CN102560792A - High-temperature resistant cutting preventing composite yarn and application thereof - Google Patents

High-temperature resistant cutting preventing composite yarn and application thereof Download PDF

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Publication number
CN102560792A
CN102560792A CN2012100251481A CN201210025148A CN102560792A CN 102560792 A CN102560792 A CN 102560792A CN 2012100251481 A CN2012100251481 A CN 2012100251481A CN 201210025148 A CN201210025148 A CN 201210025148A CN 102560792 A CN102560792 A CN 102560792A
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China
Prior art keywords
fiber
temperature resistant
high temperature
complex yarn
resistant anti
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Pending
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CN2012100251481A
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Chinese (zh)
Inventor
胡盼盼
刘兆峰
罗进峰
张一飞
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Suzhou Zhaoda Specially Fiber Technical Co Ltd
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Suzhou Zhaoda Specially Fiber Technical Co Ltd
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Priority to CN2012100251481A priority Critical patent/CN102560792A/en
Publication of CN102560792A publication Critical patent/CN102560792A/en
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Abstract

The invention relates to a high-temperature resistant cutting preventing composite yarn and the application of the high-temperature resistant cutting preventing composite yarn, belonging to the technical field of special yarn. The high-temperature resistant cutting preventing composite yarn comprises a central fiber and a coated fiber, wherein the central fiber is used as an inner core, and the coated fiber is formed by twisting, winded with the central fiber and coated outside the central fiber. The high-temperature resistant cutting preventing composite yarn is characterized in that the central fiber is the chemical filament and accounts for 30-70% by mass of the composite yarn, the coated fiber is the short aramid fiber 1414 and accounts for 70-30% by mass of the composite yarn. The high-temperature resistant cutting preventing composite yarn integrates the outstanding high-temperature resistance and fire resistance of the short aramid fiber 1414 and the advantage of excellent cutting-preventing performance of the chemical filament, and the fabric made of the high-temperature resistant cutting preventing composite yarn by processing can be used in the high-temperate and sharp work environment. The high-temperature resistant cutting preventing composite yarn is safe and durable.

