CN102603968A - High molecular polymer water absorbing material for well drilling leak stoppage - Google Patents
High molecular polymer water absorbing material for well drilling leak stoppage Download PDFInfo
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- CN102603968A CN102603968A CN2011102568190A CN201110256819A CN102603968A CN 102603968 A CN102603968 A CN 102603968A CN 2011102568190 A CN2011102568190 A CN 2011102568190A CN 201110256819 A CN201110256819 A CN 201110256819A CN 102603968 A CN102603968 A CN 102603968A
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Abstract
The invention relates to a high molecular polymer water absorbing material for well drilling leak stoppage. The water absorbing material is obtained by copolymerizing a monomer A, a monomer B, a crosslinking agent, an initiator and an inorganic filling material at a certain constant temperature. The water absorbing material has the advantages of simple preparation process, easiness and convenience for operating, 3-7 times of water absorbing multiple, high toughness, high deformation capability and capability of resisting high temperature of 150 DEG C in drilling fluid, and is suitable for high-strength leak stoppage, pressure-bearing leak stoppage and reservoir shielding temporary stoppage operation of pores, cracks and crushable leak formations in a drilling process.
Description
Technical field:
The present invention relates to a kind of drilling leakage blockage and use the high molecular polymer water-absorbing material, belong to macromolecule material preparation area, particularly relate to a kind of drilling plugging agent.
Background technology:
Leakage is the medium-term and long-term technical barrier that exists and fail fine solution of drilling process.The processing of leakage has at present been leaked by seeing of beginning and has just stifledly been developed into present putting prevention first, anti-blocking bonded technical thought, but along with the going deep into of exploratory development, the complicated Slot Handling of bad ground remains a leak stopping difficult problem.With the high molecular polymer is material of main part; Cooperate first, final set linking agent; Crosslinking time regulator and toughener etc.; Artificial control patching materials gets into drop ply with liquid state or colloidal form, and formation pore and fracture morphology and size flexibility are good with missing, and becomes one of direction of patching materials and leakage stopping technology development gradually.
High molecular polymer class patching materials generally is prepared from through hydrophilic high molecular materials such as vinylformic acid, acrylic amides, in order to improve plugging agent gelling strength and toughness, also in becoming the glue process, adds inorganic materials, like CN1080642A; Or the adding inorganic filling material forms better intensity and flexible water-absorbing material such as CN85102156 in the polymkeric substance building-up process.The aforesaid propylene acids is owing to added activation kaolin and wilkinite; Make the composite performance of water-absorbing resin increase, especially resistance toheat increases, generally below 120 ℃; Be not suitable for 150 ℃ of high-temperature stratum leak stopping demands; And the water-absorbing material that forms suction multiple is too high, and toughness is relatively poor, causes leak stopping slurry preparation difficulty, plugged zone bearing capacity low.
Summary of the invention:
The objective of the invention is for a little less than overcoming above patching materials bearing resistance, deficiency such as temperature resistance ability, develop a kind of drilling leakage blockage with high molecular polymer class water-absorbing material.
The present invention realizes through following technical proposals:
The present invention is formed by the constant temperature copolymerization at a certain temperature of monomer A, monomers B, linking agent, initiator and inorganic filling material.
Above-mentioned monomer A is an organic acid: comprise CH
2(CH
3)
RCHCOOH, R=0 wherein, 1,2 ... With in 2-acrylamido-2-methyl propane sulfonic acid one or both, or maleic anhydride;
Above-mentioned monomers B is organic amide class: CH
2(CH
3)
RCHCONH
2, R=0 wherein, 1,2 ... Or at least a in the N hydroxymethyl acrylamide;
Above-mentioned linking agent is: N,N methylene bis acrylamide;
Above-mentioned initiator is Potassium Persulphate or ammonium persulphate and sodium sulfite anhy 96.
