CN102587126A - Fabric static electricity remover and preparation method thereof - Google Patents
Fabric static electricity remover and preparation method thereof Download PDFInfo
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- CN102587126A CN102587126A CN2011104567008A CN201110456700A CN102587126A CN 102587126 A CN102587126 A CN 102587126A CN 2011104567008 A CN2011104567008 A CN 2011104567008A CN 201110456700 A CN201110456700 A CN 201110456700A CN 102587126 A CN102587126 A CN 102587126A
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Abstract
The invention provides a fabric static electricity remover and a preparation method thereof. The fabric static electricity remover is prepared from polyalcohol, silicone oil, a cation surfactant, an amphoteric surfactant and deionized water. The fabric static electricity remover is prepared by combining the antistatic performance of the surfactants, the moisture absorption of the polyalcohol and the antistatic performance and flexibility of the silicone oil, so a fiber surface has moisture absorption and ionicity, the electric conductivity of the fiber surface is improved, and the aim of preventing static electricity is fulfilled. By adoption of the fabric static electricity remover, charges of a fabric surface can be quickly removed, and the static electricity is eliminated. The fabric static electricity remover has certain capacity of preventing the charges from being gathered and can be directly applied to the fabric surface and used for removing the static electricity; the phenomena of trace formation and color change of fabric are avoided; and the fabric static electricity remover has an obvious static electricity removing effect, and the phenomena of trace formation and color change of the surface of a fabric sheet are avoided.
Description
Technical field
The invention belongs to the composition of detergent field, specifically a kind of static of the fabric remover and preparation method thereof.
Background technology
Electrostatic phenomenon is that electrostatic charge is gathered the physical phenomenon of bringing at body surface because two kinds of differences or identical object process contact, separation or phase mutual friction produce electronics and move between object.In static ubiquity and the people's life, especially in autumn and winter in dry season, the static that exists everywhere brings very big inconvenience to people's life.Fabric is dirty because of fricative static not only makes the clothes dust suction be prone to, and clothes adhesion health also can disturb the person's of wearing the clothes motion freely, the generation sense of discomfort.Lasting static also can cause pruitus, pigmentation, influences people's organism physiology balance, disturbs people's mood.Higher electrostatic pressure also can produce electric shock to human body.
In recent years because the continuous increase of artificial fibre and synthetic fabrics; And the use of people's life style such as concrete dwelling house and air-conditioning etc. causes environment too dry; Electrostatic phenomenon is more and more aggravated, and the consumer receives publicity electrostatic problem to the demand of clothes comfortable function day by day.Therefore need a kind of use simple on the market, obvious results static of the fabric remover prevents that clothing from producing static.
Summary of the invention
The purpose of this invention is to provide a kind of static of the fabric remover and preparation method thereof, contain polyalcohol, silicone oil, cationic surfactant, amphoteric surfactant, deionized water in the raw material of this static of the fabric remover; This static of the fabric remover utilizes the antistatic behaviour of surfactant, the hygroscopicity of polyalcohol, and performance is composite forms for the antistatic behaviour of silicone oil and flexibility etc., makes fiber surface have hygroscopicity and ionic, improves its conductivity, reaches the purpose that prevents static.
The objective of the invention is to realize by following technical proposals:
A kind of static of the fabric remover is characterized in that: contain polyalcohol, silicone oil, cationic surfactant, amphoteric surfactant, deionized water in the raw material of this static of the fabric remover; The weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 2.0-5.0
Silicone oil 0.5-2.5
Cationic surfactant 0.5-1.5
Amphoteric surfactant 1.0-2.5
Deionized water 88-96;
Described polyalcohol can be one or more the mixture in glycerine, propylene glycol, D-sorbite, the 1,3 butylene glycol;
Described silicone oil is one or more the mixture in methyl-silicone oil, amido silicon oil, the polysiloxanes-many alkoxyls ether copolymer;
Described cationic surfactant is one or more the mixture in two alkyl-dimethyl ammonium chlorides, dialkyl ethoxy methylsulfuric acid ammonium methyl, the 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium;
Described amphoteric surfactant is one or more the mixture in hexadecyldimethyl benzyl ammonium betaine, Cocoamidopropyl betaine, cocamidopropyl propyl amide amine oxide, the imidazoline;
The objective of the invention is to realize by following another technical scheme:
A kind of preparation method of static of the fabric remover contains polyalcohol, silicone oil, cationic surfactant, amphoteric surfactant, deionized water in the raw material of this static of the fabric remover; The weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 2.0-5.0, silicone oil 0.5-2.5, cationic surfactant 0.5-1.5, amphoteric surfactant 1.0-2.5, deionized water 88-96;
The preparation method of this static of the fabric remover may further comprise the steps successively:
Get described polyalcohol, silicone oil, cationic surfactant, amphoteric surfactant according to above-mentioned weight proportion, in the addingization material still, obtain mixed liquor A; In described mixed liquor A, add described deionized water again and obtain described static of the fabric remover.
In above-mentioned preparation process, should note whole operation clean environment health, dustproof.
