CN102558965A - Printing ink for side windshield of automobile and preparation method of printing ink - Google Patents
Printing ink for side windshield of automobile and preparation method of printing ink Download PDFInfo
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- CN102558965A CN102558965A CN2011104446658A CN201110444665A CN102558965A CN 102558965 A CN102558965 A CN 102558965A CN 2011104446658 A CN2011104446658 A CN 2011104446658A CN 201110444665 A CN201110444665 A CN 201110444665A CN 102558965 A CN102558965 A CN 102558965A
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- printing ink
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- side windshield
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- dispersion agent
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Abstract
The invention relates to a printing ink for side windshield of an automobile and a preparation method of the printing ink. The printing ink is characterized by consisting of the following components in percentage by mass: 6-24 percent of organic resin, 10-28 percent of solvent, 2-12 percent of flatting agent, 2-10 percent of dispersant and the balance of leadless glass powder. The printing ink for the side windshield of the automobile and the preparation method of the printing ink have the beneficial effects that: 1, the printing ink is mainly prepared from the leadless glass powder and can be easily accepted by people; 2, resin containing no harmful substances such as chlorine is added into the printing ink, the wettability and the surface smoothness of the printing ink and the bond strength of the printing ink and glass after sintering are good, the shading rate is high, and the printing ink can be used for completely substituting the conventional printing ink to be used in the field of production of the side windshield of the automobile; and 3, the printing ink contains no harmful substances such as lead, cadmium, mercury, sexavalent chromium, PBB (Polybrominated Biphenyl) and PBDE (Polybrominated Diphenyl Ether). By adjusting the contents of various inorganic components and organic components, the printing ink can adapt to a glass substrate, so that the product performance is more superior.
Description
Technical field
The present invention relates to a kind of automobile side windshield glass with printing ink and preparation method thereof.
Background technology
The daily ink type of seeing is a lot; Be applicable to vehicle glass mainly by three kinds: shield glass is used printing ink with printing ink, automobile side windshield glass with printing ink and automobile backstop air strengthened glass; Promptly be used for glass for vehicle window black part all around, mainly play a part to decorate and antiultraviolet.That uses in the market mostly contains compositions such as lead, cadmium, and under the big situation of current environmental protection, the pollution that use plumbous, cadmium causes makes environment need could to recover for many years.On the other hand, be applicable to the also rarely found report of ink special of automobile side windshield glass.
In view of the deficiency of above existing automobile side retaining glass with the printing ink existence, developing a kind of eco-friendly car side retaining glass ink special and substituting existing plumbiferous automobile side retaining glass just becomes the task of top priority with printing ink.
Summary of the invention
It is good that one of the object of the invention provides a kind of strong adhesion, good stability, opacifying property, has the automobile side windshield glass of excellent wetting capacity and consistency to use printing ink with glass;
Two of the object of the invention provides a kind of preparation method of above-mentioned printing ink.
A kind of automobile side windshield glass is used printing ink, and its special feature is, consists of by the quality percentage composition: 6～24% organic resins, 10～28% solvents, 2～12% smooth and level dose, 2～10% dispersion agent, surplus is a lead-free glass powder.
Wherein lead-free glass powder is that particle diameter is the borosilicic acid copper zinc glass frit of 2～5 μ m, and softening temperature is 500～600 ℃, and the coefficient of expansion is 7～9 * 10
-7/ ℃.
Wherein organic resin is TKK 021 or methylcellulose gum; Solvent is at least a in Terpineol 350 and the butyl carbitol acetic ester; Smooth and level dose is at least a in Viscotrol C, phosphotriester and the tributyl phosphate, and dispersion agent is to gather the carboxyl sodium salt, gather the carboxyl ammonium salt and gather at least a in the carboxyl sylvite.
A kind of automobile side windshield glass is with the preparation method of printing ink, and its special feature is, comprises the steps:
(1) at first by any one proportioning weighing glass powder, smooth and level dose and dispersion agent in the claim 1 to 3, for use;
(2) by any one proportioning weighing organic resin and solvent in the claim 1 to 3, mix post-heating to 60～80 ℃, it is for use to treat that resin dissolves postcooling to room temperature fully;
(3) aforesaid glass powder is joined in the mixture of organic resin and solvent mix, be ground to fineness then and get final product, smooth and level dose of disposable adding and dispersion agent in process of lapping smaller or equal to 5 μ m.
