CN102590102A - Standard sample for spectroscopic analysis of welding wire steel ER50-6 - Google Patents

Abstract

The invention discloses a standard sample for spectroscopic analysis of a welding wire steel ER50-6, and belongs to the technical fields of new materials and metallurgical analysis. The standard sample is a cylinder the standard of which is phi 40 mm* phi 40mm, and comprises the following constituents: iron serving as a matrix constituent; and alloying element constituents: 0.07-0.09% of C, 0.88-0.92% of Si, 1.45-1.55% of Mn, 0.018-0.022% of P, 0.01-0.015% of S, 0.02-0.03% of Cr, 0.005-0.01% of Ni,0.005-0.01% of Cu, and the contents of other impurity elements are all less than 0.005%. The standard sample has the advantages of good uniformity, exact magnitude and good stability, and is convenient to use; can meet job requirements of a spectrograph such as calibration and test, and provides a good material standard for measuring free cutting steel SAE1215.

Description

Standard model is used in welding wire steel ER50-6 spectral analysis

Technical field

The present invention relates to a kind of welding wire steel ER50-6 spectral analysis and use standard model, belong to new material and metallurgical analysis technical field.

Background technology

ER50-6 is the carbon steel arc welding wire, has good plasticity, toughness and cracking resistance, and especially low-temperature impact toughness is higher.Be used for the bottoming of pipeline GTAW and the arc-welding of all places, can obtain satisfied welding joint, can weld some carbon steel and low alloy steel.For strictness control product quality, the accurate mensuration of elemental composition in this steel grade is had very important significance.The constituent analysis iron and steel enterprise of alloy steel adopts emission spectrometry more, be unable to do without standard sample for spectrochemical analysis when carrying out spectral analysis.As far as the accuracy that detects, the composition of standard sample for spectrochemical analysis and matrix and test substance are approaching more, obtain accurate analytical results more easily; If particularly the composition of material is too complicated; When alloying element content is high, very easily forms spectrum and disturb, thereby influence testing result.And also not having standard sample for spectrochemical analysis at present to this steel grade detection usefulness, this steel belongs to high silicon, Gao Meng, low-carbon (LC), low-sulfur and the low alloy steel of other impurity elements, presses for a kind of component content and the approaching standard sample for spectrochemical analysis of this steel grades.

Summary of the invention

In order to satisfy the ER50-6 product is carried out quality control and the requirement that accurately detects, the accuracy that improves spectrum Instrument measuring the invention provides a kind of good uniformity, reliable and stable, definite value welding wire steel ER50-6 standard sample for spectrochemical analysis accurately.

Technical scheme of the present invention is: standard model is used in a kind of welding wire steel ER50-6 spectral analysis; It is characterized in that specification is the right cylinder of Φ 40mm * 40mm, composition is: iron is the matrix composition; Alloy element component and content thereof are seen table 1, the content of other impurity element all＜0.005wt%.

Table 1 welding wire steel ER50-6 spectral analysis is with standard model alloy element component and content

The preparation process: the preparation → segregation of composition design → material standed for checks → is rolled into Φ 45mm round steel → finishing car to process Φ 40mm spectrum piece → mark, marking → uniformity testing → definite value analysis → mathematical statistics → definite value → packing

The preparation process of standard model piece, specific as follows:

(1) by the ingredient composition of design, adopt the 500kg intermediate frequency furnace to smelt, utilize induced magnetism to stir, guarantee that molten steel component is even, deoxidizer is selected fine aluminium for use, adopts φ 180mm ingot shape metal pattern, the method for making a bet moulding by casting;

(2) steel ingot forges after 3 hours 1100 ℃-1200 ℃ insulations, is swaged into 80mm * 80mm * 2000mm square billet, the air cooling; Then essential element is carried out segregation check, the range method judged result, qualified after, 1050 ℃-1100 ℃ insulations 1 hour, be rolled into Φ 45mm * 1000mm pole;

(3) roll good pole and number, descale, tack is processed into Φ 40mm * 40mm spectrum piece.

Beneficial effect: this standard model good uniformity, value is accurate, impurity content is low, good stability, easy to use, can satisfy the job requirement such as calibration, test of spectrometer, for measuring this type of alloy steel a kind of good material standard is provided.

