CN102578698A - Method for reducing phenol substances in cigarette smoke gas - Google Patents
Method for reducing phenol substances in cigarette smoke gas Download PDFInfo
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- CN102578698A CN102578698A CN201210039343XA CN201210039343A CN102578698A CN 102578698 A CN102578698 A CN 102578698A CN 201210039343X A CN201210039343X A CN 201210039343XA CN 201210039343 A CN201210039343 A CN 201210039343A CN 102578698 A CN102578698 A CN 102578698A
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- cigarette
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- tobacco leaf
- electron accelerator
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- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 80
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title claims abstract description 55
- 239000000126 substance Substances 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title claims abstract description 36
- 239000000779 smoke Substances 0.000 title claims abstract description 36
- 241000208125 Nicotiana Species 0.000 claims abstract description 50
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims abstract description 50
- 238000010894 electron beam technology Methods 0.000 claims abstract description 7
- 230000000391 smoking effect Effects 0.000 claims description 20
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 14
- 239000003546 flue gas Substances 0.000 claims description 14
- 230000009467 reduction Effects 0.000 claims description 14
- 230000008569 process Effects 0.000 claims description 8
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 claims description 6
- 238000001868 liquid chromatography-fluorescence detection Methods 0.000 claims description 6
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 claims description 6
- 229940100630 metacresol Drugs 0.000 claims description 6
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 claims description 6
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 6
- 238000012360 testing method Methods 0.000 claims description 5
- 238000012856 packing Methods 0.000 claims description 4
- 150000005208 1,4-dihydroxybenzenes Chemical class 0.000 claims description 3
- 230000005540 biological transmission Effects 0.000 claims description 3
- 150000002989 phenols Chemical class 0.000 claims description 2
- 230000001678 irradiating effect Effects 0.000 abstract 1
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 16
- 238000012545 processing Methods 0.000 description 9
- 238000004458 analytical method Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- -1 phenol compound Chemical class 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 230000036541 health Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 230000006399 behavior Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 241000411851 herbal medicine Species 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000003907 kidney function Effects 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 210000004400 mucous membrane Anatomy 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
Abstract
The invention discloses a method for reducing phenol substances in cigarette smoke gas. The method comprises the steps of packaging tobacco leaves/cigarette finished products with cartons, wherein the stacking thickness is 26-72cm and the stacking density is 0.20-0.34g/cm<3>; and placing cigarette boxes on a conveying device with a conveying rate of 0.02-0.3m/s, and irradiating with electron beams/X-rays generated by an electron accelerator, wherein the energy of the electron accelerator is 5-10MeV, the beam current is 0.3-20mA, the beam power is 10-20kW, the maximum scanning width is 100cm, the scanning frequency is 5-15Hz, the irradiation dose is 1-10kGy, the working temperature is set to at 5-35 DEG C, the cigarette box passes through a scanning window of the electron accelerator to be irradiated twice, the distance between the cigarette box center and the scanning window of the electron accelerator during irradiation is 40-60cm, and the ambient humidity is limited to be not more than 60% during working.
Description
Technical field
The invention belongs to the irradiation technique application; Also belong to tobacco tar-reducing harm reduction technical field; Relate to the application of electron accelerator irradiation technology in reducing tobacco harm, especially a kind of electron accelerator irradiation treatment technology that can reduce volatile phenol content in the cigarette smoke.
Background technology
Tobacco is one of important industrial crops of China, in national economy, occupies an important position.At present, there are 1,100,000,000 smokers in the whole world, and in state-owned more than 300,000,000, smoking has become a kind of social group behavior.As far back as the thirties in 20th century just the someone to propose smoking meeting harm healthy, especially nineteen fifty Britain Royal Society of Medicine and U.S. doctor's political affairs general administration in 1964 formally deliver smoking and healthy relation report, it is harmful clearly to have proposed smoking.Along with people's is to the pay attention to day by day of health, cigarette suck the focus that security has become Recent study, cause showing great attention to of countries in the world government.