Automobile side windshield glass of the present invention with the beneficial effect of printing ink and preparation process thereof is:
1, printing ink is main with lead-free glass powder mainly, is because lead-free glass powder is a kind of powder of technological comparative maturity, and scale operation now is prone to accepted by people;
2, printing ink has added the not resin of objectionable impurities such as chloride element; Good behind the wettability of printing ink, surface smoothing property, the sintering with the bonding strength of glass; Shading rate is high, and acid resistance surpasses the requirement of general producer, can substitute existing printing ink fully and be used for automobile side retaining glass production manufacturing field;
3, printing ink does not contain objectionable impuritiess such as lead, cadmium, mercury, sexavalent chrome, PBB, PBDE, meets social development to environmental protection requirement.The eco-friendly car side retaining glass ink special contact performance, switching performance, the shading rate that prepare according to the method described above are good.
The present invention can adapt with glass substrate, thereby make the better effect of product performance through the content of various inorganic componentss of adjustment and organic composition, has guaranteed the steady quality of product.
Embodiment
Embodiment 1:
A kind of eco-friendly car side retaining glass ink special, its concrete preparation is to accomplish according to following process step:
At first prepare following raw material according to mass percent:
32% lead-free glass powder, 24% organic resin, 26% solvent, 8% smooth and level dose, 10% dispersion agent;
Above-mentioned lead-free glass powder is that particle diameter is the borosilicic acid copper zinc glass frit of 1～5 μ m, and softening temperature is 500～600 ℃, and the coefficient of expansion is 7～9 * 10
-7/ ℃.Above-mentioned organic resin is a TKK 021, and solvent is a butyl carbitol acetic ester, and smooth and level dose is Viscotrol C, and dispersion agent is for gathering the carboxyl sodium salt;
The preparation method of this kind eco-friendly car front windshield ink special is following:
1) the weighing particle diameter is 2～5 μ m at first by mass percentage, and softening temperature is 500～600 ℃, and the coefficient of expansion is 7～9 * 10
-7/ ℃ borosilicic acid copper zinc glass frit and smooth and level dose, dispersion agent, for use;
2) by aforementioned mass percent weighing organic resin and solvent, mix the back and under 60～80 ℃ of conditions, heats, it is for use to treat that resin dissolves postcooling to room temperature fully;
3) join aforesaid glass powder in the mixture of organic resin and solvent; Mix with stirrer; Grind with three-high mill then; Add (adopting disposable adding) smooth and level dose and dispersion agent in the process of lapping, till smaller or equal to 5 μ m, obtain eco-friendly car side retaining glass ink special up to fineness.
Embodiment 2:
A kind of eco-friendly car side retaining glass ink special, its concrete preparation is to accomplish according to following process step:
At first prepare following raw material according to mass percent:
45% lead-free glass powder, 20% organic resin, 15% solvent, 12% smooth and level dose, 8% dispersion agent;
Above-mentioned lead-free glass powder is that particle diameter is the zinc borosilicate glass frit of 1～5 μ m, and softening temperature is 500～550 ℃, and the coefficient of expansion is 8～9 * 10
-7/ ℃.Above-mentioned organic resin is a methylcellulose gum, and solvent is a Terpineol 350, and smooth and level dose is that Viscotrol C and phosphotriester mix the mixture that obtain by mass ratio at 1: 1, and dispersion agent is for gathering carboxyl sylvite;
The preparation method of this kind eco-friendly car front windshield ink special is following:
1) the weighing particle diameter is 2～5 μ m at first by mass percentage, and softening temperature is 500～600 ℃, and the coefficient of expansion is 7～9 * 10
-7/ ℃ borosilicic acid copper zinc glass frit and smooth and level dose, dispersion agent, for use;
2) by aforementioned mass percent weighing organic resin and solvent, under 60～80 ℃ of conditions, heat, it is for use to treat that resin dissolves postcooling to room temperature fully;
3) join aforesaid glass powder in the mixture of organic resin and solvent; Mix with stirrer; Grind with three-high mill then, add smooth and level dose and dispersion agent in the process of lapping, till fineness is smaller or equal to 5 μ m, obtain eco-friendly car side retaining glass ink special.