Because the present invention selects the cationic surfactant of performances such as having excellent antistatic and soft fabric for use; The amphoteric surfactant of the strong and mild low-stimulation of emulsifying ability, dispersion force, antistatic behaviour; Silicone oil antistatic by force, submissive ability is composite with having; So the present invention can remove the fabric face electric charge rapidly, eliminate static; And has an ability of certain prevention accumulation.
Because the present invention selects polyalcohol for use,, stop ion-conductance to be assembled so the present invention can increase the fabric face hygroscopicity.
Because good stability of the present invention, good water solubility so the present invention can directly be used in fabric face, is removed static, does not have fabric to stay trace, metachromatism.
According to the assay method among standard GB/T16801-1997 " mensuration of fabric conditioner antistatic property "; The fabric spray of test fixed dimension with before the present invention, resistance value afterwards, the quantity of electric charge; After can finding out obviously that use static of the fabric remover of the present invention is handled, dacron surface ratio resistance drop △ ρ s (Ω) is greater than 4.0 * 10
11So the present invention has tangible removal electrostatic efficiency.
Select the pieces of fabric of unlike material for use, static of the fabric remover of the present invention dries observation in the spraying, and pieces of fabric surface nothing stays the trace metachromatism to take place.
Description of drawings:
Fig. 1 for the static of the fabric remover of embodiment 2 spraying real silk fabric to contrasting.
Fig. 2 for another real silk fabric of the static of the fabric remover of embodiment 2 spraying to contrasting.
Fig. 3 for the static of the fabric remover of embodiment 2 spraying pure woolen fabric to contrasting.
Fig. 4 for the static of the fabric remover of embodiment 2 spraying rayon lining twill fabric to contrasting.
Fig. 5 for the static of the fabric remover of embodiment 2 spraying chemical & blended fabric to contrasting.
The specific embodiment
Embodiment 1:
A kind of static of the fabric remover contains polyalcohol, silicone oil, cationic surfactant, amphoteric surfactant, deionized water in the raw material of this static of the fabric remover; The weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 2.0-5.0
Silicone oil 0.5-2.5
Cationic surfactant 0.5-1.5
Amphoteric surfactant 1.0-2.5
Deionized water 88-96;
Described polyalcohol can be one or more the mixture in glycerine, propylene glycol, D-sorbite, the 1,3 butylene glycol;
Described silicone oil is one or more the mixture in methyl-silicone oil, amido silicon oil, the polysiloxanes-many alkoxyls ether copolymer;
Described cationic surfactant is one or more the mixture in two alkyl-dimethyl ammonium chlorides, dialkyl ethoxy methylsulfuric acid ammonium methyl, the 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium;
Described amphoteric surfactant is one or more the mixture in hexadecyldimethyl benzyl ammonium betaine, Cocoamidopropyl betaine, cocamidopropyl propyl amide amine oxide, the imidazoline;
The product brand of described 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium is USA/EVONIK-DEGUSSA, and product grade is Varisoft 3690, available from the permanent minister in Shanghai Industrial Co., Ltd..
The preparation method of this static of the fabric remover may further comprise the steps successively:
Get described polyalcohol, silicone oil, cationic surfactant, amphoteric surfactant according to above-mentioned weight proportion, in the addingization material still, obtain mixed liquor A; In described mixed liquor A, add described deionized water again, obtain described static remover.
In above-mentioned preparation process, should note whole operation clean environment health, dustproof.
The used unit of weight of present embodiment is a kilogram, also can be gram;
Each raw material described in the present embodiment is technical grade;
Each raw material described in the present embodiment is the conventional products of selling on the market;
In the present embodiment, each raw material in described can be in the ratio range that provides flexible combination, do not enumerate one by one at this.
Because the static of the fabric remover of present embodiment is selected the cationic surfactant of performances such as having excellent antistatic and soft fabric for use; The amphoteric surfactant of the strong and mild low-stimulation of emulsifying ability, dispersion force, antistatic behaviour; Silicone oil antistatic by force, submissive ability is composite with having; So the static of the fabric remover of present embodiment can be removed the fabric face electric charge rapidly, eliminate static; And has an ability of certain prevention accumulation.
Because the static of the fabric remover of present embodiment is selected polyalcohol for use,, stop ion-conductance to be assembled so the static of the fabric remover of present embodiment can increase the fabric face hygroscopicity.
Because the static of the fabric remover good stability of present embodiment, good water solubility so the static of the fabric remover of present embodiment can directly be used in fabric face, is removed static, does not have fabric to stay trace, metachromatism.
According to the assay method among standard GB/T16801-1997 " mensuration of fabric conditioner antistatic property "; The fabric spray of test fixed dimension with before the present invention, resistance value afterwards, the quantity of electric charge; After can finding out obviously that the static of the fabric remover that uses present embodiment is handled, dacron surface ratio resistance drop △ ρ s (Ω) is greater than 4.0 * 10
11So present embodiment has tangible removal electrostatic efficiency.
Select the pieces of fabric of unlike material for use, the static of the fabric remover of present embodiment dries observation in the spraying, and pieces of fabric surface nothing stays the trace metachromatism to take place.
