CN102619133A - Producing method of matt release paper - Google Patents

Producing method of matt release paper Download PDF

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Publication number
CN102619133A
CN102619133A CN2012101077552A CN201210107755A CN102619133A CN 102619133 A CN102619133 A CN 102619133A CN 2012101077552 A CN2012101077552 A CN 2012101077552A CN 201210107755 A CN201210107755 A CN 201210107755A CN 102619133 A CN102619133 A CN 102619133A
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CN
China
Prior art keywords
filler
hazes
microns
film
polymer
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Pending
Application number
CN2012101077552A
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Chinese (zh)
Inventor
金闯
周满意
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Suzhou Sidike New Material Science and Technology Co Ltd
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Suzhou Sidike New Material Science and Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Suzhou Sidike New Material Science and Technology Co Ltd filed Critical Suzhou Sidike New Material Science and Technology Co Ltd
Priority to CN2012101077552A priority Critical patent/CN102619133A/en
Publication of CN102619133A publication Critical patent/CN102619133A/en
Pending legal-status Critical Current

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  • Adhesive Tapes (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A producing method of matt release paper mainly includes the steps of firstly, laminating lamination materials on the surface of at least one side of base materials by utilizing a laminator, wherein raw material formula of the lamination materials is composed of 71.2% to 90.8% of polymer, 0.2% to 1.2% of lubricants and 9% to 27.6% of hazing padding; the polymer is selected from polyethylene, polypropylene, polyvinyl chloride (PVC) and polyethylene terephthalate (PET); and the padding is solid particles with particle sizes between 8 microns and 20 microns; and secondly, coating release agents on the surface laminated with lamination materials. By means of the producing method, matt release film with stable release forces and good pressure sensitive adhesive surface hazing effects can be produced, so that transfer adhesive surface can achieve a low reflective effect. The producing method has the advantages that the production process is simple, the equipment invested cost is low, and the operation is convenient.

