CN102627478A - Method for preparing yellow pigment by using commonly used color development for replacing rare-earth element praseodymium and vanadium color development - Google Patents
Method for preparing yellow pigment by using commonly used color development for replacing rare-earth element praseodymium and vanadium color development Download PDFInfo
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- CN102627478A CN102627478A CN2012101299079A CN201210129907A CN102627478A CN 102627478 A CN102627478 A CN 102627478A CN 2012101299079 A CN2012101299079 A CN 2012101299079A CN 201210129907 A CN201210129907 A CN 201210129907A CN 102627478 A CN102627478 A CN 102627478A
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- 238000000034 method Methods 0.000 title claims abstract description 24
- 229910052777 Praseodymium Inorganic materials 0.000 title claims abstract description 17
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 229910052720 vanadium Inorganic materials 0.000 title claims abstract description 13
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 title claims abstract description 13
- 229910052761 rare earth metal Inorganic materials 0.000 title claims abstract description 12
- 239000001052 yellow pigment Substances 0.000 title abstract description 4
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims abstract description 26
- QCUOBSQYDGUHHT-UHFFFAOYSA-L cadmium sulfate Chemical compound [Cd+2].[O-]S([O-])(=O)=O QCUOBSQYDGUHHT-UHFFFAOYSA-L 0.000 claims abstract description 23
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000011737 fluorine Substances 0.000 claims abstract description 18
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000006229 carbon black Substances 0.000 claims abstract description 17
- 235000005074 zinc chloride Nutrition 0.000 claims abstract description 13
- 239000011592 zinc chloride Substances 0.000 claims abstract description 13
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 7
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 32
- 239000000463 material Substances 0.000 claims description 27
- 239000003513 alkali Substances 0.000 claims description 16
- 230000009257 reactivity Effects 0.000 claims description 16
- 235000010265 sodium sulphite Nutrition 0.000 claims description 16
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 claims description 16
- RFAFBXGYHBOUMV-UHFFFAOYSA-N calcium chromate Chemical compound [Ca+2].[O-][Cr]([O-])(=O)=O RFAFBXGYHBOUMV-UHFFFAOYSA-N 0.000 claims description 11
- 239000007791 liquid phase Substances 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 7
- 230000002194 synthesizing effect Effects 0.000 claims description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 238000000498 ball milling Methods 0.000 claims description 5
- 238000009835 boiling Methods 0.000 claims description 5
- 239000003086 colorant Substances 0.000 claims description 5
- PSUYMGPLEJLSPA-UHFFFAOYSA-N vanadium zirconium Chemical compound [V].[V].[Zr] PSUYMGPLEJLSPA-UHFFFAOYSA-N 0.000 abstract description 14
- USEGQPUGEPSVQL-UHFFFAOYSA-N [Pr].[Zr] Chemical compound [Pr].[Zr] USEGQPUGEPSVQL-UHFFFAOYSA-N 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 11
- 239000000049 pigment Substances 0.000 abstract description 9
- 239000000919 ceramic Substances 0.000 abstract description 6
- 238000005245 sintering Methods 0.000 abstract description 5
- 238000004040 coloring Methods 0.000 abstract description 4
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052793 cadmium Inorganic materials 0.000 abstract description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052980 cadmium sulfide Inorganic materials 0.000 abstract description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052742 iron Inorganic materials 0.000 abstract description 2
- -1 iron ions Chemical class 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 abstract description 2
- 239000002243 precursor Substances 0.000 abstract description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract 3
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 abstract 1
- 229910000331 cadmium sulfate Inorganic materials 0.000 abstract 1
- 229960002089 ferrous chloride Drugs 0.000 abstract 1
- CMOAHYOGLLEOGO-UHFFFAOYSA-N oxozirconium;dihydrochloride Chemical compound Cl.Cl.[Zr]=O CMOAHYOGLLEOGO-UHFFFAOYSA-N 0.000 abstract 1
- 235000011121 sodium hydroxide Nutrition 0.000 abstract 1
- 229910052979 sodium sulfide Inorganic materials 0.000 abstract 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical group [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- PQXKHYXIUOZZFA-UHFFFAOYSA-M lithium fluoride Chemical group [Li+].[F-] PQXKHYXIUOZZFA-UHFFFAOYSA-M 0.000 description 2