Embodiment

Embodiment 1

1. composition design: iron is the matrix composition, and alloy element component and content thereof are seen table 1, the content of other impurity element all＜0.005wt%.

2. preparation method:

(1) by the ingredient composition of design, adopt the 500kg intermediate frequency furnace to smelt, utilize induced magnetism to stir, guarantee that molten steel component is even, deoxidizer is selected fine aluminium for use, adopts φ 180mm ingot shape metal pattern, the method for making a bet moulding by casting;

(2) steel ingot forges after 3 hours 1100 ℃-1200 ℃ insulations, is swaged into 80mm * 80mm * 2000mm square billet, the air cooling; Then essential element is carried out segregation check, the range method judged result, qualified after, 1050 ℃-1100 ℃ insulations 1 hour, be rolled into Φ 45mm * 1000mm pole;

(3) roll good pole and number, descale, tack is processed into Φ 40mm * 40mm spectrum piece.

3. the uniformity testing of standard model

3.1 segregation check

The portion end to end of steel ingot along horizontal diagonal, is drilled through bits shape sample respectively at center and two jiaos, essential element is carried out the chemical constitution check.Institute's employing method, C, S are infrared absorption method, all the other elements are the ICP-AES method.The evaluation method of segregation assay does, the extreme difference of the chemical constitution of the element of being checked is compared with the precision of GB/T20123-2006 and GB/T20125-2006 analytical approach, and extreme difference thinks then that less than analytical approach precision segregation is up to the standards.The segregation assay is seen table 2, and the result shows that the segregation degree of material all can meet the demands, and segregation is up to the standards.

Table 2 ER50-6 spectral analysis is with industry standard sample segregation examination table (%)

3.2 uniformity testing

According to the requirement of standard model technical manual method of analysis of variance, (among the Φ 40mm * 40mm), take the method for grab sample, randomly draw 20 samples (by the sample serial number) and test at the spectrum piece that machines.Three different parts of xsect to every sample; On photo-electric direct reading spectrometer, each element is carried out assay determination; Assay is with the statistical treatment of one-way analysis of variance method, and calculates interblock unevenness standard deviation according to the formula of GB/T15000.3-2008.

The standard uncertainty u that the interblock unevenness causes _BbBe equal to interblock unevenness standard deviation S _Bb, calculate by following formula:

$u_{\mathrm{bb}}^2=u_{\mathrm{bb}}^2=\frac{{\mathrm{MS}}_{\mathrm{among}}-{\mathrm{MS}}_{\mathrm{within}}}{n_0}$

When method of testing repeated not good enough, use MS _WithinReplace interblock homogeneity research institute with the repeated variance of measuring, at this moment u _BbComputing formula is: $u_{\mathrm{Bb}}^2=\frac{{\mathrm{MS}}_{\mathrm{Within}}}{n}\sqrt[2]{\frac{2}{{\mathrm{\υ}}_{{\mathrm{MS}}_{\mathrm{Within}}}}}$

If statistic F＜F _a, then uniformity testing is qualified, the F of this uniformity testing _aBe 1.84.The result shows that each element homogeneity of this standard model is all good, satisfies standard model to inhomogeneity requirement, and the uniformity testing statistics is seen table 3.

Table 3 uniformity testing is table (%) as a result

The check of 4 definite values

4.1 definite value analysis

The preparation of definite value analytic sample: pole is after uniformity testing is qualified, and two of picked at random are taken crust off on lathe, and the remainder car is got behind the chip mixing as the definite value sample for analysis.

Except that our unit, specially invite and asked domestic unit (comprising our unit, totally 8 families) to participate in the definite value analysis, and select one or more analytical approachs accurately and reliably for use with certain testing level.The analytical approach that definite value adopts is seen table 4 respectively.

The analytical approach that table 4 definite value adopts

4.2 analyzing data gathers and processing

Analyzing data gathers and processing: respectively organize the result with the check of Cochran criterion and whether wait precision; With each mean value of Xia Piluo-welker's method examination accord with normal distribution whether; Whether there is exceptional value with each mean value of Grubbs method inspection.

The result: accuracy tests such as Cochran are all qualified; The no abnormal value of Grubbs each mean value of check; Mean value and the equal accord with normal distribution of total data or the similar normal state distribution of data respectively organized in test of normality.

