CN102613862B - Method for preparing heat transfer sand-planted door mat - Google Patents
Method for preparing heat transfer sand-planted door mat Download PDFInfo
- Publication number
- CN102613862B CN102613862B CN201210066829.2A CN201210066829A CN102613862B CN 102613862 B CN102613862 B CN 102613862B CN 201210066829 A CN201210066829 A CN 201210066829A CN 102613862 B CN102613862 B CN 102613862B
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- China
- Prior art keywords
- sand
- doormat
- ore
- polyurethane
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title abstract 3
- 239000004814 polyurethane Substances 0.000 claims abstract description 36
- 229920002635 polyurethane Polymers 0.000 claims abstract description 33
- 239000004576 sand Substances 0.000 claims abstract description 23
- 238000003756 stirring Methods 0.000 claims abstract description 9
- 239000011248 coating agent Substances 0.000 claims abstract description 3
- 238000000576 coating method Methods 0.000 claims abstract description 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 25
- 239000000758 substrate Substances 0.000 claims description 19
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 18
- 238000010023 transfer printing Methods 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 10
- 239000000693 micelle Substances 0.000 claims description 9
- 239000004408 titanium dioxide Substances 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 7
- LYCAIKOWRPUZTN-NMQOAUCRSA-N 1,2-dideuteriooxyethane Chemical group [2H]OCCO[2H] LYCAIKOWRPUZTN-NMQOAUCRSA-N 0.000 claims description 6
- 239000010920 waste tyre Substances 0.000 claims description 4
- 238000005516 engineering process Methods 0.000 abstract description 8
- 239000000463 material Substances 0.000 abstract description 5
- 238000001816 cooling Methods 0.000 abstract description 3
- 229920001971 elastomer Polymers 0.000 abstract description 3
- 239000004753 textile Substances 0.000 abstract description 3
- 239000002912 waste gas Substances 0.000 abstract description 3
- 239000002351 wastewater Substances 0.000 abstract description 3
- 239000011159 matrix material Substances 0.000 abstract 3
- 238000001035 drying Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 239000002699 waste material Substances 0.000 abstract 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000000428 dust Substances 0.000 description 4
- 239000002932 luster Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 238000007651 thermal printing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical class CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- -1 isocyanide ester Chemical class 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Abstract
The invention discloses a method for preparing a heat transfer sand-planted door mat. The method comprises the following steps of: (1) crushing waste automobile tires into rubber grains with the granularity of 18-22 meshes, mixing and stirring the rubber grains and polyurethane PU, putting into a pattern mold, and preparing a door mat matrix at the temperature of 150DEG C under the pressure of 15MPa; (2) coating PU on the door mat matrix, planting ore sand which is processed by PU, drying at the temperature of 120DEG C for 35 to 45 minutes, taking out, and cooling to room temperature; and (3) feeding the door mat matrix which is planted with sand into a transfer machine, performing heat transfer by covering the processed transfer paper, and obtaining door mat with various patterns. The ore sand representing patterns is coated with a polyester-like material, so that the ore sand has textile properties and is suitable for a heat transfer technology; therefore, a problem that a sand-planted door mat is single in color is solved, and patterns are bright and vivid; and moreover, waste gas and waste water are not generated and the product is safe and environment-friendly.
Description
Technical field
The present invention relates to one kind and plant sand doormat, particularly a kind of adopt Thermal-printing Technology to produce plant sand doormat.
Background technology
Doormat effectively reclaims attract dust, sewage, keep indoor cleaning commodity.Traditional doormat, selected material, substantially based on fiber, PVC, rubber, the doormat made of these materials, or attract dust ability is not high, or decontaminated water effect is little, effectively cannot reclaim attract dust, sewage, reduce the using function of doormat, cost is higher.Last century Mo, abroad starting with junk vehicle tire is that raw material makes doormat, can not work the mischief on the one hand, solve damaged tire pollution on the environment on the other hand to human body.
At the initial stage in this century, adopt junk vehicle tire to make doormat and start ripe gradually, over more than 10 year, on the original basis, have developed: colored (on black micelle bag color) doormat, the doormat of the various fabric of compound, compound nonwoven cloth color printing doormat, flocking door mat, plants sand doormat.
Planting sand doormat, is conventional doormat in prior art, and mainly at doormat uppper sand embedding, the clear dirt ability of ash disposal improved on sole is strong, and cleaning effect is good.But it is single to plant sand doormat color and luster, and color and luster is bright-coloured not, can not meet the requirement of domestic environment to art work image.Plant sand transfer printing doormat pattern lively, bright in luster, solve unification practical and attractive in appearance.Plant husky transfer printing doormat husky for raw material with damaged tire, ore deposit, adopt the caloric transfer printing technology of free of contamination advanced person, not dust discharge in production process, gas, water, production technology and product all reach environment friendly and pollution-free standard.
Summary of the invention
The invention provides a kind of hot transfer printing and plant sand doormat, pattern is vividly bright-coloured, has art work image; Production process does not produce waste gas, waste water, product safety environmental protection.