Description

A kind of high temperature resistant anti-cutting complex yarn and application thereof
Technical field
The invention belongs to special yarn line technology field, be specifically related to a kind of high temperature resistant anti-cutting complex yarn, and relate to the application of this yarn
Background technology
are present, give an example being not limited to and typical high temperature occasion such as iron and steel manufacturing and sharp operating mode occasion (working environment) generally to use with the asbestos fibre like the glassware manufacturing be the main thread protective articles of composite yarn.Though asbestos have strong points such as good high temperature resistant, rub resistance, low price, light specific gravity, thermal conductivity factor low (thermal conductivity factor is 0.198-0.244W < mk >) and conductance be low; But; Because asbestos have carcinogenic and environment are had contaminative human body; Therefore the production and the use that comprise the asbestos friction material of protective articles more and more are restricted, even are under an embargo in many developed countries and even developing country.
The TECHNICAL INFORMATION SOURCES of high temperature resistant yarn can be seen in in disclosed Chinese patent document; For example CN201534902U recommends to have " the sunshade lining of high flame retardant complex yarn and application thereof "; It is outside the fiber filament bundle, to coat fluoroplastics to form shape of cross section be concentrically ringed shape, and still, this yarn does not belong to spinnability yarn category; And can't put into common loom weaves; Especially be not suitable for processed and applied in aforesaid protective articles such as iron and steel, glassware manufacturing, though because this yarn has desirable anti-flammability, the environment-friendly advantage of low-smoke low-toxicity, but very fragile for the sharp intensity of opposing with self.
again; " the macromolecule composite yarn " that CN201241223Y provides remedied the shortcoming of CN2670389Y disclosed " the fabric fluff type yarn of nonwoven "; Have good tensile strength, but do not have the achievement part for fire-retardant, high temperature resistant, anti-cutting etc.
reach; " complex yarn of anti-cutting " that application for a patent for invention publication No. CN102308035A introduces is to be that hard component and the continuous elastomer yarn of the many hard fibres of 25 μ m constitutes by average diameter; Hard component is the gel spinning silk thread of ultra-high molecular weight polyethylene and/or the yarn of staple fiber, and elastomer yarn is processed by the long-chain synthetic polymer of inclusion block polyurethane.Can know from the description of the specification the 0011st section to 0037 section (especially the 0035th section and 0037 section) of this patent application; The complex yarn of this anti-cutting belongs to the yarn category of processing dress ornament class; Though do not belong to aforesaid extraordinary yarn category, promptly should not use as the protective articles of high temperature, sharp operating mode occasion.
In sum; In disclosed patent and non-patent literature or in the aforementioned occasion (high temperature, sharp operating mode occasion) of reality, all be not seen in not only to have high temperature resistant and anti-flammability of standing out from one's fellows but also the teachings that has the yarn of ultimate attainment anti-cutting performance concurrently no matter be; The applicant has done long-term and useful exploration for this reason, and the technical scheme that will introduce below produces under this background
Summary of the invention
task of the present invention is to provide a kind of to be had the high temperature resistant and anti-flammability of standing out from one's fellows and uses to satisfy and be used to process the high temperature resistant anti-cutting complex yarn that the protective articles that uses down such as high temperature and sharp working environment and flexible transmission part require.
task of the present invention also is to provide a kind of application of high temperature resistant anti-cutting complex yarn, is applied to process using such as protective articles and transfer member of being suitable for that high temperature, sharp occasion uses and ensures safety and durable effect.
task of the present invention is accomplished like this; A kind of high temperature resistant anti-cutting complex yarn; Comprise and tangle with center fiber as the center fiber of inner core with through twisting and be coated on the outer covered fiber of center fiber; Be characterised in that: described center fiber shared mass percent in said complex yarn is 30-70%; And described covered fiber shared mass percent in complex yarn is 70-30%, and described center fiber is chemical long filament, and described covered fiber is the Fanglun l414 short fiber.
in a concrete embodiment of the present invention, the fiber number of described Fanglun l414 short fiber is 1.5-3.2dtex, and the length of fiber is 20-150 ㎜, and intensity is 17-18.5cN/dtex, modulus>=500cN/dtex.
in another concrete embodiment of the present invention, the intensity of described chemical long filament is 2-3cN/dtex, and fiber number is 55-330dtex.
in another concrete embodiment of the present invention, described chemical long filament is glass fibre, polyester fiber or polyamide fiber.
in another concrete embodiment of the present invention, described polyester fiber is a h, and described polyamide fiber is the high strength polyamide fiber.
also have among the concrete embodiment of the present invention, and described h is for being added with the h of inorganic particle in polyester slice; Described high strength polyamide fiber is for adding the high strength polyamide fiber that inorganic particle is arranged in the polyamide section.
are more of the present invention and among concrete embodiment, described inorganic particle shared percentage by weight in said polyester slice is 0.1-4%; And described inorganic particle shared percentage by weight in described polyamide section is similarly 0.1-4%.
in of the present invention and then concrete embodiment, described inorganic particle is that Mohs' hardness is nano titanium oxide or the nano silicon of 0.25-5 μ m greater than 3 grades with particle diameter.
of the present invention again more and among concrete embodiment, the specification of said complex yarn is 10S-60S.