- 150000002910 rare earth metals Chemical class 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- MMKQUGHLEMYQSG-UHFFFAOYSA-N oxygen(2-);praseodymium(3+) Chemical compound [O-2].[O-2].[O-2].[Pr+3].[Pr+3] MMKQUGHLEMYQSG-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- YLVOPDWXGHFEHW-UHFFFAOYSA-N praseodymium vanadium Chemical compound [V].[V].[V].[V].[V].[Pr] YLVOPDWXGHFEHW-UHFFFAOYSA-N 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
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- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
The invention belongs to the technical field of ceramic coloring and pigment and particularly relates to a method for preparing yellow pigment by using commonly used color development for replacing rare-earth element praseodymium and vanadium color development. The method is mainly characterized in that zirconium oxychloride, cadmium sulfate, sodium sulfide, high-activity white carbon black, fluorine-containing multi-component mineralizer, caustic soda flakes and zinc chloride or ferrous chloride are used as raw materials, a technique of doping zinc ions and iron ions in envelope cadmium sulfide pigment is adopted, a solid-liquid combination method is adopted for introducing precursors, novel mineralizer is introduced during high-temperature sintering and the yellow pigment which can replace the rare-earth element praseodymium and the vanadium color development is prepared. The resistant temperature of a product can be improved by 30-50 DEG C on the basis of the resistant temperature of the original zirconium-praseodymium yellow and vanadium-zirconium yellow, the dissolved quantity of cadmium can fully satisfy the international standard, the grain shape is more evenly and grains are spherically distributed and the color development effect is two times of the color development effect of the original product.
Description
Technical field
The invention belongs to ceramic coloring and pigment technology field, be specifically related to a kind of method for preparing yellow ultramarine with alternative REE praseodymium of color development commonly used and vanadium color development.
Background technology
Praseodymium, v element can be used as the color development element, and like zirconium praseodymium yellow that directly utilizes the generation of praseodymium color development and the vanadium zirconium Huang that directly utilizes the vanadium color development to generate, it is the maximum REE of pigment industry consumption.Zirconium praseodymium yellow, vanadium zirconium Huang are considered to best yellow ceramic pigment, still can keep stable up to 1250 ℃, can be used for disposable or heavy firing technique.The zirconium praseodymium yellow is widely used in architectural pottery and domestic ceramics is painted, also can make under-glaze pigment separately, and it the blue or green light of colour band, and is bright in luster, is hard fire colour rare on the market.And vanadium zirconium Huang is an a kind of high temperature resistant dark yellow pigment rare on the market also because of the yellow of the dark phase of its distinctive band and be widely used on architectural pottery and the domestic ceramics.Because of the integration of the scarcity of Praseodymium trioxide and Vanadium Pentoxide in FLAKES and rare-earth trade has also promoted the recurrence that rare earth is worth, it is many to cause the yellow price of praseodymium yellow and vanadium zirconium to turn over octuple even to this day but since two thousand nine.Have a strong impact on the ordinary production of the yellow material of the China and world pottery praseodymium vanadium, also slackened China's ceramic pigment glaze industry competitive power in the world greatly.Therefore, seeking the novel yellow ultramarine that a kind of ability substitutes the common element color development of zirconium praseodymium yellow, the yellow color development of vanadium zirconium highlights important.
Summary of the invention
The object of the present invention is to provide a kind ofly to reach the yellow effect of zirconium praseodymium yellow, vanadium zirconium from color, temperature tolerance, coloring degree, chemicalstability, the grain type reaches equally distributed spherical effect even more superior substitutes the method that REE praseodymium and vanadium color development prepare yellow ultramarine with color development commonly used.