Embodiment 2:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 2
Silicone oil 1.2
Cationic surfactant 0.5
Amphoteric surfactant 1
Deionized water 95.3;
Described polyalcohol is a glycerine; Described silicone oil is methyl-silicone oil and polysiloxanes-many alkoxyls ether copolymer mixture, and the weight ratio of described methyl-silicone oil and polysiloxanes-many alkoxyls ether copolymer is 0.2:1; Described cationic surfactant is two alkyl-dimethyl ammonium chlorides; Described amphoteric surfactant is a Cocoamidopropyl betaine.
The used unit of weight of present embodiment is a kilogram, also can be gram.
According to the assay method among standard GB/T16801-1997 " mensuration of fabric conditioner antistatic property "; The fabric spray of test fixed dimension with before this described static of the fabric remover, resistance value afterwards, the quantity of electric charge; After can finding out obviously that the static of the fabric remover that uses present embodiment is handled, dacron surface ratio resistance drop △ ρ s (Ω) is greater than 4.0 * 10
11So the static of the fabric remover of present embodiment has tangible removal electrostatic efficiency.
Select the pieces of fabric of unlike material for use, the static of the fabric remover of present embodiment dries observation in the spraying, and pieces of fabric surface nothing stays the trace metachromatism to take place.Fig. 1 for the static of the fabric remover of present embodiment spraying real silk fabric to contrasting; Fig. 1 left side is the real silk fabric sheet of the static of the fabric remover that do not spray present embodiment, the real silk fabric sheet of Fig. 1 right side after for the static of the fabric remover of spraying present embodiment;
Fig. 2 for another real silk fabric of the static of the fabric remover of present embodiment spraying to contrasting; Fig. 2 left side is the real silk fabric sheet of the static of the fabric remover that do not spray present embodiment, the real silk fabric sheet of Fig. 2 right side after for the static of the fabric remover of spraying present embodiment;
Fig. 3 for the static of the fabric remover of present embodiment spraying pure woolen fabric to contrasting; Fig. 3 left side is the pure woolen fabric sheet of the static of the fabric remover that do not spray present embodiment, the pure woolen fabric sheet of Fig. 3 right side after for the static of the fabric remover of spraying present embodiment;
Fig. 4 for the static of the fabric remover of present embodiment spraying rayon lining twill fabric to contrasting; Fig. 4 left side is the rayon lining twill pieces of fabric of the static of the fabric remover that do not spray present embodiment, the rayon lining twill pieces of fabric of Fig. 4 right side after for the static remover of spraying present embodiment;
Fig. 5 for the static of the fabric remover of present embodiment spraying chemical & blended fabric to contrasting; Fig. 5 left side is the chemical & blended fabric sheet of the static of the fabric remover that do not spray present embodiment, the chemical & blended fabric sheet of Fig. 5 right side after for the static remover of spraying present embodiment;
By finding out among Fig. 1-Fig. 5, the static of the fabric remover of present embodiment stays the trace metachromatism to take place in the surperficial nothing of pieces of fabric, does not influence the quality and the use of fabric.
The preparation method of present embodiment sees embodiment 1 for details.
Embodiment 3:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 5
Silicone oil 0.5
Cationic surfactant 1
Amphoteric surfactant 2
Deionized water 91.5;
Described polyalcohol is glycerine and 1,3 butylene glycol mixture, and the weight ratio of described glycerine and 1,3 butylene glycol is 2:3; Described silicone oil is methyl-silicone oil and polysiloxanes-many alkoxyls ether copolymer mixture; The weight ratio of described methyl-silicone oil and polysiloxanes-many alkoxyls ether copolymer is 0.2:0.3, and described cationic surfactant is a dialkyl ethoxy methylsulfuric acid ammonium methyl; Described amphoteric surfactant is Cocoamidopropyl betaine and imidazoline mixture, and the weight ratio of described Cocoamidopropyl betaine and imidazoline is 1:1.
The used unit of weight of present embodiment is a kilogram, also can be gram.
According to the assay method among standard GB/T16801-1997 " mensuration of fabric conditioner antistatic property "; The fabric spray of test fixed dimension with before this described static of the fabric remover, resistance value afterwards, the quantity of electric charge; After can finding out obviously that the static of the fabric remover that uses present embodiment is handled, dacron surface ratio resistance drop △ ρ s (Ω) is greater than 4.0 * 10
11So the static of the fabric remover of present embodiment has tangible removal electrostatic efficiency.
Select the pieces of fabric of unlike material for use, the static of the fabric remover of present embodiment dries observation in the spraying, and pieces of fabric surface nothing stays the trace metachromatism to take place.Static of the fabric remover spraying real silk, pure wool, rayon lining twill, chemical & blended fabric with present embodiment; Can obtain the result similar with embodiment 2; The static of the fabric remover of present embodiment stays the trace metachromatism to take place in the surperficial nothing of pieces of fabric, does not influence the quality and the use of fabric.
The preparation method of present embodiment sees embodiment 1 for details.