The present invention is realized by following technical scheme:
A preparation method for sand doormat is planted in hot transfer printing, is to be realized by following step:
(1) waste tire of automobile is ground into 18 ~ 22 object micelles, the micelle pulverized and polyurethane Pu mix and blend, put into flower pattern mould, under pressure 15MP and temperature 150 DEG C of conditions, prepare doormat substrate;
(2) after applying polyurethane Pu layer in doormat substrate, plant the ore in sand form being made processing by polyurethane Pu, under 120 DEG C of conditions, dry 35 ~ 45min, after taking-up, be cooled to room temperature;
(3) send in transfer interpreter by planting the doormat substrate that sand completes, the transfer paper processed on multiple carries out hot transfer printing, obtains the doormat of various pattern.
The polyurethane Pu that the present invention uses is commercial polyurethane, (another name base polyurethane prepolymer for use as, chemical name: poly-propoxyl group ethyoxyl ether polyurethanes end isocyanide ester.)
In described step (2), the polyurethane Pu layer of coating is 10 μm.
Ore in sand form in described step (2) is rolled into and is divided into: 100 parts, ore in sand form, wrappage polyurethane Pu5 part, titanium dioxide 0.8 part, terephthalic acid (TPA) 4 parts, ethylene glycol 2 parts.
Ore in sand form in described step (2) is rolled into and is divided into: 100 parts, ore in sand form, wrappage polyurethane Pu10 part, titanium dioxide 2 parts, terephthalic acid (TPA) 4 parts, ethylene glycol 2 parts.
In described step (2), the idiographic flow of the ore in sand form of polyurethane Pu making processing is: cleaned by ore in sand form, control temperature is dry in 150 DEG C of baking ovens; Add 100 parts, ore in sand form, polyurethane Pu5 part, titanium dioxide 0.8 part, to this dioctyl phthalate 4 parts, ethylene glycol 2 parts or 100 parts, ore in sand form, polyurethane Pu10 part, titanium dioxide 2 parts, terephthalic acid (TPA) 4 parts, ethylene glycol 2 parts.Stir under normal temperature, after obtaining the uniform white ore in sand form of color, stop stirring; Control temperature is 120 DEG C of above-mentioned white ores in sand form of baking, upset per minute 10 times.
The ore in sand form of above-mentioned processing mainly makes polyurethane Pu, titanium dioxide, terephthalic acid (TPA) (PTA), ethylene glycol (EG) be coated on ore in sand form surface, the material of a kind terylene is formed on ore in sand form surface, make ore in sand form surface become class textile, then by caloric transfer printing technology, ore in sand form is caught color.
The beneficial effects of the utility model are:
1, adopt Thermal-printing Technology surface to be wrapped up class textile ore in sand form and plant in doormat substrate, carry out hot transfer printing, solve and formerly plant the single problem of sand doormat color and luster, make pattern become bright-coloured, lively, make product have art work image;
2, former planting in the manufacturing process of sand doormat does not have organic matter to volatilize the problem of contaminated environment.
3, advanced caloric transfer printing technology, does not produce waste gas, waste water, product safety environmental protection.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described.
Embodiment 1
(1) get ore in sand form carry out clean after proceed to baking oven, control temperature is 150 DEG C dries; Get ore in sand form 100Kg, polyurethane Pu5Kg, titanium dioxide 0.8Kg, PTA4Kg, EG2Kg, stir at normal temperatures, and above-mentioned material is coated on ore in sand form surface gradually, after final the uniform white ore in sand form of color, stops stirring; Control temperature is 120 DEG C of above-mentioned white ores in sand form of baking, and upset per minute 10 times, terminates after oven dry, be cooled to room temperature.
(2) get waste tire of automobile to pulverize, be filtered into 18 ~ 22 object micelles, add polyurethane Pu mix and blend in the micelle pulverized, put into flower pattern mould, under pressure 15MP and temperature 150 DEG C of conditions, prepare doormat substrate, doormat substrate is carried out cooling and place;
(3) the doormat substrate completed in above-mentioned preparation applies polyurethane Pu layer, and this polyurethane Pu layer is 10 μm; The doormat substrate that this has polyurethane Pu layer is planted the ore in sand form being made processing in step (1) by polyurethane Pu, 35 ~ 45min is dried under 120 DEG C of conditions, be cooled to room temperature after taking-up, the doormat substrate tool surface after taking-up has fibrous material texture;
(4) send in transfer interpreter by planting the doormat substrate that sand completes, the transfer paper processed on multiple carries out hot transfer printing, obtains the doormat of various pattern.
Embodiment 2
(1) get ore in sand form carry out clean after proceed to baking oven, control temperature is 150 DEG C dries; Get ore in sand form 100Kg, polyurethane Pu10Kg, titanium dioxide 2Kg, PTA4Kg, EG2Kg mix, and stir at normal temperatures, are coated on ore in sand form surface gradually, after final the uniform white ore in sand form of color, stop stirring; Control temperature is 120 DEG C of above-mentioned white ores in sand form of baking, and upset per minute 10 times, terminates after oven dry, be cooled to room temperature.
