratio, mixed at high speed is evenly after banburying, calendering, cold cut become cylindrical particle to obtain.
4. carbon as claimed in claim 3 is moulded synthetic heat exchange preparation methods, and the wherein said mixed at high speed time was controlled at 2 minutes.
5. carbon as claimed in claim 3 is moulded synthetic heat exchange preparation methods, when the banburying temperature reaches 290 ± 5 ℃, keeps banburying 60-90 second.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210096689.3A CN102634112B (en) | 2012-04-05 | 2012-04-05 | Carbon plastic synthetic heat exchange material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210096689.3A CN102634112B (en) | 2012-04-05 | 2012-04-05 | Carbon plastic synthetic heat exchange material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102634112A true CN102634112A (en) | 2012-08-15 |
| CN102634112B CN102634112B (en) | 2014-02-26 |
Family
ID=46618696
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210096689.3A Expired - Fee Related CN102634112B (en) | 2012-04-05 | 2012-04-05 | Carbon plastic synthetic heat exchange material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102634112B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861301A (en) * | 2015-06-09 | 2015-08-26 | 安徽普瑞普勒传热技术有限公司 | Heat exchange material for heat exchange piece and preparation process of heat exchange material |
| CN104893107A (en) * | 2015-06-09 | 2015-09-09 | 安徽普瑞普勒传热技术有限公司 | Heat exchange material for heat exchangers and preparation process thereof |
| CN104927790A (en) * | 2015-06-09 | 2015-09-23 | 安徽普瑞普勒传热技术有限公司 | Heat exchange material for refrigerating machine |
| CN104946211A (en) * | 2015-06-09 | 2015-09-30 | 安徽普瑞普勒传热技术有限公司 | ErNi heat exchange material |
| CN106009332A (en) * | 2016-06-21 | 2016-10-12 | 玉环苗艺阀门制造有限公司 | Environment-friendly plastic-based heat conduction material and preparing method thereof |
| CN106987091A (en) * | 2017-05-18 | 2017-07-28 | 安徽普瑞普勒传热技术有限公司 | A kind of shell-and-tube heat exchanger heat exchange material |
| CN107057287A (en) * | 2017-05-18 | 2017-08-18 | 安徽普瑞普勒传热技术有限公司 | A kind of heat exchanger heat exchange material |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1388202A (en) * | 2002-07-09 | 2003-01-01 | 杭州华电华源环境工程有限公司 | Heat-conducting polymer material and its prepn |
| CN101186810A (en) * | 2007-11-23 | 2008-05-28 | 高原 | Environment-friendly type plastic-base heat conducting material |
| CN101787161A (en) * | 2010-01-15 | 2010-07-28 | 周士钦 | Aluminum-plastic composite heat radiator and preparation method of special heat conduction plastic alloy for inner layer |
| CN102311578A (en) * | 2011-02-28 | 2012-01-11 | 吴志祥 | Polymer composite heat conduction material and preparation method and application thereof |
-
2012
- 2012-04-05 CN CN201210096689.3A patent/CN102634112B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1388202A (en) * | 2002-07-09 | 2003-01-01 | 杭州华电华源环境工程有限公司 | Heat-conducting polymer material and its prepn |
| CN101186810A (en) * | 2007-11-23 | 2008-05-28 | 高原 | Environment-friendly type plastic-base heat conducting material |
| CN101787161A (en) * | 2010-01-15 | 2010-07-28 | 周士钦 | Aluminum-plastic composite heat radiator and preparation method of special heat conduction plastic alloy for inner layer |
| CN102311578A (en) * | 2011-02-28 | 2012-01-11 | 吴志祥 | Polymer composite heat conduction material and preparation method and application thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861301A (en) * | 2015-06-09 | 2015-08-26 | 安徽普瑞普勒传热技术有限公司 | Heat exchange material for heat exchange piece and preparation process of heat exchange material |
| CN104893107A (en) * | 2015-06-09 | 2015-09-09 | 安徽普瑞普勒传热技术有限公司 | Heat exchange material for heat exchangers and preparation process thereof |
| CN104927790A (en) * | 2015-06-09 | 2015-09-23 | 安徽普瑞普勒传热技术有限公司 | Heat exchange material for refrigerating machine |
| CN104946211A (en) * | 2015-06-09 | 2015-09-30 | 安徽普瑞普勒传热技术有限公司 | ErNi heat exchange material |
| CN106009332A (en) * | 2016-06-21 | 2016-10-12 | 玉环苗艺阀门制造有限公司 | Environment-friendly plastic-based heat conduction material and preparing method thereof |
| CN106987091A (en) * | 2017-05-18 | 2017-07-28 | 安徽普瑞普勒传热技术有限公司 | A kind of shell-and-tube heat exchanger heat exchange material |
| CN107057287A (en) * | 2017-05-18 | 2017-08-18 | 安徽普瑞普勒传热技术有限公司 | A kind of heat exchanger heat exchange material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102634112B (en) | 2014-02-26 |
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Owner name: BEIJING CAISHENG HOLDINGS CO., LTD. Free format text: FORMER OWNER: GAO YUAN Effective date: 20141115 |
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Free format text: CORRECT: ADDRESS; FROM: 065000 LANGFANG, HEBEI PROVINCE TO: 100088 HAIDIAN, BEIJING |
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Effective date of registration: 20141115 Address after: 100088, room 505, building A, 5 politics building, North Third Ring Road, Beijing Patentee after: Beijing Fortune Holdings Limited Address before: 065000 No. 13, No. 19, Dongan market, Hebei, Langfang Patentee before: Gao Yuan |
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