Embodiment 4:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 3
Silicone oil 2.5
Cationic surfactant 1.5
Amphoteric surfactant 1.5
Deionized water 91.5;
Described polyalcohol is glycerine and 1,3 butylene glycol mixture, the weight ratio 2:1 of described glycerine and 1,3 butylene glycol; Described silicone oil is polysiloxanes-many alkoxyls ether copolymer; Described cationic surfactant is 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium and dialkyl ethoxy methylsulfuric acid ammonium methyl mixture, and the weight ratio of described 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium and dialkyl ethoxy methylsulfuric acid ammonium methyl is 0.5:1; Described amphoteric surfactant is Cocoamidopropyl betaine, cocamidopropyl propyl amide amine oxide, imidazoline mixture, and the weight ratio of described Cocoamidopropyl betaine, cocamidopropyl propyl amide amine oxide, imidazoline is 0.5:0.5:0.5.
The used unit of weight of present embodiment is a kilogram, also can be gram.
According to the assay method among standard GB/T16801-1997 " mensuration of fabric conditioner antistatic property "; The fabric spray of test fixed dimension with before this described static of the fabric remover, resistance value afterwards, the quantity of electric charge; After can finding out obviously that the static of the fabric remover that uses present embodiment is handled, dacron surface ratio resistance drop △ ρ s (Ω) is greater than 4.0 * 10
11So the static of the fabric remover of present embodiment has tangible removal electrostatic efficiency.
Select the pieces of fabric of unlike material for use, the static of the fabric remover of present embodiment dries observation in the spraying, and pieces of fabric surface nothing stays the trace metachromatism to take place.Static of the fabric remover spraying real silk, pure wool, rayon lining twill, chemical & blended fabric with present embodiment; Can obtain the result similar with embodiment 2; The static of the fabric remover of present embodiment stays the trace metachromatism to take place in the surperficial nothing of pieces of fabric, does not influence the quality and the use of fabric.
The preparation method of present embodiment sees embodiment 1 for details.
Embodiment 5:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 3
Silicone oil 1.6
Cationic surfactant 1.5
Amphoteric surfactant 2.0
Deionized water 91.9;
Described polyalcohol is for being glycerine and 1,3 butylene glycol mixture, the weight ratio 1:2 of described glycerine and 1,3 butylene glycol; Described silicone oil is methyl-silicone oil and polysiloxanes-many alkoxyls ether copolymer, and the weight ratio of described methyl-silicone oil and polysiloxanes-many alkoxyls ether copolymer is 0.1:1.5; Described cationic surfactant is two alkyl-dimethyl ammonium chlorides and 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium mixture, and it is 0.5:1 that described pair of alkyl-dimethyl ammonium chloride compares with 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium mixture weight; Described amphoteric surfactant is the mixture of Cocoamidopropyl betaine and imidazoline, and the weight ratio of described Cocoamidopropyl betaine and imidazoline is 1.5:0.5.
The used unit of weight of present embodiment is a kilogram, also can be gram.
According to the assay method among standard GB/T16801-1997 " mensuration of fabric conditioner antistatic property "; The fabric spray of test fixed dimension with before this described static of the fabric remover, resistance value afterwards, the quantity of electric charge; After can finding out obviously that the static of the fabric remover that uses present embodiment is handled, dacron surface ratio resistance drop △ ρ s (Ω) is greater than 4.0 * 10
11So the static of the fabric remover of present embodiment has tangible removal electrostatic efficiency.
Select the pieces of fabric of unlike material for use, the static of the fabric remover of present embodiment dries observation in the spraying, and pieces of fabric surface nothing stays the trace metachromatism to take place.Static of the fabric remover spraying real silk, pure wool, rayon lining twill, chemical & blended fabric with present embodiment; Can obtain the result similar with embodiment 2; The static of the fabric remover of present embodiment stays the trace metachromatism to take place in the surperficial nothing of pieces of fabric, does not influence the quality and the use of fabric.
The preparation method of present embodiment sees embodiment 1 for details.
Embodiment 6:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 5
Silicone oil 2
Cationic surfactant 1.5
Amphoteric surfactant 2.5
Deionized water 89;
Described polyalcohol is a 1,3 butylene glycol; Described silicone oil is polysiloxanes-many alkoxyls ether copolymer; Described cationic surfactant is two alkyl-dimethyl ammonium chlorides, 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium, dialkyl ethoxy methylsulfuric acid ammonium methyl mixture, and the weight ratio of the described pair of alkyl-dimethyl ammonium chloride, 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium, dialkyl ethoxy methylsulfuric acid ammonium methyl is 0.5:0.5:0.5; Described amphoteric surfactant is Cocoamidopropyl betaine and cocamidopropyl propyl amide amine oxide mixture, and the weight ratio of described Cocoamidopropyl betaine and cocamidopropyl propyl amide amine oxide is 0.5:2.
The used unit of weight of present embodiment is a kilogram, also can be gram.
According to the assay method among standard GB/T16801-1997 " mensuration of fabric conditioner antistatic property "; The fabric spray of test fixed dimension with before this described static of the fabric remover, resistance value afterwards, the quantity of electric charge; After can finding out obviously that the static of the fabric remover that uses present embodiment is handled, dacron surface ratio resistance drop △ ρ s (Ω) is greater than 4.0 * 10
11So the static of the fabric remover of present embodiment has tangible removal electrostatic efficiency.