Embodiment 3:
A kind of eco-friendly car side retaining glass ink special, its concrete preparation is to accomplish according to following process step:
At first prepare following raw material according to mass percent:
58% lead-free glass powder, 10% organic resin, 28% solvent, 4% smooth and level dose, 10% dispersion agent;
Above-mentioned lead-free glass powder is that particle diameter is the zinc borosilicate glass frit of 1～5 μ m, and softening temperature is 500～550 ℃, and the coefficient of expansion is 8～9 * 10
-7/ ℃.Above-mentioned organic resin is a TKK 021, and solvent is a Terpineol 350, and smooth and level dose is tributyl phosphate, and dispersion agent is for gathering the carboxyl ammonium salt and gathering the mixture that carboxyl sylvite obtains by mass ratio mixing in 1: 1;
The preparation method of this kind eco-friendly car front windshield ink special is following:
1) the weighing particle diameter is 2～5 μ m at first by mass percentage, and softening temperature is 500～600 ℃, and the coefficient of expansion is 7～9 * 10
-7/ ℃ borosilicic acid copper zinc glass frit and smooth and level dose, dispersion agent, for use;
2) by aforementioned mass percent weighing organic resin and solvent, under 60～80 ℃ of conditions, heat, it is for use to treat that resin dissolves postcooling to room temperature fully;
3) join aforesaid glass powder in the mixture of organic resin and solvent; Mix with stirrer; Grind with three-high mill then, add smooth and level dose and dispersion agent in the process of lapping, till fineness is less than 5 μ m, obtain eco-friendly car side retaining glass ink special.
Embodiment 4:
A kind of eco-friendly car side retaining glass ink special, its concrete preparation is to accomplish according to following process step:
At first prepare following raw material according to mass percent:
80% lead-free glass powder, 6% organic resin, 10% solvent, 2% smooth and level dose, 2% dispersion agent;
Above-mentioned lead-free glass powder is that particle diameter is the zinc borosilicate glass frit of 1～5 μ m, and softening temperature is 500～550 ℃, and the coefficient of expansion is 8～9 * 10
-7/ ℃.Above-mentioned organic resin is a methylcellulose gum, and solvent is that Terpineol 350 and butyl carbitol acetic ester mix the mixture that obtain according to mass ratio at 1: 1, and smooth and level dose is Viscotrol C, and dispersion agent is for gathering the carboxyl sodium salt;
The preparation method of this kind eco-friendly car front windshield ink special is following:
1) the weighing particle diameter is 2～5 μ m at first by mass percentage, and softening temperature is 500～600 ℃, and the coefficient of expansion is 7～9 * 10
-7/ ℃ borosilicic acid copper zinc glass frit and smooth and level dose, dispersion agent, for use;
2) by aforementioned mass percent weighing organic resin and solvent, under 60～80 ℃ of conditions, heat, it is for use to treat that resin dissolves postcooling to room temperature fully;
3) join aforesaid glass powder in the mixture of organic resin and solvent; Mix with stirrer; Grind with three-high mill then, add smooth and level dose and dispersion agent in the process of lapping, till fineness is less than 5 μ m, obtain eco-friendly car side retaining glass ink special.
Claims (4)
1. an automobile side windshield glass is used printing ink, it is characterized in that, consists of by the quality percentage composition: 6～24% organic resins, 10～28% solvents, 2～12% smooth and level dose, 2～10% dispersion agent, surplus is a lead-free glass powder.
2. a kind of automobile side windshield glass as claimed in claim 1 is used printing ink, it is characterized in that: wherein lead-free glass powder is that particle diameter is the borosilicic acid copper zinc glass frit of 2～5 μ m, and softening temperature is 500～600 ℃, and the coefficient of expansion is 7～9 * 10
-7/ ℃.