(2) get waste tire of automobile to pulverize, be filtered into 18 ~ 22 object micelles, add polyurethane Pu mix and blend in the micelle pulverized, put into flower pattern mould, under pressure 15MP and temperature 150 DEG C of conditions, prepare doormat substrate, doormat substrate is carried out cooling and place;
(3) the doormat substrate completed in above-mentioned preparation applies polyurethane Pu layer, and this polyurethane Pu layer is 10 μm; The doormat substrate that this has polyurethane Pu layer is planted the ore in sand form being made processing in step (1) by polyurethane Pu, 35 ~ 45min is dried under 120 DEG C of conditions, be cooled to room temperature after taking-up, the doormat substrate tool surface after taking-up has fibrous material texture;
(4) send in transfer interpreter by planting the doormat substrate that sand completes, the transfer paper processed on multiple carries out hot transfer printing, obtains the doormat of various pattern.
Claims (3)
1. a preparation method for sand doormat is planted in hot transfer printing, it is characterized in that by following step realize:
(1) waste tire of automobile is ground into 18 ~ 22 object micelles, the micelle pulverized and polyurethane Pu mix and blend, put into flower pattern mould, under pressure 15MP and temperature 150 DEG C of conditions, prepare doormat substrate;
(2) after applying polyurethane Pu layer in doormat substrate, plant the ore in sand form being made parcel by polyurethane Pu, under 120 DEG C of conditions, dry 35 ~ 45min, after taking-up, be cooled to room temperature; Wherein, the idiographic flow that polyurethane Pu makes the ore in sand form of parcel is: cleaned by ore in sand form, control temperature is dry in 150 DEG C of baking ovens, add 100 parts, ore in sand form, polyurethane Pu5 part, titanium dioxide 0.8 part, terephthalic acid (TPA) 4 parts and ethylene glycol 2 parts, stir under normal temperature, after obtaining the uniform white ore in sand form of color, stop stirring, control temperature is 120 DEG C of above-mentioned white ores in sand form of baking, upset per minute 10 times;
(3) send in transfer interpreter by planting the doormat substrate that sand completes, the transfer paper processed on multiple carries out hot transfer printing, obtains the doormat of various pattern.
2. the preparation method of sand doormat is planted in a kind of hot transfer printing as claimed in claim 1, it is characterized in that the polyurethane Pu layer of coating in described step (2) is 10 μm.
3. the preparation method of sand doormat is planted in a kind of hot transfer printing as claimed in claim 1, it is characterized in that the composition that adds in described step (2) is: 100 parts, ore in sand form, polyurethane Pu 10 parts, titanium dioxide 2 parts, terephthalic acid (TPA) 4 parts, ethylene glycol 2 parts.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201210066829.2A CN102613862B (en) | 2012-03-14 | 2012-03-14 | Method for preparing heat transfer sand-planted door mat |
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Application Number | Priority Date | Filing Date | Title |
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CN201210066829.2A CN102613862B (en) | 2012-03-14 | 2012-03-14 | Method for preparing heat transfer sand-planted door mat |
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CN102613862A CN102613862A (en) | 2012-08-01 |
CN102613862B true CN102613862B (en) | 2015-03-11 |
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CN201210066829.2A Expired - Fee Related CN102613862B (en) | 2012-03-14 | 2012-03-14 | Method for preparing heat transfer sand-planted door mat |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1286162A (en) * | 1999-08-28 | 2001-03-07 | 苏峰霖 | Antiskid sandcloth with pattern and its making method |
US6843815B1 (en) * | 2003-09-04 | 2005-01-18 | 3M Innovative Properties Company | Coated abrasive articles and method of abrading |
CN101613500A (en) * | 2009-04-24 | 2009-12-30 | 上海惠利橡塑制品有限公司 | A kind of method of utilizing waste old to make ground cushion |
CN201734453U (en) * | 2009-04-24 | 2011-02-09 | 上海惠利橡塑制品有限公司 | Rubber ground mat with sand-plated surface |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07166155A (en) * | 1994-08-24 | 1995-06-27 | Kokusai Gijutsu Boeki Kk | Production of non-slip material |
JP4191394B2 (en) * | 2001-07-31 | 2008-12-03 | 壽弥 村山 | Method for producing colored cinnabar |
-
2012
- 2012-03-14 CN CN201210066829.2A patent/CN102613862B/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1286162A (en) * | 1999-08-28 | 2001-03-07 | 苏峰霖 | Antiskid sandcloth with pattern and its making method |
US6843815B1 (en) * | 2003-09-04 | 2005-01-18 | 3M Innovative Properties Company | Coated abrasive articles and method of abrading |
CN101613500A (en) * | 2009-04-24 | 2009-12-30 | 上海惠利橡塑制品有限公司 | A kind of method of utilizing waste old to make ground cushion |
CN201734453U (en) * | 2009-04-24 | 2011-02-09 | 上海惠利橡塑制品有限公司 | Rubber ground mat with sand-plated surface |
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Granted publication date: 20150311 Termination date: 20180314 |