Select the pieces of fabric of unlike material for use, the static of the fabric remover of present embodiment dries observation in the spraying, and pieces of fabric surface nothing stays the trace metachromatism to take place.Static of the fabric remover spraying real silk, pure wool, rayon lining twill, chemical & blended fabric with present embodiment; Can obtain the result similar with embodiment 2; The static of the fabric remover of present embodiment stays the trace metachromatism to take place in the surperficial nothing of pieces of fabric, does not influence the quality and the use of fabric.
The preparation method of present embodiment sees embodiment 1 for details.
Embodiment 7:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 2
Silicone oil 0.5
Cationic surfactant 0.5
Amphoteric surfactant 1
Deionized water 96;
Described polyalcohol is a D-sorbite; Described silicone oil is amido silicon oil; Described cationic surfactant is two alkyl-dimethyl ammonium chlorides; Described amphoteric surfactant is the hexadecyldimethyl benzyl ammonium betaine.
The used unit of weight of present embodiment is a kilogram, also can be gram.
According to the assay method among standard GB/T16801-1997 " mensuration of fabric conditioner antistatic property "; The fabric spray of test fixed dimension with before this described static of the fabric remover, resistance value afterwards, the quantity of electric charge; After can finding out obviously that the static of the fabric remover that uses present embodiment is handled, dacron surface ratio resistance drop △ ρ s (Ω) is greater than 4.0 * 10
11So the static of the fabric remover of present embodiment has tangible removal electrostatic efficiency.
Select the pieces of fabric of unlike material for use, the static of the fabric remover of present embodiment dries observation in the spraying, and pieces of fabric surface nothing stays the trace metachromatism to take place.Static of the fabric remover spraying real silk, pure wool, rayon lining twill, chemical & blended fabric with present embodiment; Can obtain the result similar with embodiment 2; The static of the fabric remover of present embodiment stays the trace metachromatism to take place in the surperficial nothing of pieces of fabric, does not influence the quality and the use of fabric.
The preparation method of present embodiment sees embodiment 1 for details.
Embodiment 8:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the weight ratio of each raw material of this static of the fabric remover is:
The used unit of weight of present embodiment is a kilogram, also can be gram.
Polyalcohol 5
Silicone oil 1
Cationic surfactant 1
Amphoteric surfactant 2
Deionized water 91;
Described polyalcohol is D-sorbite and 1,3 butylene glycol mixture, and the weight ratio of described D-sorbite and 1,3 butylene glycol is 2:3; Described silicone oil is amido silicon oil; Described cationic surfactant is a dialkyl ethoxy methylsulfuric acid ammonium methyl; Described amphoteric surfactant is hexadecyldimethyl benzyl ammonium betaine and imidazoline mixture, and the weight ratio of described hexadecyldimethyl benzyl ammonium betaine and imidazoline is 1:1.
According to the assay method among standard GB/T16801-1997 " mensuration of fabric conditioner antistatic property "; The fabric spray of test fixed dimension with before this described static of the fabric remover, resistance value afterwards, the quantity of electric charge; After can finding out obviously that the static of the fabric remover that uses present embodiment is handled, dacron surface ratio resistance drop △ ρ s (Ω) is greater than 4.0 * 10
11So the static of the fabric remover of present embodiment has tangible removal electrostatic efficiency.
Select the pieces of fabric of unlike material for use, the static of the fabric remover of present embodiment dries observation in the spraying, and pieces of fabric surface nothing stays the trace metachromatism to take place.Static of the fabric remover spraying real silk, pure wool, rayon lining twill, chemical & blended fabric with present embodiment; Can obtain the result similar with embodiment 2; The static of the fabric remover of present embodiment stays the trace metachromatism to take place in the surperficial nothing of pieces of fabric, does not influence the quality and the use of fabric.
The preparation method of present embodiment sees embodiment 1 for details.
Embodiment 9:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 3
Silicone oil 2.5
Cationic surfactant 1.5
Amphoteric surfactant 1
Deionized water 92;
Described polyalcohol is D-sorbite and 1,3 butylene glycol mixture, and the weight ratio of described D-sorbite and 1,3 butylene glycol is 2:1; Described silicone oil is amido silicon oil; Described cationic surfactant is 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium and dialkyl ethoxy methylsulfuric acid ammonium methyl mixture, and the weight ratio of described 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium and dialkyl ethoxy methylsulfuric acid ammonium methyl is 0.5:1; Described amphoteric surfactant is hexadecyldimethyl benzyl ammonium betaine and imidazoline mixture, and the weight ratio of described hexadecyldimethyl benzyl ammonium betaine and imidazoline is 0.5:0.5.
The used unit of weight of present embodiment is a kilogram, also can be gram.
According to the assay method among standard GB/T16801-1997 " mensuration of fabric conditioner antistatic property "; The fabric spray of test fixed dimension with before this described static of the fabric remover, resistance value afterwards, the quantity of electric charge; After can finding out obviously that the static of the fabric remover that uses present embodiment is handled, dacron surface ratio resistance drop △ ρ s (Ω) is greater than 4.0 * 10
11So the static of the fabric remover of present embodiment has tangible removal electrostatic efficiency.