The inventive method is:
(a) substitute the praseodymium color development and prepare the step that yellow ultramarine comprises following order:
(1) selects following raw material: basic zirconium chloride, Cadmium Sulphate, sodium sulphite, high reactivity WHITE CARBON BLACK, fluorine-containing many group mineralizers, sheet alkali, zinc chloride;
(2) adopt liquid phase synthesizing method, basic zirconium chloride, Cadmium Sulphate, sodium sulphite, zinc chloride, sheet alkali are mixed, zinc chloride is introduced in the Cadmium Sulphate dissolving, pH value is controlled at 5.5～8.5;
(3) adopt solid-state mixing, after the material rinsing of the synthetic gained of a last step liquid phase, oven dry, add fluorine-containing many group mineralizers and high reactivity WHITE CARBON BLACK again, evenly and will pass through 600 order fine screen mesh mixing of materials;
(4) step (3) gained mixture is fired, adopted backing plate to burn colorant roller kiln equipment and fire, temperature is controlled at 1080 ℃～1120 ℃;
(5) at last material is carried out that acidifying, ball milling, acid are floated, the soda boiling operation, promptly get product after the oven dry;
(b) substitute the vanadium color development and prepare the step that yellow ultramarine comprises following order:
(1) selects following raw material: basic zirconium chloride, Cadmium Sulphate, sodium sulphite, high reactivity WHITE CARBON BLACK, fluorine-containing many group mineralizers, sheet alkali, iron protochloride;
(2) adopt liquid phase synthesizing method, basic zirconium chloride, Cadmium Sulphate, sodium sulphite, iron protochloride, sheet alkali are mixed, iron protochloride is dissolved in Cadmium Sulphate and introduce, pH value is controlled at 7.8;
(3) adopt solid-state mixing, after the material rinsing of the synthetic gained of a last step liquid phase, oven dry, add fluorine-containing many group mineralizers and high reactivity WHITE CARBON BLACK again, evenly and will pass through 600 order fine screen mesh mixing of materials;
(4) will go up a step gained mixture and fire, and adopt backing plate to burn colorant roller kiln equipment and fire, temperature will be controlled at 1080 ℃～1120 ℃;
(5) at last material is carried out that acidifying, ball milling, acid are floated, the soda boiling operation, promptly get product after the oven dry.
More particularly; In the step (2) of item (a); The mass percent of component basic zirconium chloride, Cadmium Sulphate, sodium sulphite, zinc chloride, sheet alkali is respectively: 67～68%, 11.5～12%, 7～8%, 0.5～2%, 11～12%, and the adding concentration of controlling each material is respectively: 180～200g/ml, 30～34 g/ml, 20～22 g/ml, 2～6 g/ml, 30～36 g/ml; In the step (3) of item (a), the weight parts of oven dry material, fluorine-containing many group mineralizers, high reactivity WHITE CARBON BLACK are respectively: 100,7～10,20～36.
In the step (2) of item (b); The mass percent of component basic zirconium chloride, Cadmium Sulphate, sodium sulphite, iron protochloride, sheet alkali is respectively: 66～68%, 10.5～11.5%, 7～8%, 1.5～3.5%, 11～12%, and the adding concentration of controlling each material is respectively: 180～200g/ml, 30～34 g/ml, 20～22 g/ml, 3～7 g/ml, 30～36 g/ml; In item (b) step (3), the weight parts of oven dry material, fluorine-containing many group mineralizers, high reactivity WHITE CARBON BLACK are respectively: 100,7～10,20～36.
The present invention reaches zirconium praseodymium yellow, yellow color, temperature tolerance, coloring degree, the chemicalstability of vanadium zirconium; And adopt a kind of combination coating Cadmium Sulfide pigment zine ion, iron ion technology of mixing again; Solid-liquid combination is adopted in introducing to precursor, introduces novel mineralizer during high temperature sintering.Product temperature tolerance of the present invention can improve 30～50 ℃ on the yellow basis of original zirconium praseodymium yellow, vanadium zirconium, and quantity of cadmium release can meet international standards fully, and comparatively homogeneous is spherical distributes for the grain type, and the color development effect is 2 times of existing product.
Beneficial effect of the present invention be embodied in following some:
(1) granules of pigments is shaped as 90% spherical effect, has solved in use, and bad because of the grain type, glaze is difficult to fill, and the part fault location has air to exist, thereby causes the phenomenon that pin hole is at high temperature arranged.
(2) from the color development angle, the color development of this product is zirconium praseodymium yellow, vanadium zirconium Huang 2-2.5 a times, has demonstrated fully the requirement that economizes on resources.
(3) temperature tolerance of this product improves 30～50 ℃ at zirconium praseodymium yellow, vanadium zirconium on the yellow basis, and the product application scope of this tone is further enlarged.
(4) fundamentally, solved the use that reduces scarce resource praseodymium, vanadium, the resource that ensured sustained development is more arranged is provided for enterprise.
Description of drawings
Fig. 1 is technological process of production figure of the present invention.
Embodiment
Below in conjunction with accompanying drawing and concrete experiment embodiment the present invention is described in further detail.