3. a kind of automobile side windshield glass as claimed in claim 1 is used printing ink; It is characterized in that: wherein organic resin is TKK 021 or methylcellulose gum; Solvent is at least a in Terpineol 350 and the butyl carbitol acetic ester; Smooth and level dose is at least a in Viscotrol C, phosphotriester and the tributyl phosphate, and dispersion agent is to gather the carboxyl sodium salt, gather the carboxyl ammonium salt and gather at least a in the carboxyl sylvite.
4. an automobile side windshield glass is characterized in that with the preparation method of printing ink, comprises the steps:
(1) at first by any one proportioning weighing glass powder, smooth and level dose and dispersion agent in the claim 1 to 3, for use;
(2) by any one proportioning weighing organic resin and solvent in the claim 1 to 3, mix post-heating to 60～80 ℃, it is for use to treat that resin dissolves postcooling to room temperature fully;
(3) aforesaid glass powder is joined in the mixture of organic resin and solvent mix, be ground to fineness then and get final product, in process of lapping, add smooth and level dose and dispersion agent smaller or equal to 5 μ m.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110444665.8A CN102558965B (en) | 2011-12-27 | 2011-12-27 | Printing ink for side windshield of automobile and preparation method of printing ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110444665.8A CN102558965B (en) | 2011-12-27 | 2011-12-27 | Printing ink for side windshield of automobile and preparation method of printing ink |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102558965A true CN102558965A (en) | 2012-07-11 |
| CN102558965B CN102558965B (en) | 2014-03-26 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110444665.8A Expired - Fee Related CN102558965B (en) | 2011-12-27 | 2011-12-27 | Printing ink for side windshield of automobile and preparation method of printing ink |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003034550A (en) * | 2001-07-24 | 2003-02-07 | Asahi Glass Co Ltd | Lead-free glass, glass frit, glass paste, electronic circuit part and electronic circuit |
| CN1970657A (en) * | 2005-09-16 | 2007-05-30 | 三菱麻铁里亚尔株式会社 | Printing oil ink and production method of coating film using the oil ink |
| CN101088947A (en) * | 2006-06-13 | 2007-12-19 | 上海宝银电子材料有限公司 | Heat resistant antisticking no-lead black glaze for automobile glass and its prepn process |
| CN101174487A (en) * | 2006-10-04 | 2008-05-07 | 昭荣化学工业株式会社 | Conductive paste for multilayer electronic part |
| CN101617001A (en) * | 2007-03-09 | 2009-12-30 | 株式会社东进世美肯 | Black paste composition having conductive property, filter for shielding electromagnetic interference and display device comprising the same |
| CN101942281A (en) * | 2010-09-29 | 2011-01-12 | 彩虹集团公司 | Organic binding agent for back aluminum paste of silicon-based solar battery and preparation method thereof |
| JP2011018561A (en) * | 2009-07-09 | 2011-01-27 | Murata Mfg Co Ltd | Conductive paste |
-
2011
- 2011-12-27 CN CN201110444665.8A patent/CN102558965B/en not_active Expired - Fee Related
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003034550A (en) * | 2001-07-24 | 2003-02-07 | Asahi Glass Co Ltd | Lead-free glass, glass frit, glass paste, electronic circuit part and electronic circuit |
| CN1970657A (en) * | 2005-09-16 | 2007-05-30 | 三菱麻铁里亚尔株式会社 | Printing oil ink and production method of coating film using the oil ink |
| CN101088947A (en) * | 2006-06-13 | 2007-12-19 | 上海宝银电子材料有限公司 | Heat resistant antisticking no-lead black glaze for automobile glass and its prepn process |
| CN101174487A (en) * | 2006-10-04 | 2008-05-07 | 昭荣化学工业株式会社 | Conductive paste for multilayer electronic part |
| CN101617001A (en) * | 2007-03-09 | 2009-12-30 | 株式会社东进世美肯 | Black paste composition having conductive property, filter for shielding electromagnetic interference and display device comprising the same |
| JP2011018561A (en) * | 2009-07-09 | 2011-01-27 | Murata Mfg Co Ltd | Conductive paste |
| CN101942281A (en) * | 2010-09-29 | 2011-01-12 | 彩虹集团公司 | Organic binding agent for back aluminum paste of silicon-based solar battery and preparation method thereof |
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| CN102558965B (en) | 2014-03-26 |
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