Calculate arithmetic mean and the standard deviation of respectively organizing data, to the significant digit of standard value, carry out the revision of the convention according to the method precision by GB 8170 " numerical value rule for rounding off ", standard deviation is by the principle revision of the convention that only advances not give up, and standard deviation aligns with the figure place of standard value.

4.3 confirming and assessment on uncertainty of standard value

Standard value is the mean value of 8 tame unit definite values, and uncertainty comprises the instability standard deviation that the mean value standard deviation of definite value statistics and interblock unevenness standard deviation that uniformity testing counts and stable statistical test go out.Final standard value, the standard deviation of confirming sees the following form 5.

Table 5 ER50-6 spectral standard sample standard value, standard deviation and uncertain kilsyth basalt (wt%)

Annotate: expanded uncertainty in the table (k=2)

5, study on the stability

Iron and steel class standard stability of sample is good.Requirement by the standard model technical manual has been carried out study on the stability to this standard model, and the difference of twice measurement of all study on the stability projects does not all surpass the uncertainty of definite value.According to the 8.4.2 of GB/T15000.3-2008, if condition meets:

$|x_{\mathrm{CRM}}-x_{\mathrm{meas}}|\≤k\sqrt{u_{\mathrm{CRM}}^2+u_{\mathrm{meas}}^2}$

X in the formula _CRMThe characteristic value of expression CRM, x _MeasBe the observed reading of measuring, k comprises the factor, k=2 during confidence level 95%, u _CRMBe the uncertainty of characteristic value, u _MeasBe uncertainty of measurement.

The uncertainty of characteristic value is generally less than the uncertainty of measured value; The uncertainty of consideration characteristics value illustrative problem more only; Therefore with the absolute value of the difference of observed reading and characteristic value and the uncertainty comparison of characteristic value; If less than or approach the uncertainty of characteristic value, can think that so material is enough stable, stability has obtained proof.Compared the measured value of this standard specimen and the standard value of confirming in May, 2010, and the result sees table 6, has good stability.With reference to the standard sample for spectrochemical analysis of international and domestic other steel, stationary phase is more than 15 years.

Table 6 ER50-6 spectral analysis industry standard sample stability is investigated table

6, user's operation report (Laigang) is as shown in table 7

Table 7 user operation report (Laigang)

Can find out that from table 7 standard value of this standard model is very approaching with the measured value that adopts ICP or infrared method to measure, and proves that this standard model value is accurate.

Claims (3)

1. standard model is used in welding wire steel ER50-6 spectral analysis, it is characterized in that, specification is the right cylinder of Φ 40mm * 40mm, and composition is: iron is the matrix composition; Alloy element component and content thereof are: C 0.07～0.09wt%, Si 0.88～0.92wt%, Mn 1.45～1.55wt%; P 0.018～0.022wt%, S 0.01～0.015wt%, Cr 0.02～0.03wt%; Ni0.005～0.01wt%, Cu 0.005～0.01wt%, the content of other impurity element all＜0.005wt%.

2. standard model is used in a kind of welding wire steel ER50-6 as claimed in claim 1 spectral analysis, it is characterized in that, said alloy element component and content thereof are: C 0.076wt%; Si 0.90wt%, Mn 1.49wt%, P 0.020wt%; S 0.011wt%; Cr 0.024wt%, Ni 0.0059wt%, Cu 0.0076wt%.

3. a method for preparing the said welding wire steel ER50-6 of claim 1 spectral analysis with standard model is characterized in that,

(1) by the ingredient composition of claim 1, adopt the 500kg intermediate frequency furnace to smelt, utilize induced magnetism to stir, deoxidizer adopts fine aluminium; Adopt φ 180mm ingot shape metal pattern, the method for making a bet moulding by casting;

(2) steel ingot forges after 3 hours 1100 ℃-1200 ℃ insulations, is swaged into 80mm * 80mm * 2000mm square billet, the air cooling; Then essential element is carried out segregation check, the range method judged result, qualified after, 1050 ℃-1100 ℃ insulations 1 hour, be rolled into Φ 45mm * 1000mm pole;

(3) roll good pole and number, descale, tack is processed into Φ 40mm * 40mm spectrum piece.