Description

A kind of preparation method of cloudy surface release liners
Technical field
The present invention relates to a kind of preparation method of cloudy surface release liners, belong to cloudy surface material technology field.
Background technology
Release liners is claimed barrier paper again, and separate paper is a kind ofly both can prevent the prepreg adhesion, can protect the not contaminated separate paper of prepreg again.
Release liners is will drench membrane material (like polyethylene, polypropylene) pouring film on body paper (base material) surface through drenching the film machine; Form the certain thickness leaching membrane layer of one deck; Again the silicone mould release is coated on the leaching membrane layer, let it can show extremely light and stable off-type force for various organic pressure sensitivity glue.
Different organic pressure-sensing glue are for example: the pressure-sensing glue of hot melt adhesive, acryl glue and rubber system etc.; The off-type force of required release liners is different; Viscosity to the glue of need isolated product is different, and the off-type force correspondence is adjusted, and makes it the off-type force that when peeling off, reaches extremely light and stable.
The flatness of the leaching membrane layer that prior art makes is high; Poor adhesive force between mould release coating and the leaching membrane layer; When release liners attaches with the pad pasting that is coated with trowel adhesive; Cause the mould release coating on the release liners to be taken away easily, thereby form the mould release coating area that is difficult to clean out, destroyed whole pure, the uniformity of pad pasting in the local surfaces of pad pasting by the bigger adhesive of adhesion.
Summary of the invention
The object of the invention provides a kind of preparation method of cloudy surface release liners.
For achieving the above object, the technical scheme that the present invention adopts is: a kind of preparation method of cloudy surface release liners, mainly form by the following step:
The first step: adopt and drench at least one side surface pouring film pouring membrane material of film machine to base material, this composition of raw materials that drenches membrane material is made up of the material of following quality percentage composition:
Polymer 71.2% ~ 90.8%;
Lubricant 0.2% ~ 1.2%;
Filler 9% ~ 27.6% hazes;
Wherein, said polymer is selected from polyethylene, polypropylene, polyvinyl chloride, PETG, polybutylene terephthalate (PBT); Said lubricant is selected from paraffin, white oil, stearic acid, stearate; The said filler that hazes is that particle diameter is 3 ~ 20 microns a solid particle;
Second step: the surface coated mould release that drenches membrane material is arranged at the pouring film.
Related content in the technique scheme is explained as follows:
1, in the such scheme, the said filler that hazes is at least a in silica, calcium hydroxide, talcum powder and the calcium sulfate.The effect of filler of hazing is to make the roughness of drenching the laminated polyester film of film on body paper reach 1.000um ~ 5.524um.The filler selection that hazes standard is: fusing point is higher than the solid particle of polymer, such as selecting titania powder etc.
2, said white oil is meant slab oil.White oil is the specialty minerals oil product of ultra deep refining, and it is that main component is the mixture of the positive isoparaffin of C16~C31, belongs to lube cut, and colourless, tasteless, nothing is smelt, and has chemical inertness and good light, heat endurance.
3, in the such scheme, said stearate comprises calcium stearate, dolomol, zinc stearate and odium stearate.
4, in the such scheme, said paraffin comprises atoleine and solid paraffin.
5, in the such scheme, the effect of said lubricant is the smooth property that improves when drenching film, improves the speed of drenching film of extruding.
6, in the such scheme, drench film and can extrude to drench on the film machine at single screw rod or twin-screw and carry out.
7, in the such scheme, the particle diameter of the said filler that hazes is 8 ~ 15 microns.
8, in the such scheme, base material comprises that single face drenches film common leaching membrane layer (drenching the leaching membrane layer of the surfacing of film like prior art) is arranged, and what make like this is that one side is smooth, the release liners that another side is coarse.
Because the technique scheme utilization, the present invention compared with prior art has advantage and effect:
1, the present invention is drenched the film machine spoons fusion on the paper surface of body paper or single face leaching membrane paper pouring membrane material through extruding; Surface at body paper forms leaching membrane layer; On the even roughness face of cloudy surface leaching membrane layer, be coated with mould release then; The pressure-sensing glue glue face cloudy surface release liners that makes can make transfer when protection glue face after has concavo-convex uniformly, thereby makes the mist degree of glue face reach good effect; Further improve the fastness that combines between resin molding and the body paper.
2, the present invention can produce stable, the good cloudy surface release liners of pressure-sensing glue glue face mist degree effect of off-type force, makes transfer adhesive glue face reach low reflecting effect.Production technology of the present invention is simple, and the equipment input cost is low, and is easy to operate.
3, to select particle diameter for use be 3 ~ 20 microns solid particle in the present invention, thereby on base material, form coarse surface.When particle diameter will not have the effect of cloudy surface during less than 3 microns, when particle diameter can stop up the extruder head that drenches the film machine during greater than 20 microns.
The specific embodiment
Below in conjunction with embodiment the present invention is further described:
Embodiment one: a kind of preparation method of cloudy surface release liners
A kind of preparation method of cloudy surface release liners comprises the following steps to form:
The first step: the surface of clean base material (body paper).
Second step: adopt and drench at least one side surface pouring film pouring membrane material of film machine to base material, this composition of raw materials that drenches membrane material is made up of the material of following quality percentage composition:
Polymer 71.2% ~ 90.8%;
Lubricant 0.2% ~ 1.2%;
Filler 9% ~ 27.6% hazes;
Wherein, said polymer is selected from polyethylene, polypropylene, polyvinyl chloride, PETG, polybutylene terephthalate (PBT); Said lubricant is selected from paraffin, white oil, stearic acid, stearate; Said filler is that particle diameter is 3 ~ 20 microns a solid particle.
The 3rd step: will drench film has the body paper cooling of drenching membrane material.
The 4th step: the surface coated mould release that drenches membrane material is arranged at the pouring film.
The 5th step: rolling.
Optimal technical scheme of the present invention, the said filler that hazes are at least a in silica, calcium hydroxide, talcum powder and the calcium sulfate.
Optimal technical scheme of the present invention, said stearate comprises calcium stearate, dolomol, zinc stearate and odium stearate.
Optimal technical scheme of the present invention, said paraffin comprises atoleine and solid paraffin.
The concrete operations in ~ the four step of second step are: by behind the prescription weighing good material of the present invention; Be placed in the feeding mouth that drenches the film machine; Drench film then on body paper; After the leaching membrane layer cooling, on leaching membrane layer, apply one deck silicon mould release again, the roughness of the cloudy surface release liners that makes can reach 1.000um ~ 5.524um (roughness tester: the TR200 hand-held roughmeter of Beijing epoch peak Science and Technology Ltd. production).Mould release also can be selected water-based mould release etc. for use, and the kind of mould release and coating technique can adopt the ordinary skill in the art.
Embodiment two ~ six: a kind of preparation method of cloudy surface release liners
A kind of preparation method of cloudy surface release liners, mainly form by the following step:
The first step: adopt and drench at least one side surface pouring film pouring membrane material of film machine to base material, this composition of raw materials that drenches membrane material is made up of the material of following quality percentage composition:
? Polymer Lubricant Filler hazes
Embodiment two 71.2% 1.2% 27.6%
Embodiment three 90.8% 0.2% 9%
Embodiment four 85% 0.4% 14.6%
Embodiment five 80% 0.5% 19.5%
Embodiment six 75% 0.6% 24.4%
Annotate: what 1, the percentage sign in the form was represented is the quality percentage composition.
2, polymer: embodiment two, polyethylene; Embodiment three, polypropylene; Embodiment four, PVC; Embodiment five, PET; Embodiment six, polypropylene and polyethylene are according to the mass ratio of 1 ︰ 1.
3, lubricant: embodiment two, white oil; Embodiment three, dolomol; Embodiment four, solid paraffin; Embodiment five, white oil and stearic acid are according to the mass ratio of 2 ︰ 1; Embodiment six, calcium stearate.
4, haze filler: embodiment two, silica; Embodiment three, calcium hydroxide; Embodiment four, talcum powder; Embodiment five, calcium sulfate; Embodiment six, silica and talcum powder are according to the mass ratio of 1 ︰ 1.
Second step: the surface coated mould release that drenches membrane material is arranged at the pouring film.
The foregoing description only is explanation technical conceive of the present invention and characteristics, and its purpose is to let the personage who is familiar with this technology can understand content of the present invention and enforcement according to this, can not limit protection scope of the present invention with this.All equivalences that spirit is done according to the present invention change or modify, and all should be encompassed within protection scope of the present invention.