Above-mentioned inorganic filling material can be at least a in kaolin, wilkinite, atlapulgite, the silica flour.
The quality ratio range of above-mentioned each material is: monomer A: monomers B: linking agent: initiator: inorganic filling material=(5% ~ 30%): (20% ~ 70%): (0.08% ~ 0.4%): (0.8% ~ 1.9%): (20% ~ 55%).
The invention has the beneficial effects as follows that preparation technology is simple; Easy and simple to handle; Products obtained therefrom suction multiple is 3 ~ 7 times, better toughness and deformability are arranged; In drilling fluid, can tolerate 150 ℃ of high temperature, be applicable to HS leak stopping, pressure-bearing leak stopping and the operation of reservoir shield-temporary plugging on hole, crack and crumbliness leakage stratum in the drilling process.
Embodiment:
Add 10g vinylformic acid in the embodiment 1:300g water, the sodium hydroxide solution with 40% is regulated pH value to 8 ~ 11, adds the 40g acrylic amide again; The 50g wilkinite stirs; Add 0.8g Potassium Persulphate and 0.08g N, the N-DMAA is at 50 ℃ of following isothermal reaction 3h; Obtain block aquogel polymer, after broken, oven dry, pulverizing, obtain drilling leakage blockage with high molecular polymer class water-absorbing material.
Other specific embodiments provide component according to table 1 and prepare.
Table 1 drilling leakage blockage is with high molecular polymer water-absorbing material embodiment (unit by percentage to the quality)
Table 2 has been listed the performance index of the given embodiment of table 1
Can know that by table 2 the suction multiple of normal temperature of the present invention is 3 ~ 7 times, explain to have better toughness and deformability, in drilling fluid, can tolerate 150 ℃ of high temperature.
Claims (6)
1. a drilling leakage blockage is used the high molecular polymer water-absorbing material, it is characterized in that: form by monomer A, monomers B, linking agent, initiator and inorganic filling material copolymerization,
Monomer A is an organic acid, comprising: CH
2(CH
3)
RCHCOOH, R=0 wherein, 1,2 ... With in 2-acrylamido-2-methyl propane sulfonic acid one or both, or maleic anhydride;
Monomers B is the organic amide class: comprise CH
2(CH
3)
RCHCONH
2, R=0 wherein, 1,2 ... Or in the N hydroxymethyl acrylamide one or both.
2. a kind of drilling leakage blockage according to claim 1 is used the high molecular polymer water-absorbing material, it is characterized in that: said linking agent is a N,N methylene bis acrylamide.
3. a kind of drilling leakage blockage according to claim 1 and 2 is used the high molecular polymer water-absorbing material, it is characterized in that: said initiator is Potassium Persulphate or ammonium persulphate and sodium sulfite anhy 96.
4. a kind of drilling leakage blockage according to claim 1 is used the high molecular polymer water-absorbing material, it is characterized in that: said inorganic filling material is a kind of or its arbitrary combination in kaolin, wilkinite, atlapulgite or the silica flour.
5. use the high molecular polymer water-absorbing material according to claim 1 or 2 or 4 described a kind of drilling leakage blockages, it is characterized in that: the quality ratio range of above-mentioned each material is: monomer A: monomers B: linking agent: initiator: inorganic filling material=(5% ~ 30%): (20% ~ 70%): (0.08% ~ 0.4%): (0.8 ~ %1.9%): (20% ~ 55%).
6. a kind of drilling leakage blockage according to claim 5 is used the high molecular polymer water-absorbing material, it is characterized in that: the quality ratio range of above-mentioned each material is: monomer A: monomers B: linking agent: initiator: inorganic filling material=(5% ~ 30%): (20% ~ 60%): (0.08% ~ 0.4%): (0.8% ~ 1.9%): (25% ~ 50%).