Select the pieces of fabric of unlike material for use, the static of the fabric remover of present embodiment dries observation in the spraying, and pieces of fabric surface nothing stays the trace metachromatism to take place.Static of the fabric remover spraying real silk, pure wool, rayon lining twill, chemical & blended fabric with present embodiment; Can obtain the result similar with embodiment 2; The static of the fabric remover of present embodiment stays the trace metachromatism to take place in the surperficial nothing of pieces of fabric, does not influence the quality and the use of fabric.
The preparation method of present embodiment sees embodiment 1 for details.
Embodiment 10:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 3
Silicone oil 1.5
Cationic surfactant 1.5
Amphoteric surfactant 2
Deionized water 92;
Described polyalcohol is D-sorbite and 1,3 butylene glycol mixture, and the weight ratio of described D-sorbite and 1,3 butylene glycol is 1:2; Described silicone oil is amido silicon oil; Described cationic surfactant is two alkyl-dimethyl ammonium chlorides and 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium mixture, and the described pair of alkyl-dimethyl ammonium chloride and 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium weight ratio are 0.5:1; Described amphoteric surfactant is hexadecyldimethyl benzyl ammonium betaine, imidazoline mixture, and the weight ratio of described hexadecyldimethyl benzyl ammonium betaine, imidazoline is 1.5:0.5.
The used unit of weight of present embodiment is a kilogram, also can be gram.
According to the assay method among standard GB/T16801-1997 " mensuration of fabric conditioner antistatic property "; The fabric spray of test fixed dimension with before this described static of the fabric remover, resistance value afterwards, the quantity of electric charge; After can finding out obviously that the static of the fabric remover that uses present embodiment is handled, dacron surface ratio resistance drop △ ρ s (Ω) is greater than 4.0 * 10
11So the static of the fabric remover of present embodiment has tangible removal electrostatic efficiency.
Select the pieces of fabric of unlike material for use, the static of the fabric remover of present embodiment dries observation in the spraying, and pieces of fabric surface nothing stays the trace metachromatism to take place.Static of the fabric remover spraying real silk, pure wool, rayon lining twill, chemical & blended fabric with present embodiment; Can obtain the result similar with embodiment 2; The static of the fabric remover of present embodiment stays the trace metachromatism to take place in the surperficial nothing of pieces of fabric, does not influence the quality and the use of fabric.
The preparation method of present embodiment sees embodiment 1 for details.
Embodiment 11:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 3
Silicone oil 2
Cationic surfactant 1.5
Amphoteric surfactant 0.5
Deionized water 93;
Described polyalcohol is D-sorbite and 1,3 butylene glycol mixture, and described polyalcohol is that the weight ratio of D-sorbite and 1,3 butylene glycol is 1.5:1.5; Described silicone oil is amido silicon oil; Described cationic surfactant is two alkyl-dimethyl ammonium chlorides, 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium, dialkyl ethoxy methylsulfuric acid ammonium methyl mixture, and the weight ratio of the described pair of alkyl-dimethyl ammonium chloride, 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium, dialkyl ethoxy methylsulfuric acid ammonium methyl is 0.5:0.5:0.5; Described amphoteric surfactant is the hexadecyldimethyl benzyl ammonium betaine.
The used unit of weight of present embodiment is a kilogram, also can be gram.
According to the assay method among standard GB/T16801-1997 " mensuration of fabric conditioner antistatic property "; The fabric spray of test fixed dimension with before this described static of the fabric remover, resistance value afterwards, the quantity of electric charge; After can finding out obviously that the static of the fabric remover that uses present embodiment is handled, dacron surface ratio resistance drop △ ρ s (Ω) is greater than 4.0 * 10
11So the static of the fabric remover of present embodiment has tangible removal electrostatic efficiency.
Select the pieces of fabric of unlike material for use, the static of the fabric remover of present embodiment dries observation in the spraying, and pieces of fabric surface nothing stays the trace metachromatism to take place.Static of the fabric remover spraying real silk, pure wool, rayon lining twill, chemical & blended fabric with present embodiment; Can obtain the result similar with embodiment 2; The static of the fabric remover of present embodiment stays the trace metachromatism to take place in the surperficial nothing of pieces of fabric, does not influence the quality and the use of fabric.
The preparation method of present embodiment sees embodiment 1 for details.
Embodiment 12:
Present embodiment is the preferred version on embodiment 1 basis, and raw materials used quality is identical with embodiment 1, and the weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 3
Silicone oil 0.5
Cationic surfactant 1.5
Amphoteric surfactant 2.5
Deionized water 92.5;
Described polyalcohol is D-sorbite and 1,3 butylene glycol mixture, described D-sorbite
With the weight ratio of 1,3 butylene glycol be 2:1; Described silicone oil is amido silicon oil; Described cationic surfactant is 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium and dialkyl ethoxy methylsulfuric acid ammonium methyl mixture, and the weight ratio of described 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium, dialkyl ethoxy methylsulfuric acid ammonium methyl is 0.5:1; Described amphoteric surfactant is hexadecyldimethyl benzyl ammonium betaine, imidazoline mixture, and described hexadecyldimethyl benzyl ammonium betaine and imidazoline weight ratio are 0.5:2.
The used unit of weight of present embodiment is a kilogram, also can be gram.