Claims (3)

1. the preparation method of a cloudy surface release liners is characterized in that: mainly be made up of the following step:
The first step: adopt and drench at least one side surface pouring film pouring membrane material of film machine to base material, this composition of raw materials that drenches membrane material is made up of the material of following quality percentage composition:
Polymer 71.2% ~ 90.8%;
Lubricant 0.2% ~ 1.2%;
Filler 9% ~ 27.6% hazes;
Wherein, said polymer is selected from polyethylene, polypropylene, polyvinyl chloride, PETG, polybutylene terephthalate (PBT); Said lubricant is selected from paraffin, white oil, stearic acid, stearate; The said filler that hazes is that particle diameter is 3 ~ 20 microns a solid particle;
Second step: the surface coated mould release that drenches membrane material is arranged at the pouring film.
2. the preparation method of cloudy surface release liners according to claim 1 is characterized in that: the said filler that hazes is at least a in silica, calcium hydroxide, talcum powder and the calcium sulfate.
3. the preparation method of cloudy surface release liners according to claim 1 and 2 is characterized in that: the particle diameter of the said filler that hazes is 8 ~ 15 microns.
CN2012101077552A 2012-04-13 2012-04-13 Producing method of matt release paper Pending CN102619133A (en)

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Application Number Priority Date Filing Date Title
CN2012101077552A CN102619133A (en) 2012-04-13 2012-04-13 Producing method of matt release paper

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Application Number Priority Date Filing Date Title
CN2012101077552A CN102619133A (en) 2012-04-13 2012-04-13 Producing method of matt release paper