The harmful substances that mainly contains that influences the smoking property of cigarette security is tarry matters in smoke, but the material of 99.4% in the tar is harmless, and is aroma component mostly, and harmful components only account for 0.6%, and wherein phenol compound is one type of harmful substance that people pay close attention to.Phenol type substances has strong corrosiveness to skin, mucous membrane, can suppress nervous centralis or infringement liver, renal function, can also promote carcinogenic.Representative in these compounds is phenol, hydroquinones, resorcinol, catechol, paracresol, metacresol and orthoresol, wherein maximum with the harmfulness of phenol again, is classified as one of 7 kinds of cigarette smoke harmful components of evaluating cigarette harmfulness.Phenol compound in the flue gas produces in sucking process, and in smoking process, macromolecular compound mainly is that the polyphenol compound cracking generates phenol type substances in the tobacco leaf.But, the smoker that the whole world is numerous, it is unpractical eliminating tobacco, also is impossible.Therefore, harmful components improve the target that the smoking security has become current international consensus and pursuit to the harm of health in the reduction cigarette smoke, also are one of great research topics that needs to be resolved hurrily in the current tobacco industry development.
At present; Taking a series of reducing tar and reducing harm measures aspect the cigarette process technology in the world; Developed various forms of filter tips, improve cigarette paper natural permeable degree, punching dilution, add technology such as Chinese herbal medicine and chemical addition agent, expanded cut tobacco, stem and reconstituted tobacoo (tobacco science and technology; 2000, (8): 3-6).Comprehensive utilization each item technology can be regulated the tar content of cigarette, but especially not obviously minimizing of phenol type substances of harmful components does not reach the purpose that improves the smoking security.In addition, along with the reduction of tar content, the smoke perfume composition also reduces thereupon, makes the cigarette desalination, also can change cigarette odor-absorbing, causes bad mouthfeel, can not satisfy smoker's requirement.In addition, the method that reduces content of phenol type substances in the flue gas through microwave processing method is arranged also, disclose a kind of cigarette technological method for processing of low phenol content like one Chinese patent application CN 201010288186.7.This invention is to utilize microwave means through changing the content that the cigarette technology for making tobacco threds reduces phenol in the cigarette mainstream flue gas; Though phenol content has certain effect in the flue gas to reducing; But microwave equipment is expensive; Processing cost is high, is difficult for combining with existing tobacco processing technology, is difficult in the suitability for industrialized production and applies.Therefore, these treatment measures do not possess and conform with desirable selectivity, and it is necessary to develop a kind of method of phenol type substances that reduces in the cigarette smoke.
Summary of the invention
A kind of method that can reduce phenol harmful components in the cigarette smoke that the object of the invention provides to above-mentioned existing in prior technology problem just; After its main feature is the electron beam or x-ray irradiation of tobacco leaf/finished cigarette through the electron accelerator generation; Can effectively reduce the phenol harmful components in the flue gas; Improve the security of sucking of cigarette, and can desinsection, sterilization, and do not influence its sucking quality.
The objective of the invention is to realize through following technical scheme:
7, the method for phenol type substances in the reduction cigarette smoke of the present invention is characterized in that said method comprises the steps:
A) tobacco leaf/finished cigarette is adopted packed in cases, the ulking thickness of tobacco leaf/finished cigarette in carton is 26～72cm, and bulk density is 0.20～0.34g/cm
3
B) have the carton of tobacco leaf/finished cigarette to place on the conveyer packing, the transporting velocity of said conveyer is 0.02～0.3m/s;
C) place the tobacco leaf/finished cigarette on the conveyer to accept electron beam/x-ray irradiation that electron accelerator produces,
The energy of said electron accelerator is 5～10MeV, and line is 0.3～20mA, and beam power is 10～20kW, and maximum sweep width is 100cm, and scan frequency is 5～15Hz, and irradiation dose is 1～10kGy,
Said irradiation is taked the mode of secondary irradiation; Tobacco leaf/finished cigarette scans window through the conveyer transmission through electron accelerator twice accepts irradiation; Once accept half the irradiation dose; For the first time spin upside down smoke box behind the irradiation, the ray another side that passes smoke box carries out irradiation, the scanning window 40～60cm of smoke box centre distance electron accelerator during irradiation for the second time;
D) in the operating process of step c), the operating temperature of electron accelerator is set in 5～35 ℃ of scopes, and ambient humidity is limited in and is not more than 60%;
Accomplish above-mentioned steps a)～d) after; Tobacco leaf is rolled into cigarette; Get some of the cigarette that rolls into or above-mentioned finished cigarettes,, utilize smoking machine anthropomorphic dummy smoking state according to GB/T 19609-2004 specified standard condition; Use cambridge filter to gather the phenol type substances in the flue gas; Adopt high performance liquid chromatography-fluorescence detection to measure the content of phenol type substances, with correspondence without the cigarette sample of irradiation as contrast, come the reduction degree of content of phenol type substances in the testing cigarette tarry matters in smoke thus.