According to the assay method among standard GB/T16801-1997 " mensuration of fabric conditioner antistatic property "; The fabric spray of test fixed dimension with before this described static of the fabric remover, resistance value afterwards, the quantity of electric charge; After can finding out obviously that the static of the fabric remover that uses present embodiment is handled, dacron surface ratio resistance drop △ ρ s (Ω) is greater than 4.0 * 10
11So the static of the fabric remover of present embodiment has tangible removal electrostatic efficiency.
Select the pieces of fabric of unlike material for use, the static of the fabric remover of present embodiment dries observation in the spraying, and pieces of fabric surface nothing stays the trace metachromatism to take place.Static of the fabric remover spraying real silk, pure wool, rayon lining twill, chemical & blended fabric with present embodiment; Can obtain the result similar with embodiment 2; The static of the fabric remover of present embodiment stays the trace metachromatism to take place in the surperficial nothing of pieces of fabric, does not influence the quality and the use of fabric.
The preparation method of present embodiment sees embodiment 1 for details.
Claims (10)
1. a static of the fabric remover is characterized in that: contain polyalcohol, silicone oil, cationic surfactant, amphoteric surfactant, deionized water in the raw material of this static of the fabric remover; The weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 2.0-5.0
Silicone oil 0.5-2.5
Cationic surfactant 0.5-1.5
Amphoteric surfactant 1.0-2.5
Deionized water 88-96;
The preparation method of this static of the fabric remover may further comprise the steps successively:
Get described polyalcohol, silicone oil, cationic surfactant, amphoteric surfactant according to above-mentioned weight proportion, in the addingization material still, obtain mixed liquor A; In described mixed liquor A, add described deionized water again, obtain described static of the fabric remover.
2. static of the fabric remover according to claim 1 is characterized in that: described polyalcohol can be one or more the mixture in glycerine, propylene glycol, D-sorbite, the 1,3 butylene glycol;
Described silicone oil is one or more the mixture in methyl-silicone oil, amido silicon oil, the polysiloxanes-many alkoxyls ether copolymer;
Described cationic surfactant is one or more the mixture in two alkyl-dimethyl ammonium chlorides, dialkyl ethoxy methylsulfuric acid ammonium methyl, the 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium;
Described amphoteric surfactant is one or more the mixture in hexadecyldimethyl benzyl ammonium betaine, Cocoamidopropyl betaine, cocamidopropyl propyl amide amine oxide, the imidazoline.
3. static of the fabric remover according to claim 1 and 2 is characterized in that: the weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 2
Silicone oil 1.2
Cationic surfactant 0.5
Amphoteric surfactant 1
Deionized water 95.3;
Described polyalcohol is a glycerine; Described silicone oil is methyl-silicone oil and polysiloxanes-many alkoxyls ether copolymer mixture, and the weight ratio of described methyl-silicone oil and polysiloxanes-many alkoxyls ether copolymer is 0.2:1; Described cationic surfactant is two alkyl-dimethyl ammonium chlorides; Described amphoteric surfactant is a Cocoamidopropyl betaine.
4. static of the fabric remover according to claim 1 and 2 is characterized in that: the weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 5
Silicone oil 0.5
Cationic surfactant 1
Amphoteric surfactant 2
Deionized water 91.5;
Described polyalcohol is glycerine and 1,3 butylene glycol mixture, and the weight ratio of described glycerine and 1,3 butylene glycol is 2:3; Described silicone oil is methyl-silicone oil and polysiloxanes-many alkoxyls ether copolymer mixture; The weight ratio of described methyl-silicone oil and polysiloxanes-many alkoxyls ether copolymer is 0.2:0.3, and described cationic surfactant is a dialkyl ethoxy methylsulfuric acid ammonium methyl; Described amphoteric surfactant is Cocoamidopropyl betaine and imidazoline mixture, and the weight ratio of described Cocoamidopropyl betaine and imidazoline is 1:1.
5. static of the fabric remover according to claim 1 and 2 is characterized in that: the weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 3
Silicone oil 2.5
Cationic surfactant 1.5
Amphoteric surfactant 1.5
Deionized water 91.5;
Described polyalcohol is glycerine and 1,3 butylene glycol mixture, the weight ratio 2:1 of described glycerine and 1,3 butylene glycol; Described silicone oil is polysiloxanes-many alkoxyls ether copolymer; Described cationic surfactant is 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium and dialkyl ethoxy methylsulfuric acid ammonium methyl mixture, and the weight ratio of described 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium and dialkyl ethoxy methylsulfuric acid ammonium methyl is 0.5:1; Described amphoteric surfactant is Cocoamidopropyl betaine, cocamidopropyl propyl amide amine oxide, imidazoline mixture, and the weight ratio of described Cocoamidopropyl betaine, cocamidopropyl propyl amide amine oxide, imidazoline is 0.5:0.5:0.5.