also task of the present invention is accomplished like this; A kind of application of high temperature resistant anti-cutting complex yarn supplies knitting or woven being made into to be used to make the gloves, apron and the protective clothing dress ornament that use under high temperature and the sharp operating mode with lining and transport tape.
The resulting high temperature resistant anti-cutting complex yarn of technical scheme provided by the invention is because covered fiber is a Fanglun l414 short fiber and middle core fibre is chemical long filament; The strong point of anti-cutting of excellence of the high temperature resistant and anti-flammability of standing out from one's fellows and the chemical long filament of Fanglun l414 short fiber is gathered in one; The lining that uses this complex yarn to be processed into can satisfy the instructions for use under high temperature, sharp working environment, uses and embodies safety and durable result of use.
The specific embodiment
Embodiment 1:
high temperature resistant anti-cutting complex yarn; Comprise as the center fiber of inner core and tangle with center fiber through twisting and be coated on the outer covered fiber of center fiber; That is to say that the described high temperature resistant anti-cutting complex yarn of present embodiment is by constituting as the center fiber of inner core and these two kinds of compositions of covered fiber or the title component that combines with center fiber and be positioned at outside the center fiber.Center fiber shared mass percent in complex yarn is 30%, and covered fiber shared mass percent in yarn is 70%.The center fiber working strength is that 2.1N/dtex and fiber number are the high strength chemistry fiber filament of 55dtex; This high strength chemistry fiber filament is obtained through spinning technique by polyester slice, and wherein: adding in polyester slice that percentage by weight is arranged is 2.5% Mohs' hardness greater than 3 grades and particle diameter is the nano titanium oxide (promptly in every 100g polyester slice, adding the aforesaid nano titanium oxide of 2.5g) of 0.25-5 μ m.It is that 58 ㎜, fiber number are that 1.5dpf, intensity be 17.2CN/dtex and modulus greater than the aramid fiber short fiber of 500cN/dtex are aramid fiber short fibre that aforesaid covered fiber adopts length.
center fiber be aforesaid high strength chemistry fiber filament with covered fiber be the twisting center that aforesaid Fanglun l414 short fiber yarn is located in yarn when converging; In the composite twist process, keep the enough tension force of long filament; Make its (high strength chemistry fiber filament) be located on the axis at twisting center all the time and keep linearity; And angular displacement takes place around long filament (twisting center) in the short fiber yarn under the effect of twisting effect; Become the columned while in the yarn cross section by flat, the inside and outside transfer can take place by rule separately in staple fibre, not only can be coated on the surface of long filament; And in the process of inside and outside transfer and between long filament and short fiber and the short fiber, tangle; Make yarn have firm skin-core structure, and the short fiber yarn be not form looping with yarn at filament surface, but with filamentary form looping at filament surface.Therefore short fiber is that aforesaid covered fiber and long filament are that aforesaid center fiber looping fastness is good, and long filament is coated fully, and complex yarn intensity is high.Because extexine is the Fanglun l414 short fiber; Therefore have the heat-resisting quantity and the anti-flammability of standing out from one's fellows; And have excellent anti-cutting performance as the center fiber long filament of inner core, be that cutting resistance, intensity and the heatproof of the complex yarn of 32S reaches by the technique effect shown in the table 1 thereby make the specification that obtains.
Embodiment 2:
only change center fiber shared mass percent in complex yarn into 70%; And change covered fiber shared mass percent in complex yarn into 30%; The center fiber working strength is that 3cN/dtex and fiber number are the glass fiber of 330dtex; It is that 3.2dtex, length are that 100 ㎜ and intensity are the aramid fiber short fiber of 17.57cN/dtex that covered fiber adopts fiber number, and the technology indication of high temperature resistant anti-cutting complex yarn that obtains specification and be 10S is by shown in the table 1.All the other are all with the description to embodiment 1.
Embodiment 3:
only change center fiber shared mass percent in complex yarn into 50%; And change covered fiber shared mass percent in complex yarn into 50%; The center fiber working strength is that 2.8cN/dtex and fiber number are the high strength chemistry fiber filament of 75dtex; This high strength chemistry fiber filament is that the PA66 section obtains through spinning technique by the polyamide section, and wherein: adding in the polyamide section that percentage by weight is arranged is 4% Mohs' hardness greater than 3 grades and particle diameter is the nano silicon (also can use similarly other inorganic particle) of 0.3-3 μ m.It is that 2.8dtex, length are that 38 ㎜ and intensity are the aramid fiber short fiber of 18.01cN/dtex that covered fiber adopts fiber number, and the technology indication of high temperature resistant anti-cutting complex yarn that obtains specification and be 40S is by shown in the table 1.
Embodiment 4:
only the percentage by weight with nano titanium oxide change 0.1% into, and all the other are all with the description to embodiment 3.
The physical property of the high temperature resistant anti-cutting complex yarn of the present invention that is obtained by the foregoing description detects the anti-cutting performance of fabric and the technical indicator that obtains is as shown in table 1 by CNS GB/T19975-2005 operative norm with by U.S. D-388 standard:
Table 1
Embodiment Cutting performance Complex yarn intensity Maximum heatproof temperature
1 4 8.9cN/dtex 250℃
2 5 7.8cN/dtex 250℃
3 5 9.2cN/dtex 250℃
4 5 9.1cN/dtex 250℃
Application examples:
The lining that the high temperature resistant anti-cutting complex yarn (single thread line or multistrand yarn) that arbitrary embodiment among the foregoing description 1-4 is obtained is processed after supplying loom to weave can be used for being produced on protective articles such as gloves, apron and the protective clothing dress ornament that uses in high temperature and the sharp working environment, and weaves various conveyer belts and the conveyer belt that uses under the high temperature resistant anti-cutting operating mode