In the disclosed technique scheme of the present invention; Improved the method for only simply carrying out irradiation in the prior art through electron accelerator; Through to each item parameters Optimization in the whole piece irradiation working chain; Promptly, significantly improved and used electron accelerator irradiation to reduce the effect of content of phenol type substances in the cigarette smoke through to multinomial parameters Optimization such as the energy of the transporting velocity of the distance between the ulking thickness of tobacco leaf/finished cigarette in carton, bulk density, carton and the electron accelerator scanning window, conveyer and electron accelerator, line, beam power, maximum sweep width, scan frequency, irradiation doses.
Said cigarette is that finished cigarette or tobacco leaf roll the cigarette that forms behind irradiation.
Said tobacco leaf can be any one of junior tobacco leaf, redried leaf tobacco, airing tobacco.
Said conveyer can be belt, roller rod-type, chain type.
Described phenol type substances comprises one or more in the phenol compounds such as phenol, hydroquinones, resorcinol, catechol, paracresol, metacresol, orthoresol.
Advantage of the present invention is:
(1) method of phenol type substances in the minimizing cigarette smoke of the present invention; Electron beam/x-ray irradiation that the electron accelerator that adopts produces has higher energy; Can effectively reduce the phenol harmful components in the flue gas, improve the security of sucking of cigarette, and can desinsection, sterilization; And do not influence its sucking quality, have practicality;
(2) method of phenol type substances in the minimizing cigarette smoke of the present invention adopts the electron accelerator irradiation technology to belong to emerging radiation processing technology, and irradiation efficiency is high; The irradiation good evenness, processing safety is strong, and equipment control is simple; Adaptability is strong, and is high in technological content, has novelty;
(3) method of phenol type substances in the minimizing cigarette smoke of the present invention adopts this green new and high technology of electron accelerator irradiation technology, for the tobacco tar-reducing harm reduction opens up a new way, has broad application prospects and great economic implications;
(4) method of phenol type substances among minimizing cigarette smoke Jiao of the present invention; Adopt electron accelerator, be easy to combine with existing tobacco processing technology, can be according to present China tobacco processing technology; Design and manufacture and be applied to the special-purpose electron accelerator of tobacco irradiation; Be directly installed on electron accelerator in the streamline of tobacco processing, one process procedure as in the tobacco leaf processing process is easy to realize industrialization;
(5) method of phenol type substances in the minimizing cigarette smoke of the present invention, safety and sanitation, noresidue, free from environmental pollution;
(6) method of phenol type substances in the minimizing cigarette smoke of the present invention, it is low to consume energy, and can practice thrift cost.
The specific embodiment
For a better understanding of the present invention, further illustrate content of the present invention, but content of the present invention is not limited to following embodiment below in conjunction with embodiment.
Embodiment 1
Get junior tobacco leaf 150kg at random, every 50kg packing one case, totally 3 casees pack for the corrugated case of 70cm * 60cm * 50cm with long * wide * height, and the ulking thickness of tobacco leaf in carton is 26～72cm, and bulk density is 0.20～0.34g/cm
3It is on the conveyer of 0.02～0.3m/s that packaged tobacco leaf is placed transporting velocity; Place the tobacco leaf on the conveyer to accept electron beam/x-ray irradiation that electron accelerator produces, the energy of electron accelerator is 5～10MeV, and line is 0.3～20mA; Beam power is 10～20kW, and maximum sweep width is 100cm, and scan frequency is 5～15Hz; Irradiation dose is 1kGy, adopts the mode of secondary irradiation, and tobacco leaf scans window through the conveyer transmission through electron accelerator twice accepts irradiation; Once accept half the irradiation dose; For the first time spin upside down smoke box behind the irradiation, the ray another side that passes smoke box carries out irradiation, the scanning window 40～60cm of smoke box centre distance electron accelerator during irradiation for the second time; In the aforesaid operations process, the operating temperature of electron accelerator is set in 5～35 ℃ of scopes, and ambient humidity is limited in and is not more than 60%; After accomplishing above-mentioned steps, tobacco leaf is rolled into cigarette, get 40 of the cigarette that roll into; According to GB/T 19609-2004 specified standard condition; Utilize smoking machine anthropomorphic dummy smoking state, use cambridge filter to gather the phenol type substances in the flue gas, adopt high performance liquid chromatography-fluorescence detection to measure the content of phenol type substances; With correspondence without the cigarette sample of irradiation as contrast, and suck evaluation.The result sees table 1.