6. static of the fabric remover according to claim 1 and 2 is characterized in that: the weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 3
Silicone oil 1.6
Cationic surfactant 1.5
Amphoteric surfactant 2.0
Deionized water 91.9;
Described polyalcohol is for being glycerine and 1,3 butylene glycol mixture, the weight ratio 1:2 of described glycerine and 1,3 butylene glycol; Described silicone oil is methyl-silicone oil and polysiloxanes-many alkoxyls ether copolymer, and the weight ratio of described methyl-silicone oil and polysiloxanes-many alkoxyls ether copolymer is 0.1:1.5; Described cationic surfactant is two alkyl-dimethyl ammonium chlorides and 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium mixture, and it is 0.5:1 that described pair of alkyl-dimethyl ammonium chloride compares with 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium mixture weight; Described amphoteric surfactant is the mixture of Cocoamidopropyl betaine and imidazoline, and the weight ratio of described Cocoamidopropyl betaine and imidazoline is 1.5:0.5.
7. static of the fabric remover according to claim 1 and 2 is characterized in that: the weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 5
Silicone oil 2
Cationic surfactant 1.5
Amphoteric surfactant 2.5
Deionized water 89;
Described polyalcohol is a 1,3 butylene glycol; Described silicone oil is polysiloxanes-many alkoxyls ether copolymer; Described cationic surfactant is two alkyl-dimethyl ammonium chlorides, 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium, dialkyl ethoxy methylsulfuric acid ammonium methyl mixture, and the weight ratio of the described pair of alkyl-dimethyl ammonium chloride, 1-methyl-2-butter-3-buserelin-imidazoline sulfate methyl ammonium, dialkyl ethoxy methylsulfuric acid ammonium methyl is 0.5:0.5:0.5; Described amphoteric surfactant is Cocoamidopropyl betaine and cocamidopropyl propyl amide amine oxide mixture, and the weight ratio of described Cocoamidopropyl betaine and cocamidopropyl propyl amide amine oxide is 0.5:2.
8. static of the fabric remover according to claim 1 and 2 is characterized in that: the weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 2
Silicone oil 0.5
Cationic surfactant 0.5
Amphoteric surfactant 1
Deionized water 96;
Described polyalcohol is a D-sorbite; Described silicone oil is amido silicon oil; Described cationic surfactant is two alkyl-dimethyl ammonium chlorides; Described amphoteric surfactant is the hexadecyldimethyl benzyl ammonium betaine.
9. static of the fabric remover according to claim 1 and 2 is characterized in that: the weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 5
Silicone oil 1
Cationic surfactant 1
Amphoteric surfactant 2
Deionized water 91;
Described polyalcohol is D-sorbite and 1,3 butylene glycol mixture, and the weight ratio of described D-sorbite and 1,3 butylene glycol is 2:3; Described silicone oil is amido silicon oil; Described cationic surfactant is a dialkyl ethoxy methylsulfuric acid ammonium methyl; Described amphoteric surfactant is hexadecyldimethyl benzyl ammonium betaine and imidazoline mixture, and the weight ratio of described hexadecyldimethyl benzyl ammonium betaine and imidazoline is 1:1.
10. the preparation method of a static of the fabric remover is characterized in that: contain polyalcohol, silicone oil, cationic surfactant, amphoteric surfactant, deionized water in the raw material of this static of the fabric remover; The weight ratio of each raw material of this static of the fabric remover is:
Polyalcohol 2.0-5.0, silicone oil 0.5-2.5, cationic surfactant 0.5-1.5, amphoteric surfactant 1.0-2.5, deionized water 88-96;
The preparation method of this static of the fabric remover may further comprise the steps successively:
Get described polyalcohol, silicone oil, cationic surfactant, amphoteric surfactant according to above-mentioned weight proportion, in the addingization material still, obtain mixed liquor A; In described mixed liquor A, add described deionized water again and obtain described static of the fabric remover.
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| CN103437184A (en) * | 2013-08-30 | 2013-12-11 | 蔡萍 | Novel special curing agent for wool fabrics |
| CN103614919A (en) * | 2013-11-21 | 2014-03-05 | 湖州厉华妤婕联合纺织有限公司 | Special curing agent for wool fabrics |
| CN103757904A (en) * | 2013-12-23 | 2014-04-30 | 吴江亿泰真空设备科技有限公司 | Fabric softening agent |
| CN108342185A (en) * | 2018-01-03 | 2018-07-31 | 浙江绿岛科技有限公司 | Antistatic aerosol based on cationic surfactant and preparation method thereof |
| CN109208325A (en) * | 2018-08-20 | 2019-01-15 | 福建凤竹纺织科技股份有限公司 | A kind of preparation process of softness Anti-static textile fabric |
| CN109778547A (en) * | 2019-01-11 | 2019-05-21 | 青岛理工大学 | Antibacterial antistatic finishing agent and antibacterial antistatic synthetic fabrics and preparation method thereof |
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| US11168244B2 (en) | 2016-10-26 | 2021-11-09 | Championx Usa Inc. | Compositions for enhanced oil recovery |
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| CN108342185B (en) * | 2018-01-03 | 2020-09-01 | 浙江绿岛科技有限公司 | Antistatic aerosol based on cationic surfactant and preparation method thereof |
| CN109208325A (en) * | 2018-08-20 | 2019-01-15 | 福建凤竹纺织科技股份有限公司 | A kind of preparation process of softness Anti-static textile fabric |
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| CN102587126B (en) | 2014-04-16 |
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