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103061207A (en) * 2012-12-20 2013-04-24 苏州斯迪克新材料科技股份有限公司 Preparation method of novel matte anti-static release paper
CN103709952A (en) * 2013-12-31 2014-04-09 深圳市摩码科技有限公司 Black matt rubber belt and making method thereof
CN104790253A (en) * 2012-12-20 2015-07-22 苏州斯迪克新材料科技股份有限公司 Matte release agent with anti-static function
CN104961948A (en) * 2015-05-29 2015-10-07 吉翔宝(太仓)离型材料科技发展有限公司 PE release film having weathering resistance
CN104962043A (en) * 2015-05-29 2015-10-07 吉翔宝(太仓)离型材料科技发展有限公司 PET photodiffusion release film
CN104975538A (en) * 2015-06-08 2015-10-14 东莞市尚鑫纸业有限公司 FPI release paper with flame retardant function
CN104988803A (en) * 2015-06-08 2015-10-21 东莞市尚鑫纸业有限公司 Anti-microbial release paper used in medical field
CN104988792A (en) * 2015-06-08 2015-10-21 东莞市尚鑫纸业有限公司 Method for preparing low-transfer release paper
CN105254976A (en) * 2015-10-28 2016-01-20 武汉华丽生物股份有限公司 Biomass lamination material for lamination paper and preparation method thereof
CN108166318A (en) * 2017-12-22 2018-06-15 嘉兴百川特种纸业有限公司 The special coating of release paper peeling effect can be improved
CN114108369A (en) * 2022-01-04 2022-03-01 苏州恒聪科技股份有限公司 Release layer high-temperature-resistant coating of release paper and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1916569A1 (en) * 2005-08-17 2008-04-30 Nippon Paper Industries Co., Ltd. Electrophotographic transfer paper
CN101886357A (en) * 2010-07-02 2010-11-17 中国乐凯胶片集团公司 Matt release paper for synthetic leather
CN102330381A (en) * 2011-07-12 2012-01-25 苏州斯迪克电子胶粘材料有限公司 Method for making fog face release paper
CN102391558A (en) * 2011-08-22 2012-03-28 湖南福泰数码材料科技有限公司 Method for preparing release paper with concave-convex grooved texture

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1916569A1 (en) * 2005-08-17 2008-04-30 Nippon Paper Industries Co., Ltd. Electrophotographic transfer paper
CN101886357A (en) * 2010-07-02 2010-11-17 中国乐凯胶片集团公司 Matt release paper for synthetic leather
CN102330381A (en) * 2011-07-12 2012-01-25 苏州斯迪克电子胶粘材料有限公司 Method for making fog face release paper
CN102391558A (en) * 2011-08-22 2012-03-28 湖南福泰数码材料科技有限公司 Method for preparing release paper with concave-convex grooved texture

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105111921A (en) * 2012-12-20 2015-12-02 苏州斯迪克新材料科技股份有限公司 Antistatic release material for protecting adhesive tapes
CN104790253A (en) * 2012-12-20 2015-07-22 苏州斯迪克新材料科技股份有限公司 Matte release agent with anti-static function
CN104790252A (en) * 2012-12-20 2015-07-22 苏州斯迪克新材料科技股份有限公司 Anti-static matte release agent
CN104788637A (en) * 2012-12-20 2015-07-22 苏州斯迪克新材料科技股份有限公司 Release film with small release force
CN103061207B (en) * 2012-12-20 2015-07-22 苏州斯迪克新材料科技股份有限公司 Preparation method of novel matte anti-static release paper
CN103061207A (en) * 2012-12-20 2013-04-24 苏州斯迪克新材料科技股份有限公司 Preparation method of novel matte anti-static release paper
CN103709952A (en) * 2013-12-31 2014-04-09 深圳市摩码科技有限公司 Black matt rubber belt and making method thereof
CN104961948A (en) * 2015-05-29 2015-10-07 吉翔宝(太仓)离型材料科技发展有限公司 PE release film having weathering resistance
CN104962043A (en) * 2015-05-29 2015-10-07 吉翔宝(太仓)离型材料科技发展有限公司 PET photodiffusion release film
CN104975538A (en) * 2015-06-08 2015-10-14 东莞市尚鑫纸业有限公司 FPI release paper with flame retardant function
CN104988803A (en) * 2015-06-08 2015-10-21 东莞市尚鑫纸业有限公司 Anti-microbial release paper used in medical field
CN104988792A (en) * 2015-06-08 2015-10-21 东莞市尚鑫纸业有限公司 Method for preparing low-transfer release paper
CN105254976A (en) * 2015-10-28 2016-01-20 武汉华丽生物股份有限公司 Biomass lamination material for lamination paper and preparation method thereof
CN108166318A (en) * 2017-12-22 2018-06-15 嘉兴百川特种纸业有限公司 The special coating of release paper peeling effect can be improved
CN114108369A (en) * 2022-01-04 2022-03-01 苏州恒聪科技股份有限公司 Release layer high-temperature-resistant coating of release paper and preparation method thereof

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Application publication date: 20120801