Claims (10)

1. a kind of high temperature resistant anti-cutting complex yarn; Comprise and tangle with center fiber as the center fiber of inner core with through twisting and be coated on the outer covered fiber of center fiber; It is characterized in that: described center fiber shared mass percent in said complex yarn is 30-70%; And described covered fiber shared mass percent in complex yarn is 70-30%, and described center fiber is chemical long filament, and described covered fiber is the Fanglun l414 short fiber.
2. high temperature resistant anti-cutting complex yarn according to claim 1; The fiber number that it is characterized in that described Fanglun l414 short fiber is 1.5-3.2dtex; The length of fiber is 20-150 ㎜, and intensity is 17-18.5cN/dtex, modulus>=500cN/dtex.
3. high temperature resistant anti-cutting complex yarn according to claim 1, the intensity that it is characterized in that described chemical long filament is 2-3cN/dtex, fiber number is 55-330dtex.
4. is characterized in that according to claim 1 or 3 described high temperature resistant anti-cutting complex yarns described chemical long filament is glass fibre, polyester fiber or polyamide fiber.
5. high temperature resistant anti-cutting complex yarn according to claim 4 is characterized in that described polyester fiber is a h, and described polyamide fiber is the high strength polyamide fiber.
6. high temperature resistant anti-cutting complex yarn according to claim 5 is characterized in that described h is for being added with the h of inorganic particle in polyester slice; Described high strength polyamide fiber is for adding the high strength polyamide fiber that inorganic particle is arranged in the polyamide section.
7. high temperature resistant anti-cutting complex yarn according to claim 6 is characterized in that described inorganic particle shared percentage by weight in said polyester slice is 0.1-4%; And described inorganic particle shared percentage by weight in described polyamide section is similarly 0.1-4%.
8. high temperature resistant anti-cutting complex yarn according to claim 7 is characterized in that described inorganic particle is that Mohs' hardness is nano titanium oxide or the nano silicon of 0.25-5 μ m greater than 3 grades with particle diameter.
9. according to the described high temperature resistant anti-cutting complex yarn of the arbitrary claim of claim 1-8, the specification that it is characterized in that said complex yarn is 10S-60S.
10. A kind of application of high temperature resistant anti-cutting complex yarn as claimed in claim 1 is characterized in that supplying knitting or woven being made into to be used to make the gloves, apron and the protective clothing dress ornament that use under high temperature and the sharp operating mode with lining and transport tape
CN2012100251481A 2012-02-06 2012-02-06 High-temperature resistant cutting preventing composite yarn and application thereof Pending CN102560792A (en)