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Cited By (24)
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CN103923257A (en) * | 2014-04-18 | 2014-07-16 | 中国石油集团渤海钻探工程有限公司 | Compound super absorbent resin and preparation method thereof |
CN104357026A (en) * | 2014-05-30 | 2015-02-18 | 中国石油化工集团公司 | Treating agent for zwitter-ion inorganic-organic monomer polymer drilling fluid and preparation method of treating agent |
CN104371062A (en) * | 2013-08-16 | 2015-02-25 | 中国石油化工股份有限公司 | Acrylamide quadripolymer, preparation method and application thereof |
CN104388066A (en) * | 2014-10-31 | 2015-03-04 | 中国石油化工集团公司 | Preparation method of plugging agent for drilling fluid |
CN104387530A (en) * | 2014-11-21 | 2015-03-04 | 天津科技大学 | Preparation method of high-content calcium bentonite water shutoff agent |
CN104448136A (en) * | 2014-10-31 | 2015-03-25 | 中国石油化工集团公司 | Preparation method of while-drilling plugging fluid for oil-based drilling fluid |
CN104449613A (en) * | 2014-10-31 | 2015-03-25 | 中国石油化工集团公司 | Water-absorbent resin temporary plugging agent and preparation method thereof |
CN105154032A (en) * | 2014-06-12 | 2015-12-16 | 中国石油化工股份有限公司 | Inorganic-organic polymer processing agent for drilling fluid and preparation method thereof |
CN105154030A (en) * | 2014-06-12 | 2015-12-16 | 中国石油化工股份有限公司 | Inorganic-organic polymer processing agent for drilling fluid and preparation method thereof |
CN105219358A (en) * | 2014-06-12 | 2016-01-06 | 中国石油化工股份有限公司 | A kind of drilling fluid inorganic-organic polymer treatment agent and preparation method thereof |
CN105295857A (en) * | 2014-06-12 | 2016-02-03 | 中国石油化工股份有限公司 | Inorganic-organic polymer treatment agent for drilling fluid and preparation method therefor |
CN105368424A (en) * | 2015-10-20 | 2016-03-02 | 西南石油大学 | Intercalation delay in-situ polymerization water shutoff gel for high-temperature oil reservoir |
CN106010485A (en) * | 2016-05-23 | 2016-10-12 | 中国石油集团渤海钻探工程有限公司 | Self-cementing leaking stoppage agent and leaking stoppage method |
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CN107189772A (en) * | 2017-05-02 | 2017-09-22 | 中国地质大学(武汉) | One kind can water swelling sealing agent |
CN108727535A (en) * | 2017-04-21 | 2018-11-02 | 中国石油化工股份有限公司 | A kind of delay water swelling sealing agent and preparation method thereof |
CN109942748A (en) * | 2019-03-26 | 2019-06-28 | 刘骞 | A kind of viscous crude flooding polymers and its preparation method and application |
CN110144198A (en) * | 2019-06-13 | 2019-08-20 | 中国石油集团长城钻探工程有限公司 | A kind of oil base drilling fluid GEL USED FOR PLUGGING WELL LOST CIRCULATION and preparation method thereof |
CN110746950A (en) * | 2019-11-04 | 2020-02-04 | 陕西科技大学 | Temperature switch type temporary plugging agent and preparation method and application thereof |
CN110746537A (en) * | 2019-12-04 | 2020-02-04 | 中南林业科技大学 | Binary copolymer super absorbent resin |
CN111100238A (en) * | 2019-12-20 | 2020-05-05 | 克拉玛依市正诚有限公司 | Salt water resistant plugging agent and preparation method thereof |
CN111777854A (en) * | 2020-07-23 | 2020-10-16 | 杭州每步材料科技有限公司 | Novel environment-friendly flame-retardant polyurethane grouting material and preparation method thereof |
CN112940694A (en) * | 2021-02-05 | 2021-06-11 | 中国石油天然气股份有限公司 | Environment-friendly composite leakage-stopping liquid for water-based drilling fluid and preparation method thereof |
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