Content of phenol type substances and variation thereof behind the first flue-cured tobacco predose of table 1
Annotate: in the actual analysis test, paracresol is difficult to separate with metacresol, when calculating, both is merged.
Embodiment 2
According to the step similar with the foregoing description 1, get redried leaf tobacco 3 casees of standard container packing at random, carton length * wide * height is 113.6cm * 72cm * 72.5cm, every case weight 200kg.Adopt the X ray of 5kGy dosage to carry out radiation treatment, tobacco leaf rolls through cigarette machine behind the irradiation, gets at random to meet and measures 40 of the cigarette that require; According to GB/T 19609-2004 specified standard condition; Utilize smoking machine anthropomorphic dummy smoking state, use cambridge filter to gather the phenol type substances in the flue gas, adopt high performance liquid chromatography-fluorescence detection to measure the content of phenol type substances; With correspondence without the cigarette sample of irradiation as contrast, and suck evaluation.The result sees table 2.
Content of phenol type substances and variation thereof behind the table 2 redrying cigarette predose
Annotate: in the actual analysis test, paracresol is difficult to separate with metacresol, when calculating, both is merged.
Embodiment 3
According to the step similar with embodiment 1, get finished cigarette 3 casees at random, carton length * wide * height is 47.5cm * 26cm * 59.5cm, the heavy 15kg of every case, 50 of quantity.Adopt the electron beam of 10kGy dosage to carry out radiation treatment, get at random behind the irradiation to meet and measure 40 of the cigarette that require, according to GB/T 19609-2004 specified standard condition; Utilize smoking machine anthropomorphic dummy smoking state; Use cambridge filter to gather the phenol type substances in the flue gas, use cambridge filter to gather the phenol type substances in the flue gas, adopt high performance liquid chromatography-fluorescence detection to measure the content of phenol type substances; With correspondence without the cigarette sample of irradiation as contrast, and suck evaluation.The result sees table 3.
Content of phenol type substances and variation thereof behind the table 3 finished cigarette predose
Annotate: in the actual analysis test, paracresol is difficult to separate with metacresol, when calculating, both is merged.
Can know by table 1～3, the method for content of phenol type substances in the reduction cigarette smoke of the present invention, electron accelerator irradiation is obvious to the reduction effect of phenol harmful substance in the cigarette smoke, but does not influence its sucking quality.
Above-described specific embodiment has carried out further explain to the object of the invention, technical scheme and beneficial effect.Institute it should be understood that the above is merely specific embodiment of the present invention, is not limited to the present invention, and is all within spirit of the present invention and principle, any modification of being made, is equal to replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (6)
1. a method that reduces phenol type substances in the cigarette smoke is characterized in that, said method comprises the steps:
A) tobacco leaf/finished cigarette is adopted packed in cases, the ulking thickness of tobacco leaf/finished cigarette in carton is 26～72cm, and bulk density is 0.20～0.34g/cm
3
B) have the carton of tobacco leaf/finished cigarette to place on the conveyer packing, the transporting velocity of said conveyer is 0.02～0.3m/s;
C) place the tobacco leaf/finished cigarette on the conveyer to accept electron beam/x-ray irradiation that electron accelerator produces,
The energy of said electron accelerator is 5～10MeV, and line is 0.3～20mA, and beam power is 10～20kW, and maximum sweep width is 100cm, and scan frequency is 5～15Hz, and irradiation dose is 1～10kGy,
Said irradiation is taked the mode of secondary irradiation; Tobacco leaf/finished cigarette scans window through the conveyer transmission through electron accelerator twice accepts irradiation; Once accept half the irradiation dose; For the first time spin upside down smoke box behind the irradiation, the ray another side that passes smoke box carries out irradiation, the scanning window 40～60cm of smoke box centre distance electron accelerator during irradiation for the second time;
D) in the operating process of step c), the operating temperature of electron accelerator is set in 5～35 ℃ of scopes, and ambient humidity is limited in and is not more than 60%;
E) accomplish above-mentioned steps a)～d) after; Tobacco leaf is rolled into cigarette; Get some of the cigarette that rolls into or above-mentioned finished cigarettes,, utilize smoking machine anthropomorphic dummy smoking state according to GB/T 19609-2004 specified standard condition; Use cambridge filter to gather the phenol type substances in the flue gas, adopt high performance liquid chromatography-fluorescence detection to measure the content of phenol type substances.