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103266376A (en) * 2013-04-16 2013-08-28 浙江春江轻纺集团有限责任公司 Flame-retardant covering yarn and processing method
CN103422377A (en) * 2013-07-31 2013-12-04 泰安鲁普耐特塑料有限公司 Production method used for fire scene escaping safety rope
CN103981610A (en) * 2014-04-08 2014-08-13 际华三五零六纺织服装有限公司 Flame-retardant composite yarns and production method for same
CN104894736A (en) * 2015-06-25 2015-09-09 东华大学 Aramid fiber coated continuous glass fiber cut-resistant fabric and preparation method thereof
CN104947268A (en) * 2015-06-25 2015-09-30 东华大学 High-strength thermal insulation base fabric with friction spinning aramid fibers 1414 covering glass filaments and preparation method thereof
CN104963052A (en) * 2015-07-10 2015-10-07 上海兰邦工业纤维有限公司 Composite yarn for high-cutting-resisting-degree fabric
CN104988627A (en) * 2015-07-09 2015-10-21 上海兰邦工业纤维有限公司 High-strength aramid fiber sewing thread with excellent sewing performance
CN105155066A (en) * 2015-09-07 2015-12-16 南通强生安全防护科技有限公司 Dacron wrapped yarn, preparing method and application
CN105506832A (en) * 2015-12-03 2016-04-20 上海曙雀贸易有限公司 High-strength heat-insulation and heat-preservation base cloth
CN110499559A (en) * 2019-07-30 2019-11-26 武汉纺织大学 A kind of preparation method of high-strength complex yarns and fabric
CN111286836A (en) * 2020-03-11 2020-06-16 山东星宇手套有限公司 Flame-retardant anti-cutting yarn based on modified polyphenylene sulfide, preparation method and glove
CN112941698A (en) * 2021-01-22 2021-06-11 北京复维新材科技有限公司 High-performance fiber filament and staple fiber composite fabric and composite material containing same
CN114250542A (en) * 2021-12-23 2022-03-29 无锡宝强工业织造有限公司 Compression-resistant aramid fiber impregnated canvas fabric structure for high-temperature-resistant conveying belt and preparation method thereof

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Publication number Priority date Publication date Assignee Title
CN100359064C (en) * 2000-06-16 2008-01-02 纳幕尔杜邦公司 Comfortable cut-abrasion resistant fiber composition

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100359064C (en) * 2000-06-16 2008-01-02 纳幕尔杜邦公司 Comfortable cut-abrasion resistant fiber composition

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103266376A (en) * 2013-04-16 2013-08-28 浙江春江轻纺集团有限责任公司 Flame-retardant covering yarn and processing method
CN103422377A (en) * 2013-07-31 2013-12-04 泰安鲁普耐特塑料有限公司 Production method used for fire scene escaping safety rope
CN103981610A (en) * 2014-04-08 2014-08-13 际华三五零六纺织服装有限公司 Flame-retardant composite yarns and production method for same
CN104894736A (en) * 2015-06-25 2015-09-09 东华大学 Aramid fiber coated continuous glass fiber cut-resistant fabric and preparation method thereof
CN104947268A (en) * 2015-06-25 2015-09-30 东华大学 High-strength thermal insulation base fabric with friction spinning aramid fibers 1414 covering glass filaments and preparation method thereof
CN104988627A (en) * 2015-07-09 2015-10-21 上海兰邦工业纤维有限公司 High-strength aramid fiber sewing thread with excellent sewing performance
CN104963052A (en) * 2015-07-10 2015-10-07 上海兰邦工业纤维有限公司 Composite yarn for high-cutting-resisting-degree fabric
CN105155066A (en) * 2015-09-07 2015-12-16 南通强生安全防护科技有限公司 Dacron wrapped yarn, preparing method and application
CN105506832A (en) * 2015-12-03 2016-04-20 上海曙雀贸易有限公司 High-strength heat-insulation and heat-preservation base cloth
CN110499559A (en) * 2019-07-30 2019-11-26 武汉纺织大学 A kind of preparation method of high-strength complex yarns and fabric
CN111286836A (en) * 2020-03-11 2020-06-16 山东星宇手套有限公司 Flame-retardant anti-cutting yarn based on modified polyphenylene sulfide, preparation method and glove
CN112941698A (en) * 2021-01-22 2021-06-11 北京复维新材科技有限公司 High-performance fiber filament and staple fiber composite fabric and composite material containing same
CN114250542A (en) * 2021-12-23 2022-03-29 无锡宝强工业织造有限公司 Compression-resistant aramid fiber impregnated canvas fabric structure for high-temperature-resistant conveying belt and preparation method thereof
CN114250542B (en) * 2021-12-23 2024-02-23 无锡宝强工业织造有限公司 Compression-resistant aramid fiber impregnated canvas fabric structure for high-temperature-resistant conveyer belt and preparation method thereof

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Application publication date: 20120711