One of scheme of the present invention is for substituting the zirconium praseodymium yellow:
Selecting basic zirconium chloride, Cadmium Sulphate, sodium sulphite, high reactivity WHITE CARBON BLACK, fluorine-containing many group mineralizers, sheet alkali, zinc chloride is raw material.The first step adopts liquid phase synthesizing method; Utilize zinc chloride doping zine ion; The mass percent of major control component basic zirconium chloride, Cadmium Sulphate, sodium sulphite, zinc chloride, sheet alkali is respectively: 67～68%, 11.5～12%, 7～8%, 0.5～2%, 11～12%, and the adding concentration of controlling each material is respectively: 180～200g/ml, 30～34 g/ml, 20～22 g/ml, 2～6 g/ml, 30～36 g/ml; Zinc chloride dissolves in Cadmium Sulphate and introduces, and pH value is controlled at 5.5～8.5.Second step was adopted solid-state mixing, after the synthetic material rinsing of the liquid phase of the first step, oven dry, added fluorine-containing many group mineralizers and high reactivity WHITE CARBON BLACK; The weight part of control oven dry material, fluorine-containing many group mineralizers, high reactivity WHITE CARBON BLACK is respectively 100,7～10,20～36, and wherein fluorine-containing many group mineralizers play a crucial role to sintering, and many sintering degree is good more more; But surpass certain amount, sintering procedure is difficult to control, and sintered particles is increased; Pellet hardness increases; In experiment embodiment of the present invention, be the best with 7～10% mass percents of total material, its component is by the combination of many groups such as lithium fluoride, lithium chloride mineralizers.Mixture is even and will pass through 600 order fine screen mesh, gets into ablating work procedure again, adopts backing plate to burn colorant roller kiln (1200 ℃) equipment and fires, and controlled temperature is at 1080 ℃～1120 ℃; Get at last that acidifying, ball milling, acid are floated, the soda boiling operation, go out finished product after the oven dry.The mass effect of its product is: the grain type is 90% sphere, and tinctorial yield can reach the twice of market zirconium praseodymium yellow, and temperature tolerance can improve 30～50 ℃.Synthesis process is as shown in Figure 1.In experimentation, the effect of the material rate of each embodiment composition (mass percent) influence and trend are shown in table one:
In the table, tinctorial yield, form and aspect are and praseodymium yellow result relatively.
Two of scheme of the present invention is alternative vanadium zirconium Huang:
Selecting basic zirconium chloride, Cadmium Sulphate, sodium sulphite, high reactivity WHITE CARBON BLACK, fluorine-containing many group mineralizers, sheet alkali, iron protochloride is raw material.The first step adopts liquid phase synthesizing method; The mass percent of major control component basic zirconium chloride, Cadmium Sulphate, sodium sulphite, iron protochloride, sheet alkali is respectively: 66～68%, 10.5～11.5%, 7～8%, 1.5～3.5%, 11～12%, and the adding concentration of controlling each material is respectively: 180～200g/ml, 30～34 g/ml, 20～22 g/ml, 3～7 g/ml, 30～36 g/ml; Iron protochloride dissolves in Cadmium Sulphate and introduces, and pH value is controlled at 7.8.Other production process is identical with alternative zirconium praseodymium yellow technology.The mass effect of its product is: the grain type is 90% sphere, and tinctorial yield can reach more than the yellow twice of market vanadium zirconium, and temperature tolerance can improve 30～50 ℃.Synthesis process is as shown in Figure 1.In experimentation, the effect of the material rate of each embodiment composition (mass percent) influence and trend are shown in table two:
In the table, tinctorial yield, form and aspect are and the yellow result relatively of vanadium zirconium.
Claims (3)
1. one kind substitutes the method that REE praseodymium and vanadium color development prepare yellow ultramarine with color development commonly used, it is characterized in that:
(a) substitute the praseodymium color development and prepare the step that yellow ultramarine comprises following order:
(1) selects following raw material: basic zirconium chloride, Cadmium Sulphate, sodium sulphite, high reactivity WHITE CARBON BLACK, fluorine-containing many group mineralizers, sheet alkali, zinc chloride;
(2) adopt liquid phase synthesizing method, basic zirconium chloride, Cadmium Sulphate, sodium sulphite, zinc chloride, sheet alkali are mixed, zinc chloride is introduced in the Cadmium Sulphate dissolving, pH value is controlled at 5.5～8.5;
(3) adopt solid-state mixing, after the material rinsing of the synthetic gained of a last step liquid phase, oven dry, add fluorine-containing many group mineralizers and high reactivity WHITE CARBON BLACK again, evenly and will pass through 600 order fine screen mesh mixing of materials;
(4) step (3) gained mixture is fired, adopted backing plate to burn colorant roller kiln equipment and fire, temperature is controlled at 1080 ℃～1120 ℃;
(5) at last material is carried out that acidifying, ball milling, acid are floated, the soda boiling operation, promptly get product after the oven dry;
(b) substitute the vanadium color development and prepare the step that yellow ultramarine comprises following order:
(1) selects following raw material: basic zirconium chloride, Cadmium Sulphate, sodium sulphite, high reactivity WHITE CARBON BLACK, fluorine-containing many group mineralizers, sheet alkali, iron protochloride;
(2) adopt liquid phase synthesizing method, basic zirconium chloride, Cadmium Sulphate, sodium sulphite, iron protochloride, sheet alkali are mixed, iron protochloride is dissolved in Cadmium Sulphate and introduce, pH value is controlled to 7.8;
(3) adopt solid-state mixing, after the material rinsing of the synthetic gained of a last step liquid phase, oven dry, add fluorine-containing many group mineralizers and high reactivity WHITE CARBON BLACK again, evenly and will pass through 600 order fine screen mesh mixing of materials;
(4) will go up a step gained mixture and fire, and adopt backing plate to burn colorant roller kiln equipment and fire, temperature will be controlled at 1080 ℃～1120 ℃;
(5) at last material is carried out that acidifying, ball milling, acid are floated, the soda boiling operation, promptly get product after the oven dry.
2. the method for preparing yellow ultramarine with alternative REE praseodymium of color development commonly used and vanadium color development according to claim 1; It is characterized in that: in the step (2) of (a); The mass percent of component basic zirconium chloride, Cadmium Sulphate, sodium sulphite, zinc chloride, sheet alkali is respectively: 67～68%, 11.5～12%, 7～8%, 0.5～2%, 11～12%, and the adding concentration of controlling each material is respectively: 180～200g/ml, 30～34 g/ml, 20～22 g/ml, 2～6 g/ml, 30～36 g/ml; In the step (3) of item (a), the weight parts of oven dry material, fluorine-containing many group mineralizers, high reactivity WHITE CARBON BLACK are respectively: 100,7～10,20～36.
3. the method for preparing yellow ultramarine with alternative REE praseodymium of color development commonly used and vanadium color development according to claim 1; It is characterized in that: in the step (2) of (b); The mass percent of component basic zirconium chloride, Cadmium Sulphate, sodium sulphite, iron protochloride, sheet alkali is respectively: 66～68%, 10.5～11.5%, 7～8%, 1.5～3.5%, 11～12%, and the adding concentration of controlling each material is respectively: 180～200g/ml, 30～34 g/ml, 20～22 g/ml, 3～7 g/ml, 30～36 g/ml; In item (b) step (3), the weight parts of oven dry material, fluorine-containing many group mineralizers, high reactivity WHITE CARBON BLACK are respectively: 100,7～10,20～36.
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| CN103804025A (en) * | 2014-02-26 | 2014-05-21 | 佛山市远泰陶瓷化工有限公司 | High-temperature grain inhibitor for ceramic pigment, ceramic pigment and preparation method |
| CN105801777A (en) * | 2016-03-31 | 2016-07-27 | 江西金环颜料有限公司 | Preparation method of high-temperature yellow pigment for ceramic laser printing |
| CN106752108A (en) * | 2016-12-02 | 2017-05-31 | 佛山市华意陶瓷颜料有限公司 | A kind of yellow cadmium system occlusion pigment, ceramic ink and preparation method thereof |
| CN111196898A (en) * | 2020-01-08 | 2020-05-26 | 佛山市大千色釉料有限公司 | Eutectic synthetic zirconium praseodymium yellow material and preparation method thereof |
| CN111690282A (en) * | 2020-07-31 | 2020-09-22 | 江西金环颜料有限公司 | Preparation method of blue pigment for coating/ink-jet printing/nano zirconia ceramic |
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| CN1639273A (en) * | 2002-03-08 | 2005-07-13 | 意大利库劳比公司 | Embedded pigments for ceramic products and oxides in the form of nanometric particles |
| CN1884210A (en) * | 2006-06-21 | 2006-12-27 | 湘潭大学 | Process for preparing high temperature ceramic pigment |
| CN102030539A (en) * | 2010-09-29 | 2011-04-27 | 桂劲宁 | Method for preparing solid composite particles |
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| CN111196898A (en) * | 2020-01-08 | 2020-05-26 | 佛山市大千色釉料有限公司 | Eutectic synthetic zirconium praseodymium yellow material and preparation method thereof |
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