2. the method for phenol type substances in the reduction cigarette smoke according to claim 1; It is characterized in that described phenol type substances comprises one or more in the phenol compounds such as phenol, hydroquinones, resorcinol, catechol, paracresol, metacresol, orthoresol.
3. the method for phenol type substances is characterized in that in the reduction cigarette smoke according to claim 1 and 2, at above-mentioned steps e) in; According to GB/T 19609-2004 specified standard condition; Utilize smoking machine anthropomorphic dummy smoking state, use cambridge filter to gather the phenol type substances in the flue gas, adopt high performance liquid chromatography-fluorescence detection to measure the content of phenol type substances; With correspondence without the cigarette sample of irradiation as contrast, the reduction degree of content of phenol type substances in the testing cigarette flue gas.
4. the method for phenol is characterized in that in the reduction cigarette smoke according to claim 1, and said cigarette is that finished cigarette or tobacco leaf roll the cigarette that forms behind irradiation.
5. the method for phenol is characterized in that in the reduction cigarette smoke according to claim 1, and said tobacco leaf is junior tobacco leaf, redried leaf tobacco or airing tobacco.
6. according to the method for phenol in each described reduction cigarette smoke of claim 1 to 5, it is characterized in that said conveyer is belt, roller rod-type or chain type.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210039343 CN102578698B (en) | 2012-02-21 | 2012-02-21 | Method for reducing phenol substances in cigarette smoke gas |
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201210039343 CN102578698B (en) | 2012-02-21 | 2012-02-21 | Method for reducing phenol substances in cigarette smoke gas |
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| CN102578698A true CN102578698A (en) | 2012-07-18 |
| CN102578698B CN102578698B (en) | 2013-08-21 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103876269A (en) * | 2014-03-06 | 2014-06-25 | 川渝中烟工业有限责任公司 | Baking technology method capable of reducing phenol release amount in flue-cured tobaccos |
| CN104013098A (en) * | 2013-11-21 | 2014-09-03 | 白云 | Handling device and method for reducing toxic and harmful substances in tobacco |
| CN106721930A (en) * | 2016-11-22 | 2017-05-31 | 河南省科学院同位素研究所有限责任公司 | A kind of method for reducing acrylamide in starch fried food |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19826554A1 (en) * | 1998-06-15 | 1999-12-16 | Pruss Gunter | Preparation of smoking tobacco to remove harmful substances and obviate months of fermentation |
| CN1292708A (en) * | 1998-02-06 | 2001-04-25 | 梅迪斯卡恩有限公司 | Method for treating item |
| CN2568000Y (en) * | 2002-08-09 | 2003-08-27 | 鲁京序 | Electronic beam insecticidal sterilizing appts. for tobacco |
-
2012
- 2012-02-21 CN CN 201210039343 patent/CN102578698B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1292708A (en) * | 1998-02-06 | 2001-04-25 | 梅迪斯卡恩有限公司 | Method for treating item |
| DE19826554A1 (en) * | 1998-06-15 | 1999-12-16 | Pruss Gunter | Preparation of smoking tobacco to remove harmful substances and obviate months of fermentation |
| CN2568000Y (en) * | 2002-08-09 | 2003-08-27 | 鲁京序 | Electronic beam insecticidal sterilizing appts. for tobacco |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104013098A (en) * | 2013-11-21 | 2014-09-03 | 白云 | Handling device and method for reducing toxic and harmful substances in tobacco |
| CN103876269A (en) * | 2014-03-06 | 2014-06-25 | 川渝中烟工业有限责任公司 | Baking technology method capable of reducing phenol release amount in flue-cured tobaccos |
| CN103876269B (en) * | 2014-03-06 | 2016-03-02 | 川渝中烟工业有限责任公司 | The baking process method of phenol release amount in flue-cured tobacco can be reduced |
| CN106721930A (en) * | 2016-11-22 | 2017-05-31 | 河南省科学院同位素研究所有限责任公司 | A kind of method for reducing acrylamide in starch fried food |
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| CN102578698B (en) | 2